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研究了红糖、葡萄糖、木糖、甲醇和乙酸钠5种不同有机物对纳氏比色法和离子选择电极法测试氨氮的影响。结果表明,红糖、葡萄糖和木糖对纳氏比色法测试氨氮均会造成影响,使得测试结果偏大;在无铵根离子存在时,红糖质量浓度与氨氮的测试浓度线性相关、葡萄糖和木糖质量浓度与氨氮的测试浓度非线性相关;而甲醇和乙酸钠则对纳氏比色法测试氨氮没有影响。实验中采用三氯甲烷萃取+离心法、蒸馏法进行预处理都不能消除其对氨氮测试的影响。但是,采用离子选择电极法测试氨氮时,上述有机物对测试结果并无影响。并对离子选择电极法测试氨氮的测定结果运用SPSS22.0进行了显著性分析,表明不同有机物种类、有机物浓度对离子选择电极法测试氨氮均无显著影响。 相似文献
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用金属有机化合物制备铁电薄膜:工艺及进展 总被引:2,自引:0,他引:2
本文概述了以金属有机化合物为原料制备铁电薄膜的工艺过程、工艺特点及最新研究进展,着重介绍了金属有机物化学气相溶积(MOCVD),金属有机物热分解(MOD)以及溶胶-凝胶(Sol-Gel)三种制备技术在铁电薄膜制备领域中的应用。 相似文献
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利用太阳能光催化技术生产清洁燃料、降解污染物及转化高附加值产品,是解决当前能源短缺和环境污染问题的有效途径。随着对金属卤化物钙钛矿的深入研究,成功开发出一系列能够制备出成分和形貌控制精确、产物均匀性好、结晶度高的钙钛矿量子点的合成方法,使钙钛矿量子点应用到光催化领域中。综述了热注入法、配体辅助再沉淀法、溶剂热法、微波辅助法等金属卤化物钙钛矿量子点的合成方法及金属卤化物钙钛矿量子点在光催化析氢、光催化还原二氧化碳、光催化合成有机物以及光催化降解有机物等方面的研究进展,最后对金属卤化物钙钛矿光催化剂的发展前景进行了展望。 相似文献
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对含茂基有机配合物的合成及表征进行了简单介绍,例举了包括含茂基和四苯基卟啉基钇的有机金属配合物的合成,以及其他类型的有机配合物的合成,藉此探讨一般有机物配合物的合成与表征的共通性。 相似文献
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聚酯工业的进步离不开先进的催化技术。本文对聚酯合成催化体系的研究进展进行了评述。着眼于目前占主导的金属催化剂,对锑、钛、锡、锗、铝等催化剂在活性、副反应等方面所开展的金属复合、配体改性、载体负载等工作进行了总结,介绍了有机物、离子液体、酶等非金属催化体系的研究进展,并对促进聚酯合成的电、光、微波等催化辅助技术进行了评述。催化能力强、副反应少、聚合条件温和催化体系的开发有助于聚酯品质的提升,将先进的表征手段、模型研究以及聚酯构效关系规律探索结合到催化体系的研究中,可加速高效聚酯催化技术的研发。 相似文献
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几种氧化还原电对在间接电氧化合成中的应用 总被引:5,自引:0,他引:5
间接电氧化有机物是有机合成的一个重要方向。本文介绍了间接电化学氧化过程中常用的凡种氧化煤质的电生过程以及它们在间接电氧化合成中的应用,对比了Co3+、Ce3+及Mn3+的氧化活性,指出了适合于用它们来氧化的甲苯衍生物的特征。 相似文献
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C. Renault J. Roche M. R. Ciumag T. Tzedakis S. Colin K. Serrano O. Reynes C. André-Barrès P. Winterton 《Journal of Applied Electrochemistry》2012,42(9):667-677
The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemical area to increase conversion and selectivity, and secondly the shape and size of the microchannels designed for a uniform residence time distribution of the fluid. A heat exchanger is integrated into the microstructured electrode to rapidly remove (or supply) the heat required in exo- or endothermic reactions. The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes. 相似文献
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Despite substantial advancements in thermal and photochemical catalysis, the evolution of similar processes within the realm of organic electrochemistry has seen a slower pace. However, recent years have heralded a remarkable surge in molecular electrocatalysis. This innovative technique harnesses the power of molecular catalysts to expedite electrochemical transformations. This article underscores the application of ferrocene (Fc) as a redox catalyst in organic electrosynthesis. It delves into the extensive utilization of Fc in organic electrosynthesis, particularly emphasizing its role in the electrocatalytic generation and reactions of heteroatom- and carbon-centered radicals, among various other reactions. 相似文献
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P. PICHAICHANARONG R.M. SPOTNITZ R.P. KREH S.M. GOLDFARB J.T. LUNDQUIST 《Chemical Engineering Communications》2013,200(1):119-130
