Effects of rare earth on inclusions and corrosion resistance of 10PCuRE weathering steel

The types,morphologies and distributions of nonmetallic inclusions in Cu-P weathering steels with and without rare earth were analyzed through a quantitative image analyzer,scanning electron microscopy(SEM)and energy dispersive spectroscopy(EDS)attached to SEM.Solid-soluble content of rare earth in the steels was analyzed by non-aqua electroanalysis and ICP.The results showed that rare earth modified the types and the morphologies of inclusions in the weathering steels.The small spherical rare earth oxysulfides and rare earth sulphides replaced the elongated MnS inclusions in the RE weathering steels.The rare earth inclusions dispersedly distributed and most inclusions were smaller than 2 μm in size.The optimum content of RE was 0.0065%-0.016% for 10PCuRE weathering steels containing about0.002% oxygen and 0.004% sulfur.Solid-soluble content of rare earth in steels was(14-20)x 10-6,which can act as a micro-alloying element.The corrosion resistance of 10PCuRE weathering steels and Q235 were studied by dry-wet cyclic immersion test.Their corrosion rates were obtained respectively.The polarization curves and pitting corrosion behaviors of weathering steels with and without rare earth were measured by electrochemical methods.The corrosion resistance of Cu-P weathering steels was improved by adding an appropriate amount of rare earth.Less and fewer rare earth inclusions largely decreased pitting susceptibility and rate of pit propagation.The pitting potential and the resistance against pitting corrosion of the RE weathering steel were significantly improved due to the modification of rare earth to inclusions.     

Lanthanide NIR luminescence for telecommunications, bioanalyses and solar energy conversion

Present-day advanced technologies heavily rely on the exciting magnetic and spectroscopic properties of lanthanide ions. In particular, their ability to generate well-characterized and intense near-infrared (NIR) luminescence is exploited in any modern fiber-optic telecommunication network. In this feature article, we first summarize the whereabouts underlying the design of highly luminescent NIR molecular edifices and materials. We then focus on describing the main trends in three applications related to this spectral range: telecommunications, biosciences, and solar energy conversion. In telecommunications, efforts concentrate presently on getting easily processable polymer-based waveguide amplifiers. Upconversion nanophosphors emitting in the visible after NIR excitation are now ubiquitous in many bioanalyses while their application to bio-imaging is still in its early stages; however, highly sensitive NIR-NIR systems start to be at hand for both in vitro and in vivo imaging, as well as dual probes combining magnetic resonance and optical imaging. Finally, both silicon-based and dye-sensitized solar cells benefit from the downconversion and upconversion capabilities of lanthanide ions to harvest UV and NIR solar light and to boost the overall quantum efficiency of these next-generation devices.     

Evaluation of D113 cation exchange resin for the removal of Eu(Ⅲ) from aqueous solution

Batch adsorption experiments were conducted for the adsorption of Eu(Ⅲ) ions from aqueous solution by D113 resin. The results indicated that D113 resin could adsorb Eu(Ⅲ) ion effectively from aqueous solution. The adsorption was strongly dependent on pH of the medium with enhanced adsorption as the pH turned from 3.50 to 7.00 and the optimal adsorption condition was in HAc-NaAc medium with pH value of 6.50. The maximum uptake capacity of Eu(Ⅲ) ions was 290.9 mg/g D113 at 298 K, at an initial pH value of 6.50. The overall adsorption process was best described by Lagergren-first-order kinetics. When Freundlich and Langmuir isotherms were tested, the latter had a better fit with the experimental data. The thermodynamic parameters such as free energy (G) which were all negative, indicated that the adsorption of Eu(Ⅲ) ions onto D113 resin was spontaneous and the positive value of enthalpy (H) showed that the adsorption was endothermic in nature. Thomas model was applied to experimental column data to determine the characteristic parameters of column useful for process design. Furthermore, Eu(Ⅲ) could be eluted by using 3.0 mol/L HCl solution and the D113 resin could be regenerated and reused.     

