Second law analysis of supercritical CO2 recompression Brayton cycle

In the present study, exergetic analyses and optimization of S-CO₂ recompression cycle have been performed to study the effect of operating parameters on the optimum pressure ratio, energetic and exergetic efficiencies and component irreversibilities. Effect of isentropic efficiency, recuperator effectiveness and component pressure drop on the second law efficiency is presented as well. Results show that the effect of minimum operating temperature on the optimum pressure ratio and cycle efficiencies is more predominant than the maximum operating temperature, whereas the effect of maximum cycle pressure is significant only for lower values and the optimum pressure ratio leads to near critical minimum cycle pressure. Result shows that the irreversibilities of heat exchangers are significantly more compared to that of turbo-machineries and the effect of operating parameters on irreversibility is also more significant for recuperators compared to turbo-machines. Effect of isentropic efficiency of turbine is more predominant (about 2.5 times) than that of compressors and effect of high temperature recuperator (HTR) effectiveness is more predominant (about double) than that of low temperature recuperator (LTR) on the second law efficiency. Effect of pressure drop in reactor is more significant compared to others components on the second law efficiency reduction.     

New text comparison between CO2 and other supercritical working fluids (ethane,Xe, CH4 and N2) in line- focusing solar power plants coupled to supercritical Brayton power cycles

This study is focused on comparing four supercritical fluids: Ethane, Xenon, Methane and Nitrogen, as possible alternative to supercritical Carbon Dioxide (s-CO₂) in Brayton power cycles coupled to line- focusing solar power plants with Solar Salt (60% NaNO₃; 40% KNO₃) as heat transfer fluid. The Simple Brayton cycle with heat recuperation and reheating is the configuration selected in this paper, providing a balance of plant design with reduced number of equipment and cost. The gross plant efficiency is calculated fixing the recuperator conductance (UA) for different Turbine Inlet Temperatures (TIT), confirming the maximum plant gross efficiency is related with the minimum allowable recuperator pinch point temperature. The reheating pressure and compressor inlet temperature are optimized with the mathematical algorithms SUBPLEX, UOBYQA and NEWOUA. According to the REFPROP database ranges of applicability, the maximum TIT limits are established for the supercritical fluids (N₂ TIT = 550 °C, CO₂ TIT = 550 °C, C₂H₆ TIT = 400 °C, Xe TIT = 450 °C and CH₄ TIT = 350 °C). The reference scenario considered for calculating the thermosolar plant energy balances and simulations is the wet-cooling system with a Compressor Inlet Temperature (CIT = 32 °C). The gross efficiency results with the wet-cooling system are: N₂ (45.8%), CO₂ (44.37%), C₂H₆ (40.74%), Xe (39.88%), CH₄ (32.15%). The plant efficiency is also translated into solar field effective aperture area and estimated cost, for a fixed power output. For optimizing the solar collector aperture area and cost, the Primary Heat Exchanger (PHX) and the ReHeating Heat Exchanger (RHX) capacity ratio (C_R) are fixed (C_R = 1). The dry-cooling system scenario (CIT = 47 °C) is alto estimated: N₂ (43.34%), CO₂ (42.42%), C₂H₆ (37.34%), Xe (37.26%), CH₄ (29.53%).For predicting the recuperator heat exchanger dimensions for a fixed conductance (UA), the heat transfer coefficient (HTC) is calculated with the Dittus–Boelter correlation and compared with the CO₂ as reference. The C₂H₆, and CH₄ have relative higher HTC in relation with CO₂. Also is calculated the recuperator pressure drop. The C₂H₆, CH₄ and N₂ pressure drop is lower in comparison with the CO₂ for the same operating conditions.The energy efficiency in solar power station coupled to Brayton cycle is very constrained by the ambient temperature variation, impacting directly in the dry-cooling system performance. For this reason a Compressor Inlet Temperature (CIT) sensing analysis is carried out ranging from 32 °C to 57 °C, and also varying TIT from 400 °C to 550 °C. A sensing analysis is also developed varying the Turbine Inlet Pressure (TIP) from 200 bar to 375 bar. The CO₂ improves the plant efficiency when increasing the TIP from 250 bar to 350 bar, however the rest of fluids (Ethane, Methane, Nitrogen and Xenon) nearly not suffered any impact in the plant efficiency when increasing the TIP.     

