Natural convection in a vertically divided square enclosure by a solid partition into air and water regions

Numerical analyses of the flow and heat transfer due to buoyancy forces in a square enclosure divided by an impermeable partition between air and water filled chests were carried out using a finite difference technique. The enclosure was heated from left wall and cooled from right, isothermally. Horizontal walls were adiabatic. The partition divided the enclosure into air and water regions. Thus, two cases were examined: left side of partition was filled with air and right side was filled with water (Case I, air-partition-water) and left side was filled with water and right side with air (Case II, water-partition-air). Epoxy was chosen as partition material. Results were obtained for different Grashof numbers (10³  Gr  10⁶), thickness of the partition (0.05  ε  0.2) and location of the partition (0.25  c  0.75). An analytical treatment has been performed for low Grashof numbers. Numerical and analytical results gave an acceptable agreement. It was found that filling of fluid into chests is important for obtaining maximum heat transfer and energy saving. When left chest was filled with air (Case I), higher heat transfer was formed. It was an interesting result that heat transfer decreased with increasing of location of the partition for all values of partition thickness at Case I. On the contrary, heat transfer was a decreasing function of increasing value of location of the partition.     

Entropy production due to free convection in partially heated isosceles triangular enclosures

A numerical analysis of the entropy production has been performed due to natural convection heat transfer and fluid flow in isosceles triangular enclosures with partially heated from below and symmetrically cooled from sloping walls. Governing equations are solved by finite difference method. Governing parameters on flow and temperature fields are Rayleigh number (10³  Ra  8.8 × 10⁵), dimensionless length of heater (0.25  (ℓ′ = ℓ/L)  1.0), dimensionless location of heater (0.25  (c′ = c/L)  0.75) and inclination angle of slopping walls (30°  β  60°). Heat transfer results are presented in terms of local and mean Nusselt numbers (Nu) while entropy production results are shown with entropy production number (N_s) and Bejan number (Be). Isotherms, streamlines, contours of entropy production due to heat transfer and fluid friction irreversibility are plotted. It is observed that entropy production number increases but Bejan number decreases with increasing of Rayleigh number. However, both entropy production due to heat transfer and fluid friction irreversibility are affected by higher inclination angle of triangle and length of heater.     

Enhanced heat transfer in inclined solar chimneys by electrohydrodynamic technique

Heat transfer enhancement of natural convection inside the inclined solar chimneys is investigated using electrohydrodynamic technique. The interactions between electric field, flow field, and temperature field are analyzed. The ranges of parameters considered are 10⁴Ra10⁷, 7.5 kVV₀17.5 kV, 30°θ120°, and 2aspect ratio14. Flow and heat transfer enhancements are significantly influenced at low Rayleigh number. The optimum inclined angle which obtains maximum volume flow rate and heat transfer is found to be at θ=60°. A maximum volume flow rate enhancement is expressed in relation with the number of electrodes. The relation between aspect ratio of chimney and number of electrodes that performs the optimum condition between efficiency and economy is analyzed incorporating with all concerning parameters.     

The growth kinetics and optical confinement studies of porous Si for application in terrestrial Si solar cells as antireflection coating

The mesoporous porous-silicon (PS) layers were grown on 1 0 0, 1 1 0, and 1 1 1 oriented wafers at constant current density of 20 mA cm⁻². The pore sizes and surface morphologies were measured by atomic force and scanning electron microscopes. The thickness x of the PS formed and the refractive index were measured by an ellipsometer as a function of time duration t (in min) of anodization. The x vs. t data were fitted into a power law x=at^c where c is a dimensionless constant and growth kinetics was established. The growth is practically independent of orientation. This is due the reason that the growth rate is controlled largely by the availability of holes which exchange their charge with oxidizing species and desirably large concentrations of holes were available at current density of 20 mA cm⁻². For a similar reason the growth of PS layer on the front surface of the n⁺ region of n⁺–p solar cells could also be done at current density of 20 mA cm⁻² nearly at the same rate. A large concentration of holes could be injected from p region into the n⁺ region because the positive contact was made on the p side and thus the junction was forward biased. The PS ARC of thickness 70 nm showed increase 26% in the short circuit current density J_sc and 24% in efficiency of the cells. However, the improvement in the values of the open circuit voltage V_oc were lower than the expected value indicating that the PS layers had enhanced recombination of minority carriers at the front surface or in the front emitter region immediately below the PS layer.     

