共查询到20条相似文献,搜索用时 15 毫秒
1.
Peng Wang Xiaoyan Qin Shushan Yao Qi Zhang Zeyan Wang Guanghui Xu Xiangyang Jing 《Materials Letters》2007,61(26):4854-4856
Carbon spheres, with uniform diameters of about 1 μm, have been achieved via Chemical vapour deposition (CVD). The fabricated materials have been fully characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and energy dispersive X-ray analysis (EDX). The results show that the spheres are 95% carbon. The formation mechanism of carbon spheres has also been discussed. 相似文献
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直流碳弧法制备碳包覆铁纳米颗粒机理研究 总被引:1,自引:1,他引:0
采用直流碳弧等离子体法成功制备了碳包覆铁纳米颗粒,利用透射电子显微镜和高分辨透射电子显微镜、X射线衍射、X射线能谱仪对样品的形貌、物相结构、化学成分和粒度进行表征分析,并对碳包覆纳米金属颗粒的形成机理进行初步探讨。结果表明:直流碳弧等离子体技术制备的碳包覆纳米金属颗粒具有明显的铁核(bcc-Fe)/碳壳(石墨层片)包覆结构,颗粒大多呈球形和椭球形,粒径分布在20~60nm范围,平均粒径为44nm,铁粒子外碳层的厚度为5~8nm。碳包覆铁纳米铁颗粒是通过颗粒内部固态形式的碳自行扩散至颗粒表面和颗粒外部气态形式的碳沉积到颗粒表面形成的。 相似文献
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LiFePO4/carbon-network composite was synthesized by a high temperature solid-state method using the natural sawdust as carbon precursor. The microstructure of the as-synthesized sample was characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), respectively. The results revealed that the LiFePO4 particles with diameters ranging from 30 to 150 nm were well connected by carbon networks. The electrochemical performance of the composite was characterized using galvanostatic charge-discharge technique. The initial discharge capacity of LiFePO4/carbon-network cathode reached 126 mAh x g(-1) with 0.2 C rate. 相似文献
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Xuguang Liu Yongzhen Yang Hongyan Liu Weiyun Ji Chunyi Zhang Bingshe Xu 《Materials Letters》2007,61(18):3916-3919
High purity and uniform carbon nanotubes with about 35 nm in diameter were produced by pyrolysis of deoiled asphalt in the presence of ferrocene in an atmosphere of hydrogen and argon at 1000 °C. Characterization of carbon nanotubes was carried out by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectroscopy (EDS), Raman spectroscopy and X-ray diffraction (XRD). The carbon nanotubes were highly graphitized with amorphous carbons covering the outside wall. The influence of temperature on the preparation of carbon nanotubes was also discussed. 相似文献
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Carbon nanostructures were synthesized via a novel solvothermal reaction between ferrocene and sulfur. Carbon nanostructures were then added to poly styrene (PS) matrix. The thermal stability behavior of PS filled with carbon nanostructures were investigated by thermogravimetric analysis (TGA). Nanostructures were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, energy-dispersive X-ray (EDS) analysis and atomic force microscopy (AFM). The flame retardancy behavior of PS–carbon was studied by UL-94 analysis. 相似文献
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Mao B Kang Z Wang E Tian C Wang C Lan Y 《Journal of nanoscience and nanotechnology》2006,6(5):1392-1395
In this paper, a simplified ethanol-assisted arc discharge method was developed for the fabrication of multi-wall carbon nanotubes in high quality. Carbon nanotubes with high purity (80-90%) were obtained through controlling the current (15-25 V, 10-25 A) and ethanol concentration (70-100%). The products were characterized using transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), and Raman spectrometry. 相似文献
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借助偏光显微镜、扫描电镜,透射电镜以及力学性能测试研究了微观结构对双基体炭/炭复合材料力学性能的影响.结果表明:基体炭在偏光显微镜下呈现光学各向异性,材料内部形成多层次的界面结构,热解炭呈现"皱褶状"片层结构,中间相沥青炭呈现片层条带状结构,基体炭片层的走向基本上平行于纤维轴向.材料受载破坏时裂纹通过改变扩展路径而延缓其扩展速度,在纤维-基体界面处以及基体炭片层之间引起滑移,在断口形貌上体现出锯齿状的断裂形式,材料具有韧性断裂的特征,抗弯强度最高可达223MPa. 相似文献
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Urszula Narkiewicz Iwona Pe?ech Marcin Podsiad?y Micha? Ceg?owski Grzegorz Schroeder Joanna Kurczewska 《Journal of Materials Science》2010,45(4):1100-1106
The formation of metal-encapsulated carbon nanomaterials by using metallic catalysts (iron, cobalt, and nickel) has been studied.
Moreover, these materials were coated with silica surface modified by (3-Aminopropyl)-trimethoxysilane (APTS). Each intermediate
structure was confirmed by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The surface morphology of silica-coated
carbon nanomaterials was analyzed by scanning electron microscopy (SEM). The modified, APTS–silica surface was additionally
characterized by Fourier transform infrared spectroscopy (FT-IR), elemental (EA), and thermogravimetric analysis (TGA). 相似文献
10.