Performance optimization of transcritical CO2 refrigeration cycle with thermoelectric subcooler

Use of thermoelectric subcooler is one of the techniques to improve the performance of transcritical CO₂ cycle. Thermodynamic analyses and optimizations of transcritical CO₂ refrigeration cycle with thermoelectric subcooler are presented in this paper. Further, the effects of various operating parameters on cycle performances are studied. It is possible to optimize current supply, discharge pressure, and CO₂ subcooling simultaneously based on maximum cooling COP for thermoelectrically enhanced transcritical CO₂ refrigeration cycle to get best performance. Results show that thermoelectric current supply, COP improvement, and discharge pressure reduction increase with increase in cycle temperature lift, with maximum values of 11 A, 25.6%, and 15.4%, respectively, for studied ranges. Use of thermoelectric subcooler in CO₂ refrigeration system not only improves the cooling COP, also reduces the system high‐side pressure, compressor pressure ratio, and compressor discharge temperature, and enhances the volumetric cooling capacity. Component‐wise irreversibility distribution shows similar trend with basic CO₂ cycle, although values are lower leading to higher second law efficiency. Cooling capacity may be enhanced by increasing the current supply for the same thermoelectric configuration with penalty of COP. Study reveals that thermoelectrically enhanced CO₂ refrigeration cycle yields significant performance improvement especially for higher‐cycle temperature lift. Copyright © 2011 John Wiley & Sons, Ltd.     

The air membrane-ATR integrated gas turbine power cycle: A method for producing electricity with low CO2 emissions

The air membrane-auto thermal reforming (AM-ATR) gas turbine cycle combines features of the R-ATR power cycle, introduced at the University of Florence, with ceramic, air separation membranes to achieve a novel combined cycle process with fuel decarbonisation and near-zero CO₂ emissions. Within this process, the natural gas fuel is converted to H₂ and CO through the auto thermal reforming process (ATR), i.e. combined partial oxidation and steam methane reforming, within the air separation membrane reactor. In a subsequent process unit, the H₂ content of the reformed fuel is enriched by the well known CO–CO₂ shift reaction. This fuel is then sent to an amine based carbon dioxide removal unit and, finally, to two combustors: the first one is located upstream of the membrane reformer (in order to achieve the required working temperature) and the second one is downstream of the membrane to reach the desired turbine inlet temperature (TIT).The main advantage of the proposed concept over other decarbonisation processes is the coupling of the membrane and the ATR reactor. This coupling greatly reduces the mass flow of syngas with respect to the air blown ATR contained in the previously proposed R-ATR, thus lowering the size of the syngas treatment section. Furthermore, as the oxygen production is integrated at high temperatures in the power cycle, the efficiency penalty of producing oxygen is much smaller than for the traditional cryogenic oxygen separation. The main advantages over other integrated GT-membrane concepts are the lower membrane operating temperature, lower levels of required air separation at high partial pressure driving forces (leading to lower membrane surface areas) and the possibility to achieve a higher TIT with top firing without increasing CO₂ emissions. When compared to power plants with tail end CO₂ separation, the CO₂ removal process treats a gas at pressure and with a significantly higher CO₂ concentration than that of gas turbine exhausts, which allows a compact carbon dioxide removal unit with a lower energy penalty.Starting from the same basis, various configurations were considered and optimised, all of which targeted a 65 MW power output combined cycle. The efficiency level achieved is around 45% (including recompression of the separated CO₂), which is roughly 10% less than the reference GT-CC plant (without CO₂ removal). A significant part of the efficiency penalty (4.3–5.6% points) is due to the fuel reforming, whereas further penalties come from the recompression units, loss of working fluid through the expander and the steam extracted for the ATR reactor and CO₂ separation. The specific CO₂ emissions of the MCM-ATR are about 120 kg CO₂/kWh, representing 30% of the emissions without CO₂ removal. This may be reduced to 10–15% with a better design of the shift reactors and the CO₂ removal unit. Compared to other concepts with air membrane technology, such as the AZEP concept, the efficiency loss is much greater when used for fuel de-carbonisation than for previous integration options.     

