Processing and property assessment of NiTi and NiTiCu shape memory actuator springs

Among the multifarious engineering applications of NiTi shape memory alloys (SMAs), their use in actuator applications stands out. In actuator applications, where the one‐way effect (1WE) of NiTi SMAs is exploited, SM components are often applied as helical coil springs. Ingots are generally used as starting materials for the production of springs. But before SM actuator springs can be manufactured, the processing of appropriate wires from NiTi ingots poses a challenge because cold and hot working of NiTi SMAs strongly affect microstructure, and it is well known that the functional properties of NiTi SMAs are strongly dependent on their microstructure. The objective of the present paper is therefore to produce binary Ni₅₀Ti₅₀ and ternary Ni₄₀Ti₅₀Cu₁₀ SMA actuator springs, starting from ingots produced by vacuum induction melting. From these ingots springs are produced using swaging, rolling, wire drawing and a shape‐constraining procedure in combination with appropriate heat treatments. The evolution of microstructure during processing is characterized and the mechanical properties of the wires prior to spring‐making are documented. The mechanical and functional characteristics of the wires are investigated in the stress‐strain‐temperature space. Finally, functional fatigue testing of actuator springs is briefly described and preliminary results for NiTi and NiTiCu actuator springs are reported.     

Finite Element Analysis and Experimental Measurement of Deformation Behavior for NiTi Plate With Stress Concentration Part Under Uniaxial Tensile Loading

Abstract: The aim of this study is to verify the effectiveness of ordinary phenomenological constitutive relation of NiTi shape memory alloy under mechanical loading at a constant temperature, sufficiently. First, finite element analysis is performed by using ordinary phenomenological constitutive relation for rectangular plate with double notch under tensile loading at a constant temperature. Next, uniaxial tensile loading is carried out for 50.5Ni49.5Ti rectangular plate with double notch. At the same time, macroscopic stress–strain curve and local strain distribution are measured by using in‐house measurement system on the basis of digital image correlation. As a result, it is found that the stress–strain curve obtained from finite element analysis is much different from those obtained experimental measurement, especially during stress‐induced martensite transformation. The result can be derived from the phenomena of local strain band behavior arising in NiTi under mechanical loading. The phenomenological constitutive model used in present finite element analysis is constructed under assumptions that the material has isotropic characteristics and shows homogeneous deformation. However, this experimental result suggests that the material itself has anisotropy microscopically. Furthermore, material shows unique inhomogeneous deformation. Also, there is possibility that these anisotropic characteristic and inhomogeneous deformation behaviour may derive from its microstructure. In future, to sufficiently describe the macroscopic stress–strain curve of NiTi we should take into consideration the material microstructure.     

Bending rotation HCF testing of pseudoelastic Ni‐Ti shape memory alloys

In the present work, a computer‐controlled test rig for simultaneous fatigue testing of several pseudoelastic NiTi wires through bending rotation is described. Bending rotation fatigue (BRF) testing represents a displacement‐controlled experiment where a straight wire is bent into a semi‐circle und forced to rotate around its axis. Thus, each point on the wire surface is subjected to alternating tension and compression. A test rig, which allows to control loading amplitudes, rotation frequencies and temperatures is described. We report preliminary results of an experimental program, which aims for a better understanding of fatigue lives, crack initiation, and crack growth in pseudoelastic NiTi wires. It was found that a good surface quality is of utmost importance to avoid early crack initiation. Wöhler curves of pseudoelastic NiTi wires typically show two different regimes depending on the maximum imposed surface strain during bending rotation fatigue testing. Larger strain amplitudes, which are associated with macroscopic formation of stress‐induced martensite, result in relatively low fatigue lives (LCF regime). In contrast, cycle numbers exceeding 10⁷ were obtained for strain amplitudes where no large scale stress‐induced formation of martensite occurred (HCF regime).     

Tensile behaviour of superelastic NiTi alloys charged with hydrogen under applied strain

ABSTRACT

The tensile behaviour of NiTi alloys is investigated after hydrogen charging during the austenite, half-transformation and martensite phases. The specimens are charged with different current densities and charging durations. During the tensile tests, the strain of the plateau transformation decreases due to hydrogen-induced residual martensite variants. This decrease becomes important when the charging happens during the martensite phase. Accordingly, the hydrogen ensures the stability of the phase in which the charging process occurs. Moreover, a heightening of transformation stress is noticed during the plateau. The transformation stress increases when the current density grows and the charging duration rises. This occurrence is caused by the interaction between the hydrogen and NiTi structures, where hydrogen delays the NiTi martensite transformation.

