Experimental investigation on flow condensation heat transfer and pressure drop of R170 in a horizontal tube

Condensation heat transfer and pressure drop of R170 were studied experimentally in a horizontal tube with inner diameter of 4 mm. The tests were conducted at saturation pressures from 1 MPa to 2.5 MPa, mass fluxes from 100 kg (m²∙s)⁻¹ to 250 kg (m²∙s)⁻¹ and average heat fluxes from 55.3 kW m⁻² to 96.3 kW m⁻² over the entire vapor quality range. The effects of vapor quality, mass flux and saturation pressure on condensation heat transfer and pressure drop were examined and analyzed. The experimental data were compared with various well-known correlations of condensation heat transfer coefficient and pressure drop. The comparison results showed that Koyama et al. correlation agreed with the experimental heat transfer coefficient with a mean absolute relative deviation less than 25%, and the Yan and Lin correlation can accurately predict the experimental pressure drop with a mean absolute relative deviation less than 18%.     

Reducing the Uncertainty of Industrial Trace Humidity Generators through NIST Permeation-Tube Calibration

Permeation-tube moisture generators (PTGs) are commonly used by the semiconductor industry as transfer standards for the calibration of hygrometer systems measuring trace amounts of water vapor in gases (water vapor mole fractions typically below 1 × 10⁻⁶). They are relatively simple devices that generate a steady stream of humidified gas by diluting water vapor delivered at a constant rate from a permeable capsule with precisely metered purified gas, usually nitrogen. Here a new calibration service enabling the measurement of PTG permeation rates directly in terms of NIST primary standards of trace humidity generation is described. Rather than using commonly employed gravimetric methods for permeation-tube calibration, the method applied here links the permeation rate of the permeation tube to the thermodynamic properties of ice. Using a hygrometer based on cavity ringdown spectroscopy, we compare the water vapor concentrations produced by the NIST low frost-point generator (LFPG) and a specially constructed PTG containing the permeation tube undergoing calibration. A least squares fit of the data determines the permeation rate of the tube under test. We describe the calibration system, experimental procedure and present sample calibration data. The expanded relative uncertainty of NIST permeation-tube calibrations is 1.8% with a coverage factor k = 2, dominated by the Type A uncertainties.     

Near-Zero Air Pollutant Emission Technologies and Applications for Clean Coal-Fired Power

Coal is the dominant energy source in China, and coal-fired power accounts for about half of coal consumption. However, air pollutant emissions from coal-fired power plants cause severe ecological and environmental problems. This paper focuses on near-zero emission technologies and applications for clean coal-fired power. The long-term operation states of near-zero emission units were evaluated, and synergistic and special mercury (Hg) control technologies were researched. The results show that the principle technical route of near-zero emission, which was applied to 101 of China’s coal-fired units, has good adaptability to coal properties. The emission concentrations of particulate matter (PM), SO₂, and NO_x were below the emission limits of gas-fired power plants and the compliance rates of the hourly average emission concentrations reaching near-zero emission in long-term operation exceeded 99%. With the application of near-zero emission technologies, the generating costs increased by about 0.01 CNY∙(kW∙h)^–1. However, the total emissions of air pollutants decreased by about 90%, resulting in effective improvement of the ambient air quality. Furthermore, while the Hg emission concentrations of the near-zero emission units ranged from 0.51 to 2.89 μg∙m⁻³, after the modified fly ash (MFA) special Hg removal system was applied, Hg emission concentration reached as low as 0.29 μg∙m⁻³. The operating cost of this system was only 10%–15% of the cost of mainstream Hg removal technology using activated carbon injection. Based on experimental studies carried out in a 50 000 m³∙h⁻¹ coal-fired flue gas pollutant control pilot platform, the interaction relationships of multi-pollutant removal were obtained and solutions were developed for emissions reaching different limits. A combined demonstration application for clean coal-fired power, with the new “1123” eco-friendly emission limits of 1, 10, 20 mg∙m⁻³, and 3 μg∙m⁻³, respectively, for PM, SO₂, NO_x, and Hg from near-zero emission coal-fired power were put forward and realized, providing engineering and technical support for the national enhanced pollution emission standards.     

