The potential of hydrogen production from high and low-temperature electrolysis methods using solar and nuclear energy sources: the transition to a hydrogen economy in Brazil

Brazil has great potential for diversification and decarbonization of its energy matrix, with the insertion of a clean and renewable energy source such as hydrogen. This paper seeks to evaluate the surplus energy potential of solar and nuclear plants installed in the country for the production of green and purple hydrogen using high and low temperature electrolysis methods. Based on official reports and databases of energy production and demand, the results indicated that the total potential of surplus solar energy is equal to 4.29E+07 (kWh.d^?1). Further, the total potential of electricity production from the hydrogen obtained through surplus solar energy was equivalent to1.87E+07 (kWh.d^?1); and the total cost of producing solar hydrogen is equal to 1.07E+03 (USD.kWh^?1). In conclusion, the study contributed to demonstrate the pathways to the establishment of strategies that assist the transition to a hydrogen economy in Brazil.     

Generation of green hydrogen using self-sustained regenerative fuel cells: Opportunities and challenges

The ever-increasing energy demand, depleting fossil fuel reserves, and rising temperatures due to greenhouse gas emissions have necessitated the transition towards the generation of green and clean energy through renewable energy sources. Solar energy is one such renewable energy source that has received significant attention owing to its abundance and inexhaustibility. However, solar energy alone cannot replace fossil fuels in the energy portfolio. There exists a need to develop another clean energy source that can potentially act as an alternative to conventional fuels. Hydrogen proves to be an ideal candidate in this domain and can be sustainably generated by water electrolysis by powering the electrolyzer using solar energy. The hydrogen thus synthesized has net zero carbon emissions and is a suitable asset for decarbonizing the environment. This review encompasses the generation of hydrogen using PV-Electrolyzer systems and addresses the challenges associated with the same. Overcoming these drawbacks can ensure a strong position for hydrogen as an alternative fuel in the energy infrastructure. By employing electrolyzers that are fueled by renewable energy and then using that hydrogen to feed a fuel cell, this study aims to clarify the potential and constraints of producing green hydrogen. Since this area of research has not yet been fully investigated, a review article that enables and encourages academics to develop original solutions is urgently needed.     

Hydrogen production by methanol aqueous electrolysis using photovoltaic energy: Algerian potential

Hydrogen is considered as the most promising energy carrier for providing a clean, reliable and sustainable energy system. It can be produced from a diverse array of potential feed stocks including water, fossil fuels and organic matter. Electrolysis is the best option for producing hydrogen very quickly and conveniently. Water electrolysis as a source of hydrogen production has recently gained much attention since it can produce high purity hydrogen and can be compatible with renewable energies. Besides the water electrolysis, aqueous methanol electrolysis has been reported in several studies. The aqueous methanol electrolysis proceeds at much lower voltage than that with the water electrolysis. As a result of the substantially lower operating voltage, the energy efficiency for methanol electrolysis can be higher than that for water electrolysis. In this paper, we are interesting to methanol electrolysis in order to produce hydrogen. The relation linking hydrogen production rate to the power needed to electrolyse a unit volume of aqueous methanol solution has been determined. Using this relation, the potential of hydrogen from aqueous methanol solution using a PV solar as the energy system has been evaluated for different locations in Algeria.     

Power management control for off-grid solar hydrogen production and utilisation system

Climate change concerns, increasing global energy demand, coupled with pending peak supply of fossil fuels, calls for development of new power source. The rapid price drops for solar technologies and combined with international and national policy changes makes solar energy more affordable and accessible for widespread adoption. Solar energy also contributes towards the reduction of greenhouse gas emissions. The combination of electrolysis of water and fuel cells, which use hydrogen as an energy carrier extends the utility of the solar energy. For an integrated solar powered hydrogen production, storage and utilisation system, one of the elements that needs to be designed carefully is the power management system. Power management strategy has a complex function in this type of solar hydrogen system. This paper presents a power management strategy based on fuzzy logic technology to address the problems.     

