A supercritical Rankine cycle using zeotropic mixture working fluids for the conversion of low-grade heat into power

A supercritical Rankine cycle using zeotropic mixture working fluids for the conversion of low-grade heat into power is proposed and analyzed in this paper. Unlike a conventional organic Rankine cycle, a supercritical Rankine cycle does not go through the two-phase region during the heating process. By adopting zeotropic mixtures as the working fluids, the condensation process also happens non-isothermally. Both of these features create a potential for reducing the irreversibilities and improving the system efficiency. A comparative study between an organic Rankine cycle and the proposed supercritical Rankine cycle shows that the proposed cycle can achieve thermal efficiencies of 10.8-13.4% with the cycle high temperature of 393 K-473 K as compared to 9.7-10.1% for the organic Rankine cycle, which is an improvement of 10-30% over the organic Rankine cycle. When including the heating and condensation processes in the system, the system exergy efficiency is 38.6% for the proposed supercritical Rankine cycle as compared to 24.1% for the organic Rankine cycle.     

Thermal matching performance of a geothermal ORC system using zeotropic working fluids

The thermal matching performance analysis is conducted for a geothermal organic Rankine cycle system using zeotropic mixtures as working fluids. The constant isentropic efficiency is replaced by internal efficiency of an axial flow turbine with given size for each condition, and the zeotropic mixtures of isobutane and isopentane is used as working fluids of the organic Rankine cycle, in order to improve thermal match in evaporator and condenser. The results showed the use of zeotropic mixtures leads to the prominent thermodynamic first law and second law efficiencies, especially at high minimum temperature difference in evaporator (Δt₁), and there exists an optimal thermal performance at some certain mole fraction of isopentane in zeotropic mixtures (x) and Δt₁. The geothermal organic Rankine cycle with x of 0.2 and Δt₁ of 16 K shows the maximal thermodynamic first law and second law efficiency in this research. The geothermal organic Rankine cycle system using zeotropic mixtures shows the optimal overall thermal performance at some certain x, which is not necessary to be the point with the maximal temperature glide. The use of zeotropic mixtures is not always lead to a high thermal to electricity efficiency compared to the pure working fluid, and its overall net power output of P_ORC is even lower than the pure working fluids compositions at some certain x.     

Thermodynamic analysis of high-temperature regenerative organic Rankine cycles using siloxanes as working fluids

A recent novel adjustment of the Span-Wagner equation of state for siloxanes, used as working fluids in high-temperature organic Rankine cycles, is applied in a mathematical model to solve cycles under several working conditions. The proposed scheme includes a thermo-oil intermediate heat circuit between the heat source and the organic Rankine cycle. Linear and cyclic siloxanes are assayed in saturated, superheated and supercritical cycles. The cycle includes an internal heat exchanger (regenerative cycle), although a non-regenerative scheme is also solved. In the first part of the study, a current of combustion gases cooled to close to their dew point temperature is taken as the reference heat source. In the second part, the outlet temperature of the heat source is varied over a wide range, determining appropriate fluids and schemes for each thermal level. Simple linear (MM, MDM) siloxanes in saturated regenerative schemes show good efficiencies and ensure thermal stability of the working fluid.     

Electrical energy production from the integrated aerobic-anaerobic treatment of organic waste by ORC

The energetic performance of an ORC system fueled by the heat generated from the integrated aerobic/anaerobic treatment of organic waste was analyzed. The temperature and heat content of the exhaust air arising from the aerobic treatment were increased by the combustion of the biogas produced by the anaerobic digestion of a fraction of the same waste. On the basis of the amount of excess air exploited in the process, for each tonne of organic waste treated, it was possible to produce from 30 to 90 kg of exhaust air per day with a mean temperature ranging from 330 to 340 K. By processing from 0.5% to 16% of the whole organic waste in an anaerobic digestion section instead of the aerobic one, it was possible to increase the exhaust air temperature from 340 to 510 K, leading to an increase in the ORC size from about 0.05 to about 1 W/tonne/year. The best energetic utilization of the biogas was achieved for ORC compression ratios from 1.5 to 2 and for maximum air temperatures from 335 to 340 K. In these conditions, by using a micro-ORC system (i.e. <15 kW), it was possible to convert about 20% of the energy content of the biogas into electrical energy.     

