铝合金磷酸阳极化及胶接性能分析

采用磷酸阳极化方法对铝合金试片进行了处理并测试了其粘接性能.测试了铝合金试片表面预处理和阳极化后的性能,研究了阳极化工艺参数对接头胶接性能的影响,观察了磷酸阳极化处理后的铝合金试片的表面形貌和其与胶粘剂粘接时的粘接界面,分析了其粘接拉剪破坏的失效模式.结果表明,金属表面预处理和阳极化不影响铝合金试片的性能.阳极化处理不仅改变了铝合金胶接表面的材料组成,而且在铝合金试片粘接表面形成厚度可达90μm、凹凸不平的、多孔的膜.胶接时胶粘剂能够渗透进入阳极化铝合金表面孔洞并在粘接界面形成厚度约为20μm的过渡层.阳极化处理提高了铝合金粘接副之间的拉剪强度,其最大拉剪强度为45.99MPa,其接头拉剪破坏模式为混合破坏,而未阳极化的铝合金胶接副的拉剪强度只有13.59 MPa.     

铝合金裂纹板的阳极化处理与复合材料补片胶接修理效果

采用磷酸阳极化方法对胶接修理铝合金裂纹板的粘接表面进行了处理,并用单向碳纤维/环氧复合材料补片对铝合金进行了修补.测试了阳极化铝合金的粘接性能、修补结构的静态力学性能和疲劳性能,考察了粘接表面的阳极化处理对修补结构的静态力学性能和疲劳性能的影响.结果表明,磷酸阳极化在铝合金表面形成多孔膜,复合材料补片修补胶接时胶粘剂能渗透进入阳极化铝合金表面的多孔膜,在粘接界面上形成一层过渡层,该过渡层的形成能有效提高其与复合材料的粘接性能,其粘接副的拉剪强度提高了104%;铝合金裂纹板胶接修理前的粘接表面的阳极化处理能大幅度地提高修复结构的静态强度和疲劳寿命,当用单向碳纤维/环氧复合材料补片单面修补时,修补结构的破坏强度为418.13MPa,恢复到完好板的93.42%;修补结构的疲劳寿命相对裂纹板延长了1.42倍,比未阳极化的修补板的疲劳寿命增加了27.59%.修补前的阳极化处理也使修补结构在一定周次疲劳后的剩余强度有所提高.     

阳极氧化处理增强Al-Li合金胶接板剪切强度的机理

为揭示磷酸阳极氧化处理后Al-Li合金胶接接头剪切强度大幅度增强的机理,分别对其进行机械打磨和磷酸阳极化表面处理,并选用不同的分析仪器对表面处理后的Al-Li合金表面微观形貌、粗糙度、表面润湿性和表面自由能进行测试计算和分析。结果表明,机械打磨后仅在Al-Li合金表面留下纵横交错的沟槽,而磷酸阳极化处理后使得Al-Li合金表面产生了微观粗糙的多孔膜,增加了胶层与合金表面的接触面积,改善了胶质分布的均匀性;磷酸阳极化处理后Al-Li合金表面自由能明显提高,改善了粘接界面的润湿性能。两方面的共同作用,使得胶接界面的抗剪切能力大幅提高。     

Al-Li合金阳极氧化膜的制备与性能

Al-Li合金在潮湿和盐雾环境中易发生晶间腐蚀、剥落腐蚀和应力腐蚀等形式的破坏。为了提高Al-Li合金的耐蚀性,采用阳极氧化的方法,在15%硫酸溶液中在Al-Li合金表面制备了一层Al_2O_3阳极氧化膜,通过测厚仪及显微硬度计测试了膜层厚度及硬度,通过扫描电镜、电化学测试和腐蚀试验等方法,研究了电流密度、氧化时间等对阳极氧化膜耐蚀性的影响。结果显示:所得氧化膜表面呈多孔状结构,厚度在3~13μm之间,硬度在80~200 HV之间;当电流密度为2.0 A/dm~2、氧化时间为60 min、沸水封孔处理20 min时制备的阳极氧化膜耐蚀性最优。     

铝合金阳极氧化膜干燥方式对其粘接性能的影响

利用拉剪实验及楔子实验等测定2A14铝合金粘接件的结合强度和耐久性,结合扫描电镜及红外分析等方法,研究铝合金粘接前阳极氧化膜的微观结构及含水量对其粘接性能的影响.结果表明:铝合金磷酸阳极氧化膜经过冷风吹干、50℃烘干和100℃烘干处理后,粘接试样的拉剪强度随烘干温度升高略有增加;粘接试样的湿热耐久性以50℃烘干处理后的稍好,而100℃烘干处理后,由于氧化膜中产生大量微裂纹,使其耐久性有所下降;氧化膜经过沸水封闭处理后,由于膜中含水量很大及封孔处理限制了粘合剂的渗透,导致其拉剪强度和湿热耐久性皆明显降低.     