Hydrogen from solar energy,a clean energy carrier from a sustainable source of energy

Solar energy is going to play a crucial role in the future energy scenario of the world that conducts interests to solar-to-hydrogen as a means of achieving a clean energy carrier. Hydrogen is a sustainable energy carrier, capable of substituting fossil fuels and decreasing carbon dioxide (CO₂) emission to save the world from global warming. Hydrogen production from ubiquitous sustainable solar energy and an abundantly available water is an environmentally friendly solution for globally increasing energy demands and ensures long-term energy security. Among various solar hydrogen production routes, this study concentrates on solar thermolysis, solar thermal hydrogen via electrolysis, thermochemical water splitting, fossil fuels decarbonization, and photovoltaic-based hydrogen production with special focus on the concentrated photovoltaic (CPV) system. Energy management and thermodynamic analysis of CPV-based hydrogen production as the near-term sustainable option are developed. The capability of three electrolysis systems including alkaline water electrolysis (AWE), polymer electrolyte membrane electrolysis, and solid oxide electrolysis for coupling to solar systems for H₂ production is discussed. Since the cost of solar hydrogen has a very large range because of the various employed technologies, the challenges, pros and cons of the different methods, and the commercialization processes are also noticed. Among three electrolysis technologies considered for postulated solar hydrogen economy, AWE is found the most mature to integrate with the CPV system. Although substantial progresses have been made in solar hydrogen production technologies, the review indicates that these systems require further maturation to emulate the produced grid-based hydrogen.     

Optimal sites selection of oil-hydrogen combined stations considering the diversity of hydrogen sources

The popularity of hydrogen refueling stations in China is hindered by unreasonable site selection and high initial costs. Built gas stations with large consumer groups and reasonable locations can be expanded into oil-hydrogen combined stations. which can effectively reduce construction costs and approval complexity, improve hydrogenation infrastructure and reduce hydrogenation costs. Taking Chinese social-economic environment into consideration, this paper created an optimal site selection decision framework for oil-hydrogen combined stations to achieve the goal of reducing construction costs, transportation costs and carbon emissions in the whole process. A two-stage criteria system including veto criteria system and evaluation criteria system was established, and fuzzy analytic hierarchy process (AHP) method and TOmada De decis ão Interativa Multicritério (TODIM) method were utilized to determine the criteria weight and obtain the ranking of alternatives respectively. Finally, a case study was conducted and the most suitable gas station site for the construction of oil-hydrogen combined station was determined. Moreover, the economics of the several hydrogen sources were discussed from the perspective of best site selected, it is concluded that hydrogen from natural gas or coal is still the best hydrogen source for oil-hydrogen combined stations.     

Resource assessment for green hydrogen production in Kazakhstan

Kazakhstan has long been regarded as a major exporter of fossil fuel energy. As the global energy sector is undergoing an unprecedented transition to low-carbon solutions, new emerging energy technologies, such as hydrogen production, require more different resource bases than present energy technologies. Kazakhstan needs to consider whether it has enough resources to stay competitive in energy markets undergoing an energy transition. Green hydrogen can be made from water electrolysis powered by low-carbon electricity sources such as wind turbines and solar panels. We provided the first resource assessment for green hydrogen production in Kazakhstan by focusing on three essential resources: water, renewable electricity, and critical raw materials. Our estimations showed that with the current plan of Kazakhstan to keep its water budget constant in the future, producing 2–10 Mt green hydrogen would require reducing the water use of industry in Kazakhstan by 0.6–3% or 0.036–0.18 km³/year. This could be implemented by increasing the share of renewables in electricity generation and phasing out some of the water- and carbon-intensive industries. Renewable electricity potential in South and West Kazakhstan is sufficient to run electrolyzers up to 5700 and 1600 h/year for wind turbines and solar panels, respectively. In our base case scenario, 5 Mt green hydrogen production would require 50 GW solar and 67 GW wind capacity, considering Kazakhstan's wind and solar capacity factors. This could convert into 28,652 tons of nickel, 15,832 tons of titanium, and many other critical raw materials. Although our estimations for critical raw materials were based on limited geological data, Kazakhstan has access to the most critical raw materials to support original equipment manufacturers of low-carbon technologies in Kazakhstan and other countries. As new geologic exploration kicks off in Kazakhstan, it is expected that more deposits of critical raw materials will be discovered to respond to their potential future needs for green hydrogen production.     