Biomass-Derived Hybrid Hydrogel Evaporators for Cost-Effective Solar Water Purification

Solar vapor generation has presented great potential for wastewater treatment and seawater desalination with high energy conversion and utilization efficiency. However, technology gaps still exist for achieving a fast evaporation rate and high quality of water combined with low-cost deployment to provide a sustainable solar-driven water purification system. In this study, a naturally abundant biomass, konjac glucomannan, together with simple-to-fabricate iron-based metal-organic framework-derived photothermal nanoparticles is introduced into the polyvinyl alcohol networks, building hybrid hydrogel evaporators in a cost-effective fashion ($14.9 m⁻² of total materials cost). With advantageous features of adequate water transport, effective water activation, and anti-salt-fouling function, the hybrid hydrogel evaporators achieve a high evaporation rate under one sun (1 kW m⁻²) at 3.2 kg m⁻² h⁻¹ out of wastewater with wide degrees of acidity and alkalinity (pH 2–14) and high-salinity seawater (up to 330 g kg⁻¹). More notably, heavy metal ions are removed effectively by forming hydrogen and chelating bonds with excess hydroxyl groups in the hydrogel. It is anticipated that this study offers new possibilities for a deployable, cost-effective solar water purification system with assured water quality, especially for economically stressed communities.     

Die Gasdurchlässigkeit von Vakuummaterialien

This work presents investigations on the gas permeability of materials for use in unmanned space vehicles. The measurement system for determining the gas permeation coefficients of composite materials is designed on the basis of a helium leak detector. Due to permeation through the Vi-ton sealing the smallest flow that can be correctly measured by the system is 10⁻¹⁰ Pa · m³/s. The system was assessed with a PTFE polymer sample with a known helium permeability value. Furthermore, the gas perme-abilities of three composite materials were studied. The steady-state helium permeation coefficient in [Pa · m³/s] · [m/(m² · bar)] for high molecular weight polyethylene (HM-WPE) with 100 nm copper coating is 3.1 · 10⁻⁸, for high density polyethy lene (HDPE 209-07) with 100 nm copper coating it is 1.9 · 10⁻⁷; for vacuum-tight ceramics VK94-1 with glue K400 layer it is 2.2 · 10⁻⁹. Authors will be glad to measure the gas permeability of new materials that can be provided by readers of this publication.     

Characterisation of the hydraulic maldistribution in a heat exchanger by local measurement of convective heat transfer coefficients using infrared thermography

A methodology was developed to characterise the heat exchangers' performance decrease due to two-phase flow maldistribution. It consists in measuring the spatial distribution of the local heat transfer coefficients with a rapid, non-invasive and fluid independent method. The method is based on the infrared (IR) thermography measurement of the temperature response to an oscillating heat flux. The amplitude of the measured temperatures is compared to the solution of an analytical model. The problem is solved iteratively to obtain the heat transfer coefficients. This method has been applied to evaluate the uneven phase distribution of an air–water mixture in a compact heat exchanger. The exchanger is composed of seven multiport flat tubes, a vertical downward header and horizontal channels. Experiments were performed for mass flux from 29 kg m⁻² s⁻¹ to 116 kg m⁻² s⁻¹ and for quality from 0.10 to 0.70.     

Characterization of the silicon oxide thin films deposited on polyethylene terephthalate substrates by radio frequency reactive magnetron sputtering

Transparent silicon oxide films were deposited on polyethylene terephthalate substrates by means of reactive magnetron sputtering with a mixture of argon and oxygen gases. The influences of process parameters, including the oxygen flow ratio, work pressure, radio frequency (RF) power density and deposition time, on the film properties, such as: deposition rate, morphology, surface roughness, water vapor/oxygen transmission rate and flexibility, were investigated. The experimental results show that the SiO_x films deposited at RF power density of 4.9 W/cm², work pressure of 0.27 Pa and oxygen flow ratio of 40% have better performance in preventing the permeation of water vapor and oxygen. Cracks are produced in the SiO_x films after the flexion of more than 100 cycles. The minimum transmission rates of water vapor and oxygen were found to be 2.6 g/m² day atm and 15.4 cc/m² day atm, respectively.     

