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1.
A solar transcritical CO2 power cycle for hydrogen production is studied in this paper. Liquefied Natural Gas (LNG) is utilized to condense the CO2. An exergy analysis of the whole process is performed to evaluate the effects of the key parameters, including the boiler inlet temperature, the turbine inlet temperature, the turbine inlet pressure and the condensation temperature, on the system power outputs and to guide the exergy efficiency improvement. In addition, parameter optimization is conducted via Particle Swarm Optimization to maximize the exergy efficiency of hydrogen production. The exergy analysis indicates that both the solar and LNG equally provide exergy to the CO2 power system. The largest amount of exergy losses occurs in the solar collector and the condenser due to the great temperature differences during the heat transfer process. The exergy loss in condenser could be greatly reduced by increasing the LNG temperature at the inlet of the condenser. There exists an optimum turbine inlet pressure for achieving the maximum exergy efficiency. With the optimized turbine inlet pressure and other parameters, the system is able to provide 11.52 kW of cold exergy and 2.1 L/s of hydrogen. And the exergy efficiency of hydrogen production could reach 12.38%.  相似文献   

2.
This paper proposes a transcritical CO2 power cycle driven by solar energy while utilizing the cold heat rejection to an liquified natural gas (LNG) evaporation system. In order to ensure a continuous and stable operation for the system, a thermal storage system is introduced to store the collected solar energy and to provide stable power output when solar radiation is insufficient. A mathematical model is developed to simulate the solar-driven transcritical CO2 power cycle under steady-state conditions, and a modified system efficiency is defined to better evaluate the cycle performance over a period of time. The thermodynamic analysis focuses on the effects of some key parameters, including the turbine inlet pressure, the turbine inlet temperature and the condensation temperature, on the system performance. Results indicate that the net power output mainly depends on the solar radiation over a day, yet the system is still capable of generating electricity long after sunset by virtue of the thermal storage tank. An optimum turbine inlet pressure exists under given conditions where the net power output and the system efficiency both reach maximum values. The net power output and the system efficiency are less sensitive to the change in the turbine inlet temperature, but the condensation temperature exerts a significant influence on the system performance. The surface area of heat exchangers increases with the rise in the turbine inlet temperature, while changes in the turbine inlet pressure have no significant impact on the heat exchanging area under the given conditions.  相似文献   

3.
A novel energy and cost effective transport chain for stranded natural gas utilized for power production with CO2 capture and storage is developed. It includes an offshore section, a combined gas carrier and an integrated receiving terminal. The combined carrier will transport liquid carbon dioxide (LCO2) and liquid nitrogen (LIN) outbound, where natural gas (NG) is cooled and liquefied to LNG by vaporization of LIN and LCO2 onboard the carrier. The same carrier is used to transport the LNG onshore, where the NG can be used for power production with CO2 capture. The combined carrier consists of 10 cylindrical tanks with a diameter of 9.2 m and varying lengths from 14 to 40 m. The total ship volume is 13,000 m3. Assuming 85% capture rate of the CO2, the maximum ship utilization factor (SUF) is 63.4%. Due to the combined use of the storage tanks, the SUF is decreased with 1.4% points to 62%. The ship is equipped with a bi-directional submerged turret loading for anchoring and loading of NG and unloading of CO2. Two ships can deliver NG to and remove CO2 from a 400 MWnet power plant, and still obtain continuous production of LNG offshore without intermediate storage. The investment cost for each gas carrier is 40 million EUR giving total transport cost of 16.9 EUR/tonne LNG. The cost for the offshore transfer system is 6.6 million EUR per tonne LNG, whereas the cost for onshore storage and loading system is 3.1 and 0.8 million EUR per tonne LNG, respectively. The total specific costs for the ship transport, including onshore storage, loading shipping and offshore unloading are 27.5 EUR per tonne LNG for a roundtrip of 5 days, including voyage, production of LNG, unloading, connecting and berthing.  相似文献   