Numerical analysis of natural convection in an inclined trapezoidal enclosure filled with a porous medium

A theoretical study of buoyancy-driven flow and heat transfer in an inclined trapezoidal enclosure filled with a fluid-saturated porous medium heated and cooled from inclined walls has been performed in this paper. The governing non-dimensional equations were solved numerically using a finite-difference method. The effective governing parameters are: the orientation or inclination angle of the trapezoidal enclosure , which varies between 0° and 180°, the Rayleigh number Ra, which varies between 100 and 1000, the side wall inclination angle θ_s and the aspect ratio A. The side wall inclination parameter θ_s is chosen as 67°, 72° and 81° and the calculations are tested for two different values of A=0.5 and 1.0. Streamlines, isotherms, Nusselt number and flow strength are presented for these values of the governing parameters. The obtained results show that inclination angle is more influential on heat transfer and flow strength than that of the side wall inclination angle θ_s. It is also found that a Bénard regime occurs around =90°, which depends on the inclination of the side wall, Rayleigh number and aspect ratio.     

Mixed convective heat transfer in rectangular enclosures driven by a continuously moving horizontal plate

The fluid flow and heat transfer induced by the combined effects of the mechanically driven lid and the buoyancy force within rectangular enclosures were investigated in this work. The fluid filled enclosures are heated and lid-driven either on the upper or on the lower horizontal wall, thermally isolated on the right vertical wall, and cooled on the other walls. The basis of the investigation was the numerical solutions of the equations for the conservation of mass, momentum, and energy transport using the finite difference method. The effects of the flow governing parameters including the Richardson and the Prandtl numbers, and the length-to-height aspect ratio, respectively, in the range 10⁻²  Ri  10², 10⁻³  Pr  10, and 1  AR  4 for a fixed Reynolds number, Re = 100, were studied. The results are presented in the form of the hydrodynamic and thermal fields, and the profiles for vertical and horizontal components of velocity, temperature, and the local heat flux. The fluid flow and energy distributions within the enclosures and heat flux on the heated wall are enhanced by the increase in the Richardson number. While an increase in the Prandtl number improves the heat flux on the heated wall, an increase in aspect ratio suppresses it. The results can be used as base line data in the design of systems in which mixed convection heat transfer in rectangular enclosures occurs.     

Influence of hydrogen dilution on structural, electrical and optical properties of hydrogenated nanocrystalline silicon (nc-Si:H) thin films prepared by plasma enhanced chemical vapour deposition (PE-CVD)

Hydrogenated nanocrystalline silicon (nc-Si:H) thin films were deposited from pure silane (SiH₄) and hydrogen (H₂) gas mixture by conventional plasma enhanced chemical vapour deposition (PE-CVD) method at low temperature (200 °C) using high rf power. The structural, optical and electrical properties of these films are carefully and systematically investigated as a function of hydrogen dilution of silane (R). Characterization of these films with low angle X-ray diffraction and Raman spectroscopy revealed that the crystallite size in the films tends to decrease and at same time the volume fraction of crystallites increases with increase in R. The Fourier transform infrared (FTIR) spectroscopic analysis showed at low values of R, the hydrogen is predominantly incorporated in the nc-Si:H films in the mono-hydrogen (SiH) bonding configuration. However, with increasing R the hydrogen bonding in nc-Si:H films shifts from mono-hydrogen (SiH) to di-hydrogen (SiH₂) and (SiH₂)_n complexes. The hydrogen content in the nc-Si:H films decreases with increase in R and was found less than 10 at% over the entire studied range of R. On the other hand, the Tauc's optical band gap remains as high as 2 eV or much higher. The quantum size effect may responsible for higher band gap in nc-Si:H films. A correlation between electrical and structural properties has been found. For optimized deposition conditions, nc-Si:H films with crystallite size 7.67 nm having good degree of crystallinity (84% ) and high band gap (2.25 eV) were obtained with a low hydrogen content (6.5 at%). However, for these optimized conditions, the deposition rate was quite small (1.6 Å/s).     

