Indoor and outdoor PM2.5 and PM10 concentrations in the air during a dust storm

Asian dust storms (ADS) originating from the arid deserts of Mongolia and China are a well-known springtime meteorological phenomenon throughout East Asia. The ventilation systems in office utilize air from outside and therefore it is necessary to understand how these dust storms affect the concentrations of PM_2.5 and PM₁₀ in both the indoor and outdoor air. We measured dust storm pollution particles in an office building using a direct-reading instrument (PC-2 Quartz Crystal Microbalance, QCM) that measured particle size and concentration every 10 min for 1 h, three times a day. A three-fold increase in the concentrations of PM_2.5 and PM₁₀ in the indoor and outdoor air was recorded during the dust storms. After adjusting for other covariates, autoregression models indicated that PM_2.5 and PM₁₀ in the indoor air increased significantly (21.7 μg/m³ and 23.0 μg/m³ respectively) during dust storms. The ventilation systems in high-rise buildings utilize air from outside and therefore the indoor concentrations of fine and coarse particles in the air inside the buildings are significantly affected by outside air pollutants, especially during dust storms.     

Transformation of metals speciation in a combined landfill leachate treatment

Landfill leachate was treated by a combined sequential batch reactor (SBR), coagulation, Fenton oxidation and biological aerated filter (BAF) technology. The metals in treatment process were fractionated into three fractions: particulate and colloidal (size charge filtration), free ion/labile (cation exchange) and non-labile fractions. Fifty percent to 66% Cu, Ni, Zn, Mn, Pb and Cd were present as particulate/colloidal matter in raw leachate, whereas Cr was present 94.9% as non-labile complexes. The free ion/labile fractions of Ni, Zn, Mg, Mn, Pb and Cd increased significantly after treatment except Cr. Fifty-nine percent to 100% of Al was present mainly as particulate/colloidal matter > 0.45 μm and the remaining portions were predicted as non-labile complexes except in coagulation effluent. The speciation of Fe varied significantly in various individual processes. Visual MINTEQ simulation showed that 95-100% colloidal species for Cu, Cd and Pb were present as metal-humic complexes even with the lower dissolved organic carbon. Optimum agreements for the free ion/labile species were within acidic solution, whereas under-estimated in alkaline effluents. Overestimated particulate/colloidal fraction consisted with the hypothesis that a portion of colloids in fraction < 0.45 μm were considered as dissolved.     

Measurements of the explosibility of peat dust

Results from dust explosion tests carried out with peat dust samples are reported. The maximum explosion pressure and the K_St value have been measured, and especially their dependences on the moisture content and mean particle size have been investigated. It is concluded that the maximum explosion pressure and the K_St value of homogeneous dry (moisture content <35% W/W) and fine (mean particle size <200 μ)_peat dust can be estimated with a reasonable accuracy from the moisture content and the mean particle size. For moist (moisture content >35% W/W) and/or coarse (mean particle size >200 μm) peat dust, it is often possible only to predict whether the dust is explosible or not. For heterogeneous peat mixtures composed of dusts with very different moisture contents and/or mean particle sizes, it is not possible in a reliable way to estimate the maximum explosion pressure or the K_St value based on the mean moisture content and the mean particle size of the mixture. It is not always even possible to predict whether the mixture is explosible or not.     

A general mechanistic model for predicting the fate and transport of phthalates in indoor environments