烟气驱动复叠式非共沸工质有机朗肯循环系统㶲分析

通过构建复叠式非共沸工质有机朗肯循环系统模型,并采用■分析方法,研究了系统■效率随工质摩尔组分的变化规律以及不同摩尔组分下,系统各部件■损失分布情况。研究结果表明:受蒸发器泡点温度与高温级蒸发器夹点位置影响,当高温级循环工质环戊烷摩尔分数为0.8,低温级循环工质异丁烷摩尔分数为0.1时,系统■效率取得最大值48.56%,比采用纯工质时相对提高了3.83%;且采用非共沸工质后,排烟损失、高温级蒸发器■损失、低温级冷凝器■损失均有显著降低。     

分级抽汽回热式太阳能低温有机朗肯循环系统的热力性能分析

研究了分级抽汽回热式太阳能低温有机朗肯循环系统的热力性能。以R600和R245fa作为循环工质,利用热力学第一定律和第二定律,在不同的蒸发温度和膨胀比的条件下,对分级抽汽回热式系统和基本有机朗肯循环系统的热力性能变化进行比较和分析,指出分级抽汽回热式系统的热效率和效率更高,产生的不可逆损失更小,具有更优越的性能。     

Performance comparison of three trigeneration systems using organic rankine cycles

In this paper, energetic performance comparison of three trigeneration systems is presented. The systems considered are SOFC-trigeneration, biomass-trigeneration, and solar-trigeneration systems. This study compares the performance of the systems considered when there is only electrical power and the efficiency improvement of these systems when there is trigeneration. Different key output parameters are examined: energy efficiency, net electrical power, electrical to heating and cooling ratios, and (GHG) GHG (greenhouse gas) emissions. This study shows that the SOFC-trigeneration system has the highest electrical efficiency among the three systems. Alternatively, when trigeneration is used, the efficiencies of all three systems considered increase considerably. The maximum trigeneration efficiency of the SOFC-trigeneration system is around 76% while it is around 90% for the biomass-trigeneration system. On the other hand, the maximum trigeneration efficiencies of the solar-trigeneration system is around 90% for the solar mode, 45% for storage and storage mode, and 41% for the storage mode. In addition, this study shows that the emissions of CO₂ in kg per MWh of electrical power are high for the biomass-trigeneration and SOFC-trigeneration systems. However, by considering the emissions per MWh of trigeneration, their values drop to less than one fourth.     

Sustainable application of renewable sources in water pumping systems: Optimized energy system configuration

Eighteen years ago, in Portugal, the expenses in a water supply system associated with energy consumption were quite low. However, with the successive crises of energy fuel and the increase of the energy tariff as well as the water demand, the energy consumption is becoming a larger and a more important part of the total budget of water supply pumping systems. Also, new governmental policies, essentially in developed countries, are trying to implement renewable energies. For these reasons, a case-study in Portugal of a water pumping system was analysed to operate connected to solar and wind energy sources.     

Assessment of power and hydrogen production performance of an integrated system based on middle-grade geothermal source and solar energy

In this study, power and hydrogen production performance of an integrated system is investigated. The system consists of an organic Rankine cycle (ORC), parabolic trough solar collectors (PTSCs) having a surface area of 545 m², middle-grade geothermal source (MGGS), cooling tower and proton exchange membrane (PEM). The final product of this system is hydrogen that produced via PEM. For this purpose, the fluid temperature of the geothermal source is upgraded by the solar collectors to drive the ORC. To improve the electricity generation efficiency, four working fluids namely n-butane, n-pentane, n-hexane, and cyclohexane are tried in the ORC. The mass flow rate of each working fluid is set as 0.1, 0.2, 0.3, 0.4 kg/s and calculations are made for 16 different situations (four types of working fluids and four different mass flow rates for each). As a result, n-butane with a mass flow rate of 0.4 kg/s is found to be the best option. The average electricity generation is 66.02 kW between the hours of 11⁰⁰-13⁰⁰. The total hydrogen production is 9807.1 g for a day. The energy and exergy efficiency is calculated to be 5.85% and 8.27%, respectively.     