On the splitting of water

Future energy needs and requirements in manufacturing processes (like fertilizers, synfuels, etc.) makes hydrogen an important chemical commodity. It is projected that hydrogen required for various processes may reach 1.8 × 10⁹ MBTU by the year 2000. This increases the importance of producing hydrogen especially from a cheap raw material like water. A survey of the different approaches for splitting water (electrolysis, plasmolysis, magnetolysis, magmalysis, photolysis, photoelectrochemical methods, radiolysis, etc.) is made and discussed in detail in this review.     

Optimal dispatch model for PV-electrolysis plants in self-consumption regime to produce green hydrogen: A Spanish case study

The production of green hydrogen from renewable energy by means of water electrolysis is a promising approach to support energy sector decarbonization. This paper presents a techno-economic model of plants with PV sources connected to electrolysis in self-consumption regime that considers the dynamics of electrolysis systems. The model calculates the optimal hourly dispatch of the electrolysis system including the operational states (production, standby, and idle), the load factor in production, and the energy imports and exports to the electricity grid. Results indicate that the model is a useful decision support tool to operate electrolysis plants connected to PV plants in self-consumption regimes with the target of reducing hydrogen production costs.     

Econometric analysis of the R&D performance in the national hydrogen energy technology development for measuring relative efficiency: The fuzzy AHP/DEA integrated model approach

Hydrogen energy technology can be one of the best key players related to the sector of the United Nations Framework Convention on Climate Change (UNFCCC) and the hydrogen economy. Comparing to other technologies, hydrogen energy technology is more environmentally sound and friendly energy technology and has great potential as a future dominant energy carrier. Advanced nations including Korea have been focusing on the development of hydrogen energy technology R&D for the sustainable development and low carbon green society. In this paper, we applied the integrated fuzzy analytic hierarchy process (Fuzzy AHP) and the data envelopment analysis (DEA) for measuring the relative efficiency of the R&D performance in the national hydrogen energy technology development. On the first stage, the fuzzy AHP effectively reflects the vagueness of human thought. On the second stage, the DEA approach measures the relative efficiency of the national R&D performance in the sector of hydrogen energy technology development with economic viewpoints. The efficiency score can be the fundamental data for policymakers for the well focused R&D planning.     

Two-step thermochemical electrolysis: An approach for green hydrogen production

Electrolysis and thermochemical water splitting are approaches to produce green hydrogen that use either an electrical potential (electrolysis) or a chemical potential (thermochemical water splitting) to split water. Electrolysis is technologically mature when applied at low temperatures, but it requires large quantities of electrical energy. In contrast to electrolysis, thermochemical water splitting uses thermal energy, as thermal energy can typically be supplied at a lower unit cost than electrical energy using concentrating solar power. Thermochemical water splitting, however, typically suffers from high thermal losses at the extremely high process temperatures required, substantially increasing the total energy required. We show how, by combining electrical and chemical potentials, a novel and cost-efficient water splitting process can be envisioned that overcomes some of the challenges faced by conventional electrolysis and thermochemical water splitting. It uses a mixed ionic and electronic conducting perovskite with temperature-dependent oxygen non-stoichiometry as an anode in an electrolyzer. If solar energy is used as the primary source of all energy required in the process, the cost of the energy required to produce hydrogen could be lower than in high-temperature electrolysis by up to 7%.     

An analysis of hydrogen production from renewable electricity sources

Three aspects of producing hydrogen via renewable electricity sources are analyzed to determine the potential for solar and wind hydrogen production pathways: a renewable hydrogen resource assessment, a cost analysis of hydrogen production via electrolysis, and the annual energy requirements of producing hydrogen for refueling. The results indicate that ample resources exist to produce transportation fuel from wind and solar power. However, hydrogen prices are highly dependent on electricity prices. For renewables to produce hydrogen at $2 kg⁻¹, using electrolyzers available in 2004, electricity prices would have to be less than $0.01 kWh⁻¹. Additionally, energy requirements for hydrogen refueling stations are in excess of 20 GWh/year. It may be challenging for dedicated renewable systems at the filling station to meet such requirements. Therefore, while plentiful resources exist to provide clean electricity for the production of hydrogen for transportation fuel, challenges remain to identify optimum economic and technical configurations to provide renewable energy to distributed hydrogen refueling stations.     

