Nucleate boiling heat transfer coefficients of flammable refrigerants on various enhanced tubes

In this study, nucleate boiling heat transfer coefficients (HTCs) of five flammable refrigerants of propylene (R1270), propane (R290), isobutane (R600a), butane (R600), and dimethylether (RE170) were measured at the liquid temperature of 7 °C on a low fin tube of 1023 fins per meter, Turbo-B, and Thermoexcel-E tubes. All data were taken from 80 to 10 kW m⁻² with an interval of 10 kW m⁻² in the decreasing order of heat flux. Flammable refrigerants' data showed a typical trend that nucleate boiling HTCs obtained on enhanced tubes also increase with the vapor pressure. Fluids with lower reduced pressure such as DME, isobutene, and butane took more advantage of the heat transfer enhancement mechanism of enhanced tubes than those with higher reduced pressure such as propylene and propane. Finally, Thermoexcel-E showed the highest heat transfer enhancement ratios of 2.3–9.4 among the tubes tested due to its sub-channels and re-entrant cavities.     

Nucleate boiling heat transfer coefficients of mixtures containing HFC32, HFC125, and HFC134a

Nucleate boiling heat transfer coefficients (HTCs) of binary and ternary mixtures composed of HFC32, HFC125, and HFC134a on a horizontal smooth tube of 19.0 mm outside diameter were measured. A cartridge heater was used to generate uniform heat flux on the tube. Data were taken in the order of decreasing heat flux from 80 kW m⁻² to 10 kW m⁻² with an interval of 10 kW m⁻² in the pool temperature at 7 °C. HTCs of nonazeotropic mixtures of HFC32/HFC134a, HFC125/HFC134a, and HFC32/HFC125/HFC134a showed a reduction of HTCs as much as 40% from the ideal values while the near azeotropic mixture of HFC32/HFC125 did not show the reduction. Four of the well known correlations were compared against the present data for binary mixtures. Stephan and Körner's and Schlünder's correlations yielded a good agreement with a deviation of less than 10% but they can not be easily extended to multi-component mixtures of more than three components. A new correlation was developed utilizing only the phase equilibrium data and physical properties. A regression analysis was carried out to account for the reduction of HTCs and the final correlation, which can be easily extended to multi-component mixtures of more than three components, yielded a deviation of 7% for all binary and ternary mixtures.     

A semi-theoretical model for predicting refrigerant/lubricant mixture pool boiling heat transfer

This paper outlines the framework of a semi-theoretical model for predicting the pool boiling heat transfer of refrigerant/lubricant mixtures on a roughened, horizontal, flat pool-boiling surface. The predictive model is based on the mechanisms involved in the formation of the lubricant excess layer that exists on the heat transfer surface. The lubricant accumulates on the surface in excess of the bulk concentration via preferential evaporation of the refrigerant from the bulk refrigerant/lubricant mixture. As a result, excess lubricant resides in a thin layer on the surface and influences the boiling performance, giving either an enhancement or degradation in heat transfer. A dimensionless excess layer parameter and a thermal boundary layer constant were derived and fitted to data in an attempt to generalize the model to other refrigerant/lubricant mixtures. The model inputs include transport and thermodynamic refrigerant properties and the lubricant composition, viscosity, and critical solution temperature with the refrigerant. The model predicts the boiling heat transfer coefficient of three different mixtures of R123 and lubricant to within ±10%. Comparisons of heat transfer predictions to measurements for 13 different refrigerant/lubricant mixtures were made, including two different refrigerants and three different lubricants.     

Flow condensation heat transfer coefficients of pure refrigerants

Flow condensation heat transfer coefficients (HTCs) of R12, R22, R32, R123, R125, R134a, and R142b were measured experimentally on a horizontal plain tube. The experimental apparatus was composed of three main parts; a refrigerant loop, a water loop and a water-glycol loop. The test section in the refrigerant loop was made of a copper tube with an outside diameter of 9.52 mm and 1 m length. The refrigerant was cooled by cold water passing through an annulus surrounding the test section. All tests were performed at a fixed refrigerant saturation temperature of 40 °C with mass fluxes of 100, 200, 300 kg m⁻² s⁻¹ and heat flux of 7.3–7.7 kW m⁻². Experimental results showed that flow condensation HTCs increase as the quality and mass flux increase. At the same mass flux, the HTCs of R142b and R32 are higher than those of R22 by 8–34% while HTCs of R134a and R123 are similar to those of R22. On the other hand, HTCs of R12 and R125 are lower than those of R22 by 24–30%. Previous correlations predicted the present data satisfactorily with mean deviations of less than 20% substantiating indirectly the reliability of the present data. Finally, a new correlation was developed by modifying Dobson and Chato's correlation with an introduction of a heat and mass flux ratio combined with latent heat of condensation. The correlation showed a mean deviation of 10.7% for all pure halogenated refrigerants' data obtained in this study.     

