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琥珀酸二辛酯磺酸钠合成工艺研究辛基对合成工艺的影响 总被引:12,自引:2,他引:12
报道了一种无外加相转移催化剂 ,在敞开体系中制备琥珀酸二辛酯磺酸钠的简易工艺。对于不同辛醇做原料时的合成条件进行了研究对比。结果表明 :对于酯化反应 ,不同辛醇作原料时反应条件有较大不同 ;对于正辛醇合成的酯的磺化反应 ,需加助溶剂 ,否则反应不能达到终点 相似文献
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相转移催化剂在赖默-梯曼反应中的应用 总被引:1,自引:0,他引:1
介绍了相转移催化剂在合成羟基苯甲醛的赖默梯曼(Reimer-Tiemann,简称R-T)反应中的应用:较了季铵盐和叔胺的相转移催化效果,并优选了相转移催化的工艺条件,使羟基苯甲醛的总收率达到80%左右;对叔胺的R-T反应机理进行了初探。 相似文献
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PEG活化催化合成香豆素 总被引:5,自引:0,他引:5
对以水杨醛和乙酸酐为原料合成香豆素的工艺进行了改进。采用以乙酸钙为催化剂、PEG为催化活化剂的工艺路线 ,提高了产物的收率。同时对催化剂和活化剂的用量及反应温度和反应时间的影响进行了研究 ,确定了最佳工艺条件 ,并提出PEG的活化催化作用主要是配位作用和对催化剂的增溶作用。反应物的质量比为水杨醛 /乙酸酐 /乙酸钙 /PEG =1 / 1 6/ 0 0 3 / 0 1 ,反应近终点时在 ( 2 1 4± 2 )℃再保温反应 0 5h ,香豆素收率可达 80 6%。 相似文献
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在研究FX-01催化剂上苯与二乙苯烷基转移反应的工艺条件以及寿命试验的基础上,对该过程进行了动力学试验和液-固反应器模拟。建立了一维拟均相反应器数学模型,并给出了模型的求解方法。结合年产15kt乙苯的实际工业过程,对与烷基化反应配套的烷基转移反应器进行了模拟,计算得到了烷基转移反应器的工艺尺寸:反应器直径为0.35m,高度为9m。催化剂装填量为486kg。合适的工艺操作条件为:反应温度250~260℃,nB/nDEB=8/1~12/1,总质量空速大于5h-1。 相似文献
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以端基取代的二氯代烃和丙二酸二乙酯为原料,经烃基化反应和脱羧反应合成了8-氯辛酸乙酯系列化合物,并利用~1H NMR、~(13)C NMR和GC-MS对目标产物的结构进行了确证。以8-氯辛酸乙酯的合成反应作为模板,考察了碱、相转移催化剂、物料配比、反应温度和反应时间对烃基化反应的影响,以及酸的种类和用量、反应温度、反应时间对脱羧反应的影响。结果表明,烃基化反应适宜的反应条件为:1,6-二氯己烷、丙二酸二乙酯、粉末状碳酸钾和相转移催化剂四甲基氯化铵的物质的量比为1∶1∶0.4∶0.03,反应温度60℃,反应时间1 h。脱羧反应适宜的反应条件为:浓硫酸与2-(6-氯己基)丙二酸二乙酯的物质的量比为0.1∶1,反应温度120℃,反应时间8.0 h。 相似文献
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综述了近年相转移催化法合成羧酸酯所用的各类相转移催化剂,如十六烷基三甲基氯/溴化铵、四丁基氯/溴化铵等,并对其优缺点进行了分析和比较.指出了此类合成反应中所采用的重要相转移催化剂是季铵盐类. 相似文献
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以二氧化硅负载磷钨杂多酸为催化剂,以长链α-烯烃为烷基化试剂和萘发生烷基化反应,考察不同烯烃、不同反应条件对产品收率和产品质量的影响,结果表明,采用1-十六烯作为烷基化试剂,在催化剂加入量为4%、反应温度130℃、烯烃与萘摩尔比为1.35、反应时间50min的条件下,产品收率为88.2%,DSC(O2)氧化分解温度为225.3℃,粘度指数104,倾点-27℃。 相似文献
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Zubin Cao Xianlun Xu Yutai Qi Shuwen Lu Bangfeng Qi 《Petroleum Science and Technology》2004,22(5):617-629
Tetralin was chosen as a model compound to investigate the reaction networks and kinetics of hydrocracking of polynuclear aromatic hydrocarbons on modified zeolite Y based molybdenum-nickel dual functional catalysts using a continuous flow microreactor at 320-380°C, 8.5 MPa. According to the product distributions, the reaction network of hydrocracking of tetralin was proposed. The pseudo-first-order kinetics rate constants of each step in the network of hydrocracking of tetralin were evaluated by the nonlinear parameter estimation method. The results showed that reaction of hydrocracking of tetralin was a complicated parallel and serial reaction including hydrogenation, isomerization, and cracking (ring opening and dealkylation). The key steps of hydrocracking of tetralin, the conversion of double ring compounds and the yields of mono-ring compounds were affected by reaction temperature and acidity of supports on the catalysts. 相似文献
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《Petroleum Science and Technology》2013,31(5-6):617-629