X-ray scattering measurements on nanosized TiO2 micelles

Titanium dioxide, micelles on glass substrate were generated in situ in a water-in-oil (w/o) microemulsion composed of water, dioctyl sulfosuccinate sodium salt (AOT), and cyclohexane, by controlled hydrolysis of TiCl₄. The average grain size R, obtained by grazing-incidence small-angle X-ray scattering (GISAXS), was 6.3±0.8 nm. “Corrected specific surface” of TiO₂ micelles was determined as 5.0×10⁵ cm⁻¹. The average grain size R of 5.0±1.3 nm obtained by grazing-incidence wide-angle X-ray scattering (GIWAXS) agrees with GISAXS value. GIWAXS can detect smaller amounts of additional phases or impurities than classical X-ray diffraction equipment.     

Ruthenium oxide films for selective coatings

Although commercial selective surfaces are already available, investigation on different deposition methods and materials still goes on at many laboratories. In this work, ruthenium oxide films upon metallic substrates are assessed for this usage. Deposition of the films was made at room temperature by either spraying or dipping method in a ruthenium chloride alcoholic solution. After deposited on titanium substrates, the films were heat-treated at temperatures between 450 and 500 °C. When deposited on no-polished substrates, such films not only exhibit a high solar absorptance (α0.98), but also a high infrared emittance (ε0.8), which yield a low selectivity (S=α/ε=1.2). By deposition of similar films on polished substrates, absorptance decreases (α0.74), but emittance significantly decreases as well (ε0.12), resulting in a net selectivity increase (S6). On the other hand, evaporating a thin (20 nm) gold film upon the surface of a coating on a no-polished substrate also improves noticeably its emittance value (ε0.16) and a lower decrease in absorptance is achieved (α0.91), resulting in a selectivity increase (S5.7). These preliminary promising results indicate the high potential for using these films as solar selective coatings, but in order to optimize such selectivity values, further work to establish a close control on the deposition parameters and the substrate roughness value, should be done.     

Solid-state dye-sensitized photocell based on pentacene as a hole collector

A solid-state dye-sensitized photovoltaic cell consisting of vacuum deposited pentacene onto ruthenium dye-coated TiO₂ electrode doped with iodine was fabricated. Cell delivers a short-circuit current of 3.6 mA cm⁻² and an open-circuit voltage of 415 mV at 100 mW cm^–2 (1.5 air mass). The efficiency and the fill factors of the above cell are 0.8% and 0.5%, respectively. Studies of the photocurrent action spectra showed that the dye is mainly responsible for this photocurrent generation. Preliminary results under extended illumination suggested that “long term” stability of the cell is promising.     

Heat and fluid flow resulting from the chimney effect in a symmetrically heated vertical channel with adiabatic extensions

An experimental study on a channel-chimney system was carried out in order to elucidate the behavior of heat transfer and fluid flow. The results are presented in terms of local air temperature measurements inside the symmetrically heated channel and between the adiabatic extensions. Different fluid motion regions are observed inside the chimney. Inflows of air are detected in the lower extension ratio, particularly for large values of the ratio of the width of chimney to that of the heated channel. Some typical configurations show the presence of a vortex structure for an expansion ratio greater than one close to the corner regions in the chimney. Some monomial correlation equations between the local Nusselt number, the channel Rayleigh number and the geometric parameters are proposed. The dimensionless parameters are in the following ranges: 10²Ra^*(B/b)10⁶; 1.5L/L_h4.0; 1.0B/b4.0, in which L is the total height of the system, L_h is the height of the heated channel, B is the width of the chimney and b is the width of the heated channel. A good agreement between the correlation and the experimental data is observed.     