Effects of active chitosan-flaxseed mucilage-based films on the preservation of minced trout fillets: A comparison among aerobic,vacuum, and modified atmosphere packaging

The objectives of the current study were to examine physical–mechanical, structural, and morphological characteristics of chitosan-flaxseed mucilage films enriched with Ziziphora clinopodioides essential oil (ZEO; 0%, 0.25%, and 0.5%) and sesame oil (SO; 0% and 0.75%) and to provide useful information for the preservation of minced trout fillet's using antimicrobial films under aerobic, vacuum, and modified atmosphere conditions for 16 days. The films showed thickness, tensile strength, puncture force, puncture deformation, water vapor transmission rate, water vapor permeability, swelling index, and oxygen permeability values ranging 0.082–0.86 mm, 33.34–46.83 MPa, 25.69–53.08 N, 11.45–28.45 mm, 17.48–26.73 g/m² h, 8.57–12.49 × 10⁻⁴ g mm/m² h Pa, 12.45–38.43%, and 3.02–13.32 × 10⁻¹² cm³/m² s Pa, respectively. The following order of effect on the microbial spoilage population of treated samples was found in the applied packaging methods: modified atmosphere packaging > vacuum packaging > aerobic packaging. The final microbial population of treated samples was 0.35–4.91 log CFU/g lower than the controls after 16 days of refrigerated storage. At the end of the storage, the total volatile base nitrogen, peroxide value, and thiobarbituric acid reactive substances of untreated samples were 34.02–48.6 mg of N/100 g, 1.43–2.32 meq of peroxide/1000 g, and 3.33–4.24 mg of malondialdehyde/kg, respectively. The lowest corresponding values were recorded for the treated samples with ZEO 0.5% + SO 0.75% films by 14.26–17.73 mg of N/100 g, 0.48–0.86 meq of peroxide/1000 g, and 1.08–1.48 mg of malondialdehyde/kg, respectively.     

Nanoconfined Water-Molecule Channels for High-Yield Solar Vapor Generation under Weaker Sunlight

Solar vapor generation is a promising method to efficiently produce fresh water. However, the insufficient vapor yields under natural daylight restrict its practical applications, and the basic evaporation mechanisms are deficient for reasonable design of evaporator structure. Here, hydrophobic nano-confined water molecule channels (NCWMCs) are demonstrated, which can reduce the vaporization enthalpy for water evaporation and achieve a record vapor generation rate of 1.25 kg m⁻² h⁻¹ under 0.5 sun irradiation. Molecular dynamics simulations reveal the cluster-evaporation process in the NCWMC system. As a result, the evaporator with NCWMC system can effectively purify seawater and wastewater samples using this environmentally friendly strategy.     

Tunable molecular transport and sieving enabled by covalent organic framework with programmable surface charge

Molecular separation is critical to mitigating the issues of water contamination and shortage and currently focuses on the use of framework materials fabricated by special building blocks. However, developing a simple and tunable synthesis methodology for materials with alternative permeation and selectivity remains challenging. Here, we fabricate a series of nanochannel membranes composed of uniform spherical covalent organic frameworks (COFs). Diversified spherical COFs have diameters ranging from ∼150 to ∼800 nm, therefore demonstrating a programmable surface charge distribution from −24 to −63 mV. COF membranes with tailor-made surface charge enable different surface energy levels and allow increasing water permeation of 15.5 to 34.5 L m⁻² h⁻¹ bar⁻¹. Furthermore, COFs can also act as filters, achieving up to 99.7% rejection and separation of the opposite charged dyes. We expect these COFs with tunable surface charge to be applicable to variety of fields, including sieving, batteries, and water treatments.     

New methods for accurate water dosage in concrete central mix plants

Online mixer measurements appear as being essential to the improvement of concrete manufacturing methods, as imposed by new economical and environmental demands. However, the lack of a well-established calibration procedure contributes to the poor reputation sometimes given to these measurements. The original in situ method developed and evaluated herein requires installing a sampler, yet only slightly disturbs the production process. By using this calibration method the mixing power becomes a reliable online indication of concrete water content (measurement standard deviation of 2.85 l/m³). A procedure for improving the regularity of water content in truck mixers has been presented to illustrate the benefit of well-calibrated online water content measurements in batch concrete in a central mix plant. The correction algorithms proposed herein have the potential to be automated and may improve up to 5 times the water content regularity in the truck mixers.     

