Effects of high-temperature annealing on the microstructure and properties of C/SiC–ZrB2 composites

C/SiC–ZrB₂ composites prepared via precursor infiltration and pyrolysis (PIP) were treated at high temperatures ranging from 1200 °C to 1800 °C. The mass loss rate of the composites increased with increasing annealing temperature and the flexural properties of the composites increased initially and then decreased reversely. Out of the four samples, the flexural strength and the modulus of the specimen treated at 1400 °C are maximal at 216.9 MPa and 35.5 GPa, suggesting the optimal annealing temperature for mechanical properties is 1400 °C. The fiber microstructure evolution during high-temperature annealing would not cause the decrease of fiber strength, and moderate annealing temperature enhanced the thermal stress whereas weakened the interface bonding, thus boosting the mechanical properties. However, once the annealing temperature exceeded 1600 °C, element diffusion and carbothermal reduction between ZrO₂ impurity and carbon fibers led to fiber erosion and a strong interface, jeopardizing the mechanical properties of the composites. The mass loss rate and linear recession rate of composites treated at 1800 °C are merely 0.0141 g/s and 0.0161 mm/s, respectively.     

The effect of Ni additions on the oxidation behaviour of Co–Re–Cr high-temperature alloys

Abstract

The present study focused on the influence of Ni on the microstructure and oxidation behaviour of Co–Re–Cr-based alloys. Alloys with three different Ni contents were tested in laboratory air at 800–1100 °C. A refinement and a reduction of the σ phase volume fraction as well as a change in the matrix microstructure were observed. Thermogravimetric measurements showed that the alloys with higher Ni contents possess a better oxidation resistance when exposed to higher temperatures. All alloys suffered from continuous mass loss during oxidation at 800 °C due to the formation of porous oxides scales, consisting of Co₃O₄, Co(Ni)O and Ni-doped CoCr₂O₄, which allow the evaporation of Re-oxides. At 900–1100 °C, only the alloy with 25 at. % Ni showed parabolic oxidation kinetics after a short period of transient oxidation. This is a result of the fast formation of a protective Cr₂O₃ layer. It was also found that exposure to air at 1000 °C leads to a phase transformation of the bulk material; an oxidation-induced formation of fine hexagonal close-packed (hcp) grains was observed near the oxide scales. It is supposed that the improved oxidation resistance of Ni-containing Co–Re–Cr alloys is a result of enhanced Cr diffusion caused by the Ni addition. The extensive formation of the fcc phase in the alloy matrix had a detrimental effect on the oxidation behaviour of the Ni-containing Co–Re–Cr-based alloys.     

The effect of size of the SiC inclusions in the AlN–SiC composite structure on its electrophysical properties

AlN–SiC–Y₃Al₅O₁₂ composite materials with a high absorption of microwave frequency (27–65 dB/cm) produced by pressureless sintering of mixtures consisting of AlN(2H), Y₂O₃, and SiC (6H) in 46, 4, 50 wt %, respectively, have been studied. The SiC components of the mixtures were used in sizes of 1, 5, and 50 μm. It has been shown that the resistivity of the developed materials depends essentially on the materials structures: sizes of SiC inclusions, distances between them, and state of the interfaces. It has been found that the increase of the SiC inclusions sizes in the material structure from 3 to 7 μm results in the decrease of the resistivity from 10⁴ to 90 Ω·m, and at the decrease of the SiC inclusions sizes from 3 to 0.5 μm there forms a SiC uninterrupted skeleton, which also decreases the resistivity to 210 Ω·m. Thus, composite materials that contain 50 wt % SiC (inclusions sizes of 3 μm) are the most efficient in producing absorbers of microwave radiation. Interlayers of yttrium aluminum garnet, which are located at the SiC grains boundaries, prevent the forming of AlN(2H)–SiC(6H) solid solutions and thus, make it possible to keep high dielectric characteristics of a composite material based on aluminum nitride and afford a high absorption of a microwave radiation.     