A mechanistic model that considers particle dynamics and their effects on surface emissions and sorptions was developed to predict the fate and transport of phthalates in indoor environments. A controlled case study was conducted in a test house to evaluate the model. The model‐predicted evolving concentrations of benzyl butyl phthalate in indoor air and settled dust and on interior surfaces are in good agreement with measurements. Sensitivity analysis was performed to quantify the effects of parameter uncertainties on model predictions. The model was then applied to a typical residential environment to investigate the fate of di‐2‐ethylhexyl phthalate (DEHP) and the factors that affect its transport. The predicted steady‐state DEHP concentrations were 0.14 μg/m³ in indoor air and ranged from 80 to 46 000 μg/g in settled dust on various surfaces, which are generally consistent with the measurements of previous studies in homes in different countries. An increase in the mass concentration of indoor particles may significantly enhance DEHP emission and its concentrations in air and on surfaces, whereas increasing ventilation has only a limited effect in reducing DEHP in indoor air. The influence of cleaning activities on reducing DEHP concentration in indoor air and on interior surfaces was quantified, and the results showed that DEHP exposure can be reduced by frequent and effective cleaning activities and the removal of existing sources, though it may take a relatively long period of time for the levels to drop significantly. Finally, the model was adjusted to identify the relative contributions of gaseous sorption and particulate‐bound deposition to the overall uptake of semi‐volatile organic compounds (SVOCs) by indoor surfaces as functions of time and the octanol‐air partition coefficient (K_oa) of the chemical. Overall, the model clarifies the mechanisms that govern the emission of phthalates and the subsequent interactions among air, suspended particles, settled dust, and interior surfaces. This model can be easily extended to incorporate additional indoor source materials/products, sorption surfaces, particle sources, and room spaces. It can also be modified to predict the fate and transport of other SVOCs, such as phthalate‐alternative plasticizers, flame retardants, and biocides, and serves to improve our understanding of human exposure to SVOCs in indoor environments.     

装有静电除尘及高效过滤器的新风系统在建筑中的应用及研究

为改善建筑室内空气品质,对位于湖南省长沙市一栋办公楼加装带有静电除尘和高效过滤器的新风系统,并对建筑改造前后的室内空气品质进行测试。利用德图Testo435多功能环境测量仪、甲醛检测仪、CW-HPC600颗粒物检测仪等仪器对室内温湿度、二氧化碳浓度、甲醛、颗粒物进行实测分析。结果显示,改造后该建筑室内空气中的二氧化碳浓度在1000 ppm以下,甲醛含量小于0.05 mg/m3,颗粒物的含量接近0μg/m3,远远高于GB/T 18883-2002《室内空气质量标准》的规定。     

A comparative study of walking‐induced dust resuspension using a consistent test mechanism

Human walking influences indoor air quality mainly by resuspending dust particles settled on the floor. This study characterized walking‐induced particle resuspension as a function of flooring type, relative humidity (RH), surface dust loading, and particle size using a consistent resuspension mechanism. Five types of flooring, including hardwood, vinyl, high‐density cut pile carpet, low‐density cut pile carpet, and high‐density loop carpet, were tested with two levels of RH (40% and 70%) and surface dust loading (2 and 8 g/m²), respectively. Resuspension fraction r_a (fraction of surface dust resuspended per step) for house dust was found to be varied from 10^?7 to 10^?4 (particle size: 0.4–10 µm). Results showed that for particles at 0.4–3.0 µm, the difference in resuspension fraction between carpets and hard floorings was not significant. For particles at 3.0–10.0 µm, carpets exhibited higher resuspension fractions compared with hard floorings. Increased RH level enhanced resuspension on high‐density cut pile carpet, whereas the opposite effect was observed on hard floorings. Higher surface dust loading was associated with lower resuspension fractions on carpets, while on hard floorings the effect of surface dust loading varied with different RH levels.     

The physicochemical speciation of Cd, Pb, Cu, Fe and Mn in the final effluent of a sewage treatment works and its impact on speciation in the receiving river

A scheme for the speciation of metals in freshwaters has been applied to the analysis of the final effluent from a sewage treatment plant and to the receiving river upstream and downstream of the effluent outfall. The treatment plant was selected because of the high influent and effluent concentrations of Cd. The metal speciation patterns in the effluent are interpreted primarily in terms of organic interactions, which appear to be exerting a solubilizing effect on Cd and Cu, but not on the Pb and Fe which are principally associated with the particulate size fraction (> 12 μm). The influx of metals with the sewage effluent alters the speciation pattern in the river. A large part of the Cd is added to the smallest size fraction (< 0.015 μm). However, the major part of each metal, with the exception of Mn, is associated with the colloidal and particulate size fractions, thus minimising the immediate toxic significance to aquatic life.     

