共查询到20条相似文献,搜索用时 93 毫秒
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玻璃固化是目前各国对高放废液进行固化处理的首选方式,与硼硅酸盐玻璃相比,铁磷酸盐玻璃具有很好的化学耐蚀性和较低的熔融温度,是一类新型的核废物固化基质材料。本文综述了铁磷酸盐玻璃的特点及其在核废物固化方面的研究进展。 相似文献
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论述磷肥按溶解性分类情况。根据不同磷肥的溶解性(水溶性、弱酸溶性和枸溶性)选择合适的溶剂、称量范围和溶解条件,测定其有效磷(水溶性磷和枸溶性磷总和)含量,才能得到准确的结果。 相似文献
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Agronomic and environmental aspects of phosphate fertilizers varying in source and solubility: an update review 总被引:1,自引:0,他引:1
S. H. Chien L. I. Prochnow S. Tu C. S. Snyder 《Nutrient Cycling in Agroecosystems》2011,89(2):229-255
This review discusses and summarizes the latest reports regarding the agronomic utilization and potential environmental effects
of different types of phosphate (P) fertilizers that vary in solubility. The agronomic effectiveness of P fertilizer can be
influenced by the following factors: (1) water and citrate solubility; (2) chemical composition of solid water-soluble P (WSP)
fertilizers; (3) fluid and solid forms of WSP fertilizers; and (4) chemical reactions of P fertilizers in soils. Non-conventional
P fertilizers are compared with WSP fertilizers in terms of P use efficiency in crop production. Non-conventional P fertilizers
include directly applied phosphate rock (PR), partially acidulated PR (PAPR), and compacted mixtures of PR and WSP. The potential
impacts of the use of P fertilizers from both conventional (fully acidulated) and non-conventional sources are discussed in
terms of (1) contamination of soils and plants with toxic heavy metals, such as cadmium (Cd), and (2) the contribution of
P runoff to eutrophication. Best practices of integrated nutrient management should be implemented when applying P fertilizers
to different cropping systems. The ideal management system will use appropriate sources, application rates, timing, and placement
in consideration of soil properties. The goal of P fertilizer use should be to optimize crop production without causing environmental
problems. 相似文献
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S. H. Chien 《Nutrient Cycling in Agroecosystems》1993,35(1-2):93-99
Various methods have been used worldwide for measuring the solubility of phosphate rock (PR) and fertilizers containing PR. In this review, chemical, mineralogical, and physical factors affecting various measurements of PR solubility are discussed. The most important factors are (1) PR solubility expression, (2) mineralogical composition of PR, (3) free carbonate (calcite dolomite) effect, (4) effect of apatite crystallinity and cementing of apatite with silica, and (5) effect of monocalcium phosphate and gypsum in the mixture of PR and TSP or SSP. 相似文献
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Effects of organic manure on solubility and mobility of different phosphate fertilizers in two paddy soils 总被引:1,自引:0,他引:1
The solubility and mobility of three phosphate fertilizers [superphosphate (SP), Ca-Mg phosphate (Ca-Mg-P) and diammonium phosphate (DAP)] with or without combination of farmyard manure (FYM) and/or farmyard manure juice (FYMJ) in two paddy soils (Ultisol and Entisol) from the Zhejiang Province of China were determined. Incubation experiments were conducted under controlled greenhouse conditions in the Institute of Agricultural Chemistry, Bonn University, Germany. The results showed that water soluble P and Olsen P in both the application band and the adjacent zones (10 and 20 mm from the application band) was highest with DAP, and lowest with Ca-Mg-P. Both FYM and FYMJ increased water soluble P (100–300%) and Olsen P (80–300%) for the application band in both soils. Moreover, the combination of FYM significantly increased water soluble P and Olsen P for the adjacent zones (20 mm for the Ultisol and 10 mm for the Entisol), but such effects were not significant in combination with FYMJ. Consequently, the main effect of FYM is due to organic substances from decomposition rather than organic compounds in the FYMJ. Also, the combination of FYMJ with SP and DAP significantly increased the pH value in the application band. The pH in the adjacent zone (10 mm) was slightly increased by the combination of FYM with each of three P fertilizers. The solubility and mobility of phosphate in soils differed greatly among phosphate fertilizers. The combinations of organic manure with mineral phosphate fertilizers increased solubility and mobility of phosphate in both paddy soils, especially in the Ultisol.This paper is dedicated to Professor Xi Sun. 相似文献
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Because various phosphate (P) fertilizers differ widely in their solubility, it is commonly observed that crop response to P fertilizers varies under the same soil and crop conditions. Furthermore, a major problem encountered in the methods for determining the relative effectiveness (RE) of water-insoluble P fertilizer (e.g., phosphate rock) with respect to water-soluble P fertilizers, e.g., single superphosphate (SSP) and triple superphosphate (TSP), is that their growth response curves are usually nonlinear and often do not share a common maximum yield. In this paper, we review and discuss the advantages and disadvantages of the three most commonly used methods for calculating the RE of phosphate rock with respect to TSP (or SSP). The three methods are vertical comparison, horizontal (substitution rate) comparison, and linear-response comparison. 相似文献
