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Im-Gyu Byun Ju-Hyun Ko Young-Rok Jung Tae-Ho Lee Chang-Won Kim Tae-Joo Park 《Korean Journal of Chemical Engineering》2005,22(6):910-916
Batch experiments using acclimated sludge to sulfur utilizing autotrophic denitrification were performed to determine the
applicability of spent sulfidic caustic in autotrophic denitrification as alternative sulfur and alkalinity sources. Fluorescence
insitu hybridization (FISH) analysis showed that the microbial community of β-proteobacteria/ Eubacteria increased from 45% to 69%
during enrichment period and nitrate removal reached up to 84% under this enriched sludge condition. In thiosulfate utilizing
autotrophic denitrification, the initial condition at a sulfur/nitrate (S/N) ratio of 1.5 showed higher nitrate removal with
95.9%, and nitrate removal could be expressed by a first-order function of biomass concentration if all parameters such as
pH, alkalinity and S/N ratio were in the optimum range. In spent sulfidic caustic utilizing autotrophic denitrification, the
sulfate formation ratios to nitrate reduction were lower than those in thiosulfate utilizing autotrophic denitrification with
a range of 2.65 to 2.78, and nitrate removal was over 95% at 1.0 and 1.5 S/N ratios. For S/N ratios of 1.0 and 1.5, initial
alkalinities were sufficient to maintain optimum pH range of autotrophic denitrification. Furthermore, well enriched seeding
sludge showed good activity of autotrophic denitrification at pH over 10. Therefore, spent sulfidic caustic could be effectively
applied to autotrophic denitrification as an alternative sulfur source and an alkalinity source 相似文献
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Jae-Ho Lee Jeung-Jin Park Kyo-Seong Seo Gi-Choong Choi Tae-Ho Lee 《Korean Journal of Chemical Engineering》2013,30(1):139-144
Spent sulfidic caustic (SSC), produced from petroleum plants, contains high levels of H2S and alkalinity. It can be used to denitrify nitrate-nitrogen via a biological nitrogen removal process, as both the electron donor and buffering agent for sulfur-based autotrophic denitrification. However, SSC also contains some recalcitrant organic compounds such as BTEX, so it has to be refined. To remove BTEX, air stripping was conducted in a laboratory scale, and as a result, over 93% of the BTEX were removed within 30min. For the reformation of the refined SSC, Na2S2O3 · 5H2O, methanol and organic material, produced from a biodiesel production plant, were supplemented, and referred to as new sulfidic caustic I (NSCI), II (NSCII), III (NSCIII), respectively. Thereafter, these products were applied to a modified Ludzack-Ettinger (MLE) process to evaluate their effects on the effluent COD and TN concentrations. As a result, there was no increase in the COD level on the injection of NSC due to the removal of BTEX via air stripping. In addition, compared to no NSC injection, 44.0% more TN was removed with an injection of NSC III, which were the most effective conditions. Thus, the application of NSC to the biological nitrogen removal process was successfully performed. These results may contribute to the development of resource recovery technology. 相似文献
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Jeung-Jin Park Im-Gyu Byun So-Ra Park Jae-Ho Lee Seung-Han Park Tae-Joo Park Tae-Ho Lee 《Journal of Industrial and Engineering Chemistry》2009,15(3):316-322