硅烷处理对有机涂层／金属胶接接头力学性能的影响

研究了硅烷处理的胶接接头的力学性能,分析了硅烷处理对涂层/金属界面力学性能的影响.对碳钢表面进行硅烷处理,用环氧树脂胶黏剂粘接.对疲劳后的胶接接头施加静态载荷,通过分析硅烷处理胶接接头的应力-应变曲线及接头破坏形式,得出疲劳破坏与静载破坏的区别.结果表明:硅烷处理的胶接接头经一定周次疲劳后能提高接头的粘接强度,接头的破坏形式虽然为界面断裂但却为韧性断裂;接头静拉破坏形式为界面破坏和内聚破坏的混和破坏.     

氟橡胶与金属粘接用新型环氧树脂胶粘剂

用4,4’-二羟基二苯砜与E-51反应制备的树脂配制了可直接用于氟橡胶与金属粘接的新型环氧树脂胶粘剂,系统研究了胶粘剂的粘接性能及耐久性。结果表明:用于胺类硫化的氟橡胶与金属粘接时的平均拉剪强度大于6MPa,所制备试样在自然环境中放置一年后测试,其拉剪强度仍不低于6MPa。通过差示扫描量热法(DSC)和热失重(TGA)分析表明该胶不仅耐热性好,同时也具有很高的热稳定性。此外,所研制胶粘剂用于双酚AF硫化的氟橡胶与金属粘接时的平均拉剪强度大于4.5MPa,其对硅橡胶也有一定的粘接效果,已试用于汽车同步环中氟橡胶与金属的粘接。     

AZ31镁合金的微弧氧化处理及其对粘接性能的影响

采用正交试验方法对镁合金硅酸盐体系的微弧氧化处理工艺进行优化,采用SEM、EDS、XPS和XRD对微弧氧化膜的微观成分与结构进行了表征,进而分析探讨了电解液成分及氧化参数对镁合金表面膜粘接性能的影响规律。研究结果表明,所研究的几种工艺参数对AZ31镁合金表面的粘接性能的影响程度从小到大排列为:KOH的浓度<频率相似文献   

磷酸阳极化工艺对铝合金胶接性能的影响

磷酸阳极化能有效提高铝合金的胶接性能和胶接接头耐久性。介绍了铝合金磷酸阳极化的机理、工艺、流程、各工艺参数对铝合金胶接性能的作用及规律以及对胶接副耐久性的影响。指出今后应优化铝合金阳极化工艺参数,以提高非胶接部分的耐腐蚀性能,从而提高铝合金胶接件的整体性能。     

基于废弃包装纸的纳米纤维素制备及其对淀粉胶黏剂性能的影响

目的探索纸包装废弃物的高附加值利用途径。方法以废瓦楞纸箱、办公废纸和废包装纸板作为原料,采用硫酸法降解制备纳米纤维素;利用所制备的纳米纤维素作为添加剂,加入过氧化氢氧化淀粉胶黏剂中,研究了不同原料、不同添加量的纳米纤维素对淀粉胶黏剂性能的影响。结果纳米纤维素的添加改良了氧化淀粉胶黏剂,当纳米纤维素的添加量为1%时,可以使氧化淀粉胶黏剂获得最优良的性能,此时黏度、干燥速度以及粘接强度均达到最大值,黏度为0.217 Pa·s,4 h时的失水率为43.43%,最大粘接强度为1.243 MPa,3种性能分别提升了5.8%,6.78%,17.26%。结论得到了不同原料制备的纳米纤维素对氧化淀粉胶黏剂性能的影响结果,为废弃纸包装的循环再利用找到了一种方法。     

有机硅改性丙烯酸酯聚合物对环氧树脂胶粘剂性能的影响

采用有机硅改性丙烯酸酯聚合物改性环氧树脂,以聚酰胺为固化剂,研究了有机硅改性丙烯酸酯聚合物对环氧树脂黏度、粘接性能、固化行为、耐热性能和微观形貌的影响。黏度、剪切强度、差示扫描量热（DSC）、动态力学性能（DMA）和透射电镜（TEM）测试表明：有机硅改性丙烯酸酯聚合物与环氧树脂形成互穿网络结构,并且存在较多氢键,剪切强...     