Electrical and optical properties of highly conducting CdO:F thin film deposited by sol–gel dip coating technique

Highly conducting fluorine-doped cadmium oxide (CdO:F) thin films were deposited by sol–gel dip coating technique on glass and Si substrates. F concentration in the films was varied from 2.0% to 13.8% as determined from energy dispersive X-ray analysis. X-ray diffraction pattern showed that the films were polycrystalline in nature. The optimum F concentration for obtaining maximum conductivity was found to be 9.7%. The corresponding electrical conductivity was found to be 1.088×10⁴ S/cm and mobility 60.41 V/cm². Analysis of UV-VIS-NIR spectrum of the film with F concentration 9.7% showed a direct band gap energy of 2.3 eV.     

Energy analysis of silicon solar cell modules based on an optical model for arbitrary layers

An optical model for arbitrary layers is developed and a one-dimensional steady-state thermal model is applied to analyze the energy balance of silicon solar cell modules. Experimental measurements show that simulations are in good agreement, with a maximum relative error of 8.43%. The wind speed v_wind, ambient temperature T_amb and irradiance G are three main factors influencing the temperature of a photovoltaic panel. Over the course of a day the electrical output is reduced by the module temperature to only 32.5% of the rated value. Optical studies reveal that before 8:00 hours and after 16:00 hours, significant incident energy is lost by reflection because of the large angle of incidence θ_in, while at other times of day optical losses are nearly the same due to only small changes of transmission for θ_in < 45°. In addition, some optical losses result from the mismatched refractive indexes of encapsulating materials, especially at the ethylene-vinyl-acetate (EVA)/anti-reflection coating (ARC) and the ARC/Si interfaces. The uses of SiO₂ and TiO₂ as ARC materials for un-encapsulated and encapsulated Si solar cells are investigated by simulation. Comparing the results indicates that TiO₂ as ARC reduces the reflective optical loss within λ = 0.4–1.1 μm after encapsulation, while SiO₂ as ARC increases the loss by 5%. Energy allotment analysis shows that from 9:00 to 15:00, the reflective and transmissive optical losses are relatively steady at 26% and 13% of the incident energy, while the convective and radiative heat losses account for a further 30% and 24%, respectively. Thus, only 7% of incident energy is converted to electrical power.     

A note on fast protonic solid state electrochromic device: NiOx/Ta2O5/WO3−x

In the present investigation, the electrochromic properties of a fast protonic solid state device: NiO_x/Ta₂O₅/WO_3−x prepared at room temperature (300 K) is reported. The non-stoichiometric tungsten oxide thin film is prepared by reactive DC magnetron sputtering technique on ITO coated glass; the oxides of tantalum (300 nm) and nickel (100 nm) are prepared by electron beam evaporation. This proton device has a coloration efficiency of 82.4 cm²/C and coloration and bleaching time of 6 and 5 s, respectively, and a transmittance variation of 60%. The work function of WO_3−x thin films by Kelvin probe in uncolored and colored states are 4.73 and 4.30 eV, respectively.     