Performance and heat transfer characteristics of hydrocarbon refrigerants in a heat pump systemPerformance et caractéristiques de transfert de chaleur des frigorigènes hydrocarbures utilisés dans un système de pompe à chaleur

Performance of a heat pump system using hydrocarbon refrigerants has been investigated experimentally. Single component hydrocarbon refrigerants (propane, isobutane, butane and propylene) and binary mixtures of propane/isobutane and propane/butane are considered as working fluids in a heat pump system. The heat pump system consists of compressor, condenser, evaporator, and expansion device with auxiliary facilities such as evacuating and charging unit, the secondary heat transfer fluid circulation unit, and several measurement units. Performance of each refrigerant is compared at several compressor speeds and temperature levels of the secondary heat transfer fluid. Coefficient of performance (COP) and cooling/heating capacity of hydrocarbon refrigerants are presented. Experimental results show that some hydrocarbon refrigerants are comparable to R22. Condensation and evaporation heat transfer coefficients of selected refrigerants are obtained from overall conductance measurements for subsections of heat exchangers, and compared with those of R22. It is found that heat transfer is degraded for hydrocarbon refrigerant mixtures due to composition variation with phase change. Empirical correlations to estimate heat transfer coefficients for pure and mixed hydrocarbons are developed, and they show good agreement with experimental data. Some hydrocarbon refrigerants have better performance characteristics than R22.     

Evaluation of heat and mass transfer coefficients for falling-films on tubular absorbers

A coupled heat and mass transfer model is developed to extract the transfer coefficients for falling-films from the measurements on a tubular absorber. The mass transfer coefficients obtained from the coupled model and the log-mean-difference approach agree within about 10%. For the heat transfer coefficient, the values given by the two models can differ quite significantly. The cooling water temperature distribution predicted by the coupled model agrees well with measurements. The transfer coefficients obtained from experimental measurements using the various methods reported in the literature show wide variations.     

Forced convective boiling heat transfer of R-410A in horizontal minichannels

Convective boiling heat transfer experiments were performed in horizontal minichannels with binary mixture refrigerant, R-410A. The test section is made of stainless steel tubes with inner diameters of 1.5 mm and 3.0 mm and with lengths of 1500 mm and 3000 mm, respectively, and is uniformly heated by applying electric current directly to the tubes. Local heat transfer coefficients were obtained for a heat flux range of 10–30 kW m⁻², a mass flux range of 300–600 kg m⁻² s⁻¹, and quality ranges of up to 1.0. The experimental results were mapped on Wang et al.'s (C.C. Wang, C.S. Chiang, D.C. Lu, Visual observation of two-phase flow pattern of R-22, R-134a, and R-407C in a 6.5-mm smooth tube, Experimental, Thermal and Fluid Science 15 (1997) 395–405) and Wojtan et al.'s (L. Wojtan, T. Ursenbacher, J.R. Thome, Investigation of flow boiling in horizontal tubes: part I – a new diabatic two-phase flow pattern map, International Journal of Heat and Mass Transfer 48 (2005) 2955–2969) flow pattern maps to observe the flow regimes. Laminar flow appears in flow with minichannels. A new boiling heat transfer coefficient correlation based on the superposition model for R-410A was developed with 11.20% mean deviation; it showed a good agreement between the measured data and the calculated heat transfer coefficients.     

Nucleate boiling heat transfer coefficients of HCFC22, HFC134a, HFC125, and HFC32 on various enhanced tubes

In this study, nucleate boiling heat transfer coefficients (HTCs) of HCFC22, HFC134a, HFC125, HFC32 were measured on a low fin, Turbo-B, and Thermoexcel-E tubes. All data were taken at the liquid pool temperature of 7 °C on horizontal tubes of 152 mm length and 18.6–18.8 mm outside diameter at heat fluxes of 10–80 kW m⁻² with an interval of 10 kW m⁻² in the decreasing order of heat flux. For a plain and low fin tubes, refrigerants with higher vapor pressures showed higher nucleate boiling HTCs consistently. This was due to the fact that the wall superheat required to activate given size cavities became smaller as pressure increased. For Turbo-B and Thermoexcel-E tubes, HFC125 showed a peculiar behavior exhibiting much reduced HTCs due to its high reduced pressure. The heat transfer enhancement ratios of the low fin, Turbo-B, and Thermoexcel-E tubes were 1.09–1.68, 1.77–5.41, 1.64–8.77 respectively in the range of heat fluxes tested.     