This paper is part of a thematic issue on Hydrogen in Metallic Alloys     

Micromechanics of Tension‐Compression Asymmetry of Polycrystalline Shape‐Memory‐Alloys

The asymmetry associated with martensitic transformations observed in tension/compression experiments of shape‐memory‐alloys (SMAs) is investigated on the basis of a recently suggested micromechanical model. The approach is based on crystallographic theory and utilizes a framework of energy minimization in a finite deformation context. Polycrystalline NiTi under tension demonstrates smaller phase‐transformation start‐strain, differe phase‐transformation stress‐levels and flatter phase‐transformation stress‐strain slopes than that under compression in our numerical simulation. The phase‐transformation start‐stress is followed to have a linear relationship with respect to the temperature within a certain range. These results agree well with experimental results reported in the literature.     

Fatigue behaviour of nickel–titanium superelastic wires and endodontic instruments

Endodontic files made of nickel–titanium (NiTi) superelastic wires can be employed in rotary techniques for cleaning and shaping curved root canals, suffering tensile–compressive strain cycles with maximum amplitudes between 3 and 5%. The aim of this work was to study the fatigue behaviour of this material under such high deformation conditions, using NiTi instruments and superelastic wires taken from their production line. One hundred load–unload tensile cycles in the superelastic regime (4% elongation) were applied to NiTi wires. New endodontic instruments were fatigue‐tested simulating the geometrical conditions found in their clinical use. It was found that only small changes took place in the parameters describing the mechanical behaviour of the cycled wires. The measured average number of cycles to failure varies inversely with the maximum tensile strain amplitude in the fatigue tests (r= 0.993).     

State‐of‐the‐art review on extended stress intensity factor concepts

The stress intensity factor concept for describing the stress field at pointed crack or slit tips is well known from fracture mechanics. It has been substantially extended since Williams' basic contribution (1952) on stress fields at angular corners. One extension refers to pointed V‐notches with stress intensities depending on the notch opening angle. The loading‐mode‐related simple notch stress intensity factors K₁, K₂ and K₃ are introduced. Another extension refers to rounded notches with crack shape or V‐notch shape in two variants: parabolic, elliptic or hyperbolic notches (‘blunt notches’) on the one hand and root hole notches (‘keyholes’ when considering crack shapes) on the other hand. Here, the loading‐mode‐related generalised notch stress intensity factors K_1ρ, K_2ρ and K_3ρ are defined. The concepts of elastic stress intensity factor, notch stress intensity factor and generalised notch stress intensity factor are extended into the range of elastic–plastic (work‐hardening) or perfectly plastic notch tip or notch root behaviour. Here, the plastic notch stress intensity factors K_1p, K_2p and K_3p are of relevance. The elastic notch stress intensity factors are used to describe the fatigue strength of fillet‐welded attachment joints. The fracture toughness of brittle materials may also be evaluated on this basis. The plastic notch stress intensity factors characterise the stress and strain field at pointed V‐notch tips. A new version of the Neuber rule accounting for the influence of the notch opening angle is presented.     

Phase transformation and microstructure and mechanical properties of as cast NiTiRe shape memory alloys

Abstract

The microstructure, martensitic transformation and mechanical properties of as cast Ni₅₂Ti_48?xRe_x shape memory alloys (SMAs) were investigated. The microstructure of these alloys consists of B19′ martensite phase as a matrix and B2 austenite in small percentages in addition to some precipitations of NiTi intermetallic compounds. There are two types of NiTi precipitates: the first one is Ti₂Ni, which can be seen in the all microstructures of the three alloys, and the other is Ni₂Ti, which is found only in the microstructure of Ni₅₂Ti_47·7Re_0·3 alloy. According to differential scanning calorimetry measurements, one stage of transformation reaction B2 to B19′ accompanied with forward and backward martensitic transformation was observed. The martensitic peak and the austenitic peak were increased with the addition of rhenium. Both are increased as the number of valence electron per atom increase and the valence electron concentration decrease. Hardness measurements of Ni₅₂Ti_48?xRe_x SMAs are improved by the Re additions.     

形状记忆合金热疲劳前后的显微结构变化(英文)

为了改进形状记忆合金的性能和延长形状记忆合金的寿命,跟踪和研究疲劳前后形状记忆合金的显微结构变化是十分重要的。通过比较ＴｉＮｉ 形状记忆合金疲劳前和疲劳后的显微结构变化,发现除了疲劳后的样品产生一些沉积物之外没有差别。本研究证明这些沉积物是１０２０ 纳米的ＴｉＮｉ３ 相颗粒。正是由于这些ＴｉＮｉ３ 相颗粒的存在,严重影响ＴｉＮｉ 形状记忆合金的性能,并可能进一步引起形状记忆合金的断裂。     

Simulation‐based optimization of the local material state in the field of cyclically highly stressed case hardened construction details with notch effect*