Miniaturization limits for single-chamber micro-solid oxide fuel cells with coplanar electrodes

Single-chamber solid oxide fuel cells with coplanar microelectrodes were operated in methane–air mixtures (R_mix = 2) at 700 °C. The performance of cells with one pair of NiO–YSZ (yttria stabilized zirconia) anode and (La_0.8Sr_0.2)_0.98MnO₃–YSZ cathode, arranged parallel on a YSZ electrolyte substrate, was found to be significantly dependent on the electrode width. For an interelectrode gap of 250 μm, cells with average electrode widths exceeding 850 μm could establish a stable open circuit voltage (OCV) of 0.8 V, while those with widths less than 550 μm could not establish any OCV. In the intermediate range, the cells exhibited significant fluctuations in voltage and power under our testing conditions. This behavior suggests that a lower limit to electrode dimensions exists for cells with single electrode pairs, below which neither a stable difference in oxygen partial pressure, nor an OCV, can be established. Conversely, increasing the electrode width imposes a penalty in the form of an increase in the cell resistance. However, both size limits can be circumvented by employing multiple pairs of microscale electrodes in an interdigitated configuration.     

Organic photovoltaic devices based on polythiophene films electrodeposited on FTO substrates

We investigated photovoltaic devices based on electrochemically deposited monolayer of neat polythiophene (PT) films onto fluorine-doped tin oxide (FTO)/glass substrates. The photo-electrical behavior of these devices, using FTO and aluminum as electrodes, presented symbatic and antibatic response. These devices presented V_oc700 mV, under monochromatic irradiation (λ=610 nm; 1 W/m²) and the Incident Photon Converted to Electron Efficiency (IPCE) around 5%, with illumination through the FTO electrode (λ=610 nm; 1 W/m²). Cyclic voltammogramms and optical measurements were used to estimate the PT HOMO and LUMO energy levels, as well to demonstrate that the potential synthesis did not produce any polymer degradation. Using the Schottky model expression in the dark current voltage characteristics it was possible to obtain the barrier height value (_b), for the interface PT/Al. The _b was quite near to the difference between the aluminum work function and the PT electronic affinity and coherent with the V_oc values.     

Structural and transport evolution in the LixAg2V4O11 system

We investigated the effect of inserting lithium into Ag₂V₄O₁₁ (-SVO) on the structure, electronic properties and redox committed by combining in situ XRD measurements, ESR spectroscopy and 4 probes DC conductivity coupled with thermopower measurements. The electrochemical discharge occurs in three consecutive steps above 2 V (vs. Li⁺/Li). The first one, between 0 < x < 0.7 in Li_x-SVO, has been ascribed to the V⁵⁺ reduction through a solid solution mechanism. This reduction competes with a Li⁺/Ag⁺ displacement reaction which leads to a structural collapse owing to the ionic radii mismatch between the withdrawn Ag⁺ and the inserted Li⁺. The silver reduction progresses continuously with two different slopes along two composition–potential plateaus at 2.81 V and 2.55 V. Finally, the reduction continues until we obtain an amorphous structure with V⁴⁺ and a of V³⁺. Although, the silver re-enters the structure during the subsequent recharge, the original structure is not recovered. The reduction of silver forming silver metal nano-clusters acts to increase the electronic conductivity from 3.8 × 10⁻⁵ S cm⁻¹ to 1.4 × 10⁻³ S cm⁻¹. In complement to this study, we also report on a low temperature hydro-(solvo)-thermal approach using HF_(aq) as a mineralizer, which enables the synthesis of nano-sized -SVO particles that exhibit superior electrochemical performances compared to conventional particles synthesized by solid-state reaction.     

Analytic solutions for the geometric and optical properties of stationary compound parabolic concentrators with fully illuminated inverted V receiver

