Biomass ashes and their phosphorus fertilizing effect on different crops

The reutilization of biomass ashes in agriculture is an important issue to create nutrient cycles and to save fertilizer. To analyse the P fertilization effect of crop biomass ashes (rape meal ash (RMA), straw ash (SA), and cereal ash (CA)) in interaction with different crops, two pot experiments with a poor loamy sand deficient in P were carried out. Besides the three ash treatments, other treatments included triple superphosphate (TSP) as a high soluble P source, potassium chloride (KCl) as a high soluble K source, and a control (CON) without P and K. The main crops (maize, lupin, summer barley, and oilseed rape) were cultivated in the first experiment from April to May and the catch crops (oil radish, phacelia, italian ryegrass, and buckwheat) were cultivated in the second experiment from August to September. Plant parameters (biomass and P uptake of shoots), soil pH, different P pools of the soil (total P (Pt), water soluble P (Pw), double lactate soluble P (Pdl), oxalate soluble P (Pox)), P sorption capacity (PSC), and the degree of P saturation (DPS) were investigated. The fertilization effect of biomass ashes was comparable with that of TSP. On average of all crops, the highest P uptake (86.7 mg pot⁻¹) was found after RMA application, and the lowest P uptake (66.6 mg pot⁻¹) for CON. The readily bio-available soil P contents (Pw and Pdl) were significantly increased when P was supplied, regardless of whether P was given with ash or with high soluble TSP. The P fertilization effects also depended on the cultivated crops. The ash treatments resulted in highest increases of soil Pw values when combined with buckwheat cultivation. After buckwheat harvest the Pw content in the control was 8.0 mg kg⁻¹, and in the ash treatments between 13.9 mg kg⁻¹ (CA) and 15.7 mg kg⁻¹ (RMA). From the results of this study we conclude, that crop biomass ashes can be an adequate P source comparable to that of highly soluble commercial P fertilizer.     

Interspecific facilitation of nutrient uptake by intercropped maize and faba bean

Interspecific complementary interactions in N, P and K uptake betweenintercropped maize (Zea mays L. cv. Zhongdan No. 2) andfababean (Vicia faba L. cv. Linxia Dacaidou) were investigatedin a field experiment. A root barrier study was also set up in whichbelowgroundpartitions were used to determine the contribution of interspecific rootinteractions to crop nutrient uptake. Nitrogen uptake by intercropped faba beanwas higher than (no P fertilizer) or similar to (33 kg Pha^–1 of P fertilizer) that by sole faba bean during theearly growth stages (first to third sampling) of faba bean, and was similar to(no P fertilizer) or higher than (33 kg P ha^–1 ofP fertilizer) that by sole faba bean at maturity. Nitrogen uptake byintercropped maize did not differ from that by sole maize at maturity, exceptwhen P fertilizer was applied. Intermingling of maize and faba bean rootsincreased N uptake by both crop species by about 20% compared with complete orpartial separation of the root systems. Intercropping also led to someimprovement in P nutrition of both crop species. Maize shoot P concentrationswere similar to those of sole maize during early growth stages and becameprogressively higher until they were significantly higher than those of solemaize at maturity. Intercropping increased shoot P concentration in faba beanatthe flowering stage and in maize at maturity, and increased P uptake by bothplant species at maturity. Phosphorus uptake by faba bean with rootintermingling (no root partition) was 28 and 11% higher than with complete(plastic sheet) and partial (400 mesh nylon net) root barriers, respectively.Maize showed similar trends, with corresponding P uptake values of 29 and 17%.Unlike N and P, K nutrition was not affected by the presence of root barriers.     

Nitrogen and phosphorus benefits from faba bean (Vicia faba L.) residues to subsequent wheat crop in the humid highlands of Ethiopia

