盐湖水中包铝对超硬铝合金基材的保护作用

利用带包铝LC4铝合金在东部地区海水、西部地区盐湖水、中部地区淡水中的暴露腐蚀试验,对盐湖水中包铝对铝合金基体的保护作用行为进行了探讨,得到带有包铝的LC4铝合金在水系统中的腐蚀规律.经过半年和一年的腐蚀试验表明,在不同的水介质中包铝对铝合金基材的保护作用表现不同.在海水和淡水中,包铝层可以对铝合金基材起到完全的保护作用,使基材免遭腐蚀;而在盐湖水中,半年时LC4铝合金表面尚有包铝存在,而一年时LC4铝合金表面包铝已完全消耗至尽,LC4的基体发生严重腐蚀.     

变形次数对LC4合金T6态组织与性能的影响

在420℃对超硬铝合金LC4进行不同次数的压缩,并结合金相显微组织观察、力学性能测试等方法,研究试样在相同变形温度、相同变形量下,变形次数对其T6态显微组织和性能的影响。结果表明:随着热变形次数的增加,LC4铝合金经固溶处理、时效处理后的硬度值显著增加。     

变形条件对2124铝合金超厚板流变行为与显微组织的影响

在Gleeble-1500热/力机上进行了变形条件对2124铝合金超厚板流变行为与显微组织的影响规律的系列实验研究,得到了不同变形条件下2124铝合金超厚板高温压缩成形过程中的流变曲线。实验结果表明,2124铝合金在0.01s-1~1s-1范围内,高温压缩变形过程存在近稳态流变特征,近稳态流变应力随着应变速率的降低和变形温度的升高而降低。当应变速率为10s-1时,真应力-真应变曲线出现锯齿状,说明合金发生动态再结晶现象。利用OM和TEM分别研究了变形温度、应变速率、应变量对2124铝合金高温压缩变形显微组织的影响,在此基础上,分析并建立了2124铝合金热压缩变形发生动态再结晶的临界条件。     

LC4高强铝合金的腐蚀性能研究

利用慢应变速率拉伸试验方法研究了LC4铝合金在空气和3．5％NaCl溶液中的应力腐蚀断裂行为；利用HB5455－90标准研究了LC4铝合金的剥蚀行为；利用HB5255－83标准研究了LC4铝合金的晶间腐蚀行为。结果表明：LC4铝合金具有应力腐蚀敏感性，应力腐蚀的断口形貌受应变速率ε的影响较大；LC4铝合金对剥蚀很敏感，对晶间腐蚀不是很敏感。     

往复挤压道次对车用LC9合金表面组织和性能的影响

采用光学显微镜、维氏硬度、极限拉伸强度和压缩屈服强度等试验手段,评价了不同往复挤压道次对LC9铝合金表面微观形貌和力学性能的影响。结果表明,往复挤压道次能显著影响LC9铝合金的组织和力学性能。合金的力学性能随着往复挤压道次的增加呈现出先增加后降低的趋势,500℃条件下当往复变形道次为4次时合金的力学性能最佳。     

铝合金和铜合金在我国东西部水系统中暴露1年的腐蚀规律

通过对含银5056铝合金、高纯LY6铝合金、LC4铝合金、纯铝L6M、LF6铝合金及紫铜T2和硅青铜在青岛海水、舟山海水、厦门海水、盐湖、淡水投放,得到这些有色金属材料在水系统中的腐蚀规律.经过半年和一年两个周期的腐蚀试验表明,含银5056铝合金和L6M在各试验站主要表现点蚀现象;带包铝的高纯LF6和LC4由于包铝的保护作用在淡水和海水中腐蚀较轻,在盐湖高纯LY6合金表面的包铝将消耗至尽,LC4的基体已经发生严重腐蚀;带包铝的LF6由于“电解质效应”在盐湖发生严重腐蚀;铜合金在盐湖表现比海水更好的适应性.      

基于元胞自动机法的7055铝合金动态再结晶变形参数优化（英文）

为了研究7055铝合金在热压缩过程中的组织演变规律,基于元胞自动机法(CA)建立7055铝合金动态再结晶(DRX)模型。为了获得模型的材料参数,进行单道次热压缩实验,通过最小二乘法拟合获得7055铝合金的位错密度模型、形核率模型和再结晶晶粒长大模型。研究应变、应变速率、变形温度和初始晶粒尺寸对热压缩过程中显微组织演变的影响。结果表明:在热压缩过程中,动态再结晶使材料晶粒明显细化。大应变、高温和低应变速率有利于晶粒细化;动态再结晶晶粒的稳态晶粒尺寸与初始晶粒大小无关,而取决于温度和应变速率的变化;分析热压缩过程动态再结晶动力学规律。由CA仿真流变应力值和仿真组织图与实验结果的对比可知,所建立的基于CA法的动态再结晶模型能有效地预测7055铝合金在热变形过程中的动态再结晶组织演变规律。     