Stationary low concentrator collectors (C < 2), of the CPC type, are of great interest to supply thermal energy for industrial processes, at temperatures below or around 90 °C. In particular, concentrators with fully illuminated inverted V absorbers have attractive properties for thermal energy production. Two classes of CPC’s with inverted V absorber are identified, according to the relationship between the vertex angle of the absorber (γ) and the acceptance angle of the cavity (θ_a), (γ  θ_a) or (γ < θ_a). The first class of CPC’s (γ  θ_a) converge to the fully illuminated CPC with horizontal flat receiver when (γ = 90°). The second class of CPC’s (γ < θ_a) converge to the fully illuminated CPC with vertical flat receiver when (γ = 0°). Both limiting cases have been published in the technical literature. This paper analyzes the class of concentrators satisfying (γ  θ_a). The ideal concentrator corresponding to a fully illuminated wedge absorber and (γ  θ_a) is a circular involute plus three parabolic segments. Closed-form analytic solutions are derived for its geometric and optical properties: reflector geometry, aperture, height, reflector length, angular acceptance function and average number of reflections for any degree of truncation. The equations obtained can be used as important design tools, for simulation techniques and optimization purposes. The collectible energy for North–South and East–West oriented collectors, for various receiver vertex angle and acceptance angle, was calculated. A cost-benefit figure, given by the relationship between collectible energy and reflector surface, is also estimated. Numerical results for any degree of cavity truncation are presented. As the degree of truncation varies, a clear minimum of the length over aperture ratio (L/A) occurs. The geometric and optical characteristics of different low concentration CPC’s (C, between 1 and 2, range of interest of stationary concentrators) show that the cavities with the minimal relationship between the length or height of the reflector surface and the aperture, (L/A) and (H/A), and the lower average number of reflections n correspond to the lowest angular acceptance concentrator (highest nominal concentration). If a concentration of 1.2 is desired, then the smallest ratios of (L/A), (H/A) and n, within the set of concentrators with maximal concentration (C) between 1 and 2, occur for (C = 2) (nominal acceptance half angle θ_a = 30°). Collectible energy results together with a cost-benefit relationship enable to conclude that a good choice for a well-designed collector for the city of Recife-PE, Brazil is: (a) East–West orientation; (b) receiver vertex angles (γ) of the order of (65°); (c) acceptance angle of the CPC (θ_a = 30°) and (d) concentration of the truncated cavity (C_t) in the interval (1.0–1.2).     

p-OXA-X: A new Oligo photosensitizer for organic solar cells

A two-dimensional conjugated oligo p-phenylenevinylene-based photoactive electron donor (p-OXA-X) has been utilized for harvesting incident light and transferring electrons to generate charge carriers in PCBM-based solar cells demonstrating AM1.5 efficiencies of 0.6% and IPCE values of 27% at 400 nm. Nanoscale morphology variations induced in the photoactive layer by varied processing conditions were studied by a combination of SEM, AFM, and profilometry showing that thinner films with minimal surface roughness provided the best photovoltaic performance.     

Thermoeconomic analysis of a novel zero-CO2-emission high-efficiency power cycle using LNG coldness

This paper presents a thermoeconomic analysis aimed at the optimization of a novel zero-CO₂ and other emissions and high-efficiency power and refrigeration cogeneration system, COOLCEP-S (Patent pending), which uses the liquefied natural gas (LNG) coldness during its revaporization. It was predicted that at the turbine inlet temperature (TIT) of 900 °C, the energy efficiency of the COOLCEP-S system reaches 59%. The thermoeconomic analysis determines the specific cost, the cost of electricity, the system payback period and the total net revenue. The optimization started by performing a thermodynamic sensitivity analysis, which has shown that for a fixed TIT and pressure ratio, the pinch point temperature difference in the recuperator, ΔT_p1, and that in the condenser, ΔT_p2 are the most significant unconstrained variables to have a significant effect on the thermal performance of novel cycle. The payback period of this novel cycle (with fixed net power output of 20 MW and plant life of 40 years) was 5.9 years at most, and would be reduced to 3.1 years at most when there is a market for the refrigeration byproduct. The capital investment cost of the economically optimized plant is estimated to be about 1000 $/kWe, and the cost of electricity is estimated to be 0.34–0.37 CNY/kWh (0.04 $/kWh). These values are much lower than those of conventional coal power plants being installed at this time in China, which, in contrast to COOLCEP-S, do produce CO₂ emissions at that.