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1.
Abstract A mixture of fatty hydroxamic acids (FHA), synthesized from a commercial palm olein, was evaluated as an extractant for extraction of copper ion from aqueous media. The content of hydroxamic acid groups in the FHA, analyzed by elemental analysis, was 3.52 mmol/g. Copper extraction from aqueous media was studied by solvent extraction technique using octanol as an organic phase. The extraction of copper ion was through the formation of 1∶2 (Cu(II)∶FHA) complex, pH dependent and not affected by the presence of a large amount of Co(II), Ni(II), Cd(II) and Zn(II) ions. 相似文献
2.
E. A. Mowafy 《溶剂提取与离子交换》2013,31(6):791-807
Abstract The feasibility of using two new diamides namely; N,N′‐dimethyl‐N,N′‐di(4‐chlorophenyl)malonamide (DMDPhClMA) and N,N′‐dimethyl‐N,N′‐di(4‐chlorophenyl)tetradecylmalonamide (DMDPhClTDMA), as agents for the selective extraction of iron(III) from chloride solution was investigated. A systematic investigation has been carried out on the detailed extraction properties of iron(III) with these extractants from chloride media. The extraction of iron(III) from an aqueous chloride solution in the presence of metal ions, such as Zn(II), Co(II), Mn(II) Cu(II), Pb(II), Ni(II) and Ag(I) was carried out using DMDPhClMA or DMDPhClTDMA in binary and multicomponent mixtures. The quantitative extraction of iron(III) with DMDPhClMA and DMDPhClTDMA in toluene is observed at 4 and 7 M HCl, respectively. The quantitative stripping of Fe(III), from the loaded organic phase was successfully achieved by simple contact with water. 相似文献
3.
Abstract The extraction of iron(III) has been studied from chloride solutions with di(2‐ethylhexyl)phosphoric acid (D2EHPA), bis(2,4,4‐trimethylpentyl)phosphinic acid (CYANEX 272) and its sulfur‐substituted analogs, called CYANEX 302, and CYANEX 301, and 5‐dodecylsalicylaldoxime (Aloxime 800). Job's method was applied for the characterization of the iron(III) complexes dissolved in hexane. In the case of D2EHPA and CYANEX 272, a 1:1 ligand‐to‐metal ratio was observed, thus inferring the coordination of additional compounds. No chloride transport occurred during extraction, therefore suggesting the formation of [Fe(OH)2L] complexes. With CYANEX 302, a ratio of 2:1 was obtained, whereas for CYANEX 301, the results of Job's method indicated the presence of four extractant molecules around the metal ion. Less hydrolysis or the possible oxidation of the sulfur‐substituted organophosphinic acids and the corresponding reduction of Fe(III) towards Fe(II) may explain this behavior. In the case of Aloxime 800, the formation of the [FeL3] species is suggested. A comparative study was carried out to identify the ligand‐to‐metal ratio of the iron(III) complexes in anhydrous circumstances. These studies showed that 1:1 ligand‐metal complexes are easily formed in the case of the organophosphoric‐ and organophosphinic‐acid extractants. A higher ligand‐metal ratio may be possible, but is not always a necessary condition for iron(III) extraction. Even the coexistence of [FeCl2L], [FeClL2] and to a smaller extent [FeL3] is quite presumable in anhydrous media. Finally, FT‐IR spectra as well as UV‐VIS spectra of the hexane phases make it possible to gain a better insight into the complexation characteristics of iron(III). 相似文献
4.
Glennon JD Horne E O'Sullivan P Hutchinson S McKervey MA Harris SJ 《Metal-Based Drugs》1994,1(2-3):151-160
The functionalisation of macrocyclic p-tertbutylcalix[4]arenes at the lower rim with hydroxamic acid and proline hydroxamic acid groups gives the calixarenes chelating properties similar to siderophores. The (1)H NMR spectrum of p-tertbutylcalix[4]arene tetrahydroxamic acid shows a broad band at 10.8 ppm in DMSO-d(6) attributed to NHOH protons. Diffuse reflectance spectral analysis of PVC membranes containing the calixarene hydroxamic acids show absorption bands at 485 nm and 504 nm following contact with aqueous solutions of Fe(III) and V(V) respectively. The pH dependency of this extractive selectivity is examined for Fe(III), Co(II), Pb(II), Mn(II), Cu(II) and Ni(II) using a solid phase extraction approach. Spectrophotometric evidence for the complexation of Cu(II) in methanol by p-tertbutylcalix[4]arene tetraproline acid is also provided. 相似文献
5.