Indoor aerosols: from personal exposure to risk assessment

Motivated by growing considerations of the scale, severity, and risks associated with human exposure to indoor particulate matter, this work reviewed existing literature to: (i) identify state‐of‐the‐art experimental techniques used for personal exposure assessment; (ii) compare exposure levels reported for domestic/school settings in different countries (excluding exposure to environmental tobacco smoke and particulate matter from biomass cooking in developing countries); (iii) assess the contribution of outdoor background vs indoor sources to personal exposure; and (iv) examine scientific understanding of the risks posed by personal exposure to indoor aerosols. Limited studies assessing integrated daily residential exposure to just one particle size fraction, ultrafine particles, show that the contribution of indoor sources ranged from 19% to 76%. This indicates a strong dependence on resident activities, source events and site specificity, and highlights the importance of indoor sources for total personal exposure. Further, it was assessed that 10–30% of the total burden of disease from particulate matter exposure was due to indoor‐generated particles, signifying that indoor environments are likely to be a dominant environmental factor affecting human health. However, due to challenges associated with conducting epidemiological assessments, the role of indoor‐generated particles has not been fully acknowledged, and improved exposure/risk assessment methods are still needed, together with a serious focus on exposure control.     

Characterization of particulate emissions from occupant activities in offices

This paper characterizes the relationship between occupant activities and indoor air particulate levels in a non-smoking office building. Occupant activities were recorded on video. Particulate concentrations were monitored by three optical particle counters (OPCs) in five size ranges at three heights. Particulate mass concentrations were measured gravimetrically and bioaerosol concentrations were determined by impaction methods. Occupant activities and number concentrations were determined with 1-min resolution over a 1-week period. Occupant activities such as walking past or visiting the monitoring site explained 24-55% of the variation of 1- to 25-micron diameter particle number concentrations. Statistical models associating particulate concentrations with occupant activities depended on the size fraction and included an autocorrelative term. Occupant activities are estimated to contribute up to 10 micrograms m-3 in particulate concentrations per person. Number concentrations of particles smaller than 1 micron had little correlation with indoor activities other than cigarette smoking and were highly correlated with outdoor levels. The method can be used to characterize emissions from activities if rapid measurements can be made and if activities can be coded from the video record.     

Environmental pollution by wind blown lead mine waste: A case study in wales,U.K.

This paper reports an investigation of environmental Pb pollution by wind blown material from a spoil heap at a derelict Pb mine in West Wales. Most of the <2 mm fraction of the spoil is of sufficiently small particle diameter to move by saltation and the material <2 μm probably approximates to the composition of PbS. Meteorological data for 1977/1978 were analysed. During dry weather northerly winds predominate and these are probably funnelled in an east-west direction by the valley in which the mine is situated. It is calculated that the spoil can be set moving by winds of Force 4 or greater and such winds were experienced for 193 days in the reference year. Atmospheric transport of Pb-rich dust was monitored by moss bags and Pb isoline maps were constructed from the data. There is a marked movement of dust westwards from the spoil heap to nearly 1800 m down the valley. A survey of Pb in soil revealed a characteristic east-west alignment of the Pb isolines which suggests that air-borne dust is the major source of pollution. Pb in unwashed lettuce leaves was some 5 times greater than in washed leaves while the latter contained Pb in excess of the British legal limit. Pb in domestic water was not a problem. It is concluded that blowing spoil is an immediate environmental hazard through deposition on plant leaves and through inhalation by people or animals. Pb which has accumulated in the soil may present a dietary problem.     

Linear alkylbenzene sulfonates in indoor floor dust

A method was developed to analyse linear alkylbenzene sulfonates (C10-C13 LAS) in vacuumed floor dust in office buildings by the use of HPLC chromatography. Floor dust was sampled with a specially designed vacuum cleaner and fractionated into fibres and particles. The content of LAS in the particle fraction of floor dust sampled from seven different public buildings varied between 34 microg LAS g(-1) dust and 1,500 microg LAS g(-1) dust, while the content of the fibre fractions was generally higher with up to 3,500 microg LAS g(-1) dust. The use of a cleaning agent with LAS resulted in increases approximately 30% of the amount of LAS in the floor dust after floor wash relative to just before floor wash. However, the most important source of LAS in the indoor floor dust appeared to be residues of detergent in clothing. Thus, a newly washed shirt contained 2,960 microg LAS g(-1) clothing. The analysis of the office dust samples indicated that LAS (and probably other detergents) might be of importance for the indoor environment.     

