Comparing two‐step and one‐step chromatic adaptation transforms using the CAT16 model

Color‐appearance models, CIECAM02 and CAM16, usually include two one‐step chromatic adaptation transforms: a forward (one‐step) transform to convert data from a first illuminant to CIE illuminant E, plus a reverse (one‐step) transform to convert the results from CIE illuminant E to a second illuminant. In practice, however, one‐step chromatic adaptation models, that avoid the use of the intermediate CIE illuminant E, are also employed. Tests using the one‐step CAT16 model indicate failures of both the symmetry and transitivity properties, except in the case where the degree of adaptation D is equal to unity. The magnitude of these failures depends on the specific illuminants selected, and increases as the degree of adaptation decreases. From four possible two‐step CAT16 models, we have identified two that obey the symmetry and transitivity properties, one with slightly better predictions of the experimental corresponding‐color datasets available in the literature, and more consistent with the one‐step CAT16 model. The findings of this article confirm that, for incomplete adaptation, the use of the one‐step CAT is incorrect, and we propose that the use of a two‐step CAT16 model be mandatory for future applications.     

Evaluation of color matching performances for SPEM and other models

We performed subjective experiments to evaluate color matching performance of the Spectral Properties Estimation Model (SPEM) and six other models (von Kries, CIELAB, LLAB, RLAB, Nayatani, and CIECAM97s) between two CRT monitors whose whites were quite different. Moreover, we evaluated color matching of these models between a CRT monitor and a printed image set in a dark room. The SPEM we developed is a new chromatic adaptation model based on hypothetical spectral properties estimation. This article describes the subjective experiments and the results obtained. The SPEM produced good color matching performance in the experiments. The detailed algorithm of the SPEM is given in the Appendix. © 2003 Wiley Periodicals, Inc. Col Res Appl, 28, 445–453, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.10197     

Differences in attributes between color difference and color appearance (chroma and hue) for near‐neutral colors

Chroma‐step perception and its corresponding color difference in the same hue direction are the different attributes on color perception. The differences between them are different for different hues. Hue‐appearance step and its corresponding color difference along the same hue circle also have completely different concepts. The causes of the above two facts are clarified. The information based on various experiments and theoretical considerations are given for supporting the facts. In addition, it is clarified that the relationship on color‐appearance step and color difference has completely different characteristics between the quantitative (chroma) and the qualitative (hue) attributes of object colors. The importance of chromatic strength (CS) on hue is clarified in each of the three color attributes hue, value, and chroma. © 2004 Wiley Periodicals, Inc. Col Res Appl, 30, 42–52, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20073     

Comprehensive color solutions: CAM16, CAT16, and CAM16‐UCS

The CIECAM02 color‐appearance model enjoys popularity in scientific research and industrial applications since it was recommended by the CIE in 2002. However, it has been found that computational failures can occur in certain cases such as during the image processing of cross‐media color reproduction applications. Some proposals have been developed to repair the CIECAM02 model. However, all the proposals developed have the same structure as the original CIECAM02 model and solve the problems concerned at the expense of losing accuracy of predicted visual data compared with the original model. In this article, the structure of the CIECAM02 model is changed and the color and luminance adaptations to the illuminant are completed in the same space rather than in two different spaces, as in the original CIECAM02 model. It has been found that the new model (named CAM16) not only overcomes the previous problems, but also the performance in predicting the visual results is as good as if not better than that of the original CIECAM02 model. Furthermore the new CAM16 model is simpler than the original CIECAM02 model. In addition, if considering only chromatic adaptation, a new transformation, CAT16, is proposed to replace the previous CAT02 transformation. Finally, the new CAM16‐UCS uniform color space is proposed to replace the previous CAM02‐UCS space. A new complete solution for color‐appearance prediction and color‐difference evaluation can now be offered.     

