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1.
Urea–formaldehyde-bonded wood products are limited to interior nonstructural applications because of their poor durability under cyclic moisture or humid environments. The stability of solid-wood joints and particleboards can be enhanced by bonding with urea–formaldehyde adhesives modified with di- and trifunctional amines at an effective resin formaldehyde-to-urea mol ratio (F/U) of 1.6; however, particleboard formaldehyde emissions were not improved over those from boards made with unmodified adhesives and were unacceptably high. The relative effectiveness of selected modifications was investigated at resin form aldehyde-to-urea (F/U) molar ratios of 1.4 and 1.2 Solid-wood joints and particleboards made with modified adhesives, an unmodified adhesive, and a phenol formaldehyde (PF) resin were subjected to cyclic soak-dry (cyclic stress) treatments and moist-heat aging. Formaldehyde emissions from particleboards were also determined. At F/U 1.4, the resistance of solid-wood joints made with modified adhesives to cyclic stress and moist-heat aging was equal to that of PF-bonded joints and superior to that of joints bonded with unmodified adhesive. The resistance of particleboards made with modified adhesives was greater than that of boards made with unmodified adhesive but less than that of PF-bonded board. Solid-wood joints and particleboards made with F/U 1.4 resins performed better than did those made with F/U 1.2 resins. Particleboards made with F/U 1.2 resins had formaldehyde emissions well below the standard, and room temperature aging or bonding at high temperature reduced emissions substantially. © 1994 John Wiley & Sons, Inc. 1 1 This article is a US Government work and, as such, is in the public domain in the United States of America. 相似文献
2.
The objective of this study was to improve the durability and stability of urea–formaldehyde-bonded wood products by decreasing the internal stress developed during the resin cure and by improving the ability of the cured system to withstand cyclic stresses. Urea–formaldehyde resins were modified either by incorporating urea-capped di-and trifunctional amines into the resin structure or by using the hydrochloride derivatives of some of these amines as the curing agent, or by both methods. This study supplements our previous work by examining the effects of additional amines and subjecting bonded products to additional testing. Solid wood joints bonded with a variety (7 of 15) of modified adhesives had resistance to cyclic stress superior compared to that of joints bonded with unmodified urea–formaldehyde adhesive; at least three of the modified adhesives approached the behavior of phenol–formaldehyde-bonded joints. Resistance to moist heat aging, although still inferior to that of phenol–formaldehyde-bonded joints, was significantly improved for joints bonded with modified adhesives over joints made with unmodified resins. The fracture behavior of joints made with modified adhesives was different from that of joints made with unmodified resins. The fracture energy was greater for joints made with three of four modified adhesives than for joints made with unmodified resins. Modified adhesives produced particleboards made with enhanced cyclic stress resistance. Formaldehyde emission from particleboards made with resins modified with urea-terminated amines was less than emission from boards made with unmodified resins. However, emissions from particleboards made with amine hydrochlorides were not improved compared to those from boards made with an ammonium chloride curing agent. © 1993 John Wiley & Sons, Inc. 1 This article is a US Government work and, as such, is in the public domain in the United States of America. 相似文献
3.
Apitong (Dipterocarpus spp.) and Caribbean pine (Pinus caribaea Morelet) contain high amounts of extractives that contribute to poor bonding. To reduce, if not to eliminate, the effects of these extraneous substances, surfaces of small wood blocks were Soxhlet-extracted for 8 hours by different solvents. Wettability of the wood surfaces was then measured by droplet and dynamic methods using water and dilute NaOH as liquids. Tensile shear strengths of extracted wood bonded with aqueous vinyl polymer isocyanate (API), resorcinol formaldehyde (RF) and polyvinyl acetate (PVAc) resin adhesives were also measured. Results revealed that although Caribbean pine had much higher resin content than Apitong, the former had better wettability than the latter. Solvent extraction of the adherend with either hexane or ethanol-benzene (1:2) for 8 hours was not enough to improve its wettability but enough to improve its gluability. However, successive extraction with hexane, methanol and ethanol benzene rendered the wood satisfactorily wettable. Generally, a direct relationship between wettability and bond strength could not be observed. In a separate experiment to improve bonding strengths, test specimens were either overheated or autoclaved for 4 minutes at 125°C during the pressing period. Autoclave treatment was found to be useful in increasing the bond strengths of API, RF, PVAc and urea formaldehyde (UF)-bonded Apitong and Caribbean pine. 相似文献
4.