Steel components very often show construction details, such as cross holes and rounded shaft shoulders which lead to local stress concentrations of the multiaxial stress state in case of mechanical loads (notch effect). Under cyclic loading these stress concentrations (hot spots) can cause crack initiation, crack propagation and finally failure of structural components. The fatigue strength of cyclically loaded components can be considerably increased by the heat treatment case hardening. The shape of the construction detail has a significant influence for the sub‐processes of the case hardening. This can be related to the carbon diffusion process during carburizing and the local heat transfer during quenching. As a result, the local material state following a case hardening process is often not optimal with respect to phase composition and residual stress field. In order to optimize the hardening process a heat treatment simulation based on the Finite Element Method was coupled with procedures for sensitivity analysis and optimization. Taking into account the operational loading conditions for the component, it was possible to adapt technological parameters of the case hardening process for the specific shape of the construction detail, leading to a substantially increased fatigue strength and therewith improvement of the efficiency of the case hardening process itself.     

A physical mechanism based constitutive model for temperature-dependent transformation ratchetting of NiTi shape memory alloy: One-dimensional model

In this paper, the effect of test temperature on the transformation ratchetting of super-elastic NiTi shape memory alloy was first investigated in the cyclic tension-unloading tests. It is shown that all the residual strain, dissipation energy, the start stress of martensite transformation and their evolutions during the cyclic loading depend greatly upon the test temperature. Based on the experimental observations, a new one-dimensional constitutive model is constructed by considering two different inelastic deformation mechanisms (i.e., martensite transformation and transformation-induced plasticity). The proposed model employs a new evolution rule of transformation-induced plasticity which considers the physical mechanism of the plastic deformation, i.e., the dislocation slipping in the austenite phase near the austenite–martensite interfaces. Furthermore, the interaction between dislocation and martensite transformation is also taken into account in the proposed model. The capability of the proposed model to predict the uniaxial temperature-dependent transformation ratchetting of NiTi shape memory alloy is verified by comparing the predictions with the experimental data.     

Powder Metallurgical Near‐Net‐Shape Fabrication of Porous NiTi Shape Memory Alloys for Use as Long‐Term Implants by the Combination of the Metal Injection Molding Process with the Space‐Holder Technique

A new method was developed for producing highly porous NiTi for use as an implant material. The combination of the space‐holder technique with the metal injection molding process allows a net‐shape fabrication of geometrically complex samples and the possibility of mass production for porous NiTi. Further, the porosity can be easily adjusted with respect to pore size, pore shape, and total porosity. The influence of the surface properties of powder metallurgical NiTi on the biocompatibility was first examined using human mesenchymal stem cells (hMSCs). It was found that pre‐alloyed NiTi powders with an average particle size smaller than 45 μm led to the surface properties most suitable for the adhesion and proliferation of hMSCs. For the production of highly porous NiTi, different space‐holder materials were investigated regarding low C‐ and O‐impurity contents and the reproducibility of the process. NaCl was the most promising space‐holder material compared to PMMA and saccharose and was used in subsequent studies. In these studies, the influence of the total porosity on the mechanical properties of NiTi is investigated in detail. As a result, bone‐like mechanical properties were achieved by the choice of Ni‐rich NiTi powder and a space‐holder content of 50 vol% with a particle size fraction of 355–500 μm. Pseudoelasticity of up to 6% was achieved in compression tests at 37 °C as well as a bone‐like loading stiffness of 6.5 GPa, a sufficient plateau stress σ₂₅ of 261 MPa and a value for σ₅₀ of 415 MPa. The first biological tests of the porous NiTi samples produced by this method showed promising results regarding proliferation and ingrowth of mesenchymal stem cells, also in the pores of the implant material.     

PM‐Composites with Nickel‐Titanium Shape Memory Alloys

Starting from NiTi‐powders, composites of nickel‐titanium shape memory alloys (NiTi‐SMA) and different stainless steels as well as of different NiTi‐SMAs were produced by using the process of hot isostatic pressing (HIP). Metallographic investigations focussed on the interface between NiTi‐SMA and stainless steel with special emphasis placed on the characterization of the typical structure of the diffusion zones in both components.     

Effect of microstructure on the fatigue of hot-rolled and cold-drawn NiTi shape memory alloys

We present results from a systematic study linking material microstructure to monotonic and fatigue properties of NiTi shape memory alloys. We consider Ni-rich materials that are either (1) hot rolled or (2) hot rolled and cold drawn. In addition to the two material processing routes, heat treatments are used to systematically alter material microstructure giving rise to a broad range of thermal, monotonic and cyclic properties. The strength and hardness of the austenite and martensite phases initially increase with mild heat treatment (300 °C), and subsequently decrease with increased aging temperature above 300 °C. This trend is consistent with transmission electron microscopy observed precipitation hardening in the hot-rolled material and precipitation hardening plus recovery and recrystallization in the cold-drawn materials. The low-cycle pseudoelastic fatigue properties of the NiTi materials generally improve with increasing material strength, although comparison across the two product forms demonstrates that higher measured flow strength does not assure superior resistance to pseudoelastic cyclic degradation. Fatigue crack growth rates in the hot-rolled material are relatively independent of heat treatment and demonstrate similar fatigue crack growth rates to other NiTi product forms; however, the cold-drawn material demonstrates fatigue threshold values some 5 times smaller than the hot-rolled material. The difference in the fatigue performance of hot-rolled and cold-drawn NiTi bars is attributed to significant residual stresses in the cold-drawn material, which amplify fatigue susceptibility despite superior measured monotonic properties.     