Phase structure and temperature dependent luminescence properties of Sr2LiSiO4F: Eu2+ and Sr2MgSi2O7: Eu2+ phosphors

Green-emitting Sr2LiSiO4F:Eu2+ and blue-emitting Sr2MgSi2O7:Eu2+ phosphors were synthesized by the conventional high temperature solid-state route,respectively.Their structures and photoluminescenee properties were comparatively investigated.It was found that the mixture phases of Sr2MgSi2O7 and SrF2 were obtained when a part of Sr2+ in Sr2LiSiO4F was replaced by some amount of Mg2+ in order to design the possible SrMgLiSiO4F:Eu2+ phosphor.Based on the photoluminescence analysis,Sr2LiSiO4F:Eu2+ phosphor exhibited a green broad emission band of main peak at 513 nm under the excitation of 365 nm,while the Sr2MgSi2O7:Eu2+ and SrMgLiSiO4F:Eu2+ phosphor showed blue emission centered at 467 nm.The temperature dependent photoluminescence properties and room temperature decay time for the three kinds of phosphors were also discussed in this paper.     

Er3+-substituted W-type barium ferrite: preparation and electromagnetic properties

Er3+-substituted W-type barium ferrites Ba1-xErx(Zn0.3Co0.7)2Fe16O27(x=0.00,0.05,0.10,0.15,0.20)were synthesized by polymer adsorbent combustion method.Samples were characterized by X-ray diffraction analysis(XRD),X-ray fluorescence(XRF),scanning electron microscopy(SEM)and network analyzer to investigate the relationships among Er3+concentration,crystal structure,surface mcrphology and electromagnetic properties.All the XRD patterns showed pure phase of W-type barium ferrite when x≤0.15,while the impurity phase of ErFeO3 appeared when x=0.20.The pure W-type barium ferrite showed a hexagonal flake shape.In addition,the microwave electromagnetic properties of samples were analyzed in the frequency range of 2-18 GHz.It was indicated that the electromagnetic properties were significantly improved when Er3+doping content was 0.10.The reasons were also discussed using electromagnetic theory.The optimized ferrite exhibited excellent microwave absoption performance.The maximum of reflection loss(RL)reached about-27.4 dB and RL was below-10dB at the frequency range from 8.4 GHz to 18 GHz,when the thickness was 2.6 mm.     

EXAFS investigation and luminescent properties of nanosized Tb: Lu2O3 phosphors

Nanosized terbium doped Lu2O3 phosphors were synthesized via a modified co-precipitation processing.The as-prepared Tb:Lu2O3 phosphors was consisted of well crystallized nanosized sphere particles with a diameter of about 30 nnx Local structure of Tb ions in Lu2O3 lattice was investigated by an analytical approach based on Fourier transformation of the extended X-ray absorption fine structure(EXAFS) data.X-ray near edge structure (XANES) spectra suggested that all Tb ions doped were tervalonce.EXAFS results indicated that Tb ions have entered the Lu2O3 cubic lattice by means of solid solution.The coordination number and first shell Tb-O distance dropped with the increasing of Tb concentration.Emission spectra of the phosphors was shown to be typical for Tb3+ with main components at 542,550 and 490 nm,derived from irradiative relaxation of 5D4 level.The emission intensity decreased severely with the increasing of Tb concentration from 1 mol.% to 15 tool.%,suggesting a significant concentration quenching above 1 mol.% Tb.The reduction of emission intensity was interpreted by higher distortion derived relaxation among the surface state resident Tb3+ ions.     

Multi-Pass Simulation of Heavy Plate Rolling Including Intermediate Forced Cooling

Thermomechanical Controlled Processing (TMCP) including accelerated cooling after the final hot rolling pass is a well-established technology,widely applied in HSLA steel plate production.However,there are still certain limitations,especially for thicker plate.The rolling schedule includes a long holding period (HP) after the roughing stage to allow the temperature to fall sufficiently for optimised TMCP during finishing.Intermediate Forced Cooling (IFC) applied during the HP can increase productivity by decreasing the required hold time,can restrict austenite grain growth,and can also improve the subsequent strain penetration in thick plate with further metallurgical benefits.Multi-pass plane strain compression (PSC) tests have been performed on the thermomechanical compression (TMC) machine at Sheffield University including different severities of IFC.Clearly it is impossible to simulate all aspects of the temperature and strain gradients present in thick plates in laboratory specimens,and most of the tests were conducted at temperatures and strains calculated by Finite Element modelling as relevant to specific positions through the plate thickness.However,some aspects of the gradients were addressed with tests using cold platens.The results have indeed shown that IFC can shorten the HP and reduce austenite grain growth and its variation across thick plate.     

