The Change of Orientation Relationships Between Austenite and α'-Martensite During Deformation in High Manganese TRIP Steel

In situ observation of electron backscattering diffraction technique was used to evaluate the orientation relationships between austenite and α′-martensite(α′-M) for high manganese transformation-induced plasticity steel.It was noted that different from the thermal martensite,which well obeyed K-S relationship with austenite,the orientation relationship between deformation-induced α′-M with austenite changed during deformation,namely K-S and N-W relations coexisted.No clear differences existed between α′-M variants with two kinds of relationships in terms of martensitic orientation,shape and the misorientation between α′-M variants.And this phenomenon happened in almost all austenitic grains with different orientations investigated in this study.An atom displacement mechanism through conjugate complex slips of partial dislocations in the distorted fcc lattice was applied in this article to interpret the coexistence of K-S and N-W relationships.     

Microstructure and martensitic transformation behavior of Ni56-xMn25FexGa19 shape memory alloys简

Microstructure, martensitic transformation behavior, mechanical and shape memory properties of Ni56-x Mn25 Fex Ga19(x = 0, 2, 4, 6, 8) shape memory alloys were investigated using optical microscopy(OM), X-ray diffraction analysis(XRD), differential scanning calorimeter(DSC), and compressive test. It is found that these alloys are composed of single non-modulated martensite phase with tetragonal structure at room temperature, which means substituting Fe for Ni in Ni56 Mn25 Ga19 alloy has no effect on phase structure. These alloys all exhibit a thermoelastic martensitic transformation between the cubic parent phase and the tetragonal martensite phase. With the increase of Fe content, the martensitic transformation peak temperature(Mp) decreases from 356 °C for x = 0 to 20 °C for x = 8, which is contributed to the depressed electron concentration and tetragonality of martensite. Fe addition remarkably reduces the transformation hysteresis of Ni–Mn–Ga alloys. Substituting Fe for Ni in Ni56 Mn25 Ga19 alloy can decrease the strength of the alloys and almost has no influence on the ductility and shape memory property.     

High-temperature Oxidation Behavior of a High Manganese Austenitic Steel Fe–25Mn–3Cr–3Al–0.3C–0.01N

In this paper, a Fe–Mn–Al–C austenitic steel with certain addition of Cr and N alloy was used as experimental material. By using the SETSYS Evolution synchronous differential thermal analysis apparatus, the scanning electron microscope(SEM), the electron microprobe(EPMA) and the X-ray diffraction(XRD), the high-temperature oxidation behavior microstructure and the phase compositions of this steel in air at 600–1,000 °C for 8 h have been studied. The results show that in the whole oxidation temperature range, there are three distinct stages in the mass gain curves at temperature higher than 800 °C and the oxidation process can be divided into two stages at temperature lower than 800 °C.At the earlier stage the gain rate of the weight oxidized in temperature range of 850 °C to 1,000 °C are extremely lower.The oxidation products having different surface microstructures and phase compositions were produced in oxidation reaction at different temperatures. The phase compositions of oxide scale formed at 1,000 °C are composed of Fe and Mn oxide without Cr. However, protective film of Cr oxide with complicated structure can be formed when the oxidation temperature is lower than 800 °C.     

Effect of Aging Isothermal Time on the Microstructure and Room-Temperature Impact Toughness of Fe–24.8Mn–7.3Al–1.2C Austenitic Steel with κ-Carbides Precipitation

The microstructure and impact toughness of the as-cast Fe–24.8Mn–7.3Al–1.2C austenitic steel after solution treatment and subsequent aging treatment were investigated in the present work. Research on the κ-carbides precipitation behavior was carried out by transmission electron microscope. The results show that nano-sized coherent κ-carbides were obtained in the as-solutionized steel after aging treatment, which produced precipitation hardening. After being aging treated at 550 °C for 1 h, the steel with regular hexagonal grain structure exhibited a good combination of yield strength (~?574 MPa) and room-temperature impact toughness (~?168 J). In the present steel, the typical cube-on-cube orientation relationship between austenite and κ-carbides was observed. However, due to the long aging isothermal time and high C content, the coarse intergranular κ′-carbide was formed and grew along the austenite grain boundary, which caused this orientation relationship to be destroyed and a dramatical increase of the coherency strain energy at grain boundary. Furthermore, serious embrittlement of grain boundaries caused that cleavage cracks trend to propagate along the grain boundaries. Accordingly, the room-temperature impact toughness decreased sharply. After aging isothermal time prolonging to 13 h, the Charpy V-notch impact toughness was only ~?5 J and fracture mode turned to fully brittle fracture accompanied with flat facets, shear cracks and well-developed secondary crack.     

