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1.
In this work, microvia filling was performed by copper electroplating using two plating formulas with and without a leveler at a low concentration of chloride. The base plating solution contained CuSO4, H2SO4, polyethylene glycol (PEG), bis (3-sulfopropyl) disulfide (SPS) and Cl−. When the Cl− concentration was lower than 30 ppm, the plating formula without a leveler became dead for bottom-up filling, resulting in conformal deposition. The addition of 1 ppm Alcian Blue, used as a leveler, could effectively recover the filling performance of the plating formula with low chloride concentration. Electrochemical analyses revealed possible mechanisms. The results demonstrate that the usage of Alcian Blue can widen the operation window of chloride concentration, since it can assist PEG in competing with SPS in adsorption at low chloride concentration. 相似文献
2.
This study tested the selectivity and sustainability of an alumina-supported Pd–In bimetallic catalyst for nitrate reduction with H2 in a continuous-flow packed-bed reactor in the presence of: (i) dissolved oxygen (DO), an alternative electron acceptor to nitrate, (ii) variable NO3 ?:H2 influent loadings, and (iii) the presence of a known foulant, sulfide. The sustainability of the catalyst was promising, as the catalyst was found to be stable under all conditions tested with respect to metal leaching. The presence of DO at concentrations typical of treatment conditions will increase H2 demand for NO3 ? reduction, but has no negative impact on the selectivity of the catalyst. Under optimal conditions, i.e., a pH of 5.0 and a high NO3 ?:H2 influent loading, low NH3 selectivity (5%) was achieved for extended periods (36 days), resulting in sustained levels of NH3 that approached the European legal limit. The biggest challenge to the sustainability of the catalyst was the addition of sulfide, that initially increased NH3 selectivity and ultimately resulted in complete deactivation of the catalyst. Further work is required to identify regeneration methods to restore sulfide-fouled catalyst activity and selectivity; however, the most effective use would be to remove sulfide prior to catalytic treatment. 相似文献
3.
4.
I. Manconi P. N. L. Lens 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(1):69-77
BACKGROUND: This study explores an alternative process for the abatement and/or desulfurization of H2S and volatile organic sulfur compounds (VOSC) containing waste streams, which employs a silicone‐based membrane to simultaneously remove H2S and VOSC. An extractive membrane reactor allows the selective withdrawal of VOSC and H2S simultaneously from the waste stream, while preventing direct contact between the waste stream and the absorbing solution and/or the biological treatment system. The influence of the sulfur compounds, membrane characteristics, extractant and pH was studied. RESULTS: Sulfide and the VOCS studied, i.e. methanethiol (MT), ethanethiol (ET) and dimethylsulfide (DMS) were removed from the synthetic wastewater using a silicone rubber membrane. Methanethiol showed the highest (8.72 × 10?6 m s?1) overall mass transfer coefficient (kov) and sulfide the lowest kov value (1.23 × 10?6 m s?1). Adsorption of the VOCS into the silicone membrane reduced the overall mass transfer coefficient. The kov when using Fe(III)EDTA? as extractant (5.81 × 10?7 m s?1) for sulfide extraction was one order of magnitude lower than with anaerobic water (2.54 × 10?6 m s?1). On the other hand, the sulfide removal efficiency with Fe(III)EDTA? was higher (84%) compared with anaerobic water (60%) as extractant. An additional mass transfer resistance was formed by elemental sulfur which remained attached to the membrane surface. CONCLUSIONS: Extraction of sulfide and VOCS from a synthetic wastewater solution through a silicone rubber membrane is a feasible process as alternative to the techniques developed to treat VOSC emissions. Optimizing the aqueous absorption liquid can increase the efficiency of extraction based processes. Copyright © 2008 Society of Chemical Industry 相似文献
5.
Abdul Latif Ahmad Boon Seng Ooi 《Chemical engineering journal (Lausanne, Switzerland : 1996)》2010,156(2):257-263
In this study, nanofiltration membrane is used to separate proton (H+) and copper ions from a ternary ions mixture (H+, Cu2+, SO42?). The performance of membrane in separating Cu2+ and H+ was tested under the effect of pressure, concentration and different acid strength (pH). It was found that the H+ rejection is independent of the applied pressure. Permeability of solution decreased linearly with the increase of CuSO4 concentration. In terms of H+ rejection, there is a continuous drop in rejection from 0.1 mM CuSO4 to 10 mM CuSO4 solution. H+ was poorly retained and concentrated in the permeate stream in corresponding to the electro-neutrality requirements, on the other hand, the rejection of copper ion was almost constant with pH. In overall, optimum acid reclamation and copper recovery can be achieved at higher volume flux. A Three Parameters-Combined Film-Extended Nernst-Planck Equation (CF-ENP) model is successfully applied to predict the performance of nanofiltration membrane in separating the ternary ions. 相似文献
6.