Development of an instrumented and automated single mode cavity for ceramic microwave sintering: Application to an alpha pure alumina powder

This paper describes the development of an instrumented and automated single mode microwave cavity for sintering ceramic powders. This setup includes an optical dilatometer and a motorized plunger to control heating cycles in a wide range of heating rates (from 5 °C ∙ min^− 1 to 200 °C ∙ min^− 1) up to 1600 °C and to allow reliable comparison with conventional sintering. The cavity and the sintering cells for both hybrid and direct microwave sintering were designed using finite element simulation. For accurate temperature measurement, an optical pyrometer calibrated with a specific protocol has been used. Microwave sintering of fine grained (< 100 nm) alpha alumina compacts was thus investigated and compared to conventional sintering. This pure alumina powder has been sintered by direct microwave heating, without any susceptor nor doping element to initiate heating as often achieved in the literature. The comparison of the densification kinetics along an identical thermal cycle evidenced a significant enhancement of sintering under microwaves during the first and intermediate stages.     

Amphiphilically Modified Porous Polymeric Nanosandwich-Based Membranes for Rapid and Efficient Water Treatment

Low removal efficiency, long treatment time, and high energy consumption hinder advanced and eco-friendly use of traditional adsorbents and separation membranes. Here, a class of amphiphilically modified 2D porous polymeric nanosandwich is designed and is subsequently assembled into adsorptive membranes. The 2D nanosandwich is gifted with high porosity and excellent pore accessibility, demonstrating rapid adsorption kinetics. The as-assembled membrane integrates unimpeded interlayer channels and well-developed, amphiphilic, and highly accessible intralayer nanopores, leading to ultrafast water permeation (1.2 × 10⁴ L m⁻² h⁻¹ bar⁻¹), high removal efficiency, and easy regeneration. The family of the membrane can be expanded by changing amphiphilic functional groups, further providing treatment of a wide-spectrum of pollutants, including aromatic compounds, pesticide, and pharmaceuticals. It is believed that the novel amphiphilically modified adsorptive membrane offers a distinct water treatment strategy with ultrahigh water permeation and efficient pollutants removal performances, and provides a multiple-in-one solution to the detection and elimination of pollutants.     

A Two-Sinker Densimeter for Accurate Measurements of the Density of Natural Gases at Standard Conditions

A special reference densimeter has been developed for accurate measurements of densities of natural gases and multicomponent gas mixtures at standard conditions of temperature and pressure (T _s = 273.15 K and p _s = 0.101325 MPa). The densimeter covers the range from 0.7 kg · m^?3 to 1.3 kg · m^?3; the total measurement uncertainty in density is 0.020 % (95 % level of confidence). The measurement principle used is the two-sinker method, which is based on the Archimedes buoyancy principle. The certified calibration laboratory of E.ON Ruhrgas AG, Germany, uses this densimeter to verify the standard densities of certified calibration gases (binary and multicomponent gas mixtures). Moreover, the densimeter is used to determine the compositions of commercially available binary gas mixtures with a small uncertainty of (0.01–0.03) mol%.     

Water permeation through organic-inorganic multilayer thin films

We prepared organic (self-assembled monolayer (SAM))-inorganic (TiO₂) multilayer barrier films on polyethylene terephthalate substrate using atomic layer deposition and molecular layer deposition methods in the same deposition chamber. The water permeation was mainly blocked by the inorganic TiO₂ layer. While the lag time was proportional to the thickness of the TiO₂ layer, the steady-state permeation rate was relatively independent of the thickness. The multilayer approach was effective in extending the lag time due to both the tortuous path effect and the internal desiccant effect. Water permeation occurred sequentially in the organic-inorganic multilayer barriers by water accumulation in the organic SAM layers. The water vapor transmission rate was 7.0 × 10^− 4 g/m²·day during the lag time of 155 h at 60 °C and a relative humidity of 85% with 5-dyad barrier film.     