A solar ejector air‐conditioning system using environment‐friendly working fluids

In this paper, the performance of the solar‐driven ejector air conditioning with several environment‐friendly working fluids is studied. The effect of the fluid nature and operating conditions on the ejector performance is examined. This performance is calculated using an empirical correlation. Thermodynamic properties of functioning fluids are obtained with a package REFPROP7. It appears that the refrigerant R717 offers the highest coefficient of performance (COP). For generator temperature T_B = 90°C, condenser temperature T_C = 35°C and evaporator temperature T_E = 15°C and with R717, the COP of ejector air‐conditioning system is 0.408. Using a meteorological data for the city of Tunis, the system performance is computed for three collector types. The air‐conditioning season and period were taken for six months from April to September. The daily period is between 8 and 17 h. For the solar air‐conditioning application, the COP of the overall system varied from 0.21 to 0.28 and the exergy efficiency varied from 0.14 to 0.19 with the same working conditions and total solar radiation (351–875 Wm^?2) in July. Copyright © 2008 John Wiley & Sons, Ltd.     

4E analysis of efficient waste heat recovery from SOFC using APC: An effort to reach maximum efficiency and minimum emission through an application of grey wolf optimization

This article presents an innovative combined heat and power system comprising a solid oxide fuel cell (SOFC), a heat recovery unit, and a lithium bromide absorption power cycle (APC). The energy, exergy, economic, and environmental perspectives of the proposed system are compared against the same configuration using an organic Rankine cycle (ORC), recovering the waste heat of the SOFC. A multi-criteria optimization based on the Grey Wolf approach is applied to each system to specify the best operation conditions having the exergy efficiency and total cost rate as the objectives. Furthermore, a parametric investigation is conducted to assess the effects of changing the decision variables on the systems proficiencies. The results indicate that although the ORC-based cycle is economically very slightly superior, the integration of the SOFC with the APC offers a much higher exergy efficiency due to the better temperature matching between the working fluid and heat source. Optimization can increase the exergy efficiencies of the SOFC-ORC and the SOFC-APC systems by about 13.8% and 14.7% while reducing the total cost rate by 11.2 $/h and 11.0 $/h, respectively, compared to the base system. Environmental analysis results reveal that APC use leads to a lower emission of 2.8 kg/MWh.     

不同太阳能利用区有机朗肯循环工质的选择

为太阳能有机朗肯循环系统(organic Rankine cycle,ORC)合理选择工质需要综合考虑太阳能辐射强度和环境温度的影响。基于建筑热工设计分区和太阳能资源区划标准,将我国分为了11个太阳能利用区。利用太阳能ORC热力学能量流通数学模型,以太阳能ORC系统典型月平均热发电效率最高为原则,为太阳能ORC系统绘制出推荐的工质地图。     

Effect of working fluids in a novel geothermal-based integration of organic-flash and power/cooling generation cycles with hydrogen and freshwater production units

One of the essential steps to design energy conversion-based systems is choosing an efficient working fluid under the design goals to access stable products with high efficiency and overcome environmental issues. In this regard, the current paper is motivated to devise and evaluate a novel geothermal-driven multigeneration system under the effect of various working fluids. The proposed system consists of a flash-binary geothermal power plant, an organic flash cycle (OFC), a power/cooling subsystem (an organic Rankine cycle (ORC) and a thermoelectric generator incorporated with a compression refrigeration cycle), and freshwater and hydrogen production units utilizing a humidification-dehumidification desalination unit and a low-temperature electrolyzer. Considering the design potential of the OFC and ORC, four different environmentally-friendly working fluids, i.e., R123 and R600 in the OFC and R1234yf and R1234ze(e) in the ORC are selected and classified in four groups to introduce the best one, under the energy, exergy, and economic (3E analysis) approaches. Also, the whole system is optimized through a genetic algorithm, respecting the optimal solution for the energy efficiency and unit exergy cost of the products. According to the results, R123/R1234ze(e) shows the highest cooling, hydrogen, freshwater production rates, and energy efficiency. Likewise, the maximum power generation and exergy efficiency belong to R600/R1234ze(e). Moreover, R600/R1234yf has the lowest unit exergy cost of products.     

