放电等离子烧结-热变形技术制备NdFeB永磁材料

采用放电等离子烧结(SPS)方法烧结HDDRNdFeB粉末,研究烧结温度对制备NdFeB永磁材料密度和磁性能的影响。随着烧结温度在650～900℃范围内升高,剩磁、内禀矫顽力及最大磁能积均呈现先升后降的趋势。800℃烧结所获得磁体的磁性能最佳:Br=0.78T,Hcj=577kA/m,(BH)max=78kJ/m3,其致密度达到了99%。微观组织、XRD图谱及磁性能均表明800℃烧结的磁体出现了一定程度的各向异性。900℃烧结时,晶粒长大明显。进而选择具有最佳磁性能的磁体在800℃进行热变形(HD)处理,制备出各向异性磁体。热变形制备的磁体中,大部分晶粒为扁平片状且c轴取向与热压方向一致;少量异常长大晶粒会使细小Nd2Fe14B晶粒的c轴偏离压力方向。各向异性磁体沿c轴的磁性能为:Br=1.09T,Hcj=384kA/m,(BH)max=114kJ/m3。     

应变速率对热变形NdFeB磁体微观结构和性能的影响

以放电等离子烧结(SPS)磁体为前驱烧结磁体,通过热变形制备了纳米晶各向异性磁体。研究了变形速率对磁体微观结构和性能的影响。研究发现,对于不同的应变速率,SPS磁体中不同区域的微观结构显示了不同的热变形行为。较大的晶粒尺寸不利于通过热变形制备各向异性Nd Fe B磁体。在不添加重稀土元素和较低稀土含量的情况下,制备出具有良好磁性能(Jr=1.35 T、jHc=829 k A/m和(BH)max=336 k J/m3)和较低矫顽力温度系数(β=–0.682%K-1)的纳米晶热变形磁体。     

放电等离子烧结Nd—Fe—B过程特征

研究了不同烧结温度下,放电等离子烧结的Nd-Fe-B永磁体在烧结过程中样品收缩量随温度的变化,讨论了提高样品密度的措施.放电等离子烧结的Nd-Fe-B永磁体晶粒细小且均匀,晶粒平均尺寸为3.8 μm,为一般传统粉末烧结制备Nd-Fe-B磁体晶粒尺寸的1/4.     

化学气相沉积法制备Nd-Fe-B/α-Fe纳米复合磁体

采用化学气相沉积法制备单质铁包覆Nd-Fe-B复合磁粉,经放电等离子烧结得到Nd-Fe-B/α-Fe纳米复合磁体.SEM、XRD、XPS研究表明:采用化学气相沉积法可以实现纳米单质铁对Nd-Fe-B磁粉表面的均匀包覆,有效地改善软硬磁性相的分布,提高磁体的综合磁性能.化学气相沉积温度为120℃、沉积时间为30 min时,得到的包覆层致密均匀,单质铁颗粒尺寸50～100 nm.在优化工艺条件下制备出接近全致密的纳米复合磁体,其磁性能可达:Br=0.81 T,Hcj=1286kA/m,(BH)m=108.6 kJ/m3.     

掺杂La-Ce-Cu合金对热变形Nd-Fe-B磁体磁性能和微观结构的影响

研究采用放电等离子烧结(SPS)技术制备了掺杂不同含量的La-Ce-Cu合金的Nd-Fe-B热变形磁体;研究了掺杂量对磁体磁性能和微观结构的影响。结果表明,随着掺杂量的增加,热变形Nd-Fe-B磁体的矫顽力先增加后降低;而剩磁与磁能积均有所下降。磁体的矫顽力在掺杂量为1%(质量分数)时,达到最大值为1257kA/m。微观分析表明,掺杂合金中的La元素倾向于分布在富稀土相中,不易进入主相晶粒;而Ce元素则易取代Nd进入主相晶粒中。     

DyF<sub>3</sub>掺杂热变形NdFeB磁体的微观结构和性能

基于热变形技术,研究制备了DyF3掺杂热变形NdFeB磁体的微观结构和磁性能。结果表明,通过热变形,磁体获得了具有明显C轴取向特征的扁平形状晶粒,其剩磁从前驱体烧结磁体的0.77 T提高至 1.34 T,提升了近74%。此外,热变形过程起到了晶界扩散的作用,使得DyF3进一步扩散至NdFeB主相之中,形成了(Nd, Dy)2Fe14B相,从而减小了因热变形带来的矫顽力损失。电化学测试表明,热变形过程可提高磁体腐蚀电位和减小电流密度。变形条件800 ℃/70%时,磁体具有最佳的综合磁性能和电化学性能,其磁性能可达：Br=1.34 T,Hcj=1225 kA/m和(BH)max=286 kJ/m3。     