Digital image‐color conversion between different illuminants by color‐constancy actuation in a color‐vision model based on the OSA‐UCS system

In digital image capture, the camera signals produced by the D65 illuminant, once translated into tristimulus values of the CIE 1931 standard colorimetric observer (assuming the Maxwell‐Ives‐Luther criterion is satisfied), are considered good to produce accurate color rendering. An image obtained under any illuminant other than D65 does not appear realistic and the tristimulus values of the camera must be transformed into the corresponding ones produced by the D65 illuminant. This transformation must satisfy color constancy. In this work, the transformation is obtained by a color‐vision model based on the Optical Society of America‐Uniform Color Scales system [Color Res Appl 2005; 30: 31–41] and is represented by a matrix dependent on the adaptation illuminant. This matrix is obtained by minimizing the distance between the pairs of the uniform scale chromatic responses related to the tristimulus values of the 99 different color samples of the SG Gretag‐Macbeth ColorChecker measured under a pair of different illuminants, one of which is the D65. Then any picture captured under a given light source can be translated into the picture of the same scene under the D65 illuminant. Metameric reason allows only approximate solutions. The transformations from Daylight and Planckian illuminants to the D65 illuminant have a very regular dependence on the color temperature, that appears to be the typical parameter for the color conversion. © 2012 Wiley Periodicals, Inc. Col Res Appl, 38, 412–422, 2013     

Assessing the affective feelings of two‐ and three‐dimensional objects

The aim of this study is to investigate the impact of physical appearance attributes (in terms of color and shape) on our affective feelings of 2D and 3D objects. Twelve colors were studied, each consisting of 12 two‐dimensional and 12 three‐dimensional shapes. This resulted in 144 2D and 144 3D color‐shape combinations. Each color‐shape combination was assessed using 20 emotion scales in a viewing cabinet by a panel of observers with normal color vision. The results show that there are five underlying factors of these 20 scales, i.e., “activity,” “weight,” “heat,” “softness,” and “complexity”. The first three factors were mainly related to color and the other two were linked with shape. © 2008 Wiley Periodicals, Inc. Col Res Appl, 34, 75–83, 2009.     

Optimum solution of the CIECAM02 yellow–blue and purple problems

Brill [Color Res Appl 2006;31:142‐145] and Brill and Süsstrunk [Color Res Appl 2008;33:424‐426] found that CIECAM02 has the yellow–blue and purple problems and gave partial solutions to them. In this article we model the optimum solution to the yellow–blue and purple problems simultaneously as a constrained non‐linear optimization problem. An optimum solution resulting in a new CAT02 matrix is numerically obtained. This new matrix satisfies the nesting rule and performs better than the Hunt‐Pointer‐Estévez (HPE) matrix in predicting both corresponding colours and colour appearance data sets. Specifically, it was found that the new and HPE matrices performed significantly different on nine (out of 21) corresponding colour data sets and on all corresponding colours data sets as a whole. © 2014 Wiley Periodicals, Inc. Col Res Appl, 40, 491–503, 2015     

On the field trials of CIECAM97s and its model structure

The structure of the color-appearance model CIECAM97s is examined. The problems with its chromatic-adaptation transform, called the Bradford transform, are discussed in detail. The contradictions existing between the measures at various stages of CIECAM97s are described, which are ea-eb, saturation s, chroma C, and colorfulness M. The main contradictions are (1) the inversion of chromatic components between test and reference colors at different measures; and (2) the similarity between chroma and colorfulness found in the experiments done under different adapting illuminances. The structural problems in CIECAM97s are clarified by comparing its predictions with those using CIECAT94LAB, which consists of the CIE chromatic-adaptation transform published in 1994 and the CIELAB formula. © 1999 John Wiley & Sons, Inc. Col Res Appl, 24, 439–456, 1999     

Designing white‐light LED lighting for the display of art: A feasibility study

When displaying art, several criteria must be balanced when designing illumination including the artist's intention, damage, energy efficiency, viewing experience and understanding, and for commercial galleries and sales. The most common lighting for art includes natural daylight and incandescent spotlights. Neither source is optimal for all criteria; thus there is considerable interest in the use of white‐light light‐emitting diode (LED) lighting. A feasibility study was conducted to address two questions. First, was it possible to design a three‐primary LED source that yielded the same color rendering as common museum lighting? Second, could one design the lighting to achieve specific color appearance attributes? Three‐primary lights using a Gaussian function were optimized matching the chromaticity of D65 and minimizing color differences for a set of acrylic dispersion paints. The optimal wavelengths depended on bandwidth. Lights were also optimized that either maximized or minimized average chroma. A set of real LEDs was selected that produced similar results when evaluated computationally. A source that increases chroma may be useful when used to illuminate works of art with high light sensitivity: very low illuminances are necessary and such a source will compensate for the reduction of colorfulness and visual clarity. A source that decreases chroma may be used to render art in similar fashion to low‐light conditions such as churches and caves. In general, white LED lighting is advantageous for art conservation because they do not emit UV and IR radiation and their visible radiation is reduced when compared with their continuous spectrum equivalent. © 2010 Wiley Periodicals, Inc. Col Res Appl, 2011     