Design study of configurations on system COP for a combined ORC (organic Rankine cycle) and VCC (vapor compression cycle)

The study introduced a novel thermally activated cooling concept - a combined cycle couples an ORC (organic Rankine cycle) and a VCC (vapor compression cycle). A brief comparison with other thermally activated cooling technologies was conducted. The cycle can use renewable energy sources such as solar, geothermal and waste heat, to generate cooling and power if needed. A systematic design study was conducted to investigate effects of various cycle configurations on overall cycle COP. With both subcooling and cooling recuperation in the vapor compression cycle, the overall cycle COP reaches 0.66 at extreme military conditions with outdoor temperature of 48.9 °C. A parametric trade-off study was conducted afterwards in terms of performance and weight, in order to find the most critical design parameters for the cycle configuration with both subcooling and cooling recuperation. Five most important design parameters were selected, including expander isentropic efficiency, condensing and evaporating temperatures, pump/boiling pressure and recuperator effectiveness. At the end, two additional cycle concepts with either potentially higher COP or practical advantages were proposed. It includes adding a secondary heat recuperator in the ORC side and using different working fluids in the power and cooling cycles, or so-called dual-fluid system.     

Design of an energy hub based on natural gas and renewable energy sources

This paper presents a simulation model for an energy hub consisting of natural gas (NG) turbines as the main sources of energy (including both electricity and heat) and two renewable energy sources—wind turbines (WTs) and photovoltaic (PV) solar cells. The hub also includes water electrolyzers for hydrogen production. The hydrogen serves as an energy storage medium that can be used in some transportation applications, or it can be mixed with the NG feed stream to improve the emission profile of the gas‐turbine unit. The capacity of the designed hub is meant to simulate and replace the coal‐fired Nanticoke Generating Station with a NG‐fired power plant. Therefore, the aim of this work is to develop a simulated model that combines different energy generation technologies, which are evaluated in terms of the total energy produced, the cost per kWh of energy generated, and the amount of emissions produced. The proposed model investigates the benefits, both economic and environmental, the technological barriers, and the challenges of energy hubs by developing several scenarios. The simulation of these scenarios was done using General Algebraic Modeling System (GAMS®). Although the software is strongly known for its optimization capability, the mixed complementary problems solver makes it a strong tool for solving equilibrium problems. Excess energy produced during off‐peak demand by WTs and PV solar cells was used to feed the electrolyzer to produce H₂ and O₂. The proposed approach shows that a significant reduction in energy cost and greenhouse gas emissions were achieved, in addition to the increased overall efficiency of the energy hub. Out of the examined three scenarios, Scenario C appeared to be the most feasible option for a combination of renewable and non‐renewable technologies as it did not only produce hydrogen, but also provided electricity at relatively lower prices. Copyright © 2013 John Wiley & Sons, Ltd.     

Experimental study of the energy efficiency of an incinerator for medical waste

The aim of this paper is to explore the flux of usable energy and the coefficient of energy efficiency of an incinerator for medical waste combustion. The incineration facility incorporates a heat recovery system. The installation consists of a loading unit, a combustion chamber, a thermoreactor chamber, and a recovery boiler. The analysis was carried out in the Oncological Hospital in Bydgoszcz (Poland). The primary fuel was comprised of medical waste, with natural gas used as a secondary fuel. The study shows that one can obtain about 660–800 kW of usable energy from 100 kg of medical waste. This amount corresponds to 1000–1200 kg of saturated steam, assuming that the incinerator operates at a heat load above φ > 65%. The average heat flux in additional fuel used for incinerating 100 kg of waste was 415 kW. The coefficient of energy efficiency was set within the range of 47% and 62% depending on the incinerator load. The tests revealed that the flux of usable energy and the coefficient of energy efficiency depend on the incinerator load. In the investigated range of the heat load, this dependence is significant. When the heat load of the incinerator increases, the flux of usable energy and the coefficient of energy efficiency also increase.     