Hospital indoor PM10/PM2.5 and associated trace elements in Guangzhou, China

PM10 and PM2.5 samples were collected in the indoor environments of four hospitals and their adjacent outdoor environments in Guangzhou, China during the summertime. The concentrations of 18 target elements in particles were also quantified. The results showed that indoor PM2.5 levels with an average of 99 microg m(-3) were significantly higher than outdoor PM2.5 standard of 65 microg m(-3) recommended by USEPA [United States Environmental Protection Agency. Office of Air and Radiation, Office of Air Quality Planning and Standards, Fact Sheet. EPA's Revised Particulate Matter Standards, 17, July 1997] and PM2.5 constituted a large fraction of indoor respirable particles (PM10) by an average of 78% in four hospitals. High correlation between PM2.5 and PM10 (R(2) of 0.87 for indoors and 0.90 for outdoors) suggested that PM2.5 and PM10 came from similar particulate emission sources. The indoor particulate levels were correlated with the corresponding outdoors (R(2) of 0.78 for PM2.5 and 0.67 for PM10), demonstrating that outdoor infiltration could lead to direct transportation into indoors. In addition to outdoor infiltration, human activities and ventilation types could also influence indoor particulate levels in four hospitals. Total target elements accounted for 3.18-5.56% of PM2.5 and 4.38-9.20% of PM10 by mass, respectively. Na, Al, Ca, Fe, Mg, Mn and Ti were found in the coarse particles, while K, V, Cr, Ni, Cu, Zn, Cd, Sn, Pb, As and Se existed more in the fine particles. The average indoor concentrations of total elements were lower than those measured outdoors, suggesting that indoor elements originated mainly from outdoor emission sources. Enrichment factors (EF) for trace element were calculated to show that elements of anthropogenic origins (Zn, Pb, As, Se, V, Ni, Cu and Cd) were highly enriched with respect to crustal composition (Al, Fe, Ca, Ti and Mn). Factor analysis was used to identify possible pollution source-types, namely street dust, road traffic and combustion processes.     

Surface dust contamination and perceived indoor environment in office buildings

The purpose of the study was to evaluate the impact of cleaning on indoor environment quality. Surface dust contamination and occupants' perception of the work environment factors and symptoms were the parameters studied. Six multi-floor office buildings were selected. Dust contamination on surfaces was sampled with gelatine foils and quantified using a BM-Dustdetector. Occupants' perceptions of the environment were assessed with modified MM-40 questionnaires. The results indicated that each building had its own surface dust contamination profile. Weekly cleaning maintained the surface dust contamination at the highest acceptable level for indoor environments. The occupants and their activities have a major effect on the level of dust particle contamination on desks. The correlation between the perceived surface dust contamination and the level of satisfaction with cleaning was as expected. Furthermore, surface dust contamination appeared not to be associated with work-related symptoms. PRACTICAL IMPLICATIONS: The results provide information about current program for contractors and clients, e.g. appropriate cleaning intervals of different surfaces, and the influence of disorder on result. After the evaluation of surface dust contamination levels, it will be possible for cleaning companies to focus on the most important surfaces to clean in order to enhance the quality of the indoor environment in office buildings. This should lead to future development work, which will require cooperation between contractors, clients, and research scientists. In office environments where high cleanliness is required, objective measurements (with instruments) are needed in addition to subjective measurements (the perceptions of occupants). It is essential to evaluate the efficiency of cleaning programs regularly with effective and appropriate quality-monitoring methods.     