Overview of Particles and Bubbles in Continuously Cast Steel

This paper gives an overview of phenomena associated with particles and bubbles in continuously cast steel. During steel processing from deoxidation to solidification the inclusion population undergoes changes with opportunities of removal. Flotation is an important separation mechanism. Inclusion particles may accumulate in the solidifying strand, thus forming enriched bands, which depend on the type of casting machine. Bubbles are created during inert gas injection. They also change in size, can float out, but also form accumulation bands. The interaction of bubbles and particles is discussed. Internal structure that recently has been observed on the inner surface of bubbles will be reviewed.     

烦恼 快乐 艺术——池莉“人生三部曲”解读

池莉的"人生三部曲"--<烦恼人生>、<不谈爱情>、<太阳出世>诉尽了普普通通的市民烦恼,小说中主人公被柴米油盐、吃喝拉撒、老婆孩子等琐事所烦着,从而构成他们的"烦恼人生".然而池莉通过自己的艺术创作,以积极的人生态度,又让读者体会到生活本身的快乐,"烦恼人生"中包含着"快乐人生".     

属性块在工程图形中的研究与应用

介绍了在工程图形中用属性块标注表面粗糙度的方法.采用属性块不仅能避免大量重复性的工作,还能节省大量的存储空间,具有提高绘图速度、质量,便于修改,资源共享等应用价值.     

Addition of Cobalt to Lead Anodes Used for Oxygen Evolution—A Literature Review

A review of the literature dealing with the effect of cobalt on lead-based anodes for oxygen evolution during electrolysis of sulfuric acid solutions verifies that the presence of cobalt at the anode–electrolyte interface, either as constituent of the anode material or as ions in the electrolyte, catalyzes the evolution of oxygen and reduces the corrosion of the anodes and the contamination by lead of metal cathodes produced during electrowinning. However, due to harmful effects of cobalt ions on the cathodic reaction in some processes, these benefits are limited to the electrowinning of copper. Efforts to develop a way of introducing cobalt at the anode–electrolyte interface without interfering with the cathodic reactions are reviewed in this paper. The use of lead–cobalt alloy anodes has had limited success due to issues arising from the low solubility of cobalt in lead, segregation during casting of the alloys, and nonuniform distribution of cobalt which affects the integrity of the anodes. This has been overcome in part lately by inclusion of cobalt into only the surface layer of a lead or lead alloy substrate, by thermal treatment of a cobalt salt to form a catalytic cobalt oxide surface species, or by electrodeposition of composite lead–cobalt oxide anodes. The last approach in particular has been actively investigated by several groups, but to our knowledge it is yet to find application in the industry. The review also critically examines the likely reaction mechanisms involved.     

A review of effects of silver,lead, sulfide and carbonaceous matter on gold cyanidation and mechanistic interpretation