4.
An integrated power generation system combining solid oxide fuel cell (SOFC) and oxy-fuel combustion technology is proposed. The system is revised from a pressurized SOFC-gas turbine hybrid system to capture CO2 almost completely while maintaining high efficiency. The system consists of SOFC, gas turbine, oxy-combustion bottoming cycle, and CO2 capture and compression process. An ion transport membrane (ITM) is used to separate oxygen from the cathode exit air. The fuel cell operates at an elevated pressure to facilitate the use of the ITM, which requires high pressure and temperature. The remaining fuel at the SOFC anode exit is completely burned with oxygen at the oxy-combustor. Almost all of the CO2 generated during the reforming process of the SOFC and at the oxy-fuel combustor is extracted from the condenser of the oxy-combustion cycle. The oxygen-depleted high pressure air from the SOFC cathode expands at the gas turbine. Therefore, the expander of the oxy-combustion cycle and the gas turbine provides additional power output. The two major design variables (steam expander inlet temperature and condenser pressure) of the oxy-fuel combustion system are determined through parametric analysis. There exists an optimal condenser pressure (below atmospheric pressure) in terms of global energy efficiency considering both the system power output and CO2 compression power consumption. It was shown that the integrated system can be designed to have almost equivalent system efficiency as the simple SOFC-gas turbine hybrid system. With the voltage of 0.752 V at the SOFC operating at 900 °C and 8 bar, system efficiency over 69.2% is predicted. Efficiency penalty due to the CO2 capture and compression up to 150 bar is around 6.1%.  相似文献   

5.
This paper presents a thermoeconomic analysis aimed at the optimization of a novel zero-CO2 and other emissions and high-efficiency power and refrigeration cogeneration system, COOLCEP-S (Patent pending), which uses the liquefied natural gas (LNG) coldness during its revaporization. It was predicted that at the turbine inlet temperature (TIT) of 900 °C, the energy efficiency of the COOLCEP-S system reaches 59%. The thermoeconomic analysis determines the specific cost, the cost of electricity, the system payback period and the total net revenue. The optimization started by performing a thermodynamic sensitivity analysis, which has shown that for a fixed TIT and pressure ratio, the pinch point temperature difference in the recuperator, ΔTp1, and that in the condenser, ΔTp2 are the most significant unconstrained variables to have a significant effect on the thermal performance of novel cycle. The payback period of this novel cycle (with fixed net power output of 20 MW and plant life of 40 years) was 5.9 years at most, and would be reduced to 3.1 years at most when there is a market for the refrigeration byproduct. The capital investment cost of the economically optimized plant is estimated to be about 1000 $/kWe, and the cost of electricity is estimated to be 0.34–0.37 CNY/kWh (0.04 $/kWh). These values are much lower than those of conventional coal power plants being installed at this time in China, which, in contrast to COOLCEP-S, do produce CO2 emissions at that.  相似文献   

6.
A novel transport chain for stranded natural gas utilized for power production with CO2 capture and storage is developed. It includes an offshore section, a combined gas carrier, and an onshore integrated receiving terminal. Due to utilization of the cold exergy both in the offshore and onshore processes, and combined use of the gas carrier, the transport chain is both energy and cost effective. In this paper, the liquefied energy chain (LEC) is explained, including novel processes for both the offshore field site and onshore market site. In the offshore section, natural gas (NG) is liquefied to LNG by liquid carbon dioxide (LCO2) and liquid inert nitrogen (LIN), which are used as cold carriers. The LNG is transported in a combined gas carrier to the receiving terminal where it is used as a cooling agent to liquefy CO2 and nitrogen. The LCO2 and LIN are transported offshore using the same combined carrier. Pinch and Exergy Analyses are used to determine the optimal offshore and onshore processes and the best transport conditions. The exergy efficiency for a thermodynamically optimized process is 87% and 71% for the offshore and onshore processes, respectively, yielding a total efficiency of 52%. The offshore process is self-supported with power and can operate with few units of rotating equipment and without flammable refrigerants. The loss of natural gas due to power generation for the energy requirements in the LEC processes is roughly one third of the loss in a conventional transport chain for stranded natural gas with CO2 sequestration. The LEC has several configurations and can be used for small scale (<0.25 MTPA LNG) to large-scale (>5 MTPA LNG) transport. In the example in this paper, the total costs for the simple LEC including transport of natural gas to a 400 MWnet power plant and return of 85% of the corresponding carbon as CO2 for a total sailing distance of 24 h are 58.1 EUR/tonne LNG excluding or including the cost of power. The total power requirements are 319 kWh/tonne, hence the energy costs are 31.9 EUR/tonne LNG adding up to 90.0 EUR/tonne LNG. The exergy efficiency for this energy chain including power production and CO2 capture is 46.4% with a total cost of 20.4 EUR/MWh for the produced electricity. The total emissions (in CO2 equivalents) in the chain are 1–1.5% of the transported CO2.  相似文献   

