离子氮化－PECVD TiN膜复合处理提高切边模具寿命研究

对用于制作冷作模具的两种高速钢W18Cr4V和W6Mo5Cr4V2Al进行离子渗氮－PECVDTiN复合处理,研究了复合处理层的组织与性能特点。结果表明较之单一PECVDTiN,离子渗氮－PECVDTiN复合处理改善膜基界面结合,显著提高膜基结合强度与耐磨性;采用优化的复合处理可提高高速钢制不锈钢六角螺栓切边模使用寿命一倍以上。     

渗氮—气相沉积硬质膜复合处理技术及其发展

阐述了渗氮－气相沉积硬质膜复合处理的设计思想。从渗氮－气相沉积硬质膜复合处理工艺方法的选择、复合处理层组织结构、性能研究等方面介绍了渗氮－气相沉积硬质膜复合处理技术的发展。     

AISI316奥氏体不锈钢低温PC、PN和PC+PN表面硬化处理

对AISI 31 6奥氏体不锈钢进行了低温离子渗碳 (PC)、离子渗氮 (PN)和离子渗碳 +离子渗氮 (PC +PN)双重复合处理 ,处理后的奥氏体不锈钢可以在不降低耐蚀性能的基础上大幅度地提高不锈钢表面硬度和耐磨性。渗入奥氏体晶格中的碳或 (和 )氮可以形成一种碳或 (和 )氮的过饱和固溶体 (S相 ) ,但没有铬的碳化物或 (和 )氮化物析出。由于PC +PN双重复合处理后的奥氏体不锈钢渗层内的最大含氮量位于渗层的外表面 ,而最大的含碳量则位于渗层较深的部位 ,因而经离子双重复合处理后的奥氏体不锈钢的表面既有离子渗氮处理的高硬度 ,又有离子渗碳处理后的高的渗层厚度和较好的硬度梯度等特点。     

急冷法制得的Ni—P非晶体态合金的腐蚀试验

用急冷法制得Ｎｉ－１９Ｐ合金薄带,由Ｘ－射线衍射测试证实制得的是非晶态结构,由失重法及电化学测试评价其耐蚀性,并且与３１６不锈钢,纯Ｎｉ作对比。结果表明,制得的Ｎｉ－１９Ｐ非晶态合金在１ｍｏｌ／Ｌ ＨＣＬ中的耐蚀性比３１６不锈钢及纯Ｎｉ要好,并且处理温度对比非晶态合金的耐蚀性也有影响,略低的加热温度及淬火温度有利于较好的耐蚀性。     

双相不锈钢表面奥氏体高氮层的制备技术

高温渗氮是在奥氏体/铁素体双相不锈钢表面形成奥氏体高氮层的一种有效方法.为了获得氮含量高、组织均匀且适合于后续加工的表面高氮不锈钢层，必须确定合理的高温渗氮工艺.通过优化高温渗氮工艺参数，研究了双相不锈钢高温渗氮过程中加热温度、保温时间、氮气压力等对渗氮效果的影响.结果表明，通过高温高压渗氮可使不锈钢表面形成高氮氮化层，可使双相不锈钢通过渗氮发生表面奥氏体转变，获得组织梯度变化的多相复合不锈钢材料.     

离子氮化—PECVDTiN膜复合处理提高切边模具寿命研究

对用于制作冷作模具的两种高速钢W18Cr4V和W6Mo5Cr4V2Al进行离子渗氮-PECVDTiN复合处理,研究了复合处理层的组织与性能特点,结果表明：较之单一PECVD TiN,离子渗氮-PECVDTiN复合处理改善膜基界面结合,显著提高膜基结合强度与耐磨性;采用优化的复合处理可提高高速钢制不锈钢六角螺栓切边模使用寿命一倍以上。     

固溶渗氮Cr18Mn21钢的耐蚀性研究

采用高纯氮气,在常压下对Cr18Mn21钢进行固溶渗氮处理,研究了固溶渗氮工艺对渗氮层显微组织、厚度、硬度及耐蚀性的影响。利用XRD和光学显微镜研究了Cr18Mn21钢渗氮层相组成及显微组织;利用显微硬度测试仪和电化学工作站测试了Cr18Mn21钢渗氮层的硬度分布和耐腐蚀性。     