Composite-to-metal tubular lap joints: strength and fatigue resistance

The axial strength and fatigue resistance of thick-walled, adhesively bonded E-glass composite-to-aluminum tubular lap joints have been measured for tensile and compressive loadings. The joint specimen bonds a 63 mm OD aluminium tube within each end of a 300 mm long, 6 mm thick E-glass/epoxy tube. Untapered, 12.5 mm thick aluminium adherends were used in all but four of the joint specimens. The aluminum adherends in the remaining four specimens were tapered to a thickness of 1 mm at the inner bond end (the bond end where the aluminum adherend terminates). For all loadings, joint failure initiates at the inner bond end as a crack grows in the adhesive adjacent to the interface. Test results for a tension-tension fatigue loading indicate that fatigue can severely degrade joint performance. Interestingly, measured tensile strength and fatigue resistance for joints with untapered adherends is substantially greater than compressive strength and fatigue resistance.The joint specimen has been analyzed in two different ways: one approach models the adhesive as an uncracked, elastic-perfectly plastic material, while the other approach uses a linear elastic fracture mechanics methodology. Results for the uncracked, elastic-plastic adhesive model indicate that observed bond failure occurs in the region of highest calculated stresses, extensive bond yielding occurs at load levels well below that required to fail the joint, and a tensile peel stress is generated by a compressive joint loading when the aluminum adherends are untapered. This latter result is consistent with the observed joint tensile-compressive strength differential. Results of the linear elastic fracture mechanics analysis of a joint with untapered aluminum adherends are also consistent with the observed differential strength effect since a mode I crack loading is predicted for a compressive joint loading. Calculations and a limited number of tests suggest that it may be possible to selectively control the differential strength effect by tapering the aluminum adherends. The effect of adherend material and thickness on fracture mechanics parameters is also investigated. The paper concludes by examining the applicability of linear elastic fracture mechanics to the joints tested.     

Strength and fracture behaviour of diffusion-bonded joints in Al-Li (8090) alloy

The shear strength () of overlap shear test pieces made by solid state diffusion bonding or by machining thin (2.5 or 4 mm thick) Al-Li 8090 alloy sheet has been determined for various overlap lengths (/). When / < 3 mm, was independent of / and equal to 188 to 202 MPa for the bonded joint and 199 to 209 MPa for the base metal sheet. The lower mean shear strength of the bonded joint was caused by the lower resistance of intergranular fracture in the planar grain boundary at the bond interface. The bond strengths were, however, greater than those previously reported for joints in 8090 alloy made by solid-state or liquid-phase diffusion bonding and about a factor of 7 greater than those for adhesive bonded joints.     

Geometrical effects in adhesive joints

This paper is concerned with determining the effects of the geometry of the adherends, near the end of the bond line, upon the strength of a shear lap adhesive joint. The particular two dimensional elasto-static boundary value problem of a wedge bonded to a half plane along a finite length is considered in detail. The connection transmits a resultant normal and shear force as well as a moment. A dual integral equation formulation is used and the mathematical problem is reduced to the numerical solution of simultaneous Fredholm integral equations of the second kind. Numerical results are presented for all of the stress intensity factors and the character of the stress field is discussed in detail. It is shown that if the moment, shear and normal resultants transmitted across the bond line satisfy certain relations, then the singular stress field at the ends of the bond line can be eliminated.     

New designs of adhesive joints for thick composite laminates

New joint designs are proposed for adhesive bonding of thick multilayered composite adherends. The objective is to reduce or eliminate the failure modes associated with delamination and tensile and/or shear failure of the surface plies that are often observed in lap joints, and provide for a better stress distribution in the adhesive. In contrast to lap-joint designs, which transfer in-plane tensile stresses and other loads from the adherends to doubler plates by out-of-plane shearing of the surface plies, the new joint configurations transfer most of the load by in-plane shear and normal stresses, through bonded inserts or interlocking interfaces which have the same thickness as the laminate adherends. Doublers will transfer a calculated percentage of the load. Finite-element evaluations of the internal stresses in laminates, joined in both the conventional lap method and the new manner, suggest that the proposed load-transfer mechanism may improve joint efficiency by substantially increasing the size of adhesively bonded areas, and by making the stresses in the adherends nearly uniform through the thickness of the laminate. Some of the designs allow for selected ratios of shear to normal stresses in the adhesive layers. The stress concentrations often found in conventional designs, in the adherend surface plies and the adhesive layer at the leading edges of the doublers, are substantially reduced.     