Investigation of smoke particulates generated during the thermal degradation of natural and synthetic materials

This paper describes results obtained in a program investigating the physical and chemical properties of particulates generated during the burning of three commonly used materials. Small samples of wood, rigid urethane foam and polyvinyl chloride plastic have been burned under non-flaming conditions at room temperature in a ventilated combustion products test chamber. Continuous measurements have been made of smoke particle average size, particle size distributions, particulate optical density, particulate volume and mass concentrations, and particulate index of refraction utilizing an aerosol sampling system and an in situ scattered and attenuated light optical system. Non-flaming tests have been run in different ventilation gas compositions and at three radiant heating levels in an attempt to simulate real-fire situations. A review of previous results obtained by the aerosol sampling system is followed by presentation of new data taken with the in situ optical system. This data shows that average smoke particle sizes tend to vary during a test. Furthermore, particle sizes are generally larger for tests run at the highest heating rates. Available data also indicates that the physical characteristics of the smoke particles are relatively for non-flaming conditions. These results are consistent with previously reported aerosol sampling data. Also, continuous optical density measurements are presented, which allow the determination of the relative tendency of a smoldering material to obscure vision under different conditions. Finally, scanning electron microscope photographs provide new information on the detailed nature of smoke particles generated during non-flaming combustion.     

Particulate Matter in the Hospital Environment

Abstract Investigations of particle concentration levels and size distribution were conducted in the complex hospital system of the Royal Children's and the Royal Brisbane Hospitals in Queensland, Australia. The aim of the measurements was to provide an indication of particulate sources in the hospital environment and relate particle characteristics to the operating parameters of the hospitals. The measurements were performed using the most advanced instrumentation for size classification in the submicrometer and supermicrometer levels. The conclusions from the investigation were: (i) that indoor concentration levels of particle numbers are closely related to outdoor concentration levels, indicating that outdoor particulates were the main contributor to the indoor particulates in the hospitals under investigations; and (ii) that the performance of filtration/ventilation systems is the most critical parameter in reducing general particulate concentration levels in those hospital units where medical procedures can result in generation of potentially hazardous organic aerosols.     

Influence of salinity and mineralization on trace metal sorption to cyanobacteria in natural waters

The equilibrium distribution of Cd, Cu and Pb between the cyanobacterium Anabaena spp. and natural lake water as a function of salinity and degree of algal decomposition, was studied using batch experiments. Adsorption isotherms could be described with the Freundlich equation. Distribution coefficients (K_d) for Anabaena spp. were largest for Pb, followed by Cd and Cu. The variation in K_d values for Cd was explained by a model accounting for metal complexation to the algal surface and complexation by dissolved ligands of variable concentration. The phytoplankton/water distribution of Cd in waters of different salinity appears to be regulated by the free Cd²⁺ activity in solution. Mineralization of Anabaena spp. for 42 d resulted in a decrease of the solid to water ratio by a factor of 12, and an increase in K_d for Cd (factor four), Cu (factor eight) and Pb (factor 10–20). The increase in K_d is attributed to a higher affinity of the metals for the adsorbent. The use of constant K_d values for mineralizing phytoplankton and detritus in trace metal fate models, may result in underestimations of bound fractions. The extent to which this fraction is underestimated, depends on the time course of the distribution coefficient and the solid to water ratio during the mineralization process.     

Biomonitoring of Cd, Cr, Hg and Pb in the Baluarte River basin associated to a mining area (NW Mexico)

With the purpose of knowing seasonal variations of Cd, Cr, Hg and Pb in a river basin with past and present mining activities, elemental concentrations were measured in six fish species and four crustacean species in Baluarte River, from some of the mining sites to the mouth of the river in the Pacific Ocean between May 2005 and March 2006. In fish, highest levels of Cd (0.06 μg g^− 1 dry weight) and Cr (0.01 μg g^− 1) were detected during the dry season in Gobiesox fluviatilis and Agonostomus monticola, respectively; the highest levels of Hg (0.56 μg g^− 1) were detected during the dry season in Guavina guavina and Mugil curema. In relation to Pb, the highest level (1.65 μg g^− 1) was detected in A. monticola during the dry season. In crustaceans, highest levels of Cd (0.05 μg g^− 1) occurred in Macrobrachium occidentale during both seasons; highest concentration of Cr (0.09 μg g^− 1) was also detected in M. occidentale during the dry season. With respect to Hg, highest level (0.20 μg g^− 1) was detected during the rainy season in Macrobrachium americanum; for Pb, the highest concentration (2.4 μg g^− 1) corresponded to Macrobrachium digueti collected in the dry season. Considering average concentrations of trace metals in surficial sediments from all sites, Cd (p < 0.025), Cr (p < 0.10) and Hg (p < 0.15) were significantly higher during the rainy season. Biota sediment accumulation factors above unity were detected mostly in the case of Hg in fish during both seasons. On the basis of the metal levels in fish and crustacean and the provisional tolerable weekly intake of studied elements, people can eat up to 13.99, 0.79 and 2.34 kg of fish in relation to Cd, Hg and Pb, respectively; regarding crustaceans, maximum amounts were 11.33, 2.49 and 2.68 kg of prawns relative to levels of Cd, Hg and Pb, respectively.     