An investigation of the effect of SiC particle size on Cu–SiC composites

In this study mechanical properties of copper were enhanced by adding 1 wt.%, 2 wt.%, 3 wt.% and 5 wt.% SiC particles into the matrix. SiC particles of having 1 μm, 5 μm and 30 μm sizes were used as reinforcement. Composite samples were produced by powder metallurgy method and sintering was performed in an open atmospheric furnace at 700 °C for 2 h. Optical and SEM studies showed that the distribution of the reinforced particle was uniform. XRD analysis indicated that the dominant components in the sintered composites were Cu and SiC. Relative density and electrical conductivity of the composites decreased with increasing the amount of SiC and increased with increasing SiC particle size. Hardness of the composites increased with both amount and the particle size of SiC particles. A maximum relative density of 98% and electrical conductivity of 96% IACS were obtained for Cu–1 wt.% SiC with 30 μm particle size.     

Shear strength of the Zn–Sn high-temperature lead-free solders

This study examines the shear strength behavior of the high-temperature Zn–20 wt% Sn, Zn–30 wt% Sn, and Zn–40 wt% Sn solders in the temperature range of 298–425 K. The results showed that increasing the Sn content of the alloys decreases both shear yield stress (SYS) and ultimate shear strength (USS) at all test temperatures. This can be attributed to the higher volume fraction of the softer β-Sn matrix and the eutectic α-Zn + β-Sn structure, which replaces the colonies of the harder α-Zn phase in the microstructure. The high shear strength of these high temperature solder alloys makes them suitable for application in harsh environments.     

The effect of additives on Al2O3–SiO2–SiC–C ramming monolithic refractories

Abstract

The aim of this study is to describe the effect of containing additives on increasing cold crushing strength (CCS) and bulk density (BD) of Al₂O₃–SiO₂–SiC–C monolithic refractories. Two series of carbon containing monolithics were prepared from Iranian chamotte (Samples A) and Chinese bauxite (Samples B), as 65 wt.% in each case together with, 15wt.% SiC-containing material regenerates (crushed sagger), 10 wt.% fine coke (a total of 90% aggregate) and 10 wt.% resole (phenol formaldehyde resin) as a binder. Different types of additives (such as silicon and ferrosilicon metal) are added to a batch of 100 g of mixture and the physical and mechanical properties (such as BD, apparent porosity and CCS) are measured after tempering at 200°C for 2 h and firing at 1100°C and 1400°C for 2h. After low temperature tempering at 200°C, silicon and ferrosilicon contribute to the formation of stronger cross linking in the resulting structure and provides CCS values as high as 65 MPa. After high temperature sintering, at 1400°C, SiC whiskers of nano sized diameter are formed due to the presence of Si and FeSi₂ and increases the CCS values of the refractories as high as 3–4 times in sample containing 6wt.% ferrosilicon metal as additive, compared to the material without additive. The temperature of 1100°C is a transient temperature, used in high temperature sintering.     

The effect of insulation layers on pavement strength during non-freeze–thaw season

This paper examines the effect of integrating insulation layers on pavement strength using falling weight deflectometer testing data conducted on an instrumented test road in Edmonton, Alberta, Canada. The insulated sections of this road consisted of a -metre-thick bottom ash layer and two polystyrene layers at thicknesses of 5 and 10 cm, while the adjacent conventional section functioned as the control section (CS). For the purpose of strength comparison, the effective modulus and structural number of insulated sections were compared to a conventional CS in a non-freeze–thaw season. The durations of pavement freezing, recovering and fully recovered (non-freeze–thaw) periods were established by monitoring the moisture variations in different pavement layers. The results indicated that using insulation layers generally reduces pavement strength, and this reduction is more pronounced in the insulated section with thicker polystyrene.     

The effect of bone ingrowth depth on the tensile and shear strength of the implant–bone e-beam produced interface

New technologies, such as selective electron beam melting, allow to create complex interface structures to enhance bone ingrowth in cementless implants. The efficacy of such structures can be tested in animal experiments. Although animal studies provide insight into the biological response of new structures, it remains unclear how ingrowth depth is related to interface strength. Theoretically, there could be a threshold of ingrowth, above which the interface strength does not further increase. To test the relationship between depth and strength we performed a finite element study on micro models with simulated uncoated and hydroxyapatite (HA) coated surfaces. We examined whether complete ingrowth is necessary to obtain a maximal interface strength. An increase in bone ingrowth depth did not always enhance the bone–implant interface strength. For the uncoated specimens a plateau was reached at 1,500 μm of ingrowth depth. For the specimens with a simulated HA coating, a bone ingrowth depth of 500 μm already yielded a substantial interface strength, and deeper ingrowth did not enhance the interface strength considerably. These findings may assist in optimizing interface morphology (its depth) and in judging the effect of bone ingrowth depth on interface strength.     