7.
Gas turbine inlet air cooling technologies (GTIAC), mainly including chilling with LiBr/water absorption chiller and fogging as well, are being used during hot seasons to augment the power output. To evaluate the general applicability of inlet air cooling for gas–steam combined cycle power plant (GTCCIAC), parameters such as efficiency ratio, profit ratio and relative payback period were defined and analyzed through off-design performances of both gas turbine and inlet air cooling systems. An analytical method for applicability evaluation of GTCCIAC with absorption chiller (inlet chilling) and saturated evaporative cooler (inlet fogging) was presented. The applicability study based on typical off-design performances of the components in GTCCIAC shows that, the applicability of GTCCIAC with chilling and fogging depends on the design economic efficiency of GTCC power plant. In addition, it relies heavily on the climatic data and the design capacity of inlet air cooling systems. Generally, GTCCIAC is preferable in the zones with high ambient air temperature and low humidity. Furthermore, it is more appropriate for those GTCC units with lower design economic efficiency. Comparison of the applicability between chilling and fogging shows that, inlet fogging is superior in power efficiency at ta = 15–20 °C though it gains smaller profit margin than inlet chilling. GTCC inlet chilling with absorption chiller is preferable in the zones with ta > 25 °C and RH > 0.4.  相似文献   

8.
Biomass based decentralized power generation using externally fired gas turbine (EFGT) can be a technically feasible option. In this work, thermal performance and sizing of such plants have been analyzed at different cycle pressure ratio (rp = 2−8), turbine inlet temperature (TIT = 1050–1350 K) and the heat exchanger cold end temperature difference (CETD = 200–300 K). It is found that the thermal efficiency of the EFGT plant reaches a maximum at an optimum pressure ratio depending upon the TIT and heat exchanger CETD. For a particular pressure ratio, thermal efficiency increases either with the increase in TIT or with the decrease in heat exchanger CETD. The specific air flow, associated with the size of the plant equipment, decreases with the increase in pressure ratio. This decrease is rapid at the lower end of the pressure ratio (rp < 4) but levels-off at higher rp values. An increase in the TIT reduces the specific air flow, while a change in the heat exchanger CETD has no influence on it. Based on this comparison, the performance of a 100 kW EFGT plant has been analyzed for three sets of operating parameters and a trade-off in the operating condition is reached.  相似文献   

9.
Supercritical CO2 power cycle shows a high potential to recover low-grade waste heat due to its better temperature glide matching between heat source and working fluid in the heat recovery vapor generator (HRVG). Parametric analysis and exergy analysis are conducted to examine the effects of thermodynamic parameters on the cycle performance and exergy destruction in each component. The thermodynamic parameters of the supercritical CO2 power cycle is optimized with exergy efficiency as an objective function by means of genetic algorithm (GA) under the given waste heat condition. An artificial neural network (ANN) with the multi-layer feed-forward network type and back-propagation training is used to achieve parametric optimization design rapidly. It is shown that the key thermodynamic parameters, such as turbine inlet pressure, turbine inlet temperature and environment temperature have significant effects on the performance of the supercritical CO2 power cycle and exergy destruction in each component. It is also shown that the optimum thermodynamic parameters of supercritical CO2 power cycle can be predicted with good accuracy using artificial neural network under variable waste heat conditions.  相似文献   