The thermodynamic analysis of two-step conversions of CO2/H2O for syngas production by ceria

Due to the challenges of demands on alternative fuels and CO₂ emission, the conversion of CO₂ has become a hot spot. Among various methods, two-step conversion of CO₂ with catalyst ceria (cerium oxide, CeO₂) appears to be a promising way. Solar energy is commonly employed to drive the conversion systems. This article proposes a solar-driven system with fluidized bed reactors (FBR) for CO₂/H₂O conversions. N₂ is used as the gas of the heat carrier. The products of CO/H₂ could be further used for syngas. To evaluate the capability of the system for exporting work, the system was analysed on the basis of the Second Law of Thermodynamics and the reaction mechanism of ceria. Heat transfer barriers in practical situations were considered. The lowest solar to chemical efficiency is 4.86% for CO₂ conversion, and can be enhanced to 43.2% by recuperating waste heat, raising the N₂ temperature, and increasing the concentration ratio. The analysis shows that the method is a promising approach for CO₂/H₂O conversion to produce syngas as an alternative fuel.     

Performance characteristics of refrigeration cycle with parallel compression economization

Thermodynamic analyses and economizer pressure optimizations of ammonia, propane and isobutane‐based refrigeration cycles with parallel compression economization are presented in this article. Energetic and exergetic performance comparisons with transcritical CO₂ cycle are presented as well. Results show that the optimum economizer mass fraction as well as COP improvement increase with increase in cycle temperature lift. The expression for optimum economizer pressure has been developed. Study shows that the performance improvements using parallel compression economization are strongly dependent on the refrigerant properties as well as the operating conditions. Using parallel compression economization, carbon dioxide yields maximum COP improvement of 31.9% followed by propane (29.8%), isobutane (27.2%) and ammonia (11.3%) for studies ranges. In spite of higher COP improvement, the cooling COP as well as second low efficiency for carbon dioxide is still significantly lower than that for others. Component‐wise irreversibility distributions show the similar trends for all refrigerants except CO₂. Employing parallel compression economization in refrigeration cycle not only improves the cooling COP but also increase the compactness of evaporator. Copyright © 2010 John Wiley & Sons, Ltd.     

Thermo-environmental analysis of an open cycle gas turbine power plant with regression modeling and optimization

In this paper, a gas turbine cycle is modeled to investigate the effects of important operating parameters like compressor inlet temperature (CIT), turbine inlet temperature (TIT) and pressure ratio (PR) on the overall cycle performance and CO₂ emissions. Such effects are also investigated on the exergy destruction and exergy efficiency of the cycle components. Furthermore, multiple polynomial regression models are developed to correlate the response variables (performance characteristics) and predictor variables (operating parameters). The operating parameters are then optimized. According to the results, operating parameters have a significant effect on the cycle performance and CO₂ emissions. The largest exergy destruction is found in the combustion chamber with lowest exergy efficiency. The regression models have appeared to be a good estimator of the response variables. The optimal operating parameters for maximum performance have been determined as 288 K for CIT, 1600 K for TIT and 23.2 for PR.     

Parametric optimization design for supercritical CO2 power cycle using genetic algorithm and artificial neural network

Supercritical CO₂ power cycle shows a high potential to recover low-grade waste heat due to its better temperature glide matching between heat source and working fluid in the heat recovery vapor generator (HRVG). Parametric analysis and exergy analysis are conducted to examine the effects of thermodynamic parameters on the cycle performance and exergy destruction in each component. The thermodynamic parameters of the supercritical CO₂ power cycle is optimized with exergy efficiency as an objective function by means of genetic algorithm (GA) under the given waste heat condition. An artificial neural network (ANN) with the multi-layer feed-forward network type and back-propagation training is used to achieve parametric optimization design rapidly. It is shown that the key thermodynamic parameters, such as turbine inlet pressure, turbine inlet temperature and environment temperature have significant effects on the performance of the supercritical CO₂ power cycle and exergy destruction in each component. It is also shown that the optimum thermodynamic parameters of supercritical CO₂ power cycle can be predicted with good accuracy using artificial neural network under variable waste heat conditions.     