《分离科学与技术》2012,47(6):1267-1282
Abstract Earlier studies carried out to evaluate the selectivity of solvating extractants towards silver(I) in concentrated chloride media revealed that an intriguing situation occurs if a given excess of iron(III) concentration is present in the aqueous solution: the extraction of silver(I) becomes almost quantitative and independent of the initial chloride content. On the assumption that this effect may be due to a phenomenon occurring in the aqueous phase, a systematic study involving solutions containing different Ag(I), Fe(III), and HCl concentrations was carried out by solvent extraction and capillary electrophoresis. Capillary electrophoresis suggests that the AgCl3 2? amount in solution decreases in the presence of Fe(III), whereas FeCl3 seems to be partially converted onto FeCl4 ?. From the experiments performed, it can be concluded that the presence of Fe(III) seems to facilitate the formation of less anionic Ag(I) species, which are in turn more easily extracted by solvating extractants. Furthermore, the presence of FeCl4 ? has been detected in the organic phase of triisobutylphosphine sulfide (TIBPS) by UV‐Vis spectrophotometry, after equilibration with HCl solutions containing both Ag(I) and Fe(III), which was not identified during similar experiments carried out in the absence of Ag(I). Speciation of silver(I) and iron(III) in concentrated chloride medium has also been worked out by a numerical methodology. 相似文献
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7.
Huguet F Melet A Alves de Sousa R Lieutaud A Chevalier J Maigre L Deschamps P Tomas A Leulliot N Pages JM Artaud I 《ChemMedChem》2012,7(6):1020-1030
New series of acids and hydroxamic acids linked to five-membered heterocycles including furan, oxazole, 1,2,4- or 1,3,4-oxadiazole, and imidazole were synthesized and tested as inhibitors against the Fe(II) , Co(II) , and Mn(II) forms of E. coli methionine aminopeptidase (MetAP) and as antibacterial agents against wild-type and acrAB E. coli strains. 2-Aryloxazol-4-ylcarboxylic acids appeared as potent and selective inhibitors of the Co(II) MetAP form, with IC(50) values in the micromolar range, whereas 5-aryloxazol-2-ylcarboxylic acid regioisomers and 5-aryl-1,2,4-oxadiazol-3-ylcarboxylic acids were shown to be inefficient against all forms of EcMetAP. Regardless of the heterocycle, all the hydroxamic acids are highly potent inhibitors and are selective for the Mn(II) and Fe(II) forms, with IC(50) values between 1 and 2 μM. One indole hydroxamic acid that we previously reported as a potent inhibitor of E. coli peptide deformylase also demonstrated efficiency against EcMetAP. To gain insight into the positioning of the oxazole heterocycle with reversed substitutions at positions 2 and 5, X-ray crystal structures of EcMetAP-Mn complexed with two such oxazole hydroxamic acids were solved. Irrespective of the [metal]/[apo-MetAP] ratio, the active site consistently contains a dinuclear manganese center, with the hydroxamate as bridging ligand. Asp 97, which adopts a bidentate binding mode to the Mn2 site in the holoenzyme, is twisted in both structures toward the hydroxamate bridging ligand to favor the formation of a strong hydrogen bond. Most of the compounds show weak antibacterial activity against a wild-type E. coli strain. However, increased antibacterial activity was observed mainly for compounds with a 2-substituted phenyl group in the presence of the nonapeptide polymyxin B and phenylalanine-arginine-β-naphthylamide as permeabilizer and efflux pump blocker, respectively, which boost the intracellular uptake of the inhibitors. 相似文献
8.
F. Servat D. Montet M. Pina P. Galzy A. Arnaud H. Ledon L. Marcou J. Graille 《Journal of the American Oil Chemists' Society》1990,67(10):646-649
Biotechnological synthesis of a new class of amphiphilic molecules—fatty hydroxamic acids—was carried out using the lipase
ofMucor miehei by reacting hydroxyl amine with the fatty acids in their free or methyl ester form. Concurrently with enzymatic synthesis,
chemical synthesis of hydroxamic fatty acids has also been developed by adapting methods that already existed for water-soluble
acids. Different parameters were studied to determine the optimum operating conditions: temperature, molar ratio of reagents,
quantity of biocatalyst and length of reaction. A general method, whatever the type of fatty acids used, is described. 相似文献
9.