K. Chandrasekara Pillai T. Raju Sang Joon Chung Il‐Shik Moon 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(3):447-453
BACKGROUND: Hydrogen sulfide (H2S) from industrial activities and anaerobic manure decomposition in commercial livestock animal operations is an offensive malodorous and toxic gas even in small concentrations, causing serious discomfort and health and social problems. The objective of this study was to employ for the first time a novel, attractive, low cost, environmentally benign mediated electrochemical oxidation (MEO) process with Ce(IV) as the redox catalyst for H2S gas removal from an H2S–air feed mixture. RESULTS: The influence of liquid flow rate (QL) from 2–4 L min?1, gas flow rate (QG) from 30–70 L min?1, H2S concentration in the H2S–air feed mixture from 5–15 ppm, and Ce(III) pre‐mediator concentration in the electrochemical cell from 0.1–1 mol L?1 on H2S removal efficiency were investigated. Both liquid and gas flow rates influenced the removal efficiencies, but in opposite directions. Nearly 98% H2S removal was achieved when the concentration of Ce(IV) mediator ion in the flowing scrubbing liquid reached 0.08 mol L?1. CONCLUSIONS: The new MEO method proved promising for H2S removal, achieving high removal efficiency. Integration of the electrochemical cell with the scrubber set‐up ensured continuous regeneration of the mediator and its repeated reuse for H2S removal, avoiding use of additional chemicals. Since the process works at room temperature and atmospheric pressure utilizing conventional transition metal oxide electrodes more commonly used in industrial applications, it is also safe and economical. Copyright © 2008 Society of Chemical Industry 相似文献
7.
Poly(vinyl chloride) polymers stabilized with tribasic lead sulfate discolor upon exposure to hydrogen sulfide gas as a result of lead sulfide formation. The discoloration occurs for samples in both cord and sheet forms and is shown to be a function of total H2S exposure, reaching a limiting value that is determined by the amount of lead stabilizer used in the polymer formulation. The permeation and diffusion constants for H2S through PVC stabilized with tribasic lead sulfate and with a liquid Ba–Cd–Zn formulation are found to be PPb = (6.0 ± 0.2) × 10?9, PBaCdZn = (5.2 ± 0.2) × 10?9 (both in cm3 gas?cm film/cm2 area?sec?cm Hg), DPb = (1.3 ± 0.2) × 10?7 cm2/sec, and DBaCdZn = (6.4 ± 0.6) × 10?8 cm2/sec, all measured at 21°C. The stabilizing efficiencies of the formulations were assessed by HCl evolution measurements, which show that exposure to H2S decreases the initial polymer stability for both Pb-stabilized and Ba–Ca–Zn-stabilized formulations. Protection of stabilized PVC formulations from diffusing hydrogen sulfide is thus advisable for long-term stability as well as for color integrity. 相似文献
8.
The anodic dissolution of pure iron was studied in oxygen-free solutions at high concentrations of chloride and hydrogen ions at 25°C under potentiostatic steady-state conditions. In the range cH+ ? 1 M the following kinetic data were obtained: Tafel slope b+ ? +100 mV, electrochemical reaction order related to CH+, n+.H+ = +1·1, and electrochemical reaction order related to the chloride ion concentration, n+,Cl? = +0·6. These values cannot be correlated to the currently proposed mechanisms of iron dissolution, another mechanism is suggested for the described conditions. The correlations to known mechanisms are discussed. 相似文献
9.