Wasserpermeation durch Polymere und keramische Substrate

Water permeation through polymers and oxide layers For the measurement of water permeation through solid materials plates (TorrSeal (epoxy resin) and FIMO (composite of PVC and calk)) and Polycarbonate foils – at different ambient temperatures – a device consisting of three parts, one filled with water, the second holds the material to be measured and the last contains a capacity humidity sensor, was used. Permeation of liquid water and water vapour was tested with no difference in results. The sensitivity for the measurement of the water permeation and the diffusion coefficient was 7,98 · 10^?13 m²/s. For polycarbonate foils the diffusion coefficient, its temperature dependence and its activation energy were found to be in reasonable agreement with data from literature. In later experiments the materials will be coated with different barrier layers to further decrease permeation.     

Pressure drop during flow boiling inside parallel microchannels

Pressure drop is experimentally investigated inside parallel microchannels during subcooled flow boiling of R134a in horizontal orientation. The test conditions included the inlet pressure, the inlet subcooled degree, the heat flux, the vapor quality, and the mass velocity, ranging from 600 to 900 kPa, 1 to 20 K, 5 to 220 kW m⁻², 0 to 95% and 250 to 1000 kg m⁻² s⁻¹, respectively. The effect of the mass velocity and the inlet pressure were investigated. The relative weight of the pressure drop due to two-phase flow acceleration and the friction pressure drop for single phase and two-phase flows were considered. The experimental results for the pressure drop were compared with those predicted by the homogenous model and five other semi-empirical models.     

Co-sputtered oxide thin film encapsulated organic electronic devices with prolonged lifetime

Effective top-side thin film encapsulation for organic light-emitting devices (OLEDs) was achieved by deposition of a multi-layer water diffusion barrier stack to protect the device against moisture permeation. The barrier stack was formed by alternative depositions of co-oxide and fluorocarbon (CF_x) films. The co-oxide layer was fabricated by magnetron co-sputtering of silicon dioxide (SiO₂) and aluminum oxide (Al₂O₃). While the CF_x layer was formed by plasma enhanced chemical vapor deposition. The water vapor transmission rate of the optimized diffusion barrier stack can be down to 10^− 6 g/m²/day. The OLEDs encapsulated with the multilayer stack have been shown to have operation lifetime of over 18,000 h which is nearly the same as devices with conventional glass-cover encapsulation.     

Experimental study on cooling performance of air conditioning system with dual independent evaporative condenser

Evaporative condenser is an energy efficient and environmentally friendly air conditioning equipment. This paper proposed an air conditioning system using dual independent evaporative condenser and investigated the cooling performance. Many factors, such as evaporator water inlet temperature, compressor frequency, air dry-bulb temperature, air velocity and water spray rate, which influenced the cooling performances of air conditioning system with evaporative condenser have been investigated. The results indicated that cooling capacity and coefficient of performance (COP) increased significantly with the increasing of evaporator water inlet temperature (12–25 °C), the air velocity (2.05–3.97 m s⁻¹) and the water spray rate (0.03–0.05 kg m⁻¹ s). However, COP decreased with the increasing ambient air dry-bulb temperature (31.2–35.1 °C) and the compressor frequency (50–90 Hz). Furthermore, the heat transfer coefficient (K₀) was 232–409 W m⁻² K⁻¹ in different air velocity and water spray rate.     

Estimation of moisture barrier ability of thin SiNx single layer on polymer substrates prepared by Cat-CVD method

The SiNx films with the thickness of 50 nm were prepared by Cat-CVD method on the cyclic olefin copolymer (COC) and the polyethylene terephthalate (PET) substrates, and their moisture barrier abilities were evaluated. MOCON measurement method and Ca degradation test showed the moisture permeation results of 0.02 g/(m² day) for PET substrate and 0.006 g/(m² day) for COC substrate after SiNx deposition. Applying the simple model of gas barrier property, it was estimated that the Cat-CVD method achieves the high coverage ratio of over 99% for SiNx film on these substrates, and the moisture permeation rate of single SiNx film with the thickness of 50 nm was estimated to be 0.0045 g/(m² day).