Faba bean–wheat rotation is one of the traditional cropping systems in most parts of the temperate, Mediterranean and tropical highland areas. However, the net contribution of legumes to soil nutrient balance is determined by the extent to which crop residue is removed from the field. Therefore, we assessed two possible faba bean residue management scenarios and their role in the faba bean–wheat rotation system in a two-phase field experiment. We further tested to what extent high N₂-fixing and P efficient faba bean varieties could benefit subsequently grown wheat. In the first phase, three improved faba bean varieties (Degaga, Moti, Obse) were grown at four levels of P fertilization (0, 10, 20 and 30 kg P ha^?1) along with local faba bean and reference wheat but without any fertilization. N₂-fixation, soil N balance and P uptake were determined for the faba beans. The N balance was determined via two possible residue management scenarios: scenario-I assumed that all the aboveground biomass is exported from the fields; scenario-II assumed that all the above ground biomass except grains and empty pods is incorporated to the soil. In the second phase, the N and P benefits of faba beans to rotational wheat were assessed. Scenario-I gave a negative net N balance (kg N ha^?1) in the range of ?86.5 ± 5.8 (Degaga) to ?9.4 ± 8.7 (Moti) with significant differences between varieties. Scenario-II showed that all balances were significantly (P < 0.01) improved and the varieties were positively contributing N to the system in the range of 50.6 ± 13.4 (Degaga) to 168.3 ± 13.7 (Moti) kg N ha^?1, which is equivalent to 110–365 kg N ha^?1 in the form of urea (46 % N). In the second crop phase, biomass and grain yield of wheat grown after the faba beans improved significantly (P < 0.05) by 112 and 82 %, respectively compared to the yield of wheat after wheat. Phosphorus application to the preceding faba bean varieties significantly improved total biomass and grain yield of the succeeding wheat (R² = 0.97). The incorporated legume root, nodule and straw clearly played a role in improving wheat yield through N addition via BNF and straw P. The study demonstrates the prospects and importance of improved faba bean germplasm and management as a key component for sustainable wheat based cropping systems in the humid tropical highlands.     

The characteristics of inorganic elements in ashes from a 1 MW CFB biomass gasification power generation plant

This paper investigated the characteristics of inorganic elements in ashes from biomass gasification power generation (BGPG) plant. The ash samples of the gasifier ash, separator ash and wet scrubber ash were collected in a 1 MW circulating fluidized bed (CFB) wood gasification power generation plant. Particle size distribution of ashes was determined by gravimetric measurement and super probe analyzer. The concentrations of trace elements and major ash-forming elements, such as As, Al, Ca, Cd, Cr, Cu, K, Mg, Na, Ni, Pb, Ti in different ashes as a function of particle size were determined by Inductive Coupled Plasma Spectrometer. The concentrations and distribution coefficient and enrichment factors of the inorganic elements in ashes were studied. X-ray fluorescence spectrometer and X-ray powder diffraction were used to provide information on the characteristics of the ashes. The results showed that most of the trace elements had an enrichment tendency in the finer size particles. A considerable amount of the ashes was residual carbon. Most of the volatile e.g. halogen elements and alkali elements existed mainly in wet scrubber ash and enriched in fly ash. Most of the Si, Ni, Pb, Zn, Cr, Cd were found in separator ash, indicating an enrichment of heavy metal elements in separator ash. K, S, Mn, Cu mainly existed in gasifier ash.     

煤气化细灰及其原煤的热解特性与官能团特征

对气流床水煤浆气化细灰和粉煤气化细灰及其原煤的热解特性与官能团特征进行研究,结合工业分析、元素分析、红外光谱(FTIR)方法以及热重-质谱联用(TG-MS)技术,分析了两种气化工艺所得细灰的特性,以及细灰与原煤官能团结构特征的差异。结果表明,气化细灰在经历煤气化过程后仍有部分挥发分未完全分解,细灰中的挥发分含量与其气化工艺有关;煤气化过程中,部分官能团未分解,并可能有部分官能团重排生成了较稳定的含氧化合物等新官能团。     

Durability of biomass fly ash concrete: Freezing and thawing and rapid chloride permeability tests

Strict interpretation of ASTM C 618 excludes non-coal fly ashes, such as biomass fly ashes from addition in concrete. Biomass fly ash in this investigation includes (1) cofired fly ash from burning biomass with coal; (2) wood fly ash and (3) blended fly ash (wood fly ash mixing with coal fly ash). A set of experiments conducted on concrete from pure cement and cement with fly ash provide basic data to assess the effects of several biomass fly ashes on the performances of freezing and thawing (F-T) and rapid chloride permeability test (RCPT). The F-T tests indicate that all fly ash concrete has statistically equal or less weight loss than the pure cement concrete (control). The RCPT illustrate that all kinds of fly ash concrete have lower chloride permeability than the pure cement control concrete.     