Ying‐Chien Chung Yu‐Yen Lin Ching‐Ping Tseng 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2004,79(6):570-577
The removal of high concentrations of H2S from waste gases containing mixtures of H2S and NH3 was studied using the pilot‐scale biofilter. Granular activated carbon (GAC), selected as support material in this study, demonstrated its high adsorption capacity for H2S and good gas distribution. Extensive tests to determine removal characteristics, removal efficiency, and removal capacity of high H2S levels and coexisting NH3 in the system were performed. In seeking the appropriate operating conditions, the response surface methodology (RSM) was employed. H2S removal capacities were evaluated by the inoculated bacteria (biological conversion) and BDST (Bed Depth Service Time) methods (physical adsorption). An average 98% removal efficiency for 0.083–0.167 mg dm?3 of H2S and 0.004–0.021 mg dm?3 of NH3 gases was achieved during the operational period because of rapid physical adsorption by GAC and subsequently an effective biological regeneration of GAC by inoculated Pseudomonas putida CH11 and Arthrobacter oxydans CH8. The results showed that H2S removal efficiency for the system was not affected by inlet NH3 concentrations. In addition, no acidification was observed in the BAC biofilter. High buffer capacity and low moisture demand were also advantages of this system. The maximal inlet loading and critical loading for the system were 18.9 and 7.7 g‐H2S m?3 h?1, respectively. The results of this study could be used as a guide for the further design and operation of industrial‐scale systems. Copyright © 2004 Society of Chemical Industry 相似文献
10.
The development of a new coloring technique is desirable to increase the commercial value of geopolymers. Selected copper compounds, i.e. Cu(OH)2, CuO, Cu2O, CuCO3?Cu(OH)2?H2O, CuCl2?2H2O and CuSO4?5H2O, were added to the initial reactants in order to color the geopolymers in the same manner as naturally occurring minerals. When Cu(OH)2, CuO and Cu2O were used, these compounds remained in the geopolymer matrix following hardening of the material. On the contrary, CuCO3?Cu(OH)2?H2O, CuCl2?2H2O and CuSO4?5H2O were not detected in the final products. XAFS analyses were performed to investigate the local structure of copper in the geopolymers produced. The results showed that the copper spectra of geopolymers incorporating Cu(OH)2, CuO and Cu2O correspond to those of pure Cu(OH)2, CuO and Cu2O, respectively. However, when CuCO3?Cu(OH)2?H2O, CuCl2?2H2O and CuSO4?5H2O were added, the copper generated spectra similar to that of the mineral chrysocolla ((Cu, Al)2H2Si2O5(OH)4?nH2O) than the respective copper compounds. 相似文献
11.
In this study, synthetic aqueous CuSO4 solution was prepared at various concentrations. Chevreul's salt was precipitated by passing SO2 through these solutions. Chevreul's salt, a mixed valence copper sulfite, Cu2SO3·CuSO3·2H2O, was characterized by XRD and SEM. The effects of parameters such as initial solution concentration, SO2 feeding rate, reaction time, and initial solution pH on precipitation of Chevreul's salt were investigated. 2n factorial experimental design and orthogonal central composite design methods in the precipitation experiments were used. It was observed that the effective parameters on the precipitation of Chevreul's salt were initial solution concentration, SO2 feeding rate, and initial solution pH. The optimum conditions obtained for maximum copper precipitation were: initial solution concentration 1.14 M, SO2 feeding rate 329.35 L.h.?1, reaction time 25 min, and initial solution pH 8.5. Constant parameters chosen at the initial stage of the reaction were: temperature 62°C, stirring speed 600 rpm, and reaction pH 3 (Çalban et al., 2006). Under these optimum conditions, the percentage of precipitated copper from synthetic aqueous CuSO4 solutions was 99.95. 相似文献
12.
The solvent extraction of uranium (VI) from chloride solutions by Cyphos IL-101 in xylene has been studied. Distribution coefficients were found to increase with aqueous chloride concentration and extractant concentration. The enthalpy of extraction is endothermic with ΔH = +24 ± 2 kJ·mol?1. Based upon slope analysis, an anion exchange extraction mechanism is proposed, with formation of a UO2Cl4 2- complex in association with 4 Cyphos IL-101 ligands. The extraction kinetics were fast, with complete equilibration occurring within 30 seconds. An isotherm for uranium extraction from 1.0 mol·L?1 chloride solution by 0.1 mol·L?1 Cyphos IL-101 in xylene shows that 45 mmol·L?1 uranium can be loaded into the organic phase in equilibrium with 2.1 mmol·L?1 in the aqueous phase. The absorption spectrum of the uranium loaded solvent between 350 and 550 nm is indicative of the UO2Cl4 2- complex with only chlorides present in the inner coordination sphere, unlike the more strongly hydrogen bonded Alamine 336 extracted uranium complex. Subject to the same experimental conditions, distribution coefficients for Cyphos IL-101 were significantly greater than for Alamine 336 or Aliquat 336. 相似文献
13.