超声强化氨基化多壁碳纳米管改性环氧黏接接头性能研究

目的 探究超声处理对氨基化多壁碳纳米管(MWCNTs–NH₂)改性环氧黏接接头黏接性能和热稳定性的影响,为强化MWCNTs–NH₂改性环氧胶黏剂与铝合金的黏接提供参考。方法 通过机械搅拌与声波破碎的方法将质量分数为0.75%的MWCNTs–NH₂添加到环氧胶黏剂基体中,使用MWCNTs–NH₂改性环氧胶黏剂制备铝合金黏接接头,基于超声辅助黏接工艺在铝合金黏接过程中进行超声处理。通过傅里叶变换红外光谱仪(FTIR)分析MWCNTs–NH₂改性环氧胶黏剂基体官能团的变化情况。采用单搭接剪切强度试验测定黏接接头的拉伸剪切强度。通过扫描电子显微镜(Scanning Electron Microscope,SEM)观察黏接接头拉伸失效断面以及铝合金与胶黏剂间的黏接界面。通过热失重分析仪(TGA)测试并记录胶黏剂试样质量随温度变化的曲线。结果 经超声处理后,MWCNTs–NH₂与树脂基体间的化学反应增强。与纯环氧黏接接头相比,超声处理后的MWCNTs–NH_2...     

End geometry and pin-hole effects on axially loaded adhesively bonded composite joints

An experimental investigation was performed to analyze the potential impacts of varying joint region geometries and adhesive filled pin holes on adhesively bonded composite structures. Tapers, especially half-length ones are observed to provide an anticipated progress in single lap joints. Besides, scarf joints with aligned adherends in the same plane exhibited enhanced stiffness and strength in consideration of single lap joints. In terms of the stiffness and strength, thickening of adherends was also found to be impressively efficient on composite single lap joints as well as scarf joints. Contrary to the expectation of that the hardened adhesive previously filled into the holes during adhesion would create a pin effect in load bearing, holey specimens exhibited poor performance and induced degradation in joint quality.     

胶膜连接碳纤维增强树脂复合材料板-钢搭接接头室温条件的力学性能试验

针对碳纤维增强树脂（CFRP）复合材料板-钢搭接接头连接的糊状胶黏剂粘层厚一致性控制较难、铅垂向成形可能不易等问题,将糊状胶黏剂换成胶膜,制作了胶膜连接的五种粘结长度共15个CFRP板-钢双搭接接头试件,并对该胶膜连接的CFRP板-钢搭接接头进行了室温条件下的破环模式、有效粘结长度、传力规律、粘结-滑移本构、承载力等的试验研究。结果表明:所用胶膜的连接强度略高于CFRP板层间强度（即碳纤维与树脂基体的黏聚强度）;室温下,所用胶膜连接的CFRP板-钢搭接接头有效粘结长度约为80 mm;加载初期,剪应力最大值位于接头钢板端;继续加载,其位置向接头CFRP板端移动;加载末期,其位置位于距接头钢板端20 mm （粘结长度不超过80 mm时）或者50 mm （粘结长度不小于120 mm时）处;胶膜连接的CFRP板-钢搭接接头界面粘结-滑移模型为近似梯形,不同于胶黏剂连接的CFRP板-钢搭接接头的近似三角形,胶膜连接接头的延性大为提升;所用胶膜连接接头界面峰值剪应力、断裂能、界面刚度等代表值（可视为准平均值）分别为四种典型商品胶黏剂连接接头的1.2~3.0倍、1.6~5.7倍和5.4~7.5倍;在粘结长度不小于有效粘结长度条件下,所用胶膜连接接头的抗拉承载力代表值为四种典型商品胶黏剂连接接头的1.25~2.39倍;胶膜连接接头的抗拉承载力、最大位移的变异系数与糊状胶黏剂连接接头相差不大。