This article introduces a comparative study for the simultaneous separation and preconcentration of Fe(III) and Zn(II) traces in various water samples using three well-known ligands as chelating agents and activated carbon (AC) derived from Ramelak bark as a new bio-sorbent prior to the determination by ?ame atomic absorption spectrometry. The chelating agents were 4,4’-[(4-Cyano-phenyl)methylene]bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) (CMBM), diethyldithiocarbamate (DDTC) and ammonium pyrrolidine dithiocarbamate (APDC). CMBM was synthesized by a procedure reported in the literature. The newly prepared AC was characterized by Scanning Electron Microscopy (SEM) and Fourier-Transform Infrared (FTIR) Spectrometry. The analytical parameters affecting the separation efficiency of the analytes including pH, shaking time, chelating agent volume (concentration), sorbent mass, sample ?ow rate and elution conditions were investigated and discussed. Common coexisting ions did not seriously interfere with the separation, showing the good selectivity of the proposed method. The calibration graph was linear in the range of 0.35–70, 0.50–80, 0.9–100, 0.55–75, 0.75–90 and 1.0–120 ng mL?1 for Fe-CMBM, Fe-DDTC, Fe-APDC, Zn-CMBM, Zn-DDTC and Zn-APDC, respectively. Under optimized conditions, the limits of detection were 0.11, 0.13, 0.27, 0.16, 0.22 and 0.30 ng mL?1 for Fe-CMBM, Fe-DDTC, Fe-APDC, Zn-CMBM, Zn-DDTC and Zn-APDC, respectively. The proposed method has been applied to the determination of Fe(III) and Zn(II) in different water samples with satisfactory recovery percentages. The developed method, validated with standard reference materials, was used successfully in determining the concentrations of metal ions in water samples. 相似文献
10.
M. R. Lutfor S. Sidik W. M. Z. Wan Yunus M. Z. A. Rahman A. Mansor M. J. Haron 《应用聚合物科学杂志》2001,79(7):1256-1264
A new chelating ion‐exchange resin containing the hydroxamic acid functional group was synthesized from poly(methyl acrylate) (PMA)‐grafted sago starch. The PMA grafted copolymer was obtained by a free‐radical initiating process in which ceric ammonium nitrate was used as an initiator. Conversion of the ester groups of the PMA‐grafted copolymer into hydroxamic acid was carried out by treatment of an ester with hydroxylamine in an alkaline solution. The characterization of the poly(hydroxamic acid) chelating resin was performed by FTIR spectroscopy, TG, and DSC analyses. The hydroxamic acid functional group was identified by infrared spectroscopy. The chelating behavior of the prepared resin toward some metal ions was investigated using a batch technique. The binding capacities of copper, iron, chromium, and nickel were excellent and the copper capacity was maximum (3.46 mmol g−1) at pH 6. The rate of exchange of the copper ion was very fast that is, t1/2 < 5 min. It was also observed that the metal ion‐sorption capacities of the resin were pH‐dependent and its selectivity toward the metal ions used is in the following order: Cu2+ > Fe3+ > Cr3+ > Ni2+ > Co2+ > Zn2+ > Cd2+ > As3+ > Pb2+. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 1256–1264, 2001 相似文献
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12.
S. Jimenez Gomez L. M. Lopez Valdivia C. Gonzalez Iglesias M. I. Rico Selas 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1990,49(3):267-274
The extraction and stripping of Co(II), Ni(II), Cr(III) and Fe(III) from aqueous solutions by rosin dissolved in toluene has been investigated. Results obtained show that rosin is better extractant than abietic or n-lauric acids under comparable conditions. From these results, and the data of Mn(II) solvent extraction studied previously under the same conditions, a separation and concentration process for these five cations in aqueous solutions has been designed. Saturated solutions of Fe(III), Cr(III), Mn(II) and finally Co(II) and Ni(II) have been obtained successively by extraction and stripping, by addition of ammonium hydroxide to obtain the appropriate pH value, and by modifying adequately the organic phase/aqueous phase volume ratio. 相似文献
13.