An experimental study on the organic Rankine cycle to determine as to how efficiently utilize fluctuating thermal energy

Thermal properties of the available energy such as maximum temperature and thermal energy capacity are greatly influenced to the design of energy conversion system like the organic Rankine cycle (ORC). Useful thermal energy can be obtained from: waste heat energy, geothermal energy, solar heat energy, biomass energy, and so on. However, these cannot usually be supplied at constant levels. Hence, the temperature and flowrate of the thermal energy can vary while the ORC is working. In order to efficiently utilize such fluctuating thermal energy, an experimental study was conducted while adjusting the mass flowrate and the temperature of the working fluid. Three supersonic nozzles and an impulse type turbine were applied. The supersonic nozzle was adopted to increase the spouting velocity for efficient operation of the impulse turbine. The nozzle was designed to reach a velocity of Mach 1.6 at the nozzle exit, and three nozzles were used to control the mass flowrate in this experiment. The experimental results were compared with the predicted results obtained by the cycle analysis.     

The performance of a triple pressure level absorption cycle (TPLAC) with working fluids based on the absorbent DMEU and the refrigerants R22, R32, R124, R125, R134a and R152a

This paper compares the performance of a single-stage triple pressure level (TPL) absorption cycle with different refrigerant–absorbent pairs. Four HFC refrigerants namely: R32, R125, R134a and R152a which are alternative to HCFC, such as R22 and R124, in combination with the absorbent dimethylethylenurea (DMEU) were considered. The highest coefficient of performance (COP) and the lowest circulation ratio (f), were found as a function of the generator temperature for a given evaporating and cooling water temperatures. The sensitivity of the COP and f for evaporator and cooling water temperatures changes at the maximum COP for the best three working fluids were also examined. It was obtained that the preferable pair is R124–DMEU and among working fluids based on HFC the preferable pair is the R125–DMEU.     

A server database system for remote monitoring and operational evaluation of renewable energy sources plants

The development of a server database system for monitoring and operational evaluation of remote Renewable Energy Sources (RES) plants is presented. Meteorological and operational parameters of multiple RES systems are measured and transmitted in real-time to a database (DB) server. An integrated data management system, comprised of programs running on the DB server, displays the received data on screen, stores them on local disk and inserts them in the DB in real-time. Remote clients access the DB using the TCP/IP protocol in order to create charts, calculate statistical and operational parameters regarding each RES plant and perform DB administration actions. The proposed system can be used for the exploration of the available RES potential during the design of RES systems, the development of statistical models describing the spatial variability of RES resources and the remote monitoring and control of RES plants.     

Energy,exergy, and exergoeconomics (3E) analysis and multi-objective optimization of a multi-generation energy system for day and night time power generation - Case study: Dezful city

The present study aimed to investigate a multi-generation energy system for the production of hydrogen, freshwater, electricity, cooling, heating, and hot water. Steam Rankine cycle (SRC), organic Rankine cycle (ORC), absorption chiller, Parabolic trough collectors (PTCs), geothermal well, proton exchange membrane (PEM) electrolyzer, and reverse osmosis (RO) desalination are the main subsystems of the cycle. The amount of exergy destruction is calculated for each component after modeling and thermodynamic analysis. The PTCs, absorption chiller, and PEM electrolyzer had the highest exergy destruction, respectively. According to meteorological data, the system was annually and hourly tested for Dezful City. For instance, it had a production capacity of 13.25 kg/day of hydrogen and 147.42 m³/day of freshwater on 17th September. Five design parameters are considered for multi-objective optimization after investigating objective functions, including cost rate and exergy efficiency. Using a Group method of data handling (GMDH), a mathematical relation is obtained between the input and output of the system. Next, a multi-objective optimization algorithm, a non-dominated sorting genetic algorithm (NSGA-II), was used to optimize the relations. A Pareto frontier with a set of optimal points is obtained after the optimization. In the Pareto frontier, the best point is selected by the decision criterion of TOPSIS. At the TOPSIS point, the exergy efficiency is 31.66%, and the total unit cost rate is 21.9 $/GJ.