Maize-bean intercrop response to nutrient application relative to maize sole crop response

Maize-bean intercropping is important in sub-Saharan Africa. Maize sole crop (MSC) nutrient response has been much studied but data is scarce for determination of intercrop functions. A procedure for adapting MSC functions for the maize-bean intercrop was developed. Maize sole crop and intercrop responses were near parallel with notable exceptions for P in high potential areas for maize and for K. Mean intercrop bean yield with no nutrient application was about 0.4 Mg ha^?1 and increased on average by 24, 11 and ?3% with N, P and K application, respectively. Response function coefficients for MSC adjusted with the ratio of bean to maize grain value as the dependent variable accounted for nearly all variation in intercrop response coefficients providing the basis for determining intercrop response functions from MSC functions. Maize grain yield equivalent was less with MSC compared with intercrop; exceptions were for response to N in high potential areas and for bean to maize value ratios of two or less. The economically optimal rate of N and P were on average about 15% more but less for K with intercrop compared with MSC but with inconsistency. The economically optimal rate ranged widely with variation in the cost of nutrient use relative to grain value but generally without great effect on yield; an exception was a great effect on MSC yield response to N for high potential areas. Intercrop nutrient response functions can be reliably determined once maize sole crop functions are determined for a recommendation domain.     

Utilization of solid wastes from the gasification of coal-water slurries

It was found that only fly and bottom ashes are the solid wastes of water-coal slurry gasification in a direct-flow gasifier. The yields and chemical compositions of fly and bottom ashes obtained after the gasification of water-coal slurries prepared using brown (B) and long-flame (D) coals from the Berezovskii and Mokhovskii strip mines (Kansk-Achinsk and Kuznetsk Basins, respectively) were characterized. Based on an analysis of currently available information, the areas of utilization of fly and bottom ashes after water-coal slurry gasification with dry ash removal were summarized. The use of these wastes in the construction of high-ways and earthwork structures (for the parent coals of B and D grades) and in the manufacture of ash concrete (for the parent coal of D grade) is most promising.     

Preparation and characterization of poly(vinyl alcohol) biocomposites with microalgae ash

Gasification of microalgae feedstock generates mineral ash. In this work, raw ash is produced from lipid‐extracted algal biomass of the Nannochloropsis salina strain. Prior to using it as filler for composite fabrication with poly(vinyl alcohol), raw ash (RASH) is activated with NaOH and surface modified with (3‐aminopropyl)triethoxysilane. Surface modification of activated ash (PASH) significantly improves interfacial interaction between surface‐modified ash (GASH) and polymer matrix. Higher ultimate tensile strength of PVA/GASH composites is recorded, compared with PVA/RASH and PVA/PASH. Young's modulus of biocomposites appears to increase proportionally to loading of the fillers. Thermal properties of polymeric materials of PVA with these ashes are stable. This is the first report to demonstrate the utilization of microalgal ash, the leftover after completed gasification of algal biomass, as an efficient filler for production of value‐added polymeric materials. It is proposed that microalgal ash is capable of improving the economic feasibility of microalgae‐based biorefinery. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43599.     

Microcosmic study of soil microarthropod and earthworm interaction in litter decomposition and nutrient turnover

A microcosm experiment was set up under laboratory conditions and verified under field conditions with the objective of investigating the interaction of soil microarthropods and earthworms in litter decomposition, nutrient release, and uptake by maize crop. The treatments included: soil alone (control), soil with leaf litter (Senna siamea leaves), soil with leaf litter and soil microarthropods, soil with leaf litter and earthworms (Hyperiodrilus africanus), and soil with litter and both of the soil faunal groups. After an 8-week incubation period, the amounts of litter decomposed and N, P, K, Ca, and Mg released followed the order: with microarthropods and earthworms > with earthworms > with microarthropods > no faunal addition. The presence of microarthropods and earthworms also increased the net level of mineral N in the incubated soil. The additive roles of soil microarthropods and earthworms were observed on decomposition and nutrient release. Such faunal interactions resulted in an increased N uptake by maize in the incubated soil. Despite their lower biomass, soil microarthropods contributed significantly to nutrient turnover in the presence of earthworms. This study emphasizes the need to quantify and devise ways of controlling and regulating the abundance and activities of soil fauna for effective nutrient cycling and, consequently, for better crop yields in low-input tropical agricultural ecosystems.     