M. J. Ibáñez González A. Robles Medina E. Molina Grima A. Giménez Giménez M. Carstens L. Esteban Cerdán 《Journal of the American Oil Chemists' Society》1998,75(12):1735-1740
Fatty acids in the microalga Phaeodactylum tricornutum were isolated using an optimized three-step method: extraction of crude fatty acid potassium salts made by direct saponification
of lipids in the microalgal biomass with KOH/ethanol (96%, vol/vol), separation of unsaponifiable lipids by extraction with
hexane, and final purification of fatty acids by acidification of the alcoholic solution of potassium soaps followed by extraction
of fatty acid into hexane. Direct saponification was carried out in ethanol (96%, vol/vol) using 2.09 mL ethanol (96%) per
gram of wet biomass (10 mL/g of dry biomass) mixed with 0.4 g KOH/g of biomass. Under these conditions the fatty acid yield
was 87%. The optimal water content of the alcoholic solution for extraction of the unsapononifiables was established as 40%,
w/w. Data on equilibrium carotenoid distribution between the alcoholic (40%, w/w water) and hexane phases were determined.
These data allow prediction of the carotenoid yields with different volumes of hexane in several extraction steps. The optimal
pH of the alcoholic solution before extracting the purified fatty acid was established as pH 6, and the equilibrium fatty
acid distribution between the alcoholic and hexane phases was determined. This optimized method permited a 20% reduction in
the production costs of highly purified eicosapentaenoic acid (EPA) in the three-step preparative process (extraction of fatty
acid, concentration of polyunsaturated fatty acids by the urea method, and EPA fractionation through preparative high-performance
liquid chromatography) previously developed by the authors. 相似文献
14.
Abstract Para‐substituted 4‐aroyl derivatives of 1‐phenyl‐3‐methyl‐5‐pyrazolones (HX), namely, 1‐phenyl‐3‐methyl‐4‐(4‐fluorobenzoyl)‐5‐pyrazolone (HPMFBP) and 1‐phenyl‐3‐methyl‐4‐(4‐toluoyl)‐5‐pyrazolone (HPMTP) were synthesized and examined with regard to the extraction behavior of multivalent metal ions such as magnesium(II), aluminum(III), titanium(IV), vanadium(V), chromium(III), manganese(II), iron(II), and iron(III) that are present in titania waste chloride liquors. For comparison, studies have also been carried out with 1‐phenyl‐3‐methyl‐4‐benzoyl‐5‐pyrazolone (HPMBP). The results demonstrate that vanadium(V) and iron(III) are extracted into chloroform with 4‐aroyl‐5‐pyrazolones as VO2X · HX and FeX3, respectively. On the other hand, magnesium(II), aluminum(III), titanium(IV), chromium(III), manganese(II), and iron(II) were not found to be extracted into the organic phase. The equilibrium constants of vanadium(V) and iron(III) with various 4‐aroyl‐5‐pyrazolones follow the order HPMFBP>HPMBP>HPMTP, which is in accordance with their pKa values. The selectivity between vanadium(V) and iron(III) increases with increasing hydrochloric acid concentration. Further, it is clear from the results that iron(III) is not getting extracted above 1.0 mol dm?3 hydrochloric acid solution. The electronic and IR spectra of the extracted complexes of vanadium(V) and iron(III) were used to further clarify the nature of the extracted complexes. The potential of these reagents for the selective extraction and separation of vanadium(V) from titania waste chloride liquors has also been discussed. 相似文献
15.
Crosslinked poly(N‐vinylpyrrolidone), preirradiated in air with γ rays, was grafted with ethyl acrylate in dioxane and water. A detailed study of grafting was made under various reaction conditions. The graft copolymer was treated with potassium hydroxamate in ethanol. The resulting polymer contained pendant hydroxamic acid groups ( CO NHOH) and was studied for the formation of complexes with Fe(III), Cu(II), and Ni(II). The effect of pH on the metal ion uptake by the polymer was also studied. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 475–483, 2000 相似文献
16.