Evaporation heat transfer for R-22 and R-407C refrigerant–oil mixture in a microfin tube with a U-bendTransfert de chaleur lors de l'évaporation de R-22 et de R-407C mélangés avec de l'huile dans un tube à micro-ailettes avec un coude en U

Evaporation heat transfer experiments for two refrigerants, R-407C and R-22, mixed with polyol ester and mineral oils were performed in straight and U-bend sections of a microfin tube. Experimental parameters include an oil concentration varied from 0 to 5%, an inlet quality varied from 0.1 to 0.5, two mass fluxes of 219 and 400 kg m⁻²s⁻¹ and two heat fluxes of 10 and 20 kW m⁻². Pressure drop in the test section increased by approximately 20% as the oil concentration increased from 0 to 5%. Enhancement factors decreased as oil concentration increased under inlet quality of 0.5, mass flux of 219 kg m⁻² s⁻¹, and heat flux of 10 kW m⁻², whereas they increased under inlet quality of 0.1, mass flux of 400 kg m⁻² s⁻¹, and heat flux of 20 kW m⁻². The local heat transfer coefficient at the outside curvature of an U-bend was larger than that at the inside curvature of a U-bend, and the maximum value occurred at the 90° position of the U-bend. The heat transfer coefficient was larger in a region of 30 tube diameter length at the second straight section than that at the first straight section.     

Experimental study and modelling of heat transfer during condensation of pure fluid and binary mixture on a bundle of horizontal finned tubes

An experimental investigation was conducted to measure the local heat transfer coefficient for each row in a trapezoidal finned horizontal tube bundle during condensation of both pure fluid (HFC 134a) and several compositions of the non-azeotropic binary mixture HFC 23/HFC 134a. The test section is a 13×3 (rows × columns) tube bundle and the heat transfer coefficient is measured using the modified Wilson plot method. The inlet vapour temperature is fixed at 40 °C and the water flow rate in each active row ranges from 170 to 600 l/h. The test series cover five different finned tubes all commercially available, K11 (11 fins/inch), K19 (19 fins/inch), K26 (26 fins/inch), K32 (32 fins/inch), K40 (40 fins/inch) and their performances were compared. The experimental results were checked against available models predicting the heat transfer coefficient during condensation of pure fluids on banks of finned tubes. Modelling of heat exchange during condensation of binary mixtures on bundles of finned tubes based on the curve condensation model is presented.     

Evaporation heat transfer characteristics of R-410A in 7 and 9.52 mm smooth/micro-fin tubes

In-tube evaporation heat transfer characteristics of R-410A were experimentally investigated and analyzed as a function of evaporating temperature, mass flux, heat flux, and tube geometry. Evaporation heat transfer coefficients and pressure drops were measured for 3.0 m long smooth and micro-fin tubes with outer diameters of 9.52 and 7.0 mm, respectively. The test matrix in the present study included measurements for evaporation over a refrigerant mass flux range of 70–211 kg/m²s, a heat flux range of 5–15 kW/m² and an evaporating temperature range of −15 to 5. The objective of this study is to evaluate the heat transfer enhancement of the micro-fin tube with R-410A as a function of mass flux, heat flux, evaporating temperature and tube diameter.     

Condensation heat transfer coefficients of halogenated binary refrigerant mixtures on a smooth tube

In this study, external condensation heat transfer coefficients (HTCs) of nonazeotropic refrigerant mixtures of HFC32/HFC134a and HFC134a/HCFC123 at various compositions were measured on a horizontal smooth tube of a 19 mm outside diameter. All data were taken at the vapor temperature of 39 °C with a wall subcooling of 3–8 °C. Test results showed that HTCs of the tested mixtures were 19.4–85.1% lower than the ideal values calculated by the mole fraction weighting of the HTCs of the pure components. A thermal resistance due to the diffusion vapor film seemed to be partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures.     