Crop yield and the fate of nitrogen and phosphorus following application of plant material and feces to soil

Organic materials are the most important sources of nutrients for agricultural production in farming systems of semi-arid West Africa. However, reliance on locally available organic nutrient sources for both crop and livestock production is rapidly becoming unsustainable. A series of feeding and agronomic trials have been conducted to address the role of livestock in sustainable nutrient cycling. This paper reports results of a greenhouse study that evaluated the effects of applying crop residue and browse leaves, or feces derived from these feeds, at equal organic-N application rates (150 kg ha^-1), alone or with fertilizer-N (60 kg ha^-1), on pearl millet (Pennisetum glaucum [L.] R.Br.) dry matter (DM) yield, nitrogen (N) and phosphorus (P) uptake, on soil nutrients, and on total, labile and recalcitrant fractions of soil organic matter (SOM). Millet DM and cumulative N uptake were most affected by fertilizer-N, followed by plant species and amendment type, although various interactions among these treatments were noted due to variations in the composition of the applied amendments. Fertilizer-N increased total millet DM by 39%, N uptake by 58% and P uptake by 17%, and enhanced N mineralization from most organic amendments, but was applied insufficiently to totally offset N and P immobilization in pots containing leaves of low initial N and P content. Feces alone appeared to supply sufficient N to meet millet-N demands. Nitrogen use efficiency was, in most cases, higher in pots amended with feces than with leaves. Nitrogen in feces apparently mineralized more in synchrony with millet-N demands. Also, the relatively high cell wall content of feces may have provided an effective, temporary sink for fertilizer-N, which upon remineralization provided more N to millet than pots amended with leaves. Whereas most of the P contained in feces mineralized and was taken up by millet, most leaves immobilized P. Assessing the costs and benefits associated with the direct land application of biomass as a soil fertility amendment versus feeding biomass first to livestock then using feces (and urine) to fertilize the soil requires information on both crop and livestock production and associated impacts on nutrient cycling.     

流化床气化中小龙潭褐煤灰结渣行为

为探索小龙潭褐煤流化床气化过程中的煤灰结渣行为,采用化学成分、扫描电镜(SEM)和X射线衍射(XRD)相结合对小龙潭煤气化炉内残留渣块和不同温度热处理后煤灰的成分、形貌和晶相组成进行了表征和对比分析,并对升温过程中煤灰的矿物质演变进行了研究。结果表明:在小龙潭气化过程中流化床气化过程中渣块形成时铁元素发生了明显的富集,小龙潭气化残留渣块和950℃煤灰的微观形貌和晶相组成基本相同。小龙潭褐煤在流化床气化过程中950℃左右生成低熔点共融物钙长石、钙黄长石和铁钙辉石等是引起结渣的主要因素。     

Biomass fly ash in concrete: Mixture proportioning and mechanical properties

ASTM C 618 prohibits use of biomass fly ashes in concrete. This document compares the properties of biomass fly ashes from cofired (herbaceous with coal), pure wood combustion and blended (pure wood fly ash blended with coal fly ash) to those of coal fly ash in concrete. The results illustrate that with 25% replacement (wt%) of cement by fly ash, the compressive strength (one day to one year) and the flexure strength (at 56th day curing) of cofired and blended biomass fly ash concrete is statistically equal to that of two coal fly ash concrete in this investigation (at 95% confidence interval). This implies that biomass fly ash with co-firing concentration within the concentration interest to commercial coal-biomass co-firing operations at power plants and blended biomass fly ash within a certain blending ratio should be considered in concrete.     

Catalysis of carbon-steam gasification by ash components from two lignites

Ash transfer from a reactive to a less reactive coal is an interesting possibility for improving and equalizing gasification characteristics of coals. To assess the catalytic action of coal impurities in the steam gasification of carbon, three approaches were used. In the first series, the effects of different coal ashes on the gasification kinetics of graphite were compared. A parallel study was made by adding lignite ash to a coal of low reactivity. Finally, gasification rates of chars prepared from demineralized coals were measured. While it was found that ash from reactive coals can significantly enhance the gasification rates of chars derived from coals of lesser reactivity, it was not possible to distinguish clearly between a catalytic lowering of the activation energy and an increase in the number of gasification sites. The gasification enhancement by lignite ash may open practical possibilities for blending coals of different reactivity, and warrants further study to identify the constituents associated with this effect.     