QPQ处理对Inconel718镍基合金结构的影响

采用QPQ工艺对Inconel718进行了渗氮处理,渗层的深度受扩散控制,渗层深度∝渗氮时间。XRD测试结果表明温度对渗层深度的影响更明显,氮化处理后Inconel718表面硬度大约是基体的3倍;渗氮层中有CrN相,氮与Cr反应形成CrN。通过SEM观察到渗氮表面出现一些柱状物,渗层和基体之间有一个明显的分界线。     

QPQ处理对Incone1718镍基合金结构的影响

采用QPQ工艺对Inconel718进行了渗氮处理,渗层的深度受扩散控制,渗层深度∝(√渗氮时间).XRD 测试结果表明温度对渗层深度的影响更明显,氮化处理后Inconel718表面硬度大约是基体的3倍;渗氮层中有CrN相,氮与Cr反应形成CrN.通过SEM观察到渗氮表面出现一些柱状物,渗层和基体之间有一个明显的分界线.     

AISI 316L奥氏体不锈钢在阳极电位的活性屏离子渗氮

用活性屏离子渗氮技术对处于阳极电位的AISI 316L奥氏体不锈钢进行低温渗氮处理,并将渗氮层的组织、形貌、相结构、显微硬度和耐蚀性能与在悬浮电位下处理的试样作对比。结果表明,奥氏体不锈钢在两种电位状态下渗氮处理获得了同样的、具有S相结构的单相硬化层。渗层不仅具有高的硬度,还有良好的耐蚀性能。在活性屏离子渗氮过程中,从活性屏上溅射下来的中性S相粒子起着氮载体的作用。活性屏空间粒子的撞击消除了不锈钢表面钝化膜对氮的阻隔作用。     

Microstructure and properties of nitrided layer of titanium plate,produced by simultaneous laser quenching and liquid-nitrogen cryogenics

In the present study, titanium plate was treated by a novel method of laser quenching, simultaneously combined with liquidnitrogen cryogenics(LQLNC). The microstructure and properties of the titanium plate after treatment were investigated by X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, Vickers hardness testing, and friction wear testing.The results show that the treated titanium plate is covered by a nitrided layer with a homogeneous thickness of about 60 μm,while the nitrided layer consists of Ti N and α-Ti phases. Compared to general laser quenching, the LQLNC treatment increases the hardness and wear resistance of the surface-modified layer of the titanium plate. As a result of grain refinement in the nitrided layer, the cracking induced by the rapid solidification of the conventional laser-quenching process has also been effectively solved.     

Bacteria adherence properties of nitrided layer on Ti6Al4V by the plasma nitriding technique

The nitrided layer on Ti6A14V substrate was prepared by the plasma nitriding technique. The sample was characterized by X-ray diffraction （XRD）, glow discharge optical emission spectroscopy （GDOES）, X-ray photoelectron spectroscopy （XPS）, and rough-meter. X- ray diffraction analysis reveals that TiN, Ti2N and Ti phase exist in the nitrided layer subsurface. GDOES analysis shows the thickness of the nitrided layer is about 3 ~tm. XPS analysis shows that there is higher N, lower A1 and lower V in the nitrided layer surface than in the Ti6A14V surface. Rough-meter analysis results show the roughness of the nitrided layer is greater than that of Ti6A14V alloy base. The bacteria adherence property of the nitrided layer on Ti6A14V substrate on the Streptococcus mutans was investigated and compared with that of Ti6A14V alloy by fluorescence microscope. It shows that the nitrided layer inhibits the bacteria adherence.     

Improvement in corrosion resistance of anchor steel by low temperature plasma nitriding

Plasma nitriding was used to improve the corrosion performance of anchor steel. The microstructure, phase constitution, microhardness and corrosion resistance of the nitrided layer were systematically studied. The results show that the nitrided layer is continuous and dense, and consists of Fe4N and Fe3N in the outmost surface. The microhardness of the nitrided sample is improved because of the formation of nitrides in the outer side continuous layer and the inner parts. The nitrided layer on the surface of anchor steel can effectively improve the corrosion resistance of the anchor steel.     