The effect of grain orientation on the tensile‐compressive asymmetry of polycrystalline NiTi shape memory alloy

The purpose of the present study is to thoroughly understand the influence of crystallographic texture on the stress‐strain asymmetric behavior of polycrystalline NiTi shape memory alloy under tension and compression. To do this, a 3D thermo‐mechanical model has been implemented in a finite element program and textured and untextured polycrystalline NiTi have been considered. In our polycrystalline finite element model, each element represents one grain and a set of crystal orientations which approximate the initial crystallographic texture of the NiTi are assigned to the elements. From the calculated results, it is found that the crystallographic texture is the important reason for the tension‐compression asymmetry. For the textured polycrystal, the tension‐compression asymmetry can be observed clearly, but for the polycrystal containing randomly oriented grains, the stress‐strain curves show low levers of asymmetry between tensile and compressive loading, and the evolutions of martensite volume fractions are similar under two stress states.     

Experimental study of one‐dimensional superelastic capability of a nearly equi‐atomic NiTi shape memory alloy

A series of experimental studies have been carried out on nearly equi‐atomic NiTi shape memory alloy wires. The effects of fatigue cycles, displacement rates as well as testing temperatures on the superelastic capabilities have been studied. Under cycling loading, the threshold stresses for martensitic transformation decrease and the residule strains increase. Saturation is reached after 100 cycles. With increasing displacement rates, the critical stresses required for the martensitic transformation increase and the slopes of the upper plateau in the stress‐strain curves rise. The dissipated energy increases rapidly with increasing displacement rate, reaches a maximum value at around 6.0mm/min and then decreases as the displacement rate continues to increase. Tests also show that the threshold stresses characterizing the forward/reverse transformations increase linearly with increasing test temperature.     

Fatigue assessment of laserbeam‐welded aluminium joints under multiaxial loading

This paper presents the results and evaluation of the multiaxial fatigue behaviour of laserbeam‐welded overlapped tubular joints made from the artificially hardened aluminium alloy AlSi1MgMn T6 (EN AW 6082 T6) under multiaxial loadings with constant and variable amplitudes. Several fatigue test series under pure axial and pure torsional loadings as well as combined axial and torsional proportional and non‐proportional loadings have been carried out in the range of 2·10⁴ to 2·10⁷ cycles. The assessment of the investigated thin‐walled joints is based on a local notch stress concept. In this concept the fatigue critical area of the weld root is substituted by a fictitious notch radius r_ref = 0.05 mm. The equivalent stresses in the notch, considering especially the fatigue life reducing influence of non‐proportional loading in comparison to proportional loading, were calculated by a recently developed hypothesis, which is called the Stress Space Curve Hypothesis (SSCH). This hypothesis is based on the time evolution of the stress state during one load cycle. In addition, the fatigue strength evaluation of multiaxial spectrum loading was carried out using a modified Gough‐Pollard algorithm.     

A unifying approach to estimate the high-cycle fatigue strength of notched components subjected to both uniaxial and multiaxial cyclic loadings

This paper proposes an engineering method suitable for predicting the fatigue limit of both plain and notched components subjected to uniaxial as well as to multiaxial fatigue loadings. Initially, some well‐known concepts formalized by considering the cracking behaviour of metallic material under uniaxial cyclic loads have been extended to multiaxial fatigue situations. This theoretical extension allowed us to form the hypothesis that fatigue limits can be estimated by considering the linear–elastic stress state calculated at the centre of the structural volume. This volume was assumed to be the zone where all the main physical processes take place in fatigue limit conditions. The size of the structural volume was demonstrated to be constant, that is, independent from the applied loading type, but different for different materials. Predictions have been made by Susmel and Lazzarin's multiaxial fatigue criterion, applied using the linear–elastic stress state determined at the centre of the structural volume. The accuracy of this method has been checked by using a number of data sets taken from the literature and generated by testing notch specimens both under uniaxial and multiaxial fatigue loadings. Our approach is demonstrated to be a powerful engineering tool for predicting the fatigue limit of notch components, independently of material, stress concentration feature and applied load type. In particular, it allowed us to perform predictions within an error interval of about ±25% in stress, even though some material mechanical properties were either estimated or taken from different sources.