Fly ash—a potential source of soil amendment and a component of integrated plant nutrient supply system

In sub-tropical climate the high rainfall and high temperature is responsible for low soil productivity due to losses of bases and low organic matter content in soil. In acid lateritic soil low availability of P and high content of Al and Fe posses nutritional imbalance which is generally corrected by lime materials. Alkaline fly ash can be used in such problematic soil as an amended material and also it acts as source of plant nutrition for crop production. An attempt was made to develop an integrated plant nutrient supply system utilizing the fly ash along with other organic wastes like paper factory sludge, farm yard manure, crop residue and chemical fertilizers for rice-peanut cropping system. Direct and residual effects of fly ash were assessed based on crop yield, nutrient uptake and changes in soil characteristics. The application 10 t ha⁻¹ of fly ash in combination with organic sources and chemical fertilizer increased the grain yield and nutrient uptake of rice, and pod yield of peanut compared to chemical fertilizers alone. The heavy metal contents in plant and soil system was analyzed and found to remain below the permissible level. The results indicated that fly ash could be applied safely to tropical agro eco-systems for retaining productivity of acid lateritic soil.     

Speciation of mercury in fly ashes by temperature programmed decomposition

Mercury (Hg) is a toxic trace element which is emitted mostly in gas phase during coal combustion, although some Hg compounds may be retained in the fly ashes depending on the characteristics of the ashes and process conditions. To improve the retention of Hg in the fly ashes a good knowledge of the capture mechanism and Hg species present in the fly ashes is essential. The temperature programmed decomposition technique was chosen to identify the Hg species present in fly ashes obtained from two Pulverized Coal Combustion (PCC) plants and a Fluidized Bed Combustion (FBC) plant. The fly ashes were then used as Hg sorbents in a simulated flue gas of coal combustion and gasification. The Hg compounds found in the fly ash from the FBC plant after elemental mercury retention were mainly HgCl₂ and HgSO₄. The Hg species present in the two fly ashes from the two PCC plants were HgCl₂ and Hg⁰. The Hg species formed in the coal gasification atmosphere was HgS for all three fly ashes. The only Hg compound identified in the fly ashes after the retention of mercury chloride was HgCl₂.     

Profitability of agro-forestry based soil fertility management technologies: the case of small holder food production in Western Kenya

Persistent food insecurity accompanied by low and declining farm household incomes are a common feature of many small holder maize and bean producers in western Kenya. This has been largely attributed to soil nutrient depletion, among other factors. One way of addressing soil fertility problems in many maize-based cropping systems is the use of agro-forestry based technologies. We carried out a survey in western Kenya (Vihiga and Siaya districts) aimed at analyzing the financial and social profitability of use of agroforestry based (improved tree fallows) and other soil fertility management technologies among smallholder farmers. The Policy Analysis Matrix (PAM) was used to determine the financial and social profitability of different production systems, which were categorized on the basis of the technology used to address soil fertility. Farm budgets were first prepared and in turn used to construct the PAMs for six production systems namely: maize–bean intercrop without any soil fertility management inputs; maize–bean intercrop with chemical fertilizers only; maize–bean intercrop with a combination of chemical fertilizers and improved fallows; maize–bean intercrop with improved fallows only; maize–bean intercrop with a combination of improved fallows and rock phosphate; and maize–bean intercrop with Farm Yard Manure (FYM) only. Results revealed that use of chemical fertilizers with improved fallows was the most profitable technology and thus the study recommended that farmers be encouraged to intensify the use of chemical fertilizers. To make chemical fertilizers more accessible to farmers, the study also recommended that good linkages be made between farmers and micro credit institutions so that small scale farmers are not actually biased against due to lack of collateral when credit is being advanced to clients.     