10.
A novel solid oxide fuel cell (SOFC)/gas turbine (GT) hybrid cycle system with CO2 capture is proposed based on a typical topping cycle SOFC/GT hybrid system. The H2 gas is separated from the outlet mixture gas of SOFC1 anode by employing the advanced ceramic proton membrane technology, and then, it is injected into SOFC2 to continue a new electrochemical reaction. The outlet gas of SOFC1 cathode and the exhaust gas from SOFC2 burn in the afterburner 1. The combustion gas production of the afterburner1 expands in the turbine 1. The outlet gas of SOFC1 anode employs the oxy‐fuel combustion mode in the afterburner 2 after H2 gas is separated. Then, the combustion gas production expands in the turbine 2. To ensure that the flue gas temperature does not exceed the maximum allowed turbine inlet temperature, steam is injected into the afterburner 2. The outlet gas of the afterburner 2 contains all the CO2 gas of the system. When the steam is removed by condensation, the CO2 gas can be captured. The steam generated by the waste heat boiler is used to drive a refrigerator and make CO2 gas liquefied at a lower temperature. The performance of the novel quasi‐zero CO2 emission SOFC/GT hybrid cycle system is analyzed with a case study. The effects of key parameters, such as CO2 liquefaction temperature, hydrogen separation rate, and the unit oxygen production energy consumption on the new system performance, are investigated. Compared with the other quasi‐zero CO2 emission power systems, the new system has the highest efficiency of around 64.13%. The research achievements will provide the valuable reference for further study of quasi‐zero CO2 emission power system with high efficiency. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
The attractive features of a combined cycle (CC) power plant are fuel flexibility, operational flexibility, higher efficiency and low emissions. The performance of five gas turbine‐steam turbine (GT‐ST) combined cycle power plants (four natural gas based plants and one biomass based plant) have been studied and the degree of augmentation has been compared. They are (i) combined cycle with natural gas (CC‐NG), (ii) combined cycle with water injection (CC‐WI), (iii) combined cycle with steam injection (CC‐SI), (iv) combined cycle with supplementary firing (CC‐SF) and (v) combined cycle with biomass gasification (CC‐BM). The plant performance and CO2 emissions are compared with a change in compressor pressure ratio and gas turbine inlet temperature (GTIT). The optimum pressure ratio for compressor is selected from maximum efficiency condition. The specific power, thermal efficiency and CO2 emissions of augmented power plants are compared with the CC‐NG power plant at the individual optimized pressure ratios in place of a common pressure ratio. The results show that the optimum pressure ratio is increased with water injection, steam injection, supplementary firing and biomass gasification. The specific power is increased in all the plants with a loss in thermal efficiency and rise in CO2 emissions compared to CC‐NG plant. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

12.
Organic Rankine Cycle (ORC) is a promising technology for converting the low-grade energy to electricity. This paper presents an investigation on the parameter optimization and performance comparison of the fluids in subcritical ORC and transcritical power cycle in low-temperature (i.e. 80–100 °C) binary geothermal power system. The optimization procedure was conducted with a simulation program written in Matlab using five indicators: thermal efficiency, exergy efficiency, recovery efficiency, heat exchanger area per unit power output (APR) and the levelized energy cost (LEC). With the given heat source and heat sink conditions, performances of the working fluids were evaluated and compared under their optimized internal operation parameters. The optimum cycle design and the corresponding operation parameters were provided simultaneously. The results indicate that the choice of working fluid varies the objective function and the value of the optimized operation parameters are not all the same for different indicators. R123 in subcritical ORC system yields the highest thermal efficiency and exergy efficiency of 11.1% and 54.1%, respectively. Although the thermal efficiency and exergy efficiency of R125 in transcritical cycle is 46.4% and 20% lower than that of R123 in subcritical ORC, it provides 20.7% larger recovery efficiency. And the LEC value is relatively low. Moreover, 22032L petroleum is saved and 74,019 kg CO2 is reduced per year when the LEC value is used as the objective function. In conclusion, R125 in transcritical power cycle shows excellent economic and environmental performance and can maximize utilization of the geothermal. It is preferable for the low-temperature geothermal ORC system. R41 also exhibits favorable performance except for its flammability.  相似文献   