An integrated power generation system combining solid oxide fuel cell and oxy-fuel combustion for high performance and CO2 capture

An integrated power generation system combining solid oxide fuel cell (SOFC) and oxy-fuel combustion technology is proposed. The system is revised from a pressurized SOFC-gas turbine hybrid system to capture CO₂ almost completely while maintaining high efficiency. The system consists of SOFC, gas turbine, oxy-combustion bottoming cycle, and CO₂ capture and compression process. An ion transport membrane (ITM) is used to separate oxygen from the cathode exit air. The fuel cell operates at an elevated pressure to facilitate the use of the ITM, which requires high pressure and temperature. The remaining fuel at the SOFC anode exit is completely burned with oxygen at the oxy-combustor. Almost all of the CO₂ generated during the reforming process of the SOFC and at the oxy-fuel combustor is extracted from the condenser of the oxy-combustion cycle. The oxygen-depleted high pressure air from the SOFC cathode expands at the gas turbine. Therefore, the expander of the oxy-combustion cycle and the gas turbine provides additional power output. The two major design variables (steam expander inlet temperature and condenser pressure) of the oxy-fuel combustion system are determined through parametric analysis. There exists an optimal condenser pressure (below atmospheric pressure) in terms of global energy efficiency considering both the system power output and CO₂ compression power consumption. It was shown that the integrated system can be designed to have almost equivalent system efficiency as the simple SOFC-gas turbine hybrid system. With the voltage of 0.752 V at the SOFC operating at 900 °C and 8 bar, system efficiency over 69.2% is predicted. Efficiency penalty due to the CO₂ capture and compression up to 150 bar is around 6.1%.     

Design and thermodynamic analysis of supercritical CO2 reheating recompression Brayton cycle coupled with lead‐based reactor

A reheating process is generally incorporated in a supercritical CO₂ (S‐CO₂) Brayton cycle to enhance its efficiency. The heat transfer process from the reactor coolant to the working fluid of the power cycle is a key issue encountered when designing reheating power systems for the lead‐based reactor. The traditional reheating system, called RH‐1, utilizes an intermediate coolant circuit. In this paper, a novel reheating system, called RH‐2, is proposed. It eliminates the intermediate coolant circuit and combines the processes of the primary heating and reheating in a single heat exchanger. A thermodynamic analysis of three different systems for the lead‐based reactor integrated with the S‐CO₂ power cycle with or without reheating was conducted to evaluate the performance of the proposed system. The results confirmed that the performance of RH‐2 was the best of all the three systems. Under the same reactor conditions, the system efficiency of RH‐2 was greater than those of RH‐1 and the recompression (no reheating) system by 1.2% and 1.7%, respectively. RH‐2 could also maintain higher efficiency when the main operating parameters varied. The efficiency of RH‐2 was higher at different core outlet temperatures and split ratios. The maximum efficiency at optimal maximum pressure of RH‐2 was greater than those of the other two systems. RH‐2 was less sensitive to the variations in the isentropic efficiencies of the components than the other two systems, while the turbine isentropic efficiency demonstrated a significantly higher impact on the system efficiency than the two compressors (approximately 3.8 times).     

Cost numerical optimization of the triple‐pressure steam‐reheat gas‐reheat gas‐recuperated combined power cycle that uses steam for cooling the first GT