Color‐emotion associations and color preferences: A case study for residences

This study examines existing beliefs about “color” focusing on color‐emotion associations by discussing how color can be used as a way of communicator to fulfill human needs in residences. Fifty people from various age groups participated in the study. They were asked to match a list of adjectives with the proper color samples from the catalogue of a quite popular color producer firm in Turkey. Results indicate that there is a strong dependency between the choice and use of green at residences. Emotional responses to colors change with value and saturation levels. According to the test results, gender and age are determining factors in the selection of achromatic black. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 144 – 150, 2007     

Mathematical approach for predicting non‐negative tristimulus values using the CAT02 chromatic adaptation transform

It has been reported that for certain colour samples, the chromatic adaptation transform CAT02 imbedded in the CIECAM02 colour appearance model predicts corresponding colours with negative tristimulus values (TSVs), which can cause problems in certain applications. To overcome this problem, a mathematical approach is proposed for modifying CAT02. This approach combines a non‐negativity constraint for the TSVs of corresponding colours with the minimization of the colour differences between those values for the corresponding colours obtained by visual observations and the TSVs of the corresponding colours predicted by the model, which is a constrained non‐linear optimization problem. By solving the non‐linear optimization problem, a new matrix is found. The performance of the CAT02 transform with various matrices including the original CAT02 matrix, and the new matrix are tested using visual datasets and the optimum colours. Test results show that the CAT02 with the new matrix predicted corresponding colours without negative TSVs for all optimum colours and the colour matching functions of the two CIE standard observers under the test illuminants considered. However, the accuracy with the new matrix for predicting the visual data is approximately 1 CIELAB colour difference unit worse compared with the original CAT02. This indicates that accuracy has to be sacrificed to achieve the non‐negativity constraint for the TSVs of the corresponding colours. © 2011 Wiley Periodicals, Inc. Col Res Appl, 2011     

Changes in contrast thresholds with mean luminance for chromatic and luminance gratings: A reexamination of the transition from the DeVries–Rose to Weber regions

We have examined the influence of the mean luminance level on the detection thresholds for luminance and red–green chromatic gratings for three different spatial frequencies. The changes in detection thresholds according to the mean luminance level reflect the two different regions, the DeVries–Rose and Weber ranges, found in previous studies. The results for luminance gratings suggest that the transition luminance is proportional to the spatial frequency of the grating. Predictions based on the constant‐flux hypothesis indicate, however, that the transition luminance is proportional to the square of the spatial frequency of the grating and so do not describe the distributions of luminance contrast thresholds adequately. For chromatic gratings, we obtained the same transition luminance for the two lowest spatial frequencies, showing that luminance and chromatic mechanisms behave differently as far as the dependence of the transition luminance on spatial frequency is concerned. Our results suggest that the transition luminance is related to the peak spatial frequency of visual mechanisms that respond to luminance and chromatic gratings. © 2004 Wiley Periodicals, Inc. Col Res Appl, 29, 177–182, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20003     

Color in the urban environment: A user‐oriented protocol for chromatic characterization and the development of a parametric typology

This article presents a user‐oriented protocol that can be used to characterize chromatic attributes of an urban area. A need for both affordable and reliable assessment method of color has been observed in the field of urban design. The challenge is to provide statistical answers to these two questions: how is color organized, how does it develop its own structure in the city? The main purpose of the research is hence to investigate mean color types within the city via the implementation of a characterization tool; an urban area of the four main classes (historic center, periurban housing districts, working‐class neighborhoods, and commercial zones) being characterized by a specific color palette, or a layout of specific color types. The developed instrumentation allows the assessment of the homogeneous and consistent features of an urban district. Their characterization protocol was tested through an application to several streets of the city of Liège (Belgium). © 2016 Wiley Periodicals, Inc. Col Res Appl, 42, 131–142, 2017     

Influence of surface roughness on the diffuse to near‐normal viewing reflectance factor of coatings and its consequences on color measurements