13.
A novel energy and cost effective transport chain for stranded natural gas utilized for power production with CO2 capture and storage is developed. It includes an offshore section, a combined gas carrier, and an integrated receiving terminal. In the offshore process, natural gas (NG) is liquefied to LNG by liquid carbon dioxide (LCO2) and liquid inert nitrogen (LIN), which are used as cold carriers. The offshore process is self-supported with power, hot and cold utilities and can operate with little rotating equipment and without flammable refrigerants. In the onshore process, the cryogenic exergy in LNG is used to cool and liquefy the cold carriers, which reduces the power requirement to 319 kWh/tonne LNG. Pinch and exergy analyses are used to determine thermodynamically optimized offshore and onshore processes with exergy efficiencies of 87% and 71%, respectively. There are very low emissions from the processes. The estimated specific costs for the offshore and onshore process are 8.0 and 14.6 EUR per tonne LNG, respectively, excluding energy costs. With an electricity price of 100 EUR per MWh, the specific cost of energy in the onshore process is 31.9 EUR per tonne LNG.  相似文献   

14.
This paper analyses a steam power – two-stage binary cycle plant (SPP–2BCP), in which low temperature waste heat from a conventional steam power plant can be efficiently utilized to generate electricity by installing a bottoming binary cycle. The result from a previous calculation on the installation of binary cycle technology on a Steam Power Plant (SPP) with n-Pentane working fluid indicates an increase in plant efficiency of about 9%. The purpose of this study is to analyze the sensitivity of performance of the binary cycle system against variations in the SPP operational load and the condenser’s cooling water temperature. The calculation is conducted on SPP load variations of 25%, 50%, 75% and 100%, inlet turbine pressure variations of 5 bar–30 bar, and inlet turbine temperature variations of 125 °C up to 235 °C. Each of these is also analyzed with ambient cooling water temperatures of 30 °C–37 °C. The results of the analysis indicate that the performance of this binary cycle SPP degrades slightly with SPP load, turbine inlet temperature, and turbine inlet pressure variations and with cooling water variations.  相似文献   

15.
The techno-economic evaluation of the evaporative gas turbine (EvGT) cycle with two different CO2 capture options has been carried out. Three studied systems include a reference system: the EvGT system without CO2 capture (System I), the EvGT system with chemical absorption capture (System II), and the EvGT system with oxyfuel combustion capture (System III). The cycle simulation results show that the system with chemical absorption has a higher electrical efficiency (41.6% of NG LHV) and a lower efficiency penalty caused by CO2 capture (10.5% of NG LHV) compared with the system with oxyfuel combustion capture. Based on a gas turbine of 13.78 MW, the estimated costs of electricity are 46.1 $/MW h for System I, while 70.1 $/MW h and 74.1 $/MW h for Systems II and III, respectively. It shows that the cost of electricity increment of chemical absorption is 8.7% points lower than that of the option of oxyfuel combustion. In addition, the cost of CO2 avoidance of System II which is 71.8 $/tonne CO2 is also lower than that of System III, which is 73.2 $/tonne CO2. The impacts of plant size have been analyzed as well. Results show that cost of CO2 avoidance of System III may be less than that of System II when a plant size is larger than 60 MW.  相似文献   

16.
The guiding idea behind oxy-fuel combustion power cycles is guaranteeing a high level of performance as can be obtained by today's advanced power plants, together with CO2 separation in conditions ready for transport and final disposal. In order to achieve all these goals, oxy-combustion – allowing CO2 separation by simple cooling of the combustion products – is combined with large heat recovery and staged expansions/compressions, making use of new components, technology and materials upgraded from modern gas turbine engines. In order to provide realistic results, the power plant performance should include the effects of blade cooling. In the present work an advanced cooled expansion model has been included in the model of the MATIANT cycle in order to assess the effects of blade cooling on the cycle efficiency. The results show that the penalty in efficiency due to blade cooling using steam from the heat recovery boiler is about 1.4 percentage points, mainly due to the reheat of the steam, which, on the other hand, leads to an improvement in specific work of about 6%.  相似文献   