The preferred process for the production of cuprous oxide powder is via the anodic dissolution of copper in alkaline solution of sodium chloride. The principal reactions are as follows: $$\begin{gathered} Cu + nCl^ - = CuCl_n^{1 - n} (n = 2, 3) \hfill \\ 2H_2 O + 2e = H_2 \uparrow + 2OH^ - \hfill \\ 2CuCl_n^{1 - n} + 2OH^ - = Cu_2 O \downarrow + 2nCl^ - + H_2 O \hfill \\ \end{gathered} $$ In the present investigation the basic electrode processes were studied systematically under a broad range of conditions using linear sweep voltammetry. Variables studied include the concentration of sodium chloride and sodium hydroxide (i.e., alkalinity), temperature of the solution, two categories of additives (an inhibitor for preventing the deposition of spongy metallic copper powder on the cathodes, and a chemical reducing agent for reducing the cupric ions to the cuprous state), and the effect of carbonate ions (resulting from the spontaneous absorption of carbon dioxide from the air by sodium hydroxide). Useful guidelines concerning the electrolysis conditions, additives, and the concentration limit of carbonate ions have been established. The proper operating conditions can be considered to be as follows: 80–85°C, NaCl 240–260 gl?1, NaOH below 1 gl?1. Conditions pertaining to the use of additives are the following: calcium gluconate 0–5 gl?1, Na2CrO4 below 0.5 gl?1, Na2Cr2O7 below 0.25 gl?1, NH2OH·HCl below 2.5 gl?1, N2H4·H2O below 2.5 gl?1, sucrose 0–5 gl?1. Special attention must be given to eliminate or reduce the presence of carbonate ions in the electrolyte below 0.25 gl?1 Na2CO3. 相似文献
14.
The relative concentration of hydrogen ion (H+) as a function of sulfuric acid (H2SO4) concentration (calculated using Pitzer's model) and the electrochemical processes by which irregular copper deposits are formed were correlated. Irregular deposits are formed by potentiostatic electrodeposition at a high overpotential where the hydrogen evolution reaction occurs parallel to copper electrodeposition. Two sets of acid sulfate solutions were analyzed. In one set of experiments, the concentration of CuSO4 was constant while the concentration of H2SO4 was varied. The other set of experiments was performed with a constant concentration of H2SO4 and different concentrations of CuSO4. Then, the volumes of the evolved hydrogen (calculated as the average current efficiencies of hydrogen evolution) and the morphologies of copper deposits, characterized by the SEM technique, obtained for the same ratio of CuSO4/H2SO4 were mutually compared and discussed in terms of the relative concentrations of hydrogen ions (H+) as a function of the H2SO4 concentration. Good agreement between the ionic equilibrium in the CuSO4-H2SO4-H2O system and the results of the electrochemical processes was obtained. In this way, it was shown how this ionic equilibrium can be applied to predict and analyze the solution composition in electrolytic copper deposition processes. 相似文献
15.
Carbonate-rich bentonite was modified by iron and copper chlorides in order to synthesize effective and cheap adsorbents for neutralization of H2S in low-concentrated exhaust gases. Bentonite and modified bentonite were analysed using atomic absorption spectroscopy (AAS), X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and BET surface area analysis. In addition, bentonite and modified bentonite were tested as hydrogen sulfide adsorbents. Iron-containing material showed a significant improvement in the capacity for H2S removal. The longest time of effective protective action (before H2S appears on the outlet of the column) was obtained for the bentonite modified with copper hydroxide. The results indicated that on the surface of modified samples hydrogen sulfide reacts with metal hydroxide forming sulfides. Sulfided iron-containing sample could be regenerated by exposing it to the air. 相似文献
16.
ABSTRACT A new procedure based on the use of sodium perchlorate (NaC1O4) and saturated potassium chloride (KCl) solutions for gold stripping from quaternary amine extraction systems is proposed for the first time. In this procedure, the stripping of Au(CN)2 ? is accomplished by the ClO4 ? ions in the first step, and the regeneration of quaternary amine is achieved by Cl? ions in the second step. 相似文献
17.