The effect of environment on the compression strength of notched CFRP — a fractographic investigation

Compression strength tests were carried out on notched 0° ± 45° CFRP coupons under various environmental conditions. In addition, the fracture of a number of specimens was arrested to minimize post-failure damage and thus facilitate fractographic analysis. The investigation revealed three basic environment-related failure modes. Significant compressive notch sensitivity occurred only under hot-wet conditions and, apart from this condition, laminates in which axial plies were distributed singly were weaker than those in which the 0° plies were in groups of two or three.     

Influence of the brazing parameters on microstructure,residual stresses and shear strength of diamond–metal joints

The reliability and integrity of diamond cutting tools depend on the properties of diamond–metal joints as created by a brazing process. Block-shaped monocrystalline diamonds were brazed onto a steel substrate (X2CrNiMo 18-14-3), using silver–copper based Cusil-ABA™ (Ag–35wt%Cu–1.75wt%Ti) filler alloy. The experimental procedure includes a thorough microstructural investigation of the filler alloy, the determination of the induced residual stresses by Raman spectroscopy as well as the joint’s shear strength utilizing a special shear device. The brazing processes were carried out at 850, 880 and 910 °C for dwell durations of 10 and 30 min, respectively. At the steel interface two interlayers develop. The layers grow with extended dwell duration and higher brazing temperature. The residual stresses only slightly depend on the brazing parameters and exhibit a maximum value of −400 MPa. Unlike the residual stresses, the shear strength strongly depends on the brazing parameters and thus on the microstructure. Three failure modes could be identified; a ductile fracture in the filler alloy, a brittle fracture in the interlayers and a partly shattering of the diamond.     

Investigation the effect of tightening torque on the fatigue strength of double lap simple bolted and hybrid (bolted–bonded) joints using volumetric method

In this research, the effect of the tightening torque on the fatigue strength of 2024-T3 double lap simple bolted and hybrid (bolted–bonded) joints have been investigated experimentally by conducting fatigue tests and numerically by implementing finite element analysis. To do so, three sets of specimens were prepared and each of them subjected to tightening torque of 1, 2.5 and 5 Nm and then fatigue tests were carried out under different cyclic longitudinal load levels. In the numerical method, the effect of the tightening torque on the fatigue strength of the considered joints has been studied by means of volumetric method. To obtain stress distribution around the notch (bolt hole) which is required for the volumetric method, nonlinear finite element simulations were carried out. In order to estimate the fatigue life, the available smooth S–N curve of Al2024-T3 and the fatigue notch factors obtained from the volumetric method were used. The estimated fatigue life was compared with the available experimental test results. The investigation shows that there is a good agreement between the life predicted by the volumetric method and the experimental results for different specimens with a various amount of tightening torques. The results obtained from the experimental analysis showed that the hybrid joints have a better fatigue strength compared to the simple bolted joints. In addition, the volumetric method and experimental results revealed that the fatigue life of both kinds of the joints were improved by increasing the clamping force resulting from the torque tightening due to compressive stresses which appeared around the bolt hole.     

Effect of interfacial shear strength on reliability of strength and fracture process of SiC–Al composite

Abstract

A unidirectional SiC fibre reinforced pure aluminium composite was fabricated by the hot press method. Tensile testing of the SiC–Al was carried out to determine composite and interfacial shear strengths. A Monte Carlo procedure based on the elastic–plastic finite element method, involving the interfacial layer around the fibres, was constructed to simulate the tensile testing and to calculate the strength and Weibull parameters for the SiC–Al composite. The effect of the interfacial shear strength on the composite strength and its reliability is discussed. The results show that the composite strength and the Weibull shape parameter increase with increasing interfacial shear strength. The contribution of the interfacial shear strength to the composite strength and reliability is efficient when the interfacial shear strength is lower than the matrix shear strength. It is concluded that both composite strength and reliability are closely related to the fibre fracture process.     