Sishen Xie Nan Li Zebo Zhang Wei Liu Gang Wang Shengfa Qian Chunsheng Fu 《Journal of Materials Science》1995,30(9):2291-2295
We have studied the morphologies and structures of carbon nanotubes (bucky-tubes) and carbon nanoparticles (buckyonions) using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM) and scanning tunnelling microscopy (STM). By SEM the carbon nanotubes are observed with features similar to those of some fibrous whiskers grown from pyrolytic graphite. This growth feature is supported by transmission electron microscopy (TEM) observations. The TEM results show also that the graphitic sheets can be bent into curved shapes to cap the nanotubes or form the onions. In the curved graphitic sheets elastic strains induced by layer mismatches and dislocations are revealed. The STM observations on the nanotubes show a bundle-like morphology of the carbon nanotubes, and by atomic resolution images the zigzag and armchair atomic configurations may be identified. The results also show structural distortions which may be produced by folding the graphite sheets to create the nanotubes and are responsible for the lattice mismatch. 相似文献
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Nanowires of magnetic metals (Fe, Co, Ho, Gd) have been synthesized inside the hollow interiors of single-wall carbon nanotubes (SWNTs) by filling SWNTs with precursor metal chlorides and subsequent reduction. SWNTs have been filled by either the melt-phase sealed-tube reaction or a solution-phase method. Among the metal chlorides investigated in this study, HoCl3 and GdCl3 filled the SWNTs to a significantly higher extent. The nanowires have been imaged by transmission electron microscopy (TEM), high-resolution transmission electron microscopy, and scanning transmission electron microscopy (STEM). X-ray energy dispersive spectroscopy carried out in conjunction with TEM and STEM confirmed the presence of metal chloride and metal nanowires. 相似文献
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Carbon nanospheres were synthesized from de-oiled asphalt (DOA) by chemical vapor deposition (CVD). The morphology and microstructure
of the products were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and high-resolution
transmission electron microscopy (HRTEM), and the influences of different parameters were disscussed. The results showed that
carbon nanospheres could be synthesized from DOA, which were spherical with uniform size and amorphous structure. Such controlled
growth of carbon nanospheres of DOA has never been reported; our work would offer reliable experimental data for the transformation
of DOA into high-added value carbon materials. 相似文献
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碳微球与微米镍粉按一定比例混合后,经过6h机械球磨并在1600℃真空热处理,合成了微米镍/碳复合材料。通过场发射扫描电镜(FESME)、高分辨透射电镜(HRTEM)和X射线衍射仪(XRD)对产物进行表征。结果表明,产物为碳包覆镍金属颗粒,粒径200~400nm的镍颗粒被30~100nm的碳层包覆,碳层的石墨化程度较高;产物石墨化碳层的形成缘于Ni3C的形成和分解。 相似文献
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用静电纺技术制备了多壁碳纳米管/聚氯乙烯(MWCNTs/PVC)超细纤维,对复合纤维的形貌、结构、结晶行为及热稳定性进行了分析测试,着重研究了复合纤维膜的力学性能与MWCNTs用量的关系。结果表明,MWCNTs能有效地分散于PVC溶液中,并成功纺出MWCNTs/PVC超细纤维。随着MWCNTs含量的增加,纤维直径变细,改善了纤维的结晶性,但热稳定性变差。纤维膜的拉伸断裂强度和断裂伸长率随MWCNTs含量增加出现先增加后下降的趋势。 相似文献
17.
Carbon Diffusion in Hot Strips of Low Carbon Steel Produced by CSP Line under Different Thermal Histories 总被引:3,自引:0,他引:3
Hao YU Hao REN Yonglin KANG Kelu WANG School of Materials Science Engineering University of Science Technology Beijing Beijing China Laiwu Steel Group LTD. Laiwu China Jinan Iron & Steel Group Co. Jinan ChinaPh.D. 《材料科学技术学报》2005,21(1):21-24
Two experiments were carried out on the same compact strip production (CSP) line, which differs in that one of them experienced γ→α→γ* thermal history. The differences in microstructure, precipitation, misorientation etc between two experiments were investigated by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), electron back-scattered diffraction (EBSD) and positron annihilation technique (PAT). The carbon concentration in matrix is more inhomogeneous in the experiment than that with γ→α→γ* thermal history. The specific precipitation characteristic in the experiment without γ→α→γ* thermal history is discussed on the basis of different carbon diffusion behavior and interaction between dislocation and excess carbon. 相似文献
18.
Mohsen Ghorbani Bahareh Alizadeh Mohammad Ali Salehi 《Fullerenes, Nanotubes and Carbon Nanostructures》2016,24(9):604-609
In this paper, poly (vinyl pyrrolidone) (PVP) doped multiwall carbon nanotubes (MWCNTs/polyrhodanine), were synthesized through one-step chemical oxidative polymerization of rhodanine monomers on the surface-modified carbon nanotubes. Characterization of MWCNTs/polyrhodanine was conducted by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transforms infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and EDX spectrum analyses in which the results confirmed the successful formation of MWCNTs/polyrhodanine. In addition, to investigate the thermal properties of samples, thermogravimetric analysis (TGA) was employed, and results exhibited significant improvement in the nanocomposite thermal stability due to the addition of MWCNTs with reinforcement effect in polymer matrix. 相似文献
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Qian Zhang 《Materials Research Bulletin》2008,43(3):735-742
In this study, carbon fibers with different morphologies, including coiled carbon nanofibers and straight carbon fibers, were obtained by the chemical vapor deposition using a Cu-catalytic pyrolysis of acetylene at 250 °C. The influences of nano-copper catalyst particle size and the reaction temperature on the morphology of carbon fibers were investigated. Under the same reaction condition, coiled carbon nanofibers generally were synthesized using nano-copper catalyst with smaller particles size, and bigger copper particles are apt to produce straight carbon fibers. With decreasing of reaction temperature to 200 °C, straight carbon fibers were obtained, instead of coiled carbon nanofibers at 250 °C. The product was characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and X-ray powder diffraction (XRD). 相似文献