Optimization is an important method for improving the efficiency and power of the combined cycle. In this paper, the triple‐pressure steam‐reheat gas‐reheat gas‐recuperated combined cycle that uses steam for cooling the first gas turbine (the regular steam‐cooled cycle) was optimized relative to its operating parameters. The optimized cycle generates more power and consumes more fuel than the regular steam‐cooled cycle. An objective function of the net additional revenue (the saving of the optimization process) was defined in terms of the revenue of the additional generated power and the costs of replacing the heat recovery steam generator (HRSG) and the costs of the additional operation and maintenance, installation, and fuel. Constraints were set on many operating parameters such as air compression ratio, the minimum temperature difference for pinch points (δT_ppm), the dryness fraction at steam turbine outlet, and stack temperature. The net additional revenue and cycle efficiency were optimized at 11 different maximum values of turbine inlet temperature (TIT) using two different methods: the direct search and the variable metric. The optima were found at the boundaries of many constraints such as the maximum values of air compression ratio, turbine outlet temperature (TOT), and the minimum value of stack temperature. The performance of the optimized cycles was compared with that for the regular steam‐cooled cycle. The results indicate that the optimized cycles are 1.7–1.8 percentage points higher in efficiency and 4.4–7.1% higher in total specific work than the regular steam‐cooled cycle when all cycles are compared at the same values of TIT and δT_ppm. Optimizing the net additional revenue could result in an annual saving of 21 million U.S. dollars for a 439 MW power plant. Increasing the maximum TOT to 1000°C and replacing the stainless steel recuperator heat exchanger of the optimized cycle with a super‐alloys‐recuperated heat exchanger could result in an additional efficiency increase of 1.1 percentage point and a specific work increase of 4.8–7.1%. The optimized cycles were about 3.3 percentage points higher in efficiency than the most efficient commercially available H‐system combined cycle when compared at the same value of TIT. Copyright © 2008 John Wiley & Sons, Ltd.     

The effect of capillary-trapped CO2 on oil recovery and CO2 sequestration during the WAG process

This study investigated capillary-trapped CO₂ depending on the consideration of hysteresis effect in relative permeability for various water-alternation-gas (WAG) operating conditions to ascertain the oil production process. From the simulation results of CO₂ WAG flooding method, the trapped CO₂ led to prevent water-flow, in which CO₂ acts as a gas blocker near the well. It caused the injection pressure increase during water injection period. As the trapped CO₂ in pores increased, the reservoir pressure was also increased and maintained above minimum miscibility pressure (MMP). Ultimately, it was concluded that the reservoir was kept under miscible conditions throughout WAG process, reducing residual oil and increasing oil recovery.     

Performance optimization of transcritical CO2 cycle with parallel compression economization

Being a low critical temperature fluid, CO₂ transcritical system offers low COP for a given application. Parallel compression economization is one of the techniques to improve the COP for transcritical CO₂ cycle. An optimization study of transcritical CO₂ refrigeration cycle with parallel compression economization is presented in this paper. Further, performance comparisons of three different COP improvement techniques; parallel compression economization alone, parallel compression economization with recooler and multistage compression with flash gas bypass are also presented for chosen operating conditions. Results show that the parallel compression economization is more effective at lower evaporator temperature. The expression for optimum discharge pressure has been developed which offers useful guideline for optimal system design and operation. Study shows that the parallel compression with economizer is promising transcritical CO₂ cycle modifications over other studied cycle configurations. A maximum improvement of 47.3% in optimum COP is observed by employing parallel compression economization for the studied ranges.     

Exergetic performance and comparative assessment of bottoming power cycles operating with carbon dioxide–based binary mixture as working fluid

This paper presents CO₂-toluene (CO₂-C₇H₈) binary mixture as working fluid to enhance the energetic and exergetic performance of CO₂ bottoming power cycles in warm ambient conditions. A criterion for selection of CO₂-based binary mixture is defined, and 0.9 CO₂/0.1 C₇H₈ composition is decided based on the required minimum cycle temperature compatible with ambient conditions. Bottoming simple regenerative cycle (BSRC) and bottoming preheating cycle (BPHC) configurations are selected, and their realistic operating conditions are determined based on sensitivity analysis. The performance of bottoming cycles using CO₂-C₇H₈ binary mixture is compared with the bottoming cycles using pure CO₂ as working fluid at different ambient temperatures. It is observed that the cycles operating with pure CO₂ can only perform better at lower ambient temperature conditions, whereas, at the increased ambient temperatures, bottoming cycles with CO₂-C₇H₈ binary mixture outperform and produce significant gains in exergetic and energetic performance compared with pure CO₂ bottoming cycles. A maximum gain of exergetic efficiency for BSRC and BPHC observed is 26.83% and 18.71%, respectively, at an operating ambient temperature of 313 K, whereas an overall gain in energetic efficiencies for BSRC and BPHC observed is 28.92% and 10.12%, respectively. Taking into consideration thermodynamic performance, overall UA (product of overall heat transfer coefficient and heat transfer area for the heat exchanger) and specific investment cost, BPHC configuration is suggested as reasonable choice for higher ambient temperature conditions.     