半固态5083铝合金压缩变形行为及组织特性

采用Gleeble 3500热模拟试验机,分别对铸态和SIMA法制备的半固态5083铝合金压缩变形行为进行了研究,并结合压缩后的宏观形貌和显微组织对液相的流动规律进行了分析。结果表明,变形温度和应变速率是影响5083铝合金半固态坯料热压缩变形的两个重要参数;在半固态温度区间压缩变形时,铸态坯料整体应力水平明显高于SIMA法制备的半固态坯料;而在固态温度区间内高温压缩变形时,二者流变应力曲线特征相似,半固态坯料没有明显优势;两种不同状态5083铝合金固液两相区压缩变形时,存在3个典型变形区域,半固态组织中液相均匀分布于晶粒晶界处,而铸态组织中液相分布位置极不均匀,半固态5083铝合金压缩变形后试样的致密度和均匀性优于铸态材料。     

7075铝合金热压缩变形流变应力

在Gleeble-1500热模拟试验机上,采用高温等温压缩试验,对7075铝合金在高温压缩变形中的流变应力行为进行了研究。结果表明,应变速率和变形温度的变化强烈地影响合金流变应力的大小,流变应力随变形温度升高而降低,随应变速率提高而增大;可用Zener-Hollomon参数的指数形式来描述7075铝合金高温压缩变莆时的流变应力行为。     

7075铝合金热压缩变形道次间软化规律研究

在Gleeble-1500热模拟试验机上,采用高温等温压缩试验,研究了7075铝合金两道次热压缩变形道次间的软化规律。结果表明,在热压缩变形道次间保温停歇之后,流变应力出现明显的软化现象,保温停歇时间越长,合金软化率越高;变形及停歇保持温度越高,合金软化越严重。     

Hot Corrosion Behavior of CM 247 LC Alloy in Na2SO4 and NaCl Environments

Hot corrosion studies of CM 247 LC alloy werecarried out in pure sodium sulfate, as well as sodiumchloride and sodium sulfate mixtures of differentconcentrations at various temperatures. A crucible test was employed to study the suitability of CM 247LC as a gas turbine blade material. It was observed thatbare CM 247 LC was severely corroded in just 4 hr, whileit was completely consumed in 70 hr when tested in 90% Na₂SO₄ +10% NaCl at 900°C. The results show that a chloridecontaining melt is more corrosive than pure sodiumsulfate. The weight loss is linearly related tot^1/2 (time) and temperature in the different environments studied. Thecorroded samples were characterized by EPMA, SEM, XRD,and metallographic techniques. The results show that hotcorrosion of CM 247 LC is an electrochemicalphenomenon.     

Electrochemical impedance characteristics of LC4 aluminum alloy treated with ZH1 technique

ZH1 technique was used to form a corrosion resistant layer on LC4 alloy. The composition of the layer was studied by X-ray photoelectron spectroscopy (XPS). It is found that the layer is composed of oxides of metals on the substrate, such as A12O3, ZnO, MgO2, CuO, and MnO2. The electrochemical impedance spectrums (EIS) of LC4 aluminum alloy specimen were measured in NaCl solutions to study the mechanism of the corrosion resistance of the alloy treated with ZHI technique. The results show that in NaCl solutions the capacitance of the Helmholtz layer and space charge layer of the oxide coating formed on the surface of LC4 alloy is less than that of a normal metal electrode while its ohmic resistance is relatively greater. At the same time, the thickness of the Helmholtz layer is 1-3 exponentially greater than that of a normal metal electrode. Compared with a normal metal electrode, all these characteristics make it more difficult for charges to transfer between the solution and the surface of the electrode. That is why the polarized current density of LC4 alloy treated with ZHI technique kept small in 3.5% NaCl solution within a wide range of potential, and why the polarized curves of LC4 alloy treated with ZH1 technique changed a little in 3.5% NaCl solution of different pH values.Moreover, according to the capacitance of the space charge layer (Csc) obtained at different potentials in 3.5% NaCI solution, I/Csc^2-E curve was laid out. It is found that there does not exist a simple linear relation between I/Csc^2 and the potential. Therefore, the oxide coating formed on LC4 alloy with ZH1 technique is not a semiconductor at room temperature.     

Ti8LC合金热变形及其微观组织

采用GLEEBLE-1500热模拟机对Ti8LC合金在温度为850～1000 ℃、变形速率为0.001～0.1 s-1、最大变形程度为60%的条件下,进行恒应变速率高温压缩模拟试验研究,分析合金高温变形时流变应力与应变速率及变形温度之间的关系以及组织变化.结果表明:Ti8LC合金流变应力随应变速率的增大而增大,在恒应变速率条件下,真应力水平随温度的升高而降低;在给定的变形条件下,通过回归计算,建立了一种Ti8LC合金的本构方程;根据试验分析,在850～950 ℃温度时变形,主要发生动态再结晶,随着温度的升高,软化机制主要是动态回复.     

Dynamics in polymer–liquid crystal microcomposites studied by low frequency mechanical spectroscopy

Polymer–liquid crystal (LC) microcomposites (LC droplets dispersed in a polymeric matrix) exhibit optical properties associated with the mesogenic molecules together with the mechanical properties of the polymeric matrix. The raw materials considered in this study are (i) the UV curable prepolymer and (ii) the LC molecules (cyanobiphenyl or benzoates mixtures). The morphology and thus the physical properties induced by the phase separation depend on the polymerization conditions. This morphology was observed by electron microscopy and the transition temperatures were determined by calorimetric analysis. The dynamic properties of these microcomposites were studied by low frequency mechanical spectroscopy. Different phenomena were observed, namely (i) at low temperature the secondary relaxation of the polymeric matrix and a process attributed to a liquid glass like transition in the LC domains and (ii) a strong relaxation effect near the room temperature attributed to the glass transition of the polymeric matrix. The characteristics of these phenomena were deduced from temperature and frequency scanning. The elastic modulus becomes proportional to the temperature above the main transition of the polymeric matrix, which is the classical effect of entropic elasticity. Moreover, it is shown that the glass transition of the polymeric matrix is depressed by the presence of LC molecules that remain dissolved in the matrix and act as a plasticizer.     

飞机典型连接件腐蚀及腐蚀疲劳试验研究

选取了飞机机翼与机身连接结构中LY12与30CrMnSiA、LC4与LC4两种典型连接形式,通过对典型连接件进行不同的预腐蚀,在不同腐蚀介质温度、不同腐蚀介质pH值,及不同腐蚀介质盐浓度条件下进行腐蚀疲劳试验。结果表明:LY12与30CrMnSiA典型连接形式具有较好的耐腐蚀性能,而LC4与LC4典型连接形式耐腐蚀和腐蚀疲劳性能较差,不同腐蚀介质NaCl浓度、不同腐蚀介质pH值对疲劳性能无显著影响,腐蚀介质温度对疲劳性能有一定影响。     

Ti8LC合金热处理力学性能的回归分析

采用正交试验设计了Ti8LC合金的热处理制度,并测试了不同热处理制度下Ti8LC合金的室温抗拉强度,利用多元回归模型对Ti8LC合金的热处理制度与抗拉强度进行了回归分析,建立了热处理制度与抗拉强度之间的回归方程,通过方差分析验证了该回归方程具有较高的可信度。同时分析了Ti8LC合金抗拉强度与合金相的体积分数及晶粒尺寸的关系,得到了合金室温抗拉强度与合金相的体积分数及晶粒尺寸近似呈线性关系,并从微观组织结构分析了合金相的体积分数、晶粒尺寸与热处理温度、时间之间的关系。     

High temperature deformation mechanism and evolution of dislocation structure during creep of Ni-Base superalloy 713LC

Creep deformation of cast nickel base superalloy 713LC has been investigated in a temperature range of 723 to 982°C. The values of the stress exponent and activation energy for creep of the alloy vary with a combination of temperature and stress. Introduction of threshold stress for creep of the alloy provided an explanation of the high values of the stress exponent and the apparent activation energy. Microstructural evolution of the alloy with creep deformation has also been studied. The analysis of the creep mechanism has been supplemented by microstructural observations after deformation under various test conditions. The dislocation structure of the alloy at high temperature and low stress was different from that at low temperature and high stress. Shearing of γ′ particles by dislocation pairs was the dominant creep mechanism at low temperature and high stress whereas dislocation climb over γ′ particles was the rate controlling process of creep at high temperature and low stress.     

Precipitate Formation and Evolution in the Superalloy IN738LC

IN738LC is a polycrystalline, nickel-based superalloy, which provides a high performance in aggressive environments at temperatures above 650°C. At this high temperature, the expected properties are good corrosion resistance, optimal thermal properties, and creep and fatigue resistance. These required properties are obtained via solid solution hardening and precipitation hardening of a face-centered cubic (fcc) Ni matrix phase. The size, morphology and distribution of precipitates determine the properties o...     

Formation and Microstructural Characterization of Silicon-modified Aluminide Coating on Nickel-based Superalloy IN738LC

ALUMINIDE COATINGS are used extensively forprotecting gas turbine hot section components due totheir high oxidation resistance and low capital cost.However,for some application,their properties must bemodified by adding elements such as Cr,Si and Pt tomeet high performance gas turbines requirements[l,2].Although silicon is less efficient as a protective scaleformer than chromium and aluminum,silicon-modifiedaluminide coatings,have shown better hot corrosionresistance(specially to type …