放电等离子烧结制备高性能NdFeB永磁材料

采用放电等离子烧结技术制备高性能新型NdFeB永磁材料,研究烧结工艺和热处理工艺对磁体组织性能的影响。采用扫描电子显微镜观察磁体的微观组织,利用B-H回线仪检测磁体的磁性能。结果表明:较高的烧结温度有利于磁体的致密化,但过高的温度则阻碍液相在主相晶界的浸润,从而降低磁体的致密度。在优化工艺条件下制备出具有独特的微观组织且最佳性能为Br=1.351 T,Hci=674.4 kA/m,BHm=360.4 kJ/m3的新型SPS NdFeB磁体。     

热变形温度对纳米晶Nd-Fe-B磁体性能的影响

为了研究纳米晶Nd-Fe-B磁体的热变形机理,在不同温度下对快淬粉进行热压热变形处理.通过分析不同温度下热变形过程中应力和磁体应变的变化,以及磁性能和SEM测试,研究了温度对热变形磁体性能和微观结构的影响,分析了热变形过程的热变形机理.结果表明,纳米晶磁体存在最佳的热压温度和热变形温度.当热压温度为550℃,热变形温度...     

基于快淬NdFeB粉末的放电等离子烧结永磁的组织和性能

利用纳米晶快淬NdFeB粉末为原材料,采用放电等离子烧结(SPS)技术制备了高密度各向同性块体永磁.研究了放电等离子火花烧结磁体不同部位的磁性能和显微组织形貌,比较了烧结压力对磁体的组织和性能的影响.结果表明,由于组织的差异,烧结磁体不同部位磁性能略有不同,内部的剩磁较高,磁体边缘的矫顽力较高,而半径中点处的综合磁性能最好.烧结压力对烧结磁体的密度、显微组织,晶粒大小和形状以及磁性能都有重要影响.高的烧结压力有利于提高磁体密度、减小粗晶区体积、改善磁性能.SPS磁体中存在明显的晶间交换耦合作用.     

SPS制备各向异性微米晶SmCo_5烧结磁体的研究

采用放电等离子烧结技术制备了各向异性微米晶SmCo_5磁体,研究了磁体的烧结工艺及添加Fe纳米粉对磁体结构和磁性能的影响。研究发现,SmCo_5烧结磁体的最佳烧结温度为830℃,此时磁体的室温磁性能最佳:B_r=8.19 kGs,H_(cj)=10.6 kOe,(BH)_(max)=13 MGOe;而添加Fe纳米粉的烧结磁体,饱和磁化强度升高,但剩磁和矫顽力降低。XRD结果表明,未添加Fe纳米粉的烧结磁体具有单相CaCu_5结构,而添加Fe纳米粉的烧结磁体出现了2∶17相和Fe-Co软磁相。SEM及能谱分析发现,添加的Fe纳米粉扩散进入了1∶5相,形成Sm(Fe,Co)_5和Sm_2(Fe,Co)_(17))。     

粘结剂和添加剂对注射成型各向异性粘结NdFeB磁体的影响(英文)

研究了在取向磁场下由HDDR磁粉注射成型的各向异性粘结NdFeB磁体,分析了粘结剂和添加剂对各向异性粘结NdFeB磁体的密度、磁性能以及抗压强度的影响.通过磁粉表面改性,磁粉的抗氧化性能以及磁体的磁性能都得到提高.比较了6种粘结剂对磁体性能的影响,从中得到比较理想的粘结剂,并且考察了抗氧剂以及润滑剂加入量对于磁体性能的影响.试验中,混炼温度为205～215 ℃,注射温度为265℃,注射压力为5～6 MPa,保压时间为5 s,模具加热温度为80℃.制得的磁体的性能为:Br=0.72 T,iHc=983 kA/m,(BH)max=75 kJ/m3.     

Microstructures and magnetic properties of Ce32.15Co49.36Cu9.84Fe9.65 magnet sintered at different temperatures

The microstructures and magnetic properties of Ce32.15Co49.36Cu9.84Fe9.65 magnet sintered at the temperatures ranging from 1005 to 1105 ℃ were investigated.The results on scanning electron microscopy and X-ray diffraction analysis indicate that the remanence Br of the magnets is mainly influenced by the degree of the easy-axis orientation when sintering temperature is less than 1085 ℃,the rapidly increasing amount of the secondly phase (5∶19 phase) gives rise to the deterioration of the magnetic properties of the magnet above 1085 ℃.Moreover,it is found that intrinsic coercivity Hci is strongly related to the content of copper in the matrix of the sintered magnets.The optimal sintering temperature is located in 1025～1055 ℃,the corresponding magnetic properties of the magnets are Br=0.685 T,Hci=350 kA·m-1,and maximum energy product (BH)m=85.6 kJ.m-3.     