Operating conditions of an open and direct solar thermal Brayton cycle with optimised cavity receiver and recuperator

The small-scale open and direct solar thermal Brayton cycle with recuperator has several advantages, including low cost, low operation and maintenance costs and it is highly recommended. The main disadvantages of this cycle are the pressure losses in the recuperator and receiver, turbomachine efficiencies and recuperator effectiveness, which limit the net power output of such a system. The irreversibilities of the solar thermal Brayton cycle are mainly due to heat transfer across a finite temperature difference and fluid friction. In this paper, thermodynamic optimisation is applied to concentrate on these disadvantages in order to optimise the receiver and recuperator and to maximise the net power output of the system at various steady-state conditions, limited to various constraints. The effects of wind, receiver inclination, rim angle, atmospheric temperature and pressure, recuperator height, solar irradiance and concentration ratio on the optimum geometries and performance were investigated. The dynamic trajectory optimisation method was applied. Operating points of a standard micro-turbine operating at its highest compressor efficiency and a parabolic dish concentrator diameter of 16 m were considered. The optimum geometries, minimum irreversibility rates and maximum receiver surface temperatures of the optimised systems are shown. For an environment with specific conditions and constraints, there exists an optimum receiver and recuperator geometry so that the system produces maximum net power output.     

Performance of a flat-plate solar thermal collector using supercritical carbon dioxide as heat transfer fluid

Energetic and exergetic performance analyses of flat-plate solar collector using supercritical CO₂ have been done in this study. To take care of the sharp change in thermophysical properties in near critical region, the discretisation technique has been used. Effects of zonal ambient temperature and solar radiation, fluid mass flow rate and collector geometry on heat transfer rate, collector efficiency, heat removal factor, irreversibility and second law efficiency are presented. The optimum operating pressure correlation has been established to yield maximum heat transfer coefficient of CO₂ for a certain operating temperature. Effect of metrological condition on heat transfer rate and collector efficiency is significant and that on heat removal factor is negligible. Improvement of heat transfer rate is more predominant than increase in irreversibility by using CO₂. For the studied ranges, the maximum performance improvement of flat-plate solar collector by using CO₂ as the heat transfer fluid was evaluated as 18%.     

Comparative study on the effect of CO2 and H2O dilution on laminar burning characteristics of CO/H2/air mixtures

A study on the effect of CO₂ and H₂O dilution on the laminar burning characteristics of CO/H₂/air mixtures was conducted at elevated pressures using spherically expanding flames and CHEMKIN package. Experimental conditions for the CO₂ and H₂O diluted CO/H₂/air/mixtures of hydrogen fraction in syngas from 0.2 to 0.8 are the pressures from 0.1 to 0.3 MPa, initial temperature of 373 K, with CO₂ or H₂O dilution ratios from 0 to 0.15. Laminar burning velocities of the CO₂ and H₂O diluted CO/H₂/air/mixtures were measured and calculated using the mechanism of Davis et al. and the mechanism of Li et al. Results show that the discrepancy exists between the measured values and the simulated ones using both Davis and Li mechanisms. The discrepancy shows different trends under CO₂ and H₂O dilution. Chemical kinetics analysis indicates that the elementary reaction corresponding to peak ROP of OH consumption for mixtures with CO/H₂ ratio of 20/80 changes from reaction R3 (OH + H₂ = H + H₂O) to R16 (HO₂+H = OH + OH) when CO₂ and H₂O are added. Sensitivity analysis was conducted to find out the dominant reaction when CO₂ and H₂O are added. Laminar burning velocities and kinetics analysis indicate that CO₂ has a stronger chemical effect than H₂O. The intrinsic flame instability is promoted at atmospheric pressure and is suppressed at elevated pressure for the CO₂ and H₂O diluted mixtures. This phenomenon was interpreted with the parameters of the effective Lewis number, thermal expansion ratio, flame thickness and linear theory.     

