共查询到19条相似文献,搜索用时 93 毫秒
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综述了二唑类、三唑类、四唑类缓蚀剂的国内外研究进展。三唑衍生物的毒性更低,吸附性能更优,可以合成席夫碱来拓展其在缓蚀领域的应用范围。 相似文献
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化学合成植物病毒抑制剂研究进展 总被引:9,自引:1,他引:8
介绍了近年来植物病毒抑制剂的研究情况,作为植物病毒抑制剂的化合物主要可分为三大类:1)有机酸类,包括有机羧酸和有机磺酸;2)杂环化合物,包括生物碱、三唑衍生物、噻二唑衍生物、咪唑衍生物和三嗪衍生物等;3)脲类和硫脲类化合物。 相似文献
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3-氨基-5-羧基-1,2,4-三唑席夫碱的合成 总被引:1,自引:0,他引:1
含1,2,4-三唑环的席夫碱化合物一般都具有很好的生物活性。为了进一步探讨1,2,4-三唑席夫碱的合成,文中以3-氨基-5-羧基-1,2,4-三唑为原料,与取代芳醛反应,合成了8个3-氨基-5-羧基-1,2,4-三唑类席夫碱化合物。采用的反应条件为:3-氨基-5羧基-1,2,4-三唑与取代芳醛的摩尔比为1∶1,N,N-二甲基甲酰胺(DMF)为溶剂,冰醋酸为催化剂,在回流温度下反应3.5—4.5 h。化合物的结构通过IR,1H NMR和元素分析进行了表征。样品分析结果表明,在红外光谱中,所得目标产物在波数ν=1 600—1 625 cm-1处均出现C N的特征吸收峰;在1H核磁共振中,化学位移δ9附近有CH N的质子的化学位移出现。 相似文献
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杂环类植物抗病毒剂的研究进展 总被引:2,自引:2,他引:2
介绍了近年来杂环类植物抗病毒剂的研究进展及开发情况,杂环类植物抗病毒剂化合物主要包括生物碱,吡啶衍生物,吡唑衍生物,咪唑衍一物,三唑衍生物,四唑衍生物,噻唑衍生物,噻二唑衍生物,吡唑衍生物,三嗪衍生物及喹啉肟醚等十一类。 相似文献
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三唑类抗真菌药-氟康唑的研究进展 总被引:1,自引:0,他引:1
氟康唑是三唑类抗真菌药物,对于治疗深部真菌感染有显著疗效,毒副作用小,临床应用广泛。本文从氟康唑的抗真菌作用机制,药物动力学,临床应用范围,不良反应及氟康唑衍生物的合成等方面的研究进展进行了综述。 相似文献
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农用杀菌剂研究开发的新进展(一) 总被引:2,自引:0,他引:2
刘长令 《精细与专用化学品》2000,(15):5-7
本文对近期研究开发的农用杀菌剂作了简要的介绍。文中涉及三唑类、吡咯类、苯(苄)胺基嘧啶类、恶(咪)唑啉酮类、甲氧基丙烯酸酯类、氨基酸衍生物和酰胺类等化合物的结构、生物活性、作用机理以及应用等。 相似文献
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杨朱 《合成材料老化与应用》1998,(3)
据《Polym.Degrad.Stab.》1997,57,283~292报道,埃及Mansoura大学化学系对一些有机化合物的抗氧化作用进行了研究,他们合成了一些三唑类、哑唑啉类及对苯二胺类衍生物,并在天然胶、丁苯胶及其硫化橡胶中进行了抗氧能力的研究.发现三唑类 相似文献
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3,5-Diamino-1,2,4-triazole Schiff base derivatives and their inhibition efficiency, based on the effect of changing functional
groups, were reported to establish a relationship between inhibitor efficiency and molecular structure using weight loss method,
electrochemical and Fourier transform infrared spectral techniques. It was found that the molecules containing more electron
donating groups have higher inhibition efficiency than the corresponding compounds with low electron donating groups. The
results indicate that the order of inhibition efficiency of the triazole and its Schiff bases in solution and the extent of
their tendency to adsorb on mild steel surfaces are as follows: vanilidine 3,5-diamino-1,2,4-triazole > furfuraldine 3,5-diamino-1,2,4-triazole > anisalidine
3,5-diamino-1,2,4-triazole > 3,5-diamino-1,2,4-triazole. 相似文献
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A series of new bis triazole Schiff base derivatives (4) were prepared in good yields by treatment of 4‐amino‐3,5‐diphenyl‐4H‐1,2,4‐triazole (3) with bisaldehydes (1). Schiff bases (4) were reduced with NaBH4 to afford the corresponding bisaminotriazoles (5). All the new compounds were characterized by IR, 1H NMR and 13C NMR spectral data. Their overall extraction (log Kex) constants for 1 : 1 (M : L) complexes and CHCl3/H2O systems were determined at 25 ± 0.1°C to investigate the relationship between structure and selectivity toward various metal cations. The extraction equilibrium constants were estimated using CHCl3/H2O membrane transfer with inductively coupled plasma‐atomic emission spectroscopy spectroscopy. The stability sequence of the triazole derivatives in CHCl3 for the metal cations was exhibited a characteristic preference order of extractability to metal ions [Fe(III) > Cu(II) > Pb(II) > Co(II) > Ni(II) > Mn(II) > Zn(II) > Mg(II) > Ca(II)]. The compounds were tested for anti‐microbial activity applying agar diffusion technique for 11 bacteria. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
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Nabel A. Negm Ismail A. Aiad Salah M. Tawfik 《Journal of surfactants and detergents》2010,13(4):503-511
Eight novel uracil-based cationic surfactants containing Schiff base species were synthesized and characterized using elemental
analysis, FTIR, 1H-NMR and 13C-NMR spectroscopy. The surface activities of the synthesized Schiff bases and their cationic derivatives were determined