SPS制备SmCo7-xFex块状纳米晶磁体的研究

采用高能球磨法制得SmCo7-xFex非晶粉末,然后采用放电等离子技术将其烧结为块状纳米晶磁体,对磁体的微观结构和磁性能进行了观察和测试.结果表明,SmCo7-xFex球磨5 h后成为非晶粉末,经SPS烧结后得到1:7相.TEM观察表明,磁体晶粒尺寸在20～50 nm.另外,磁体具有较好的磁性能,当x=0.4时,矫顽力为992.8 kA/m,剩磁为0.634T,(BH)max为69.75KJ/m3.     

Heat treatment process of new NdFeB magnet prepared by spark plasma sintering

1　INTRODUCTIONTraditionallysinteredNdFeBmagnetcanmeettherequirementofdimensional precisionthroughpost machining ,whichusuallyresultsin 4 5 %ofma terialloss.Post machiningnotonlywastestherareearthresources ,butalsoincreasesthe productioncost .Moreover ,itisdifficulttopreparehomogeneousworkpieceswithlargedimensionandcomplicatedshapeduetosomeuncontrollablefactorsinthecon ventionalsintering process .Ontheotherhand ,al thoughthebondedNdFeBmagnethasbetterforma bilityanddimensionalprecision ,…     

放电等离子烧结NdFeB磁体的富稀土相与矫顽力

利用放电等离子烧结技术(SPS)制备新型烧结磁体SPS NdFeB。为了更好理解磁体的磁性能,尤其是矫顽力和微组织关系的机理,本研究以热处理前后的SPS NdFeB为研究对象,利用扫描电镜(SEM)、高分辨透射电镜(HRTEM)、X射线能谱仪,B-H回线仪分别对磁体的显微组织和高分辨透射电镜像组织和磁性能进行了系统研究。结果表明,经过热处理后,磁体矫顽力明显提高,富稀土相的铁原子与稀土原子比Fe/Re明显下降;富稀土相结构形态发生明显变化,由热处理前的非晶态变为热处理后的晶态。     

Microstructure,Mechanical and Corrosion Properties of AlCoCrFeNi High-Entropy Alloy Prepared by Spark Plasma Sintering

AlCoCrFeNi is one of the most widely studied alloy systems in the high-entropy alloy(HEA) area due to the interesting microstructure and mechanical properties.In this study,the AlCoCrFeNi alloy was prepared using spark plasma sintering(SPS) with pre-alloy powders obtained through gas atomization.Then,the sintered samples were annealed at 700,800 and900℃,and the effect of annealing temperature on the microstructure,mechanical and corrosion properties was studied.The results show that phase formation takes place during annealing process with the new phase(σ) and some nano scale BCC precipitates formation.The size and quantity of the nanoscale precipitates increase with increasing annealing temperature.The twin is also observed after annealing at 900℃.The annealing temperature has an obvious effect on the mechanical properties and corrosion resistance of the spark plasma sintered AlCoCrFeNi HEA.When the annealing temperature is 700℃,the hardness,yield strength and fracture strength reach the maximum with the value of 545 HV,1430 MPa and 2230 MPa,respectively.The compressive ratio reaches the maximum of 17.2%,with the annealing temperature increasing to 800℃.The corrosion resistance of the samples decreases with increasing the annealing temperature.     

Microstructure and magnetic properties of NdFeB magnet prepared by spark plasma sintering

Nd₁₅Dy_1.2Fe_balAl_0.8B₆ magnet was prepared by spark plasma sintering (SPS) technique. Sintering between 810 and 830 °C and consequent tempering result in relatively high magnetic properties and sintering density, which are comparable to the conventionally sintered ones. Further increase of sintering temperature gains a slight increase in sintering density and decrease in magnetic properties. Grain size of NdFeB prepared by SPS is fine and uniform, which is much smaller than that of conventionally sintered ones. Continuous thin film of the Nd-rich phase is formed along the grain boundary and the density of magnet is increased through tempering, which is the main reason for improving the magnetic properties. Furthermore, TEM observations indicate a conversion of crystal structure of the Nd-rich phase at triple junction site after tempering.