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J. Hagin S. S. S. Rajan M. K. Boyes M. Upsdell 《Nutrient Cycling in Agroecosystems》1990,22(2):109-117
Five phosphate rocks varying in formic acid P solubility from 18.9 to 52.7%, expressed as percentage of total P, were acidulated with phosphoric or sulphuric acids to 0, 20%, 33% and 50% of full acidulation and granulated. In an incubation experiment fertilizer granules of diameter 1–2 mm were mixed with two acid soils and after 1 week incubation soil samples were extracted with a 0.5 M NaOH solution. In a dissipation experiment single fertilizer granules of 4 mm diameter were implanted into soil, incubated for 1 and 4 weeks and inorganic P fractionation in the residual granules and the surrounding soil was performed. Dissipated P was greater than the water soluble P content of the partly acidulated phosphate rock fertilizers indicating the dissolution of the non-acidulated phosphate rocks. The amount of P dissipated was related to the initial water soluble P content and to the formic acid solubility of phosphate rocks used for manufacturing the fertilizers. The P dissipated increased with an increase in soil acidity. 相似文献
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Theoretical Foundations of Chemical Engineering - The possibility of foaming of phosphate glass matrices for the synthesis of complex micronutrient fertilizers with prolonged action is considered.... 相似文献
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N. S. Bolan M. J. Hedley R. Harrison A. C. Braithwaite 《Nutrient Cycling in Agroecosystems》1990,26(1-3):119-138
Partially acidulated phosphate fertilizers are manufactured either by direct partial acidulation of phosphate rocks (PRs) with sulphuric and/or phosphoric acid (directly acidulated PAPR) or indirectly by mixing reactive phosphate rocks (RPRs) with single superphosphate (SSP-RPR mixture). This form of low cost fertilizer manufacture is suitable for improving the agronomic value of unreactive PRs or production of high analysis fertilizers that can have agronomic values similar to fully acidulated phosphate fertilizers.The solubility characteristics of the directly acidulated PAPRs are affected by the type, composition and concentration of the acid used for acidulation, degree of acidulation, nature and fineness of PR and the method of manufacture. In general, partial acidulation with phosphoric acids which contain minimum amounts of metallic impurities acidulates more PR and results in more soluble P in the product. In the case of SSP-RPR mixtures made by adding RPR to immature SSP, the nature of PR used for SSP manufacture and the time of addition of RPR to ex-den SSP mixture affects the quality of the product. In order to minimize the selective reaction of the RPR with residual acid present in the ex-den SSP reaction mixture, RPR should not be added until PR acidulation (used for SSP) is essentially complete.The agronomic value of partially acidulated phosphate fertilizers is affected by the amount of water soluble P and the solubility of residual PR. None of the single extraction tests such as 2% citric acid, 2% formic acid and neutral ammonium citrate appear to be appropriate as indicators of plant available P in these fertilizers. Double extraction procedures which remove both the soluble P and the residual P have been investigated, but need to be correlated with agronomic data before they can be adopted as quality tests. 相似文献
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Fused magnesium phosphate seems to be a technical solution for some problems faced by the Brazilian industry of phosphate fertilizers, namely: high P2O5 losses in the fines of the beneficiation processes; high level of phosphorus fixation for water soluble fertilizers; Brazilian high dependency on sulfur for conventional phosphate fertilizers. The technological characterization of phosphate concentrate of Anitapolis, regarding the production of fused magnesium phosphate was thus carried out.The variables studied were MgO/SiO2 ratio, fusion temperature and cooling rate. The products obtained in the tests were analyzed for P2O5 citric acid solubility and fluorine content. As expected, fast cooling showed the best results. MgO/SiO2 molar ratio showed weak influence on the solubilization of P2O5 when fast cooling was used. Fluorine removal was low for all samples. This indicates that the product is not suitable for animal feed. The Anitapolis rock concentrate showed to be an excellent feedstock for production of fused magnesium phosphate. 相似文献