�ٶ����̰��������ĥ�Ե�Ӱ��

  研究了合金元素W(0.5％～1.5％)对中锰钢常规力学性能和耐磨性的影响。试验结果表明,W改变了C在中锰奥氏体钢中的分布状态,从而使中锰钢的抗拉强度、冲击韧性和耐磨性均得到了有效提高。当W含量为15％时,水韧处理中锰钢的冲击韧性提高40％,抗拉强度提高10％,耐磨性提高40%,铸态中锰钢的耐磨性提高50％。     

中低铬锰对高碳多元合金钢耐磨性能的影响

研究铬、锰含量的变化对高碳合金钢硬度、韧性及耐磨性的影响,结果表明:当Cr<3%时,对材料的耐磨性提高的作用较显著,而材料的耐磨性随锰含量的增加而降低。增加相当含量的铬或锰,铬系材料的耐磨性是锰系材料的1～4倍。对提高材料耐磨性而言,铬的作用显著优于锰。材料的耐磨性取决于其硬度和韧性的综合作用,同时还与其基体组织相关。     

超高锰钢耐磨性及其冲击磨料磨损行为的研究

通过动载荷冲击磨料磨损试验及磨损后磨面硬度测量,利用SEM和TEM观察磨损表面形貌和磨损亚表层组织,研究了超高锰钢的耐磨性和冲击磨料磨损行为.结果表明,冲击功为0.5 J和1.0 J时,碳含量较低的超高锰钢耐磨性与普通Mn13相当,碳含量较高的超高锰钢耐磨性高于普通Mn13;冲击功为2.0 J时,超高锰钢具有好的耐磨性,是普通Mn13的1.21倍,磨面硬度较高.超高锰钢冲击磨料磨损后磨损亚表层的变形组织主要由高密度位错和变形带组成,磨损亚表层的变形带相互交叉、截割.依据实际工况条件,加工硬化和冲击韧度适当配合的超高锰钢耐磨性良好.     

铸态锰钢的抗磨性能

通过化学成分的优化,N、Cr等元素的加入和变质处理等措施,得到在稳定产低的奥氏体基体上弥散分布有粒状碳化物的铸态组织。这种铸态锰钢具有初始硬度高、韧性好、加工硬化能力强和抗磨性高等特点。并重点分析了铸态锰钢的抗磨机理。     

碳化钨增强高锰钢基复合材料冲击磨损性能的研究

为了提高高锰钢冲击磨料磨损性能,利用离心铸造法制备了WC颗粒增强高锰钢基表面复合材料,并在MLD-10型动载磨料磨损试验机上进行了冲击磨料磨损性能试验.结果表明:制备的复合材料颗粒分布均匀,WC颗粒与高锰钢基体结合良好;WC的加入提高了材料的抗冲击磨料磨损性能.     

稀土铬高锰钢的研究和应用

研究奥氏体高锰钢在非强烈冲击工况下提高抗磨性的新途径，采用高锰钢合金化及稀土变质处理、工艺措施，有效地提高抗磨性１．７倍以上，应用于磨煤机击锤获得显著的经济效益。     

微量纳米SiC粉体对高锰钢表面加工硬化及耐磨性能的影响

研究了微量纳米SiC粉体对高锰钢组织、表面加工硬化性能和耐磨性能的影响.结果表明,添加0.07％纳米SiC粉体后,高锰钢晶粒细化了约60％;纳米SiC粉体使高锰钢喷丸强化后的滑移带明显增多,喷丸表面硬度得到提高,并且随着加工硬化时间的延长,添加SiC粉体试样比未添加SiC粉体试样的加工硬化效果进一步增强,从而提高了加工硬化能力;添加0.07％纳米SiC粉体后,高锰钢磨损表面的沟槽变浅,剥落的凹坑减少,磨损质量损失降低了19.2％,高锰钢的耐磨性能得到显著提高.     

碳对高钒高速钢冷轧辊耐磨性的影响

在钒含量10％的条件下，采用铸造方法制备了碳含量1．58％～2．92％的高钒高速钢冷轧辊试样，应用自制设备WM-1型轧辊摩擦磨损试验机研究了碳含量对高钒高速钢耐磨性的影响，并与高铬铸铁（Cr20）进行了耐磨性与磨损机理的对比研究。结果表明：在试验条件下，含碳量为2．58％的高钒高速钢耐磨性最佳，其耐磨性为高铬铸铁的5倍。高钒高速钢与高铬铸铁轧辊试样的磨损机理均为高应力下的接触疲劳剥落。     

稀土、镁和钛复合变质中锰钢的耐磨性

研究了稀土、镁和钛复合变质剂对Mn6钢耐磨性的影响。结果表明，不同变质剂及其加入量对Mn6钢耐磨性的影响很大，当使用最佳变质剂及其合适的加入量时，可使Mn6钢的耐磨性提高50％左右，该变质钢在秦皇岛港务局实际使用效果良好。