A comprehensive review on PEM water electrolysis

Hydrogen is often considered the best means by which to store energy coming from renewable and intermittent power sources. With the growing capacity of localized renewable energy sources surpassing the gigawatt range, a storage system of equal magnitude is required. PEM electrolysis provides a sustainable solution for the production of hydrogen, and is well suited to couple with energy sources such as wind and solar. However, due to low demand in electrolytic hydrogen in the last century, little research has been done on PEM electrolysis with many challenges still unexplored. The ever increasing desire for green energy has rekindled the interest on PEM electrolysis, thus the compilation and recovery of past research and developments is important and necessary. In this review, PEM water electrolysis is comprehensively highlighted and discussed. The challenges new and old related to electrocatalysts, solid electrolyte, current collectors, separator plates and modeling efforts will also be addressed. The main message is to clearly set the state-of-the-art for the PEM electrolysis technology, be insightful of the research that is already done and the challenges that still exist. This information will provide several future research directions and a road map in order to aid scientists in establishing PEM electrolysis as a commercially viable hydrogen production solution.     

克拉玛依石化公司氢气系统优化运行实践

氢气是石化企业加氢工艺的重要原料。为了缓解近年来由于油品升级带来的用氢矛盾,中国石油克拉玛依石化公司对氢气系统进行了优化:①对氢气进行了分类运行管理,形成了A、B两套氢气系统(其中,A系统为天然气制氢系统,主要为2套高压加氢装置供氢;B系统为催化重整副产氢气以及其他各临氢装置回收的氢气,主要为加氢精制装置供氢),理顺了氢气系统运行方式,提高了系统的平稳率。②通过对循环氢、低分氢的回收利用,提高了氢气资源的综合利用率,降低了制氢成本。③通过对氢气品质和压力能的梯级利用,在生产环节上简化了氢气流程,提高了压缩机的利用率,降低了运行成本。④通过加强管理,实现了氢气资源的零排放,杜绝了氢气资源的浪费。上述措施实施后,克拉玛依石化公司基本达到了优化氢气资源的目标。     

Hydrogen production from solar energy

Three alternatives for hydrogen production from solar energy have been analyzed on both efficiency and economic grounds. The analysis shows that the alternative using solar energy followed by thermochemical decomposition of water to produce hydrogen is the optimum one. The other schemes considered were the direct conversion of solar energy to electricity by silicon cells and water electrolysis, and the use of solar energy to power a vapor cycle followed by electrical generation and electrolysis. The capital cost of hydrogen via the thermochemical alternative was estimated at $575/kW of hydrogen output or $3·15/million Btu. Although this cost appears high when compared with hydrogen from other primary energy sources or from fossil fuel, environmental and social costs which favor solar energy may prove this scheme feasible in the future.     

Comparison of thermochemical,electrolytic, photoelectrolytic and photochemical solar-to-hydrogen production technologies

Hydrogen produced from solar energy is one of the most promising solar energy technologies that can significantly contribute to a sustainable energy supply in the future. This paper discusses the unique advantages of using solar energy over other forms of energy to produce hydrogen. Then it examines the latest research and development progress of various solar-to-hydrogen production technologies based on thermal, electrical, and photon energy. Comparisons are made to include water splitting methods, solar energy forms, energy efficiency, basic components needed by the processes, and engineering systems, among others. The definitions of overall solar-to-hydrogen production efficiencies and the categorization criteria for various methods are examined and discussed. The examined methods include thermochemical water splitting, water electrolysis, photoelectrochemical, and photochemical methods, among others. It is concluded that large production scales are more suitable for thermochemical cycles in order to minimize the energy losses caused by high temperature requirements or multiple chemical reactions and auxiliary processes. Water electrolysis powered by solar generated electricity is currently more mature than other technologies. The solar-to-electricity conversion efficiency is the main limitation in the improvement of the overall hydrogen production efficiency. By comparison, solar powered electrolysis, photoelectrochemical and photochemical technologies can be more advantageous for hydrogen fueling stations because fewer processes are needed, external power sources can be avoided, and extra hydrogen distribution systems can be avoided as well. The narrow wavelength ranges of photosensitive materials limit the efficiencies of solar photovoltaic panels, photoelectrodes, and photocatalysts, hence limit the solar-to-hydrogen efficiencies of solar based water electrolysis, photoelectrochemical and photochemical technologies. Extension of the working wavelength of the materials is an important future research direction to improve the solar-to-hydrogen efficiency.     