In this work, we discuss the effect of surface roughness on the measurement of the diffuse to near‐normal viewing reflectance factor of coatings and evaluate its impact on the corresponding color coordinates. We compare specular component included (SCI) and excluded measurements. We introduce a gloss‐factor to account for surface roughness in specular component excluded measurements. We present experimental results on samples with different degrees of surface roughness. Samples in this study were chosen to expose the contribution of the surface in the reflectance factor. For slightly rough surfaces, the influence on the measured reflectance factor depends on whether the specular‐component is included or excluded. As the surface roughness increases, the specular‐excluded reflectance factor increases approaching its value with the SCI further roughness lead to similar measurement results in both configurations. © 2012 Wiley Periodicals, Inc. Col Res Appl, 38, 177–187, 2013.     

The effect of platinum on the performance of WO3 nanocrystal photocatalysts for the oxidation of Methyl Orange and iso‐propanol

BACKGROUND: This research investigated the effect of platinum (Pt) on the reactivity of tungsten oxide (WO₃) for the visible light photocatalytic oxidation of dyes. RESULTS: Nanocrystalline tungsten oxide (WO₃) photocatalysts were synthesised by a sol‐gel process and employed for the photocatalytic degradation of Methyl Orange under visible light. For comparison commercial bulk WO₃ materials were also studied for the same reaction. These materials were fully characterised using X‐ray diffraction (XRD), UV‐visible diffuse reflection spectroscopy and transmission electron microscopy (TEM). The photocatalytic oxidation of iso‐propanol was used as a model reaction to follow the concomitant reduction of molecular oxygen. No reactions occured in the absence of platinum, which is an essential co‐catalyst for the multi‐electron reduction of oxygen. The platinised WO₃ catalysts were stable for multiple oxidation–reduction cycles. The results from the catalytic activity measurements showed that platinised nanocrystalline WO₃ is a superior oxidation photocatalyst when compared with bulk WO₃. Methyl Orange was completely decolourised in 4 h. CONCLUSIONS: The enhanced performance of nanocrystalline Pt‐WO₃ is attributed to improved charge separation in the nanosized photocatalyst. Platinum is an essential co‐catalyst to reduce oxygen. This photocatalyst could be applied to the treatment of organic pollutants in wastewater, with the advantage of using visible light compared with the widely studied TiO₂, which requires UV light. Copyright © 2011 Society of Chemical Industry     

Molecular simulation of the glass transition and proton conductivity of 2,2′‐benzidinedisulfonic acid and 4,4′‐diaminodiphenylether‐2,2′‐disulfonic acid‐based copolyimides as polyelectrolytes for fuel cell applications

The glass transition temperatures (T_gs) and proton conductivities of polyimides synthesized from naphthalene‐1,4,5,8‐tetracarboxylic dianhydride (NTDA), 2,2′‐benzidinedisulfonic acid (BDSA), 4,4′‐diaminodiphenylether‐2,2′‐disulfonic acid (ODADS), and non‐sulfonated diamine monomers have been predicted using molecular dynamics simulations. The specific volumes for two dry and four hydrated NTDA‐based polyimides were plotted versus temperatures above and below T_gs to obtain the glass transition temperatures. The simulation results suggest that the ODADS‐based polyimide membranes exhibit lower T_gs and thus better mechanical properties than the BDSA‐based polyimides, which may be attributed to the high mobility of backbones of ODADS as supported by the vectorial autocorrelation function (VACF) results of this study. In addition, comparison of the simulated T_gs for the dry and hydrated ODADS‐based polyimides has shown that water content in polyimides can affect their T_gs. The proton conductivities of a representative polyimide in both dry and hydrated conditions have been obtained from molecular dynamics simulations of the proton and hydronium ion diffusion. The simulated conductivity for the hydrated NTDA‐ODADS/BAPB cell is in reasonable agreement with the experimental value obtained from the AC impedance method. The relationship between the chemical composition, chain flexibility, and the glass transition and proton conduction of these NTDA‐based polyimides was explored on the basis of VACF and pair correlation function analysis. Copyright © 2006 Society of Chemical Industry     

Spectral sensitivities of the normal human visual system,color‐matching functions and their principles,and how and why the two sets should coincide