Mediated electrosynthesis is a cyclic process involving electrochemical generation of a redox agent and use of that agent to effect a chemical reaction. This process is applicable to a large number of mediators and chemical substrates. Cerium in particular is an excellent mediator for syntheses of aldehydes and quinones. An ASPEN PLUS process and cost model is presented for the cerium mediated electrosynthesis of 1,4-naphthoquinone from naphthalene. The process involves two-phase reaction, phase separation, liquid-liquid extraction, electrochemical oxidation, and crystallization. The ASPEN PLUS simulator, however, does not include a module for the separation of organic and aqueous electrolyte solutions. Therefore, a liquid-liquid extractor block is developed based on distribution coefficients. The extractor model also accounts for phase entrainments. Stream compositions are controlled by maintaining fixed ratios of component mass flows. Finally, an extremely tight tolerance is required to account for minute quantities of organics in the aqueous stream. The use of the model to identify economically interesting operating conditions is demonstrated. 相似文献
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Current density in an industrial electrosynthesis process carried out in a single flow electrolyser with planar electrodes has been optimized using a model which includes the main electrochemical and economic parameters, as well as process kinetics. Results obtained using different optimization criteria have been compared. Sample calculations have been made for the cathodic reduction of oxalic acid. 相似文献
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P. Pichaichanarong R. M. Spotnitz R. P. Kreh S. M. Goldfarb J. T. Lundquist 《Chemical Engineering Communications》1990,94(1):119-130
Mediated electrosynthesis is a cyclic process involving electrochemical generation of a redox agent and use of that agent to effect a chemical reaction. This process is applicable to a large number of mediators and chemical substrates. Cerium in particular is an excellent mediator for syntheses of aldehydes and quinones. An ASPEN PLUS process and cost model is presented for the cerium mediated electrosynthesis of 1,4-naphthoquinone from naphthalene. The process involves two-phase reaction, phase separation, liquid-liquid extraction, electrochemical oxidation, and crystallization. The ASPEN PLUS simulator, however, does not include a module for the separation of organic and aqueous electrolyte solutions. Therefore, a liquid-liquid extractor block is developed based on distribution coefficients. The extractor model also accounts for phase entrainments. Stream compositions are controlled by maintaining fixed ratios of component mass flows. Finally, an extremely tight tolerance is required to account for minute quantities of organics in the aqueous stream. The use of the model to identify economically interesting operating conditions is demonstrated. 相似文献
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R. M. Spotnitz R. P. Kreh J. T. Lundquist P. J. Press 《Journal of Applied Electrochemistry》1990,20(2):209-215
Methanesulphonic acid has been found to solubilize the Ce(III)/Ce(IV) couple. This makes cerium mediated electrosynthesis practical for commercial production of several carbonyl compounds. Results are presented for the electrochemical generation of Ce(IV) in methanesulphonic acid and for naphthalene oxidation to 1,4-naphthoquinone using Ce(IV). 相似文献
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A combination of electrochemical and microgravimetric techniques, utilizing the electrochemical quartz crystal microbalance (EQCM), has been employed to study the ion transport behavior of polypyrrole films, prepared with a variety of electrolytes, during redox switching. Systems investigated include poly(pyrrole chloride), poly(pyrrole dodecylsulfate), poly{pyrrole-co-[3-(pyrrol-1-y1)propanesulfonate]}, and polypyrrole/Nafion composites. It has been demonstrated that controlled ion transport properties of polypyrrole can be achieved by incorporating properly selected dopant anions into the polypyrrole film during electrosynthesis. 相似文献