Abstract Tetralin was chosen as a model compound to investigate the reaction networks and kinetics of hydrocracking of polynuclear aromatic hydrocarbons on modified zeolite Y based molybdenum–nickel dual functional catalysts using a continuous flow microreactor at 320–380°C, 8.5 MPa. According to the product distributions, the reaction network of hydrocracking of tetralin was proposed. The pseudo-first-order kinetics rate constants of each step in the network of hydrocracking of tetralin were evaluated by the nonlinear parameter estimation method. The results showed that reaction of hydrocracking of tetralin was a complicated parallel and serial reaction including hydrogenation, isomerization, and cracking (ring opening and dealkylation). The key steps of hydrocracking of tetralin, the conversion of double ring compounds and the yields of mono-ring compounds were affected by reaction temperature and acidity of supports on the catalysts. 相似文献
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Advances in Catalytic Pyrolysis of Hydrocarbons 总被引:5,自引:0,他引:5
Xiang-hai Meng Jin-sen Gao Li Li Chun-ming Xu 《Petroleum Science and Technology》2004,22(9):1327-1341
Catalytic pyrolysis, which combines catalytic cracking and steam pyrolysis, is a technique to process petroleum hydrocarbons. Catalytic pyrolysis has the advantages of both catalytic cracking and steam pyrolysis. It can raise the yields of light olefins, expand the flexibility of products distribution, and simultaneously lower reaction temperature and decrease energy consumption for the whole system, so it has broad application prospect. Recent development on catalytic pyrolysis catalysts and technologies are reviewed in this paper, the similarities and differences of various kinds of catalysts are compared, notable processes in home and abroad are introduced, and three kinds of reaction mechanisms about catalytic pyrolysis are summarized for different types of catalysts and technologies. Owing to the shortage in supply and the inferior quality of China's crude oil, the study and development of catalytic pyrolysis techniques are crucial to China. Deep Catalytic Cracking, Catalytic Pyrolysis Process and Heavy-Oil Contact Cracking are introduced with emphasis. 相似文献
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《Petroleum Science and Technology》2013,31(9-10):1327-1341
Abstract Catalytic pyrolysis, which combines catalytic cracking and steam pyrolysis, is a technique to process petroleum hydrocarbons. Catalytic pyrolysis has the advantages of both catalytic cracking and steam pyrolysis. It can raise the yields of light olefins, expand the flexibility of products distribution, and simultaneously lower reaction temperature and decrease energy consumption for the whole system, so it has broad application prospect. Recent development on catalytic pyrolysis catalysts and technologies are reviewed in this paper, the similarities and differences of various kinds of catalysts are compared, notable processes in home and abroad are introduced, and three kinds of reaction mechanisms about catalytic pyrolysis are summarized for different types of catalysts and technologies. Owing to the shortage in supply and the inferior quality of China's crude oil, the study and development of catalytic pyrolysis techniques are crucial to China. Deep Catalytic Cracking, Catalytic Pyrolysis Process and Heavy-Oil Contact Cracking are introduced with emphasis. 相似文献
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非酸催化合成新型增塑剂偏苯三酸三(2-乙基)己酯 总被引:2,自引:0,他引:2
用钛酸四丁酯催化合成偏苯三酸三(2-乙基)己酯,研究了催化剂的选择性和用量、偏苯三酸酐和2-乙基己醇的原料配比、反应温度对酯化反应的影响,确定了最佳工艺条件:偏酐:2-乙基己醇为1:4(ml);反应温度210℃;反应时间3h;催化剂用量0.96‰。 相似文献
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二乙二醇双苯甲酸酯的非恒温化学动力学研究 总被引:1,自引:0,他引:1
对二乙二醇双苯甲酸酯(DEDB)的非恒温反应动力学进行了研究,结果表明:DEDB生成反应属二级复合反应中的连串竞争反应。测定了其反应常数K、速度常数k_1、活化能E_((?),1)及频率因子k_(0,1)。 相似文献