based on interfacial tension measurements and partition coefficient values in water/octanol system. The synthesized Schiff
bases and their cationic derivatives were evaluated as novel biocides against different bacteria and fungi strains. The results
showed that the biocidal activity of the synthesized Schiff bases was considerably increased by quaternization. The influence
of the cationic surfactants as biocides was increased by increasing the hydrophobic chain length and the presence of the methoxy
groups. The biocidal activity was also increased by increasing the partition coefficient in water/octanol system. The structure
and surface activity/biocidal activity of the different compounds were discussed. 相似文献
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C2-benzaldehyde-C6-aniline double Schiff base derivatives of chitosan were synthesized with positioning protection method for the first time. The structures and properties of the new synthesized products were characterized by Fourier transform infrared spectroscopy, 13C nuclear magnetic resonance, scanning electron microscope image, X-ray diffraction, and elemental analysis. The elemental analysis results indicated that the degrees of substitution of the products were from 39.6% to 48.2%. The synthesized compounds exhibited an excellent solubility in organic solvents. The antibacterial activities of all of the derivatives were tested in the experiment, and the results showed that the prepared chitosan derivatives had significantly improved antibacterial activity of chitosan and C2-benzaldehyde Schiff bases of chitosan toward Staphylococcus aureus (ATCC 25923) and Escherichia coli (ATCC 35218). Antibacterial activity of the Schiff bases against E. coli differs from the substituent at the same position of different anilines and increases as the sequence aniline?>?p-toluidine?>?o-toluidine, and the antibacterial activity of the Schiff bases against S. aureus increases as the sequence p-toluidine?>?aniline?>?o-toluidine. The IC50 of the C2-benzaldehyde-C6-aniline double Schiff base derivatives of chitosan against E. coli and S. aureus is 0.0035 and 0.0031?mg?L?1, respectively, much lower than that of chitosan (0.0064?mg?L?1) and C2-benzaldehyde Schiff bases of chitosan (0.0054?mg?L?1). The cytotoxicity test showed that compared with chitosan and C2-benzaldehyde Schiff bases of chitosan, the prepared chitosan derivatives had lower cytotoxicity against SCG-7901. This paper provided a new method for the synthesis of Schiff bases of chitosan, which was enlightening. 相似文献
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烷基三唑硫酮席夫碱的合成和生物活性研究 总被引:1,自引:1,他引:0
为进一步研究三唑席夫碱化合物的合成与性质,以自制的5-烷基-4-氨基-1,2,4-三唑-3-硫酮与对甲氧基苯乙酮和取代芳醛为原料,在冰醋酸催化下,回流反应0.5 h,合成了1,2,4-三唑硫酮席夫碱化合物,其结构通过元素分析、红外光谱(IR)和核磁共振(1H NMR)进行表征。分析结果表明:在IR图谱中,目标产物在波数1 587—1 603 cm-l处出现席夫碱亚胺结构CHN的特征吸收峰;在1H NMR中,席夫碱亚胺结构CHN的质子化学位移δ在10.5附近出现,NC—CH3结构中H的化学位移在2.4左右。研究了化合物对烟草赤星病、马铃薯干腐病、小麦赤霉病、番茄早疫病、西瓜枯萎病5种植物病原菌的生物活性,得到毒力回归方程及相关系数,计算EC50和EC95值,结果表明它们具有较好的抑菌活性。含有吸电子取代基的席夫碱杀菌效果比给电子取代基的好。 相似文献
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PE, one of the major phospholipids in oilseed soapstock, may react with gossypol to form Schiff bases. PE amounts to 20–30%
of the phosphorus compounds in soap-stock. In this report, the dependence on pH of the Schiff base products between PE and
gossypol was investigated using a spectrophotometer, an HPLC equipped with an ELSD, and an LC-MS system. We observed that
at pH 7 the Schiff reaction product and reactants were clearly detected by ELSD, absorption, and LC-MS spectra. The absorption
spectra displayed the characteristic peak for the Schiff bases around 430–440 nm. The absorption spectra also indicated that
the reaction was pH dependent. The reaction temperatures were 60 and 90°C. The LC-MS spectra supported the formation of Schiff
bases as well as methyl ether derivatives of gossypol in alcohol at the elevated temperatures. The implications of these experimental
findings are presented in this paper. 相似文献
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