Shiva Agarwal M. Teresa A. Reis M. Joana Neiva Correia Jorge M. R. Carvalho 《溶剂提取与离子交换》2013,31(5):536-551
The extraction equilibrium of copper from sulfate media with the aldoxime Acorga M5640 in ShellSol D70 has been investigated. The distribution results were interpreted by taking into account the nonideality of the aqueous phase. The activity of copper and hydrogen ions in the target systems CuSO4/H2SO4/Na2SO4 and CuSO4/H2SO4/Fe2(SO4)3/ZnSO4 were calculated through the speciation of the aqueous solutions and by applying the Pitzer model. The experimental pH values were found in good agreement with the predicted pH values. A model considering the dimerization of the aldoxime extractant was proposed to predict the distribution ratio and the copper loading isotherms. The extraction constant at infinite dilution and the apparent dimerization constant were evaluated from the experimental data and were found to be 103.06 ± 0.07 and 51 ± 9 M?1, respectively, at 25°C. 相似文献
18.
James R. White 《Journal of Applied Electrochemistry》1987,17(5):977-982
Coulombic or cathode efficiencies (CE) were determined for the reverse pulse plating of copper from CuSO4/H2SO4 electrolyte for a variety of pulse conditions. The CE was seen to decrease as the magnitude of the current on the anodic pulse increased. This may be explained by an increase in Cu+ intermediates near the electrode surface and was verified by polarization data obtained from a rotating ring disc electrode (RRDE). The influence of certain additives on the CE during reverse pulse plating and on the polarization curves was also examined. When polyethylene glycol and Cl– (0.86mm) were added to the electrolyte, the CE was observed to drop significantly for a particular set of pulse parameters. The polarization curves at the RRDE suggested that the copper-electrolyte interface was blocked by an adsorbed layer over a wide potential range. The results are explained in terms of a model in which Cl– ions are concentrated near the electrode surface within the adsorbed polyethylene glycol layer and this is supported by observed rotational dependencies for the RRDE. 相似文献
19.
Andrea Mecucci Keith Scott 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2002,77(4):449-457
The recovery of copper, lead and tin from scrap printed circuit boards (PCBs) has been achieved using a combination of leaching, electrochemical ion exchange and electrodeposition. A simple aqueous nitric acid stripping solution, with the concentration range of 1–6 mol dm?3, has demonstrated the potential for selective extraction of copper and lead from the PCBs. Precipitation of tin as H2SnO3 (metastannic acid) occurred at acid concentrations above 4 mol dm?3. Preliminary galvanostatic electrolysis from simulated leaching solutions has investigated the feasibility of electrodeposition of copper and lead at different concentrations of HNO3. Cathodic lead deposition, particularly at high electrolyte conditions, resulted in poor current efficiency. This was mainly due to dentritic metal formation and subsequent re‐dissolution. An alternative method investigated for recovering the metal values was the simultaneous electrodeposition of copper at the cathode and lead dioxide at the anode. Electrohydrolysis for acid and base regeneration from the spent nitric acid electrolyte has also been investigated. © 2002 Society of Chemical Industry 相似文献
20.
Y. Liu J. Wang L. Yin P. Kondos C. Parks P. Borgesen D. W. Henderson E. J. Cotts N. Dimitrov 《Journal of Applied Electrochemistry》2008,38(12):1695-1705
Interfacial voiding in solder joints formed with Sn–Ag–Cu solder alloys and electroplated Cu was examined as a function of the plating solution chemistry and parameters. Galvanostatic Cu plating of ~10 μm thick Cu films was performed in a commercially available plating solution, and in model generic plating solutions. Analysis of the current voltage behavior along with Secondary Ion Mass Spectrometry studies of organic impurity content of two plated and a wrought copper samples, yielded a conclusion that for certain chemistry solutions (e.g., H2SO4 + CuSO4 + Cl? + PEG) and current density ranges above 2.5 mA cm?2, organic impurities were incorporated into the growing Cu. Solder joints were produced with a variety of electroplated Cu samples. These joints were, then, annealed at a temperature of 175 °C for 1 week, cross sectioned and examined. In general, it was observed that interfacial voiding in laboratory electroplated Cu layers was qualitatively similar to the unexplained voiding observed in some industrially plated Cu products. More specifically, it was found that the propensity for voiding could be correlated with specific electroplating parameters that in turn were associated with significant incorporation of organic impurities in the Cu deposit. 相似文献