A comparative analysis for multiattribute selection among renewable energy alternatives using fuzzy axiomatic design and fuzzy analytic hierarchy process

Renewable energy is the energy generated from natural resources such as sunlight, wind, rain, tides and geothermal heat which are renewable. Energy resources are very important in perspective of economics and politics for all countries. Hence, the selection of the best alternative for any country takes an important role for energy investments. Among decision-making methodologies, axiomatic design (AD) and analytic hierarchy process (AHP) are often used in the literature. The fuzzy set theory is a powerful tool to treat the uncertainty in case of incomplete or vague information. In this paper, fuzzy multicriteria decision- making methodologies are suggested for the selection among renewable energy alternatives. The first methodology is based on the AHP which allows the evaluation scores from experts to be linguistic expressions, crisp, or fuzzy numbers, while the second is based on AD principles under fuzziness which evaluates the alternatives under objective or subjective criteria with respect to the functional requirements obtained from experts. The originality of the paper comes from the fuzzy AD application to the selection of the best renewable energy alternative and the comparison with fuzzy AHP. In the application of the proposed methodologies the most appropriate renewable energy alternative is determined for Turkey.     

Levelized and environmental costs of power-to-gas generation in Germany

The transformation to a greener energy system leads to new challenges, as wind and solar power are not always available. A solution for this challenge is the generation of synthetic natural gas (SNG) and hydrogen from (surplus) wind and solar power, so that the green gases can be stored in the natural gas grid long-term and be used for electricity generation when wind and solar power are not accessible. This solution is especially of interest if the storage infrastructure is already in place, as in Germany, since investment costs can be avoided. Because of that, the study investigates the levelized cost of SNG and hydrogen generation in Germany applying the cost estimation method by Rubin et al. For the investigation, different water electrolysis technologies (alkaline electrolysis, polymer exchange membrane, and solid oxide electrolyzer cell with a size of 1 and 100 MW) and energy scenarios (8,000 h grid, 2,000 h grid, wind, and solar) are contemplated. Besides that, the environmental costs of SNG and hydrogen generation in Germany are investigated due to the increasing importance of these costs for society and companies. The author concludes that the levelized costs of SNG and hydrogen are far too high compared to peer studies, as more cost factors have been considered after applying the method by Rubin et al. In terms of the environmental costs, the use of Germany's grid electricity is not recommended for SNG and hydrogen generation since the generation from wind and solar power is more environmentally friendly, whereby wind power is preferable over solar power.     

Hydrogen production through solar energy water electrolysis

Various methods of making hydrogen from water have been proposed, but at the present time the only practical way to make hydrogen from water without fossil fuel is electrolysis. The development of a new, advanced, water electrolyser has become necessary for use in hydrogen energy systems and in electricity storage systems. All the new possible electrolysis processes, suitable for large-scale plants, are being analysed, in view of their combination with solar electricity source. A study of system interactions between large-scale photovoltaic plants, for electrical energy supply, and water electrolysis, is carried out. The subsystems examined include power conditioning, control and loads, as they are going to operate. Water electrolysis systems have no doubt been improved considerably and are expected to become the principal means to produce a large amount of hydrogen in the coming hydrogen economy age. Thus, the present paper treats the subject of hydrogen energy production from direct solar energy conversion facilities located on the earth's oceans and lakes. Electrolysis interface is shown to be conveniently adapted to direct solar energy conversion, depending on technical and economical feasibility aspects as they emerge from the research phases. The intrinsic requirement for relatively immense solar collection areas for large-scale central conversion facilities, with widely variable electricity charges, is given. The operation of electrolysis and photovoltaic array combination is verified at different insolation levels. Solar cell arrays and electrolysers are giving the expected results during continuously variable solar energy inputs. Future markets will turn more and more towards larger scale systems powering significantly bigger loads, ranging from hundreds of kW to several MW in size. Detailed design and close attention to subsystem engineering in the development of high performance, high efficiency photovoltaic power plants, are carried out. An overall design of a 50 MWp photovoltaic central station for electricity and hydrogen co-generation is finally discussed.