Study on the reaction mechanism of self-propagating high-temperature synthesis of TiC in the Cu–Ti–C system

The mechanism of the self-propagating high temperature synthesis (SHS) processing in the Cu–Ti–C system was investigated. The reaction sequence and mechanism were explored using combustion front quenching method. The SHS reaction in the Cu–Ti–C system starts with the solid diffusion reaction between Cu and Ti particles, subsequently, the Cu–Ti liquid forms and spreads over C particles. The C particles dissolve into the Cu–Ti liquid, leading to the formation of the Cu–Ti–C ternary liquid, as a result, TiC particulates are gradually precipitated out of the liquid.     

Influence of the accumulated error in thread pitch on the stress–strain state and cyclic strength of threaded joints

Using the finite element method, the analysis of influence of errors in pitch during the thread production on the behavior of stress distribution in stud–nut joints is performed. The value of maximum local stresses in studs of a threaded joint is shown to substantially depend on errors in thread pitch of a stud and a nut. On the basis of the analyses of stresses and strains under cyclic loading, fatigue curves are plotted for the threaded joints having deviations in thread pitch. It is shown that, with a rational selection of the deviation in pitch, the cyclic strength of threaded joints can be considerably increased. The results of analysis agree satisfactorily with the data of fatigue tests of the M39 × 3 threaded joints.     

The effect of Ag additions on the microstructure of aluminium–lithium alloys

Minor quantities of Ag have been added to Al–Li–Cu–Mg–Zr alloys. Their microstructure has been studied by means of optical metallography, transmission electron microscopy and X-ray diffraction. In the high Li, low Cu:Mg ratio alloys the main phases found were , , S and T1, while fewer T2 and Al7Cu2Fe precipitates were also observed. The addition of up to 0.5 wt% Ag diminishes the and T1 precipitates size. This is attributed to a small increase of Li solubility in the matrix. In the low Li, high Cu:Mg ratio alloy the addition of 0.2 wt% Ag resulted in the precipitation of phase simultaneously with , , S and T1 phases. Due to the low Li concentration an unusual growth of the / precipitates at the expense of the precipitates was also observed. © 1998 Kluwer Academic Publishers     

The effect of strontium on the mechanical properties of aluminum–silicon alloy

Technical Physics Letters - We have studied the influence of strontium additives on the microstructure and mechanical properties of an aluminum alloy with 15 wt % silicon prepared by directional...     

The effect of Ag additions on the microstructure of aluminium–lithium alloys

Minor quantities of Ag have been added to Al–Li–Cu–Mg–Zr alloys. Their microstructure has been studied by means of optical metallography, transmission electron microscopy and X-ray diffraction. In the high Li, low Cu : Mg ratio alloys the main phases found were , , S and T₁, while fewer T₂ and Al₇Cu₂Fe precipitates were also observed. The addition of up to 0.5 wt% Ag diminishes the and T₁ precipitates size. This is attributed to a small increase of Li solubility in the matrix. In the low Li, high Cu : Mg ratio alloy the addition of 0.2 wt % Ag resulted in the precipitation of phase simultaneously with , , S and T₁ phases. Due to the low Li concentration an unusual growth of the / precipitates at the expense of the precipitates was also observed.     

The influence of freeze–thaw cycles on the unconfined compressive strength of fiber-reinforced clay

Freeze–thaw cycling is a weathering process that frequently occurs in cold climates. In the freeze state, thermodynamic conditions at temperatures just below 0 °C result in the translocation of water and ice. Consequently, the engineering properties of soils such as permeability, water content, stress–strain behavior, failure strength, elastic modulus, cohesion, and friction angle may be changed. Former studies have been focused on changes in physical and mechanical properties of soil due to freeze–thaw cycles. In this paper, the effect of freeze–thaw cycles on the compressive strength of fiber-reinforced clay is investigated. For this purpose, kaolinite clay reinforced by steel and polypropylene fibers is compacted in a laboratory and exposed to a maximum of 10 closed-system freezing and thawing cycles. The unconfined compressive strength of reinforced and unreinforced specimens is then determined. The results of the study show that for the soil investigated, the increase in the number of freeze–thaw cycles results in the decrease of unconfined compressive strength of clay samples by 20–25%. Moreover, inclusion of fiber in clay samples increases the unconfined compressive strength of soil and decreases the frost heave. Furthermore, the results of the study indicate that fiber addition does not decrease the soil strength against freeze–thaw cycles. Moreover, the study shows that the addition of 3% polypropylene fibers results in the increase of unconfined compressive strength of the soil before and after applying freeze–thaw cycles by 60% to 160% and decrease of frost heave by 70%.