A comprehensive comparative energy and exergy analysis in solar based hydrogen production systems

In the presented paper, energy and exergy analysis is performed for thermochemical hydrogen (H₂) production facility based on solar power. Thermal power used in thermochemical cycles and electricity production is obtained from concentrated solar power systems. In order to investigate the effect of thermochemical cycles on hydrogen production, three different cycles which are low temperature Mg–Cl, H₂SO₄ and UT-3 cycles are compared. Reheat-regenerative Rankine and recompression S–CO₂ Brayton power cycles are considered to supply electricity needed in the Mg–Cl and H₂SO₄ thermochemical cycles. Furthermore, the effects of instant solar radiation and concentration ratio on the system performance are investigated. The integration of S–CO₂ Brayton power cycle instead of reheat-regenerative Rankine enhances the system performance. The maximum exergy efficiency which is obtained in the system with Mg–Cl thermochemical and recompression S–CO₂ Brayton power cycles is 27%. Although the energy and exergy efficiencies decrease with the increase of the solar radiation, they increase with the increase of the concentration ratio. The highest exergy destruction occurred in the solar energy unit.     

COOLCEP (cool clean efficient power): A novel CO2-capturing oxy-fuel power system with LNG (liquefied natural gas) coldness energy utilization

A novel liquefied natural gas (LNG) fueled power plant is proposed, which has virtually zero CO₂ and other emissions and a high efficiency. The plant operates as a subcritical CO₂ Rankine-like cycle. Beside the power generation, the system provides refrigeration in the CO₂ subcritical evaporation process, thus it is a cogeneration system with two valued products. By coupling with the LNG evaporation system as the cycle cold sink, the cycle condensation process can be achieved at a temperature much lower than ambient, and high-pressure liquid CO₂ can be withdrawn from the cycle without consuming additional power. Two system variants are analyzed and compared, COOLCEP-S and COOLCEP-C. In the COOLCEP-S cycle configuration, the working fluid in the main turbine expands only to the CO₂ condensation pressure; in the COOLCEP-C cycle configuration, the turbine working fluid expands to a much lower pressure (near-ambient) to produce more power. The effects of some key parameters, the turbine inlet temperature and the backpressure, on the systems' performance are investigated. It was found that at the turbine inlet temperature of 900 °C, the energy efficiency of the COOLCEP-S system reaches 59%, which is higher than the 52% of the COOLCEP-C one. The capital investment cost of the economically optimized plant is estimated to be about 750 EUR/kWe and the payback period is about 8–9 years including the construction period, and the cost of electricity is estimated to be 0.031–0.034 EUR/kWh.     

Thermal effects in H2O and CO2 assisted direct carbon solid oxide fuel cells

Thermal effects in a H₂O and CO₂ assisted tubular direct carbon solid oxide fuel cell (DC-SOFC) are numerically investigated. Parametric simulations are further conducted to study the effects of operating potential, the distance between carbon and anode, inlet gas temperature, and anode inlet gas flow rate on the thermal behaviors of the fuel cell. It is found that the fuel cell with H₂O as gasification agent performs considerably better than the cell with CO₂ as gasification agent in all cases. It is also found that the temperature field of the fuel cell is highly uneven. The breakdown of the heat sources in the fuel cell shows that the H₂O assisted DC-SOFC has much higher heat generation and consumption than the CO₂ assisted cell. Interestingly, a thermal neutral voltage is observed, at which no heating or cooling of the cell is needed. In addition, the distance between the anode and the carbon layer is required to be as small as possible, which improves the temperature uniformity of the fuel cell. The results of this study demonstrates the importance of thermal effects in DC-SOFCs and form a solid foundation for DC-SOFC thermal management.