QPQ复合盐浴处理中渗氮温度对35钢渗层形貌和表面性能的影响

QPQ复合盐浴处理技术是一种金属表面化学热处理技术,多年来该技术在国内制造行业得到广泛应用,经QPQ技术处理后的零部件表面可获得良好的耐磨、耐蚀及抗疲劳性。主要研究了渗氮温度对35钢表面性能的影响,从而确定最佳渗氮温度,为实际生产提供工艺参考。结果表明：化合物层深度随渗氮温度的升高而增加,但是化合物层中疏松层厚度也在增加;不同渗氮温度下的渗层截面硬度均呈现先增大后减小的趋势,硬度峰值出现在试样次表层,并且随着温度的升高,硬度峰值有远离表面的趋势;渗氮温度为575℃时试样表面显示了良好的综合性能。     

Ti-6Al-4V基體上氮電弧熔化法制備TiN層的組織及性能

采用直流氮電弧熔化方法在鈦合金(Ti-6Al-4V)基體上原位制備了TiN表面層。采用掃描電子顯微鏡、X射線衍射和顯微硬度儀等分析測試手段對TiN表面層的組織、硬度及摩擦磨損性能等進行了分析。探討了電弧電流對TiN層組織及性能的影響。結果表明:通過氮電弧熔化法制備的TiN層組織為樹枝晶,氮化層中樹枝晶的含量隨著深度的增加而減少,表面層與基體為冶金結合;隨著電弧電流由60A增加到100A,所制備的TiN表面層中樹枝晶的含量增加,表面層的硬度及耐磨性能都提高;當電弧電流為100A時,所制備的TiN表面層的最高硬度可達到1885HV,約為基體硬度的5倍,抗磨損性能也顯著提高。     

离子渗氮层的冲蚀及破坏机理的研究

研究了３８ＣｒＭｏＡｌ、４０Ｃｒ 和灰口铸铁的离子渗氮层的冲蚀性能及破坏机理。讨论了材料的冲蚀与时间、攻角、速度和材料硬度的关系;离子渗氮层的冲蚀破坏机理;材料离子渗氮层呈现微切削和疲劳剥落,有脆性断裂特征,属于应力疲劳断裂;离子渗氮层在冲蚀破坏中可能首先在过渡层产生裂纹。     

The hydro-abrasive erosion wear behavior of duplex-treated surfaces of AISI H13 tool steel

The influence of duplex surface treatments consisting of a DC-pulsed plasma nitriding process and subsequent coatings of CrN and TiAlN deposited by physical vapor deposition(PVD)on AISI H13 tool steel was studied in this article.The treated samples were characterized using metallographic techniques,SEM,EDS,and microhardness methods.Hydro-abrasive erosion wear tests were performed in a specifically designed wear tester in which the samples were rotated in a wear tank containing a mixture of distilled water and ceramic abrasive chips with a fixed rotational speed.The wear rates caused by the abrasive particle impacts were assessed based on accumulated weight loss measurements.The worn surfaces were also characterized using optical microscopy,SEM,and EDS.Microhardness measurements indicated a significant increase in the surface hardness of the duplex-treated samples.The surfaces of the samples with the TiAlN coating were approximately 15 times harder than that of the untreated samples and 3 times that of the plasma nitrided samples.Hydro-abrasive erosion wear results showed that the duplex surface treatments,especially the CrN coating,displayed the highest erosion wear resistance.     

25Cr2MoV钢变温快速深层离子氮化工艺的研究

采用显微硬度计和ｘ射线衍射仪等手段，研究了２５Ｃｒ２ＭｏＶ钢经普通离子氮化和变温快速深层离子氮化新工艺处理后，其氮化层的性能及相组成，结果表明：在相同氮化时间内，变温快速深层离子氮化新工艺能显著地增加材料的有效氮化层深和总氮化层深，提高材料的表面硬度．     

铜合金表面Ti/TiN多层膜的制备、结构及其性能

为了研究多层膜的腐蚀性能,促进多层膜在生产中的应用,采用电弧离子镀技术,通过调整环境N₂和Ar气的时间比例在铜衬底上成功制备了不同调制周期的Ti/TiN多层膜.利用x 射线衍射谱和交流阻抗谱研究了该多层膜的结构和腐蚀性能.表面形貌显示,沉积的Ti/TiN多层膜具有明显的周期性,环境中N2和Ar气的时间比例决定了多层膜的调制周期,N₂气时间越长,多层膜中TiN相层越厚.腐蚀性能测定表明,多层膜的调制周期影响其耐蚀性,当调制周期为550nm时,沉积膜的耐腐蚀性最好.