Flow boiling heat transfer to carbon dioxide: general prediction method

An updated version of the Kattan–Thome–Favrat flow pattern based, flow boiling heat transfer model for horizontal tubes has been developed specifically for CO₂. Because CO₂ has a low critical temperature and hence high evaporating pressures compared to our previous database, it was found necessary to first correct the nucleate pool boiling correlation to better describe CO₂ at high reduced pressures and secondly to include a boiling suppression factor on the nucleate boiling heat transfer coefficient to capture the trends in the flow boiling data. The new method predicts 73% of the CO₂ database (404 data points) to within ±20% and 86% to within ±30% over the vapor quality range of 2–91%. The database covers five tube diameters from 0.79 to 10.06 mm, mass velocities from 85 to 1440 kg m⁻² s⁻¹, heat fluxes from 5 to 36 kW m⁻², saturation temperatures from −25 °C to +25 °C and saturation pressures from 1.7 to 6.4 MPa (reduced pressures up to 0.87).     

The influence of a low viscosity oil on the pool boiling heat transfer of the refrigerant R507Influence d'une huile à faible viscosité sur le transfert de chaleur lors de l'ébullition libre du frigorigène R507

This paper describes the influence of a low viscosity polyolester based lubricating oil on the pool boiling heat transfer of the refrigerant R507. The pool boiling heat transfer coefficients for this refrigerant–oil mixture are measured on a smooth tube and on an enhanced tube. The investigation is made for oil mass fractions up to 10% and for saturation temperatures between −28.6°C and +20.1°C. For the smooth tube the heat transfer increases for increasing oil mass fractions up to 3% at lower saturation temperatures. At higher saturation temperatures the heat transfer decreases for increasing oil mass fractions for both tubes. For oil mass fractions greater than 1% at the higher saturation temperatures a range of decreasing heat transfer coefficient is found for increasing heat flux. The effect is caused by the different miscibility of the oil and the components of the refrigerant mixture.     

Condensation of refrigerants in horizontal microfin tubes: comparison of prediction methods for heat transfer

A comparison was made between the predictions of previously proposed empirical correlations and theoretical model and available experimental data for the heat transfer coefficient during condensation of refrigerants in horizontal microfin tubes. The refrigerants tested were R11, R123, R134a, R22 and R410A. Experimental data for six tubes with the tube inside diameter at fin root of 6.49–8.88 mm, the fin height of 0.16–0.24 mm, fin pitch of 0.34–0.53 mm and helix angle of groove of 12–20° were adopted. The r.m.s. error of the predictions for all tubes and all refrigerants decreased in the order of the correlations proposed by Luu and Bergles [ASHRAE Trans. 86 (1980) 293], Cavallini et al. [Cavallini A, Doretti L, Klammsteiner N, Longo L G, Rossetto L. Condensation of new refrigerants inside smooth and enhanced tubes. In: Proc. 19th Int. Cong. Refrigeration, vol. IV, Hague, The Netherlands, 1995. p. 105–14], Shikazono et al. [Trans. Jap. Sco. Mech. Engrs. 64 (1995) 196], Kedzierski and Goncalves [J. Enhanced Heat Transfer 6 (1999) 16], Yu and Koyama [Yu J, Koyama S. Condensation heat transfer of pure refrigerants in microfin tubes. In: Proc. Int. Refrigeration Conference at Purdue Univ., West Lafayette, USA, 1998. p. 325–30], and the theoretical model proposed by Wang et al. [Int. J. Heat Mass Transfer 45 (2002) 1513].     

Use of fluorescence to measure the lubricant excess surface density during pool boiling

This paper presents what are believed to be the first measurements of the non-adiabatic lubricant excess surface density on a roughened, flat, plain horizontal pool-boiling surface. Pool boiling heat transfer data is given for pure R123 and a R123/lubricant mixture. Lubricant excess surface density data are given for the boiling R123/lubricant mixture. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of a R123/lubricant mixture on a test surface. The fluorescent measurement technique was used to confirm the existence of the lubricant excess layer during refrigerant/lubricant mixture boiling. The refrigerant preferentially boils, thus, concentrating and accumulating the lubricant on the surface in excess of the bulk concentration. The excess lubricant resides in a very thin layer on the surface and influences the boiling performance. Accordingly, the ability to measure the lubricant excess density on the heat transfer surface would lead to a fundamental understanding of the mechanism by which lubricants can degrade or improve boiling performance. In support of this effort, heat transfer data are provided for both pure R123 and an R123/lubricant (1.8% lubricant mass fraction) mixture at 277.6 K. The heat transfer data shows that the lubricant excess causes an average degradation of 12% in the heat flux for a given superheat.