Despite the wealth of published data on the beneficial or detrimental effects of silver, lead, sulfide, and carbonaceous matter on the rate of gold cyanidation at an anode or by dissolved oxygen, the lack of comparative studies on relative effects has hampered rationalisation of the role of these activators or passivators of gold. In the present study, the published rate data per unit surface area of gold, silver, and gold–silver alloys based on electrochemical or chemical dissolution of rotating discs or foils of constant surface area in aerated cyanide solutions at ambient temperatures are analysed on the basis of the Levich equation. The current status of the reaction mechanism is also reviewed and updated on the basis of species distribution and potential–pH diagrams, stoichiometric factors, and interim chemical species of gold(I), silver(I), and lead(II). The anodic peak potentials of reported voltammograms closely follow the potential–pH lines of Au(I)/Au(0) and Pb(II)/Pb(0) couples. Despite the formation of stable complexes between lead(II), nitrate, and hydroxide ions, the total calculated soluble lead(II) in alkaline solutions of pH range 10–11 saturated with lead hydroxide is shown to be < 0.1 g/m³. A comparison of the reported diffusion coefficients of cyanide ions and dissolved oxygen with the values based on the Levich plots of reported rates reveals the rate-controlling stoichiometric M/CN or M/O₂ molar ratios. The difference between some of these ratios and the generally accepted ratios of M/CN = 1/2 and M/O₂ = 1/0.5 or 1/0.25 based on the formation of M(CN)₂⁻, H₂O₂ or OH⁻ in the overall cyanidation reaction is attributed to the oxidation of cyanide to cyanate and passivation due to the formation of gold hydroxides/oxides. The alloyed or dissolved silver and lead eliminate passivation due to the involvement of mixed hydroxo–cyano complexes of silver and lead ions in the surface reaction. Gold dissolution by oxygen in cyanide-rich solutions is limited by oxygen diffusion, but enhanced by the presence of a low concentration of sodium sulfide due to the involvement of hydrosulfide ion in the surface reaction. However, excess lead or sulfide retards gold cyanidation due to surface blockage by metallic lead, lead hydroxide, or due to passivation by Au₂S/S. Even low concentrations of hydrosulfide passivate gold–silver alloys due to the formation of Ag₂S. This can be eliminated by adding stoichiometric quantities of lead(II) to precipitate sulfide as PbS. Large stoichiometric ratios of O₂/M for the cyanidation of graphite coated gold appears to be a result of the enhanced oxidation of cyanide by oxygen or hydrogen peroxide, leading to a cyanide deficiency at the surface and passivation of gold by hydroxide/oxide. The presence of excess cyanide or lead(II) does not override this effect.     

Failure Resistance of Historic Stone Bridge Structure of Charles Bridge. II: Susceptibility to Floods

The paper is a follow-up to the first part devoted to an analogical problem investigated with a view to the degradation of the stone structure due to the effects of nonstress load, and it deals with the probability problem of the bridge structure collapse under the effect of an extreme flood wave. The paper presents the results of the numerical analysis of the response of the historic stone bridge structure of Charles Bridge of the 14th century to the flood wave effect simulated by angular rotation, subsidence, and shifting in the footing bottom of a bridge pier. Special focus is on the effect of interventions into the stone bridge structure dating back to the last major overhaul of 1967–1975, particularly, on the effect of the reinforced concrete slab (tie plate) connecting the opposite bridge breast walls increasing the rigidity of the breast walls and their structurally efficient connection to the vaults of the bridge arches. The numerical analyses performed point out the prevailing negative effects of the implemented interventions in terms of structural rigidity of the stone bridge structure exposed to the effect of a flood wave.     

Reliability-Based Design for External Stability of Mechanically Stabilized Earth Walls

A two-phase approach was used to develop a reliability-based design (RBD) method for external stability of mechanically stabilized earth (MSE) walls. In the first phase, a parametric study was conducted using Monte Carlo simulation to identify parameters that affect the probability of external failure of MSE walls. Three modes of failure were considered: sliding, overturning, and bearing capacity. External stability was assessed by treating the reinforced soil as a rigid mass using the same procedures employed for conventional gravity-type wall systems. Results from the parametric study indicate that the mean and coefficient of variation of the backfill friction angle are significant for sliding, the mean and coefficient of variation of the friction angle of the backfill and coefficient of variation of the unit weight of the backfill are significant for overturning, and the mean and coefficient of variation of the friction angle of the foundation soil and the mean of the backfill friction angle are significant for bearing capacity. In the second phase, a series of additional simulations was conducted where the significant parameters identified in the parametric study were varied over a broad range. Results of these simulations were used to develop a set of RBD charts for external stability of MSE walls. A comparison indicates that similar reinforcement lengths are obtained using RBD and conventional methods and that the inherent probability of external failure in conventional deterministic design is ? 0.001. This probability of external failure is similar to inherent probability of failure reported by other investigators for similar geotechnical structures.     

Sham reasoning, Humpty Dumpty, and the burden of proof.