An experimental study was conducted on the strength of adhesively bonded steel joints, prepared epoxy and acrylic adhesives. At first, to obtain strength characteristics of these adhesives under uniform stress distributions in the adhesive layer, tensile tests for butt, scarf and torsional test for butt joints with thin-wall tube were conducted. Based on the above strength data, the fracture envelope in the normal stress-shear stress plane for the acrylic adhesive was compared with that for the epoxy adhesive. Furthermore, for the epoxy and acrylic adhesives, the effect of stress triaxiality parameter on the failure stress was also investigated. From those comparison, it was found that the effect of stress tri-axiality in the adhesive layer on the joint strength with the epoxy adhesive differed from that with the acrylic adhesive. Fracture toughness tests were then conducted under mode l loading using double cantilever beam (DCB) specimens with the epoxy and acrylic adhesives. The results of the fracture toughness tests revealed continuous crack propagation for the acrylic adhesive, whereas stick-slip type propagation for the epoxy one. Finally, lap shear tests were conducted using lap joints bonded by the epoxy and acrylic adhesives with several lap lengths. The results of the lap shear tests indicated that the shear strength with the epoxy adhesive rapidly decreases with increasing lap length, whereas the shear strength with the acrylic adhesive decreases gently with increasing the lap length. 相似文献
5.
Philip Klemarczyk 《The Journal of Adhesion》1999,69(3):293-306
Alkyl cyanoacrylate instant adhesives are widely used because of their fast cure speed and versatility on a large number of substrates. Recent performance improvements, such as increased thermal resistance, resulted from the addition of latent acids and polymers, which do not copolymerize with the adhesive monomer, to the adhesive formulations. However, use of these additives can increase fixture time or reduce the final adhesive strength.
Two methods for possibly improving alkyl cyanoacrylate instant adhesives, without loss of cure speed or adhesive properties, could be either crosslinking the alkyl cyanoacrylate monomer with a dicyanoacrylate or copolymerizing it with a second 1, 1 disubstituted electron-deficient olefin. A crosslinker. 1,4 butanediol dicyanoacrylate (BDDCA) and two monofunctional monomers, diethyl methylenemalonate (DEMM) and N,N diethyl-2-cyanoacrylamide (DECA), were prepared, in good purity, for adhesion studies with ethyl cyanoacrylate (ECA). Crosslinking ECA with BDDCA does improve solvent resistance, as determined by solvent swelling experiments. Glass fixture times are approximately the same for ECA, crosslinked ECA, the pure monomers, and monomer mixtures with ECA, while steel fixture times are generally slower. Crosslinking ECA with BDDCA does not improve lap-shear adhesion, either at room temperature or after thermal exposure at 121°C. Lap-shear strength data, before and after heat exposure, revealed that the ECA/DEMM and the ECA/DECA monomer mixtures exhibit weaker lap-shear adhesive strength than ECA alone. 相似文献
Two methods for possibly improving alkyl cyanoacrylate instant adhesives, without loss of cure speed or adhesive properties, could be either crosslinking the alkyl cyanoacrylate monomer with a dicyanoacrylate or copolymerizing it with a second 1, 1 disubstituted electron-deficient olefin. A crosslinker. 1,4 butanediol dicyanoacrylate (BDDCA) and two monofunctional monomers, diethyl methylenemalonate (DEMM) and N,N diethyl-2-cyanoacrylamide (DECA), were prepared, in good purity, for adhesion studies with ethyl cyanoacrylate (ECA). Crosslinking ECA with BDDCA does improve solvent resistance, as determined by solvent swelling experiments. Glass fixture times are approximately the same for ECA, crosslinked ECA, the pure monomers, and monomer mixtures with ECA, while steel fixture times are generally slower. Crosslinking ECA with BDDCA does not improve lap-shear adhesion, either at room temperature or after thermal exposure at 121°C. Lap-shear strength data, before and after heat exposure, revealed that the ECA/DEMM and the ECA/DECA monomer mixtures exhibit weaker lap-shear adhesive strength than ECA alone. 相似文献
6.
Three polyurethane elastomers (PUs) were prepared using macroglycols of different nature (varepsilon-polycaprolactone, polyadipate of 1,6-hexanediol) and length of the hydrocarbon chain (polyadipate of 1,4-butanediol, polyadipate of 1,6-hexanediol). The PUs were characterized using Gel Permeation Chromatography, Differential Scanning Calorimetry, Wide X-ray angle Diffraction, Dynamic Thermal Mechanical Analysis, stress-controlled rheometry and stress-strain experiments. The surface properties were evaluated from contact angle measurements. The PUs were used as raw materials for solvent-based adhesives, whose adhesion properties were measured from T-peel strength of plasticized poly(vinyl chloride) (PVC)/polyurethane adhesive joints. The use of polyadipate of 1,6-hexanediol produced a polyurethane with high crystallinity (i.e. poor rheological and mechanical properties) and enhanced interactions between soft segments. Low adhesion was obtained in joints produced with this polyurethane and a cohesive failure of the adhesive was produced. The decrease in the polyadipate hydrocarbon chain length decreased the degree of crystallinity between polymer chains, therefore, no reduction in rheological and mechanical properties was obtained; a higher joint strength was also obtained. In this study the best performance was obtained with the polyurethane based on varepsilon-polycaprolactone, presumably because of its higher surface energy and reduced crystallