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高温煤焦油悬浮床加氢裂化研究 总被引:2,自引:0,他引:2
利用悬浮床加氢对高温煤焦油进行加氢裂化研究。分析了煤焦油的性质,研究了反应条件对产物分布的影响。结果表明,随着温度的升高和时间的延长,反应裂解程度加深,反应生成更多的气体、石脑油和柴油馏分,同时甲苯不溶物的含量也在增高。反应压力低于15MPa,提高压力,汽柴油馏分产率提高显著,反应高于15MPa汽柴油产率提高不明显,甲苯不溶物含量显著提高。 相似文献
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该技术利用煤焦油以及焦炉煤气为原料,采用煤焦油加氢裂化技术,选择合适的催化剂和反应条件,生产清洁燃料油调和组分。新建装置主要包括加氢裂化装置和提氢装置,公用工程及辅助设施依托原焦化装置,可达到经济效益最大化。 相似文献
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煤焦油加氢裂化装置管道选材探讨 总被引:1,自引:0,他引:1
煤焦油来源广泛,组分复杂,具有富含芳烃、酚类、盐类特点。煤焦油加氢裂化过程伴随着高温、高压及临氢等工况,反应会生成大量的H2S和NH3等腐蚀性介质。文章就该类装置的主要腐蚀部位及各种腐蚀发生机理进行了阐述,并给出了各种腐蚀环境下的管道选材建议。 相似文献
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阐述了催化剂中活性金属和助剂的种类及含量对催化剂性能的影响;总结了活性金属和助剂对金属-载体相互作用、催化剂酸分布以及催化剂表面性质的影响机制。指出制备一个性能优良的催化剂应从两方面入手,首先是制备一个性能优良的载体,要求它具有合适的孔分布和酸分布, 负载的金属应具有较高的分散度和还原性能。探讨了适于煤焦油的加氢处理催化剂,主要是防止催化剂的中毒、积炭、失活,并且协调各种催化剂同步失活,以利于整个装置运行周期的延长。旨在为煤焦油加氢精制和加氢裂化催化剂研究(设计)提供一定的理论指导,避免焦油加氢精制和加氢裂化催化剂研究和开发的盲目性。 相似文献
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为考察陕北全馏分煤焦油加氢深度转化效果,在陕西延长石油(集团)碳氢高效利用技术研究中心悬浮床加氢裂化中试装置上进行试验,在系统基准压力22MPa,进料量0.5 kg/(h·L), 0.5%添加剂条件下,分别又从温度为450℃,压力为20,18,16MPa;压力为20MPa,温度为460,455,450,440℃的反应条件下,研究煤焦油加氢裂化反应后的整体转化率、>500℃重组分转化率、气体产率及<500℃液体收率。实验结果表明:温度在450℃,压力变化对煤焦油转化效果影响不大;压力为20MPa,温度在460℃,煤焦油整体转化率达97.32%,>500℃重组分转化率达90.73%,气体产率为8.34%,<500℃液体收率达86.37%。 相似文献
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中国是一个多煤少油的国家,煤制油技术在我国有着广泛的应用前景。由于超临界流体对有机物有较好的溶解性,因此越来越多地应用到煤焦油深加工过程中。本文总结了超临界流体改质煤焦油过程中,操作参数对煤焦油轻质化的影响和强化改质方法,重点分析了超临界水和超临界甲醇,超临界水改质煤焦油主要体现在物理上的溶解和分散作用,而超临界甲醇除此之外,有一定的供氢能力,可以为反应提供氢,但是供氢能力有限。因此,本文又讨论了添加催化剂、自由基引发剂、加氢等手段强化超临界流体改质煤焦油。在此基础上对超临界流体改质煤焦油进行了展望,将超临界流体的萃取和超临界改质耦合在一起,充分发挥超临界流体优越性;选择新的超临界流体、催化剂等促进煤焦油轻质化。 相似文献
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超临界流体抽提技术是一项新型、绿色、环保的技术,超临界流体抽提技术应用于煤焦油研究的主要目的分为超临界条件下提取其中成分,使煤焦油轻质化,本文介绍了超临界流体抽提技术应用于煤焦油的研究进展,指出了今后的研究方向. 相似文献
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This paper describes a new method to remove nitrogen from coal derived pitches, using catalytic hydrotreating in supercritical toluene-tetralin. The results obtained suggest that nitrogen was selectively removed from the mother pitch, the reaction rate was much higher than that in conventional processes due to higher diffusivity, and coke deposition on the catalyst could be prevented perhaps due to the high solvent power of the supercritical fluid. 相似文献
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To reduce coke production during low temperature coal tar hydrocracking in supercritical gasoline, a lump kinetic model was derived on the basis of catalytic cracking reaction mechanism. Lumps were defined by different reaction properties. Reaction rate constants, indexes of hydrogen to coal tar ratio, indexes of gasoline to coal tar ratio, activation energies, and pre-exponential factors were estimated according to the previous experimental data. The results show that the proposed model could not only predict the product yields successfully, but also provide more information which was useful for any attempts to reduce the coke content and promote the conversion of coal tar to light oils. 相似文献
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The upgrading of high-temperature coal tar in supercritical water (SCW) was investigated using an autoclave reactor. The effects of temperature (673–753 K), pressure (24–38 MPa) and residence time (1–80 min) on product distribution were studied. The yields and characteristics of products in SCW were compared with those obtained in N2. In order to study the reaction mechanism of coal tar upgrading, the experiments of model compounds were carried out in SCW at 673 K and 34 MPa for 20 min. The results indicate that the asphaltene conversion and the maltene yield are significantly higher in SCW. The H/C atom ratios of oil obtained in SCW are higher than those obtained in N2. More valuable aromatic compounds such as naphthalene, fluorene and anthracene are obtained in SCW. The results of model compounds suggest that water in SCW could participate in coal tar upgrading and promote the formation of light products. 相似文献