ABSTRACTRhodium(III) and ruthenium(III) were extracted from chloride solutions with phosphonium ionic liquids trihexyl(tetradecyl)phosphonium chloride or trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate in toluene. Influence of HCl and NaCl presence in the feed and IL concentration in the organic phase were determined. Rh(III) transport appeared to be inefficient, while over 70% of Ru(III) was extracted from 3 M HCl. Ru(III) extraction was affected by the feed acidity and the type of extractant used. The spectra of the extracts indicated some changes in the structure of Rh(III) and Ru(III) complexes in the organic phase. Also, ageing of feed solutions on the extraction of Ru(III) and Rh(III) was studied. 相似文献
17.
The extraction of palladium(II) from hydrochloric acid solutions with a novel highly basic extractant, a mixture of homologous 1-[2-(alkanoylamino)ethyl]-2-alkyl-2-imidazolines (AAI) in toluene with 15% (v/v) of n-octanol was studied. Palladium(II) is rapidly and most effectively extracted with AAI hydrochloride at the low hydrochloric acid (chloride ions) concentration (up to 1 M) and can be completely separated from Fe(III), Cu(II), and Co(II). The palladium(II) extraction at the optimum acidity occurs via an anion-exchange mechanism with the formation of ionic associates (LH)2PdCl4 (K ex = (1.5 ± 0.2) · 104 at 0.5 M HCl) and is accompanied by the dimerization of palladium(II) in the organic phase with the formation of ionic associates (LH)2Pd2Cl6 (K dim = (3.9 ± 0.4) · 10?4 at 0.5 M HCl). The anion-exchange extraction of palladium(II) at the acidity of 0.5 M HCl is temperature independent in the range 20–49°C. Complete stripping of palladium(II) can be performed using a 5% solution of thiourea in 0.1 M HCl. 相似文献
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Rauen U Springer A Weisheit D Petrat F Korth HG de Groot H Sustmann R 《Chembiochem : a European journal of chemical biology》2007,8(3):341-352
Chelatable cellular iron, and chelatable mitochondrial iron in particular, has yet to be well characterized, so the overall strength with which these "loosely bound" iron ions (presumably mainly Fe(II)) are intracellularly/intramitochondrially bound is unclear. We have previously reported the first selective mitochondrial iron indicator: rhodamine B 4-[(1,10-phenanthrolin-5-yl)aminocarbonyl]benzyl ester (RPA). With this compound as a model, we have now developed two additional mitochondrial iron indicators with very different iron-binding affinities and have applied these to the study of the chelatable iron pool in the mitochondria of isolated rat liver cells. With the new indicator rhodamine B 4-[(2,2'-bipyridin-4-yl)aminocarbonyl]benzyl ester (RDA), with 2,2'-bipyridine as chelating unit (log beta(3)=17.5), essentially the same iron concentration (16.0+/-1.9 microM) was determined as with RPA (log beta(3)=21.1), despite the four orders of magnitude difference in Fe(II)-binding affinity. This not only demonstrates the reliability of the procedure, but also confirms that iron complexation by these indicators does not induce any significant release of iron from the iron-storage proteins on the timescale of the experiment. In contrast, the indicator rhodamine B 4-[bis(pyridin-2-ylmethyl)aminomethyl]benzyl ester (PIRO), with an N,N-bis(pyridin-2-ylmethyl)amine group as chelating component (log beta(2)=12.2), could not compete against the array of endogenous ligands. The intramitochondrial concentrations of the three indicators were determined to be in the range of 100 microM: that is, about three orders of magnitude lower than the total concentration of endogenous compounds that might chelate iron ions. It is therefore estimated that chelatable mitochondrial iron ions are bound by endogenous ligands with apparent stability constants (log K(app)) of between 9 and 14. 相似文献
20.
The role of Fe(III) on the TiO2-assisted photocatalytic degradation of maleic acid has been investigated. The study on the kinetics of the removal of organic matter, as well as the identification of all the stable mineralization intermediates, demonstrates that the presence of Fe(III), adsorbed onto the TiO2 surface, renders a more efficient process through a cleaner mineralization pathway compared to bare TiO2. Furthermore, the behaviour of the system does not depend on the iron source. On the other hand, the study of the Fe(III) influence on the interaction of maleic acid with TiO2 in the solid phase, by means of ATR–FT-IR technique, has been performed. From all the reported results, it is concluded that the Fe(III) effects are mainly due to surface phenomena. The enhanced photocatalytic activity is interpreted under different perspectives, including adsorbed Fe–maleic complexes, enhanced adsorption of oxygen and lower geminate recombination yields. 相似文献