Caustic is utilized in petrochemical plants for the removal of hydrogen sulfide (H2S) from a variety of hydrocarbon streams. Because spent sulfidic caustic (SSC) harbors a high level of H2S and high alkalinity, it was injected into the anoxic zones of the biological nitrogen removal process as the electron donor and buffering agent for sulfur-based autotrophic denitrificaton. In order to determine the optimal SSC dosage, a modified Ludzack–Ettinger (MLE) process was first conducted at laboratory scale. As the result of the lab-scale experiments, the chemical oxygen demand (COD) increment of effluent and nitrification failure were observed, because SSC harbors barely biodegradable matter, and the caustic content was high, in accordance with the requirements. Thus, during the pilot-scale experiments, a hybrid Bardenpho process was designed and the SSC was neutralized from pH 13.3 to 11.5. These strategies were successful because no COD increment of effluent was observed and the pH of the unit process was stable. The heterotrophic and autotrophic denitrification ratios at each condition were calculated and, as the end product of sulfur-based autotrophic denitrification, the sulfate concentration was monitored. 相似文献
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辛醇废碱液中含有大量有机物,为此开展了萃取-大孔树脂吸附法处理辛醇废碱液、高效回收有机物的实验研究,实验结果表明:当辛醇废碱液的ρ(COD)为104651mg/L时,以辛醇为萃取剂,在pH=3、辛醇与辛醇废碱液的体积比为0.5、萃取级数为2等条件下,出水ρ(COD)可降至6453mg/L以下,COD去除率达到93.8%以上,萃取剂辛醇可以通过精馏再生循环利用;采用HYA-106大孔吸附树脂对辛醇二级萃取出水进行吸附处理,HYA-106大孔吸附树脂较佳的吸附流速为1BV/h、温度为40℃,此时出水ρ(COD)平均在155~183mg/L之间,COD去除率在97.1%~97.4%之间,单位体积树脂的废水处理量为34BV以上,树脂吸附量在213~215mgCOD/mL树脂之间,吸附-解吸效果稳定;萃取-吸附工艺的COD总去除率达到99.8%以上,最大程度地实现了辛醇废碱液中有机物的回收。 相似文献
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Milind V Jagushte Vijaykumar V Mahajani 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1999,74(5):437-444
Oxidation of thiosulfate to sulfate is often the rate controlling step during wet air oxidation (WAO) of spent caustic from the refinery and petrochemical industry and exhibits high Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD). The kinetics of WAO of thiosulfate was studied in the absence and presence of a heterogeneous copper catalyst. Wet oxidation of thiosulfate to sulfate is a free radical reaction exhibiting an induction period. In non‐catalytic oxidation, almost complete conversion of thiosulfate to sulfate was observed in 12 min at 150 °C and in 8 min at 120 °C in the presence of a heterogeneous copper catalyst at 0.69 MPa oxygen partial pressure. The presence of phenol accelerated thiosulfate oxidation. © 1999 Society of Chemical Industry 相似文献
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选择了Cu、Mn、Cu-Mn-Ce、Cu-Mn、Mn-Ce、Cu-Zn和Cu-Mn-Co七种活性组分,负载于-γAl2O3上,试验制备催化剂并对其用于碱渣废水湿式氧化的活性和稳定性进行了研究,结果表明MnOx/-γAl2O3在反应温度为200℃,室温下氧分压为1.0 MPa,反应搅拌速率为200 r/min,反应时间为2 h的试验条件下具有良好的催化性能;对COD、硫化物、挥发酚的质量浓度分别为16 149、19、3 326 mg/L,pH值为10.0的碱渣废水,经过酸化预处理的中和水通过该催化剂的催化湿式氧化处理,COD的去除率可达86.6%;同时,对MnOx/-γAl2O3负载型催化剂的制备条件也进行了研究和优化,并通过X射线衍射、BET比表面分析和孔径分析等对催化剂性能作了进一步研究,结果表明,550℃的焙烧温度下催化剂的活性成分是呈自发单层分散状态的不同价态的氧化锰,随着反应的进行,5~11 nm范围内的孔体积有较明显的减少,比表面积和孔总体积都有所下降,活性组分有部分溶出。 相似文献
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滴流床反应器催化湿式氧化法处理碱渣废水 总被引:1,自引:0,他引:1
在自行研制的滴流床反应器中,以MnOx/γ-Al2O3为催化剂,研究了反应温度、进水有机物浓度、液体流率等主要工艺参数对酸化中和预处理后的碱渣废水催化湿式氧化效果的影响。结果发现反应温度和液体流率对氧化反应效果的影响显著:温度升高,反应速率加快;液体流率越慢,反应效果越好。在滴流床处理碱渣废水最开始连续运转的15 h中出水中金属离子溶出现象比较严重,但随后趋于稳定,催化剂的活性并没有受到影响。由于滴流床中高的催化剂-液相比,废水在滴流床中表现出高的降解速率。 相似文献
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