Ash properties and environmental impact of various biomass and coal fuels and their blends

Aiming at investigating the influence of minerals in co-firing applications in existing and developing systems, as well as their environmental impact upon recycling to soils, we used a combination of techniques such as X-ray fluorescence spectroscopy, ultraviolet and visible spectroscopy, inductive coupled plasma spectroscopy, X-ray diffractometry, differential thermal analysis and fusibility analysis to characterize various biomass and coal ashes and their blends, with biomass proportions up to 20%. Slagging and fouling propensities were predicted.The results showed that biomass ashes were richer in calcium, silicon and alkali minerals and micronutrients such as Zn, Cu and Mn, in comparison to coal ashes. Some could be useful for soil amendment or the cement industry. Slagging/fouling problems should be expected in boilers operating above 1000 °C, especially those firing cotton residue, vine shoots and bituminous coal without pre-treatment. However, the environmental impact of either biomass or coal ashes upon their disposal is expected to be very low, as leaching tests have shown. For coal/biomass blends, the composition and the fusibility of the ashes varied between those of the individual components. Thus co-firing processes using the alternative fuels studied up to 20% would not entail significant limitations in the system operation or the management strategies of ashes.     

Nitrogen dynamics following grain legumes and subsequent catch crops and the effects on succeeding cereal crops

The effects of faba bean, lupin, pea and oat crops, with and without an undersown grass-clover mixture as a nitrogen (N) catch crop, on subsequent spring wheat followed by winter triticale crops were determined by aboveground dry matter (DM) harvests, nitrate (NO₃) leaching measurements and soil N balances. A 2½-year lysimeter experiment was carried out on a temperate sandy loam soil. Crops were not fertilized in the experimental period and the natural ¹⁵N abundance technique was used to determine grain legume N₂ fixation. Faba bean total aboveground DM production was significantly higher (1,300 g m^?2) compared to lupin (950 g m^?2), pea (850 g m^?2) and oat (1,100 g m^?2) independent of the catch crop strategy. Faba bean derived more than 90% of its N from N₂ fixation, which was unusually high as compared to lupin (70–75%) and pea (50–60%). No effect of preceding crop was observed on the subsequent spring wheat or winter triticale DM production. Nitrate leaching following grain legumes was significantly reduced with catch crops compared to without catch crops during autumn and winter before sowing subsequent spring wheat. Soil N balances were calculated from monitored N leaching from the lysimeters, and measured N-accumulation from the leguminous species, as N-fixation minus N removed in grains including total N accumulation belowground according to Mayer et al. (2003a). Negative soil N balances for pea, lupin and oat indicated soil N depletion, but a positive faba bean soil N balance (11 g N m^?2) after harvest indicated that more soil mineral N may have been available for subsequent cereals. However, the plant available N may have been taken up by the grass dominated grass-clover catch crop which together with microbial N immobilization and N losses could leave limited amounts of available N for uptake by the subsequent two cereal crops.     

Nitrogen balances in farmers fields under alternative uses of a cover crop legume: a case study from Nicaragua

Canavalia brasiliensis (canavalia), a drought tolerant legume, was introduced into the smallholder traditional crop-livestock production system of the Nicaraguan hillsides as green manure to improve soil fertility or as forage during the dry season for improving milk production. Since nitrogen (N) is considered the most limiting nutrient for agricultural production in the target area, the objective of this study was to quantify the soil surface N budgets at plot level in farmers fields over two cropping years for the traditional maize/bean rotation and the alternative maize/canavalia rotation. Mineral fertilizer N, seed N and symbiotically fixed N were summed up as N input to the system. Symbiotic N₂ fixation was assessed using the ¹⁵N natural abundance method. Nitrogen output was quantified as N export via harvested products. Canavalia derived in average 69% of its N from the atmosphere. The amount of N fixed per hectare varied highly according to the biomass production, which ranged from 0 to 5,700 kg ha^?1. When used as green manure, canavalia increased the N balance of the maize/canavalia rotation but had no effect on the N uptake of the following maize crop. When used as forage, it bears the risk of a soil N depletion up to 41 kg N ha^?1 unless N would be recycled to the plot by animal manure. Without N mineral fertilizer application, the N budget remains negative even if canavalia was used as green manure. Therefore, the replenishment of soil N stocks by using canavalia may need a few years, during which the application of mineral N fertilizer needs to be maintained to sustain agricultural production.