Résumé

This paper presents what are believed to be the first measurements of the non-adiabatic lubricant excess surface density on a roughened, flat, plain horizontal pool-boiling surface. Pool boiling heat transfer data is given for pure R123 and a R123/lubricant mixture. Lubricant excess surface density data are given for the boiling R123/lubricant mixture. A spectrofluorometer was used to measure the lubricant excess density that was established by the boiling of a R123/lubricant mixture on a test surface. The fluorescent measurement technique was used to confirm the existence of the lubricant excess layer during refrigerant/lubricant mixture boiling. The refrigerant preferentially boils, thus, concentrating and accumulating the lubricant on the surface in excess of the bulk concentration. The excess lubricant resides in a very thin layer on the surface and influences the boiling performance. Accordingly, the ability to measure the lubricant excess density on the heat transfer surface would lead to a fundamental understanding of the mechanism by which lubricants can degrade or improve boiling performance. In support of this effort, heat transfer data are provided for both pure R123 and an R123/lubricant (1.8% lubricant mass fraction) mixture at 277.6 K. The heat transfer data shows that the lubricant excess causes an average degradation of 12% in the heat flux for a given superheat.     

Condensation heat transfer coefficients of flammable refrigerants

In this study, external condensation heat transfer coefficients (HTCs) of six flammable refrigerants of propylene (R1270), propane (R290), isobutane (R600a), butane (R600), dimethylether (RE170), and HFC32 were measured at the vapor temperature of 39 °C on a plain tube of 19.0 mm outside diameter with a wall subcooling of 3–8 °C under a heat flux of 7–23 kW m⁻². Test results showed a typical trend that external condensation HTCs decrease with the wall subcooling. No unusual behavior or phenomenon was observed for these flammable refrigerants during experiments. HFC32 and DME showed 28–44% higher HTCs than those of HCFC22 due to their excellent thermophysical properties. Propylene and butane showed the similar HTCs as those of HCFC22 while propane and isobutane showed 9% lower HTCs than those of HCFC22. Finally, a general correlation was made by modifying Nusselt's equation based upon the measured data of eleven fluids of various vapor pressures including halogenated refrigerants. The general equation showed an excellent agreement with all data exhibiting a deviation of less than 3%.     

Enhancement of condensation heat transfer by means of passive and active condensate drainage techniques

A short state-of-the-art review on the passive and active enhancement of condensation heat transfer techniques developed recently is presented in the paper. The particular attention is paid to the methods involving the augmentation of the condensate drainage. As an example of the passive technique the method of condensate drainage enhancement by using the drainage strip is presented. For an active method of heat transfer enhancement a novel EHD technique is described. For both methods the own experimental results as well as theoretical models are provided.     

Impact of refrigerant–oil solubility on an evaporator performances working with R-407C

We propose in this study a simplified model of enthalpy calculation for a refrigerant–oil mixture, as well as a new presentation of the pressure–enthalpy–vapour quality diagram which is applied to refrigerant–oil mixtures with different oil circulating mass fractions. This presentation allows the calculation of the enthalpy change through an evaporator, with and without taking into account the effect of oil, and the prediction of the non evaporated quantity of refrigerant at the compressor suction. The results of the model for two pairs of R407C/POE oil of different solubilities show that under the same working conditions, the solubility of the refrigerant in oil can have a considerable effect on the evaporator performances. Indeed, for two oils presenting the same viscosity grade, the evaporator performances decrease when the refrigerant–oil solubility increases.     

Condensation heat transfer of R410A inside internally grooved horizontal tubes

Heat transfer coefficients were measured for the condensation of R410A and R22 inside internally grooved horizontal tubes. The experiment was performed for five different kinds of internally grooved tubes of about 8.00 mm o.d. the shapes of which were conventional helical grooved and herring-bone grooved ones. To measure the local heat transfer coefficients, the test section was subdivided into 10 small sections having 1 m working length. The ranges tested are as follows: the refrigerant mass velocity was from 130 to 400 kg/(m²/s) for R410A and R22, and the vapour pressure was 2.4l MPa for R410A and 1.53 MPa for R22. The obtained heat transfer data of R410A and R22 indicate that the values of the local heat transfer coefficients of the herring-bone grooved tube are about twice as large as those of helical one. All measured local heat transfer coefficients of condensation were compared with the predicted values from previous correlations proposed by other researchers, and were well correlated with the empirical equation using the frictional coefficients for each tube proposed by the author.