Slife and Reber ask of psychologists that they recognize their prejudice against theism and the incompatibility between theistic and naturalistic worldviews. Yet, the subtext of their article is that theism and naturalism are equally valid and that psychology’s secularism is a mistake. Given that theism is not beyond reason, the only sufficient ground for charging psychologists with prejudice is if (i) theism has survived serious attempts at conceptual and empirical test, and (ii) psychology ignores or disguises this fact. So, the grounds for believing in the reality of a supernatural existent are highly relevant to the authors’ allegation. However, their concept of God affords no such grounds. They disavow the logic involved in the ordinary meaning of the term “incompatible” and they ignore a crucial distinction between conditions of existence and qualities of things or processes. The consequence is that either God is this-worldly, and there is no ontological basis to Slife and Reber’s incompatibility thesis, or God’s mode of existence is quite different from the mode of existence of ordinary things and all the problems of dualism follow. Either way, their charge of prejudice is without foundation. The burden of proof rests with the defender of theism and, for now, psychology’s secularism can be considered a mark of the discipline’s (sometimes questionable) rationality. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

铜,砷矿物类型对金氰化浸出的影响及如何提高其浸出率的探讨

本文引用了某些理论研究的成果，考察了含铜，含砷矿物在氰化溶液中的行为和对金氰化浸出的影响的规律，找出金浸出率与各种有害矿物含量的相关关系，为制定难选金工艺方案时参考。并结合小型试验和工业实践，对矿石性质作深入了研究，同时其浸出工艺条件也进行了最佳选择和应用，为提高金的浸出率进行了讨论。     

Measuring students' connectedness to school, teachers, and family: Validation of three scales.

Connectedness to school, teachers, and family are all significant protective factors in adolescents' lives, yet the measurement of each varies considerably. This article describes the measurement properties of three composite scales of adolescent connectedness, adapted from the Add Health study and the California Healthy Kids Survey. These composite scales are created by either summing or taking the mean of all individual items, measured on an ordinal scale. This approach fails to account for the ordinal, non-normal nature of the data. Using a covariance approach, this article describes the measurement properties of the latent constructs of connectedness to school, teachers, and family and the contribution of each of the items used to compile the relevant composite score. The outcomes of this study will provide researchers and practitioners with information about the validity, reliability, and overall usefulness of each of the measures of adolescents' perception of their connectedness to school, teachers, and family. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Social psychoanalytic research and the twenty-first-century family: Comment on Wallerstein and Lewis (2007).

Seligman regards Wallerstein and Lewis' paper (see record 2007-10890-004) as an exemplary piece of social-developmental psychoanalytic research, finding it accessible, activist and empirical. He admires Wallerstein and Lewis' careful attention to the influence of social reality on the development of the internal worlds of both children and adults, following a psychoanalytic tradition which has been neglected recently. Since actual family configurations are changing so rapidly in the current American situation, analysts should develop new theoretical and research approaches that reflect these changing realities. Seligman highlights two specific implications of such adaptive shifts: the de-centering of the Oedipus complex as the standard form of psychosocial-family organization of the personality, and increased attention to the role of sibling relationships in development. He calls for more analytic clinical research efforts that will apply the substantial potentials of social-psychoanalytic research in service of the varying groups of children who are suffering in the midst of the array of psychosocial strains in the contemporary culture. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

天铁物料结算系统的开发设计

天铁为了解决物料结算由于手工操作出现的差错率高、控制成本困难等问题,开发设计了计算机物料结算系统。从系统的安全性、网络和硬件的实现等方面,介绍了该系统的主要功能和特点及运行情况。系统运行情况证明,该系统的开发实现了数据共享和集中存储,完善了采购和销售的各环节,程序运行稳定,提高了工作效率。     

Experimental and Theoretical Investigations on Geocell-Supported Embankments

This paper studies the advantages of geocell reinforcement on the performance of earth embankments constructed over weak foundation soil through laboratory model tests and proposes a simple method for the design of geocell-supported embankments. Model embankments were constructed above a layer of geocells formed using geogrids on top of a soft clay bed prepared in a steel test tank. Uniform surcharge pressure was applied on the crest and pressure-deformation behavior of the embankment and strains in the walls of geocells were monitored continuously until the failure was reached. The influence on the behavior of the embankment of various parameters—like tensile stiffness of geocell material, height and length of geocell layer, pocket-size of the cell, pattern of formation of geocells, and type of fill material inside the cells—was studied. Geocell reinforcement was found to be advantageous in increasing the load-bearing capacity and reducing the deformations of the embankments. The experimental results were validated using a general purpose slope-stability program and a design procedure useful for the preliminary design of geocell-supported embankments is illustrated.