The objectives of this article are (1) to help reestablish in technical thinking the three spectral sensitivity curves, dating from Helmholtz, of the normal human visual system (particularly their peak wavelengths); (2) to remind the reader of the principles of the sets of three color‐matching functions (CMFs) comprising a CIE Standard Observer, and to make these principles more easily understandable; (3) to show how the visual data comprising today's Standard Observers lead directly to the peak wavelengths of the spectral sensitivity curves; (4) to use modern color‐matching data to restore essential details to CMFs damaged by manipulation over the years; (5) to suggest that coincidence of corrected CMFs and the actual spectral sensitivities of the normal human visual system (a feature long tacitly assumed by color scientists of the past) is close at hand; and (7) to point out that CMFs embody a wealth of significance concerning the nature of the spectral response of the normal human visual system, despite the fact that they do not work well as weighting functions in the practice of colorimetry. The color‐matching data of the CIE 1964 10° Standard Observer are used to reproduce the visual matches upon which it is based, and to model the principles of CMFs in general. The CIE 1964 data are treated as if they had been collected directly from modern‐day visual matching experiments, in which an accurate, high‐resolution, absolute spectral power distribution (SPD) of every viewed light is measured, and power content of each component of the light determined. The experimental units and dimensions of the resulting three CMFs are established. The significance of CMF plots above and below the zero‐power level, and of the spectral shapes of the CMFs, is shown. The positions in wavelength of the nominal maximum of the red, green, and blue CMF, for a wide range of wavelengths of real spectral primaries, are noted (following MacAdam) to be “amazingly similar.” Then the much‐manipulated data of the CIE Standard Observers are left behind, and modern raw unmanipulated visual data are analyzed in the same manner. The results yield characteristics of CMFs that are more representative of the normal human visual system than are those of the CIE Standard Observers. The peak heights of the nominal maxima of the red, green, and blue CMF, for the same wide range of primaries, are importantly significant also. They serve to define, at least approximately, the forms of the three spectral sensitivities, assuming the traditional model of the visual system. © 1999 John Wiley & Sons, Inc. Col Res Appl, 24, 139–156, 1999     

Exact location of consensus and consistency colors in the osa‐ucs for the italian language

In a previous work, the authors reported on the results of a color naming experiment performed on native Italian speakers regarding the location of focal colors and centroids in the Uniform Color Scales of the Optical Society of America color system. That work was aiming at comparing such data with those previously obtained by Boynton and Olson (B&O) accounting for the differences in the paradigm and the language. The number of consistency and consensus colors in the different lightness plans was also reported but no information was provided on their placement. Though, such information is very important for any subsequent modeling stage. The objective of this article is to fill such a gap and share such data with the scientific community to provide a reference database for future investigation. Three different datasets were considered: the extended OSA (E‐OSA), the reduced OSA (R‐OSA), and the B&O's (B&O) sets of reference colors. Results show a good overlap among the locations of the consensus colors in the {L, j, g} color model between B&O and the subset of E‐OSA colors overlapping with the B&O 424 colors (R‐OSA), as well as a strong agreement on consistency. Furthermore, a close proximity among the centroids of homologue regions for the majority of the classes was found. © 2012 Wiley Periodicals, Inc. Col Res Appl, 38, 437–447, 2013     

Performance of advanced color difference and CAM02‐based formulas in prediction of the Crispening effect for reflective samples

The Crispening effect is defined as an increase in the perceived color difference of the two stimuli, when their color (chromaticity or luminance) is close to the background on which the two stimuli are compared. In this study, the amount of the Crispening effect for three achromatic backgrounds and also the performance of six different color difference formulas (CDFs) for prediction of this effect have been investigated, by preparing 85 sample pairs in 9 CIE's recommended color centers. Regarding the results, the maximum (50%) and the minimum (4%) amount of the Crispening effect belong to the gray and the purple centers, respectively. According to the results of a comparative test, the Crispening intensifies when two stimuli have just lightness difference instead of just chromaticity difference. The highest variation was for the gray samples, in which the amount of the Crispening effect increased from 35% to 65%. By using PF/3 and STRESS index, it is also concluded that CMC and CIEDE2000 perform better than CAM02‐SCD and CAM02‐UCS in prediction of the Crispening effect on the dark gray and gray backgrounds. According to the results, the significant differences between the performances of the CDFs disappear when the luminance of the background increases. Huang's power functions also do not improve these results significantly. Furthermore, the results indicate that the traditional L* equation used in CIELAB performs similar to the Whittle's formula in prediction of the Crispening effect for reflective samples, and no significant difference was obtained.