Airborne particulate matter and gaseous air pollutants in residential structures in Lodi province, Italy

The province of Lodi is located in northern Italy on the Po River plain, where high background levels of air pollutants are prevalent. Lodi province is characterized by intensive agriculture, notably animal husbandry. This paper assesses indoor levels of selected airborne pollutants in 60 homes in the province, with special attention to size-fractionated particulate matter (PM). Indoor PM?.? concentrations are frequently higher than current guidelines. PM?? and nitrogen dioxide also exceed the respective guideline recommendations in some cases, noting that 24-h nitrogen dioxide levels were compared with an annual limit value. All other studied pollutant levels are below current international guidelines. Among indoor PM size fractions, PM?.? is predominant in terms of mass concentrations corresponding to 57% of PM?? in summer and 71% in winter. A strong seasonal trend is observed for all studied pollutants, with higher levels in winter corresponding to changes in ambient concentrations. The seasonal variation in PM?? is largely due to PM?.? increase from summer to winter. Summer indoor PM levels are mainly from indoor-generated particles, while particles of outdoor origin represent the main contribution to winter indoor PM levels. On average, indoor concentrations of coarse PM are mostly constituted by indoor-generated particles. PRACTICAL IMPLICATIONS: This study presents a comparison between measured indoor concentrations in the study area and indoor air quality guideline criteria. Accordingly, particulate matter (PM) and NO? are identified as key pollutants that may pose health concerns. It is also found that indoor PM in residential units is mainly constituted by particles with aerodynamic diameters <0.5 μm, especially in winter. Risk mitigation strategies should be focused on the reduction in indoor levels of NO? and ultrafine and fine particles, both infiltrated from outdoors and generated by indoor sources.     

Dust particulate absorption by ivy (Hedera helix L) on historic walls in urban environments

The potential bio-protective role of urban greenery and how it interacts with airborne dust and pollutants has been the subject of much recent research. As particulate pollution has been implicated in both the deterioration of building materials and in damaging human health, understanding how it interacts with urban greenery is of great applied interest. Common or English Ivy (Hedera helix L) grows widely on urban walls in many parts of the world, and thus any bio-protective role it might play is of broad relevance. Using Scanning Electron Microscopy ivy leaves collected on roadways were examined to determine if ivy can absorb dust and pollutants that can instigate decay processes on stone walls and impact human health in urban environments. Results showed that ivy acts as a ‘particle sink’, absorbing particulate matter, particularly in high-traffic areas. It was effective in adhering fine (< 2.5 μm) and ultra-fine (< 1 μm) particles at densities of up to 2.9 × 10¹⁰ per m². Our findings suggest that through absorbing pollutant particles ivy can retard bio-deteriorative processes on historic walls and reduce human exposure to respiratory problems caused by vehicle pollutants.     

不同气候区城市公共建筑内微生物浓度对比分析

为研究不同气候区公共建筑室内微生物污染状况,选取昆明和南京分别代表温和地区和夏热冬冷地区,对医院和办公楼2类公共建筑内的微生物浓度进行了测量和分析。结果表明:温和气候区内医院细菌和真菌平均浓度分别为520、316 cfu/m³,办公楼细菌和真菌平均浓度分别为369、520 cfu/m³,均高于夏热冬冷气候区对应类型公共建筑;2个气候区室内细菌、真菌粒径分布相似,峰值均出现在粒径范围Ⅳ级(2.1~3.3μm)和Ⅴ级(1.1~2.1μm);2个气候区公共建筑室内相对湿度和空气真菌浓度存在确定关系,除此之外,仅在昆明医院内发现温度和微生物浓度之间存在显著相关性。