17.
Sevan Marine and Siemens have developed a floating power plant – entitled Sevan GTW (gas-to-wire) – based on Sevan’s cylindrical platform and Siemens’ SCC-800 combined cycle, and SINTEF has adapted a post-combustion CO2 capture process for on board integration including compression and preconditioning of the CO2. Main emphasis has been placed on developing an optimised conceptual design within the structural constraints, and assessing how efficient the capture unit may be operated in consideration of the dynamic behaviour induced by the sea on the absorber and desorber columns via the floating carrier. The rational behind this technology selection is the urgency in making appropriate steps for a quick start for remote power generation at sea with the inclusion of CCS to serve offshore oil and gas operations. This calls for modular power blocks made up by high efficient combined power cycles with post-combustion exhaust gas cleaning. From this point of view a system with four absorption columns and one desorber unit has been determined based on structured packing material. The capture process has been integrated with the power cycle in due consideration of the sea forces. It is shown that a permanent tilt becomes more important than periodic movements provided the harmonic periods are kept within a certain level (<20 s). Operational conditions and constraints vis-à-vis movements and trimming of the floater have been addressed and discussed with reference to available literature. This also includes the liquid hold-up and gas–liquid interfacial area in the absorption columns linked with tilting. Optimisation reveals that a reboiler duty of 3.77 GJ/ton CO2 would result in the lowest capture cost. With a energy penalty of 9%-points the Sevan GTW concept presents itself as a realistic concept deemed to be within reach today.  相似文献   

18.
In this paper, a method that utilizes CO2 vapor compression thermodynamic cycle to recover low‐temperature heat from exhausted water steam of fossil fuel thermal power plants is reported. Experimental investigation was carried out to study the characteristics of low‐temperature heat recovery by liquid CO2 evaporation process from vacuum exhausted steam condensation occurring at the turbine exit. Furthermore, measured heat recovery performances over one whole year are presented and discussed. Experimental results show that the present heat recovery process by CO2 vapor compression cycle is able to operate stably. The yearly averaged water temperature at the CO2 condenser outlet was measured at 87.5 °C with a COP value above 5.0. This high energy efficiency ratio is found to be mainly due to two factors: the transcritical CO2 vapor compression and steam condensation phase change occurring on the CO2 evaporator. The findings from this paper provide helpful guidelines for low‐temperature heat recovery system design and improving fossil fuel utilization efficiency. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

19.
This paper presents part-load evaluation of a natural gas-fired chemical looping combustion (CLC) combined cycle with CO2 capture. The novel combined cycle employs an air-based gas turbine, a CO2-turbine and a steam turbine cycle. In this combined cycle, the CLC reactors replace combustion chamber of the gas turbine. The proposed combined cycle has a net plant efficiency of about 52.2% at full-load, including CO2 compression to 200 bar. The part-load evaluation shows that reducing the load down to 60% results in an efficiency drop of 2.6%-points. However, the plant shows better relative part-load efficiency compared to conventional combined cycles. The pressure in CLC-reduction and -oxidation reactors is balanced by airflow control, using a compressor equipped with variable guide vanes. A combination of control strategies is discussed for plant start-up and shutdown and for part-load when airflow reduction is not practically possible with current generation of compressors. The results show that the combined cycle has a promising efficiency even at part-load; however, it requires an advanced control strategy.  相似文献   

20.
《Energy》2004,29(4):497-512
We propose a new cogeneration power system with two energy sources of fuel chemical energy and liquefied natural gas (LNG) cryogenic energy, and two outputs of electrical power and cooling power. Due to the advanced integration of system and cascade utilization of LNG cryogenic energy, the system has excellent energy saving: chemical energy of fuel and LNG cryogenic energy are saved by 7.5–12.2% and 13.2–14.3%, respectively. As CO2 is selected as working fluid and oxygen as fuel oxidizer, CO2 is easily recovered as a liquid with LNG vaporization. In this paper, the typical recuperative Rankine cycle and the corresponding cogeneration system are described and a detailed thermodynamic analysis is carried out to reveal the principle of the cycle and system. Furthermore, the influence of key parameters on performance is discussed. Considering the engineering application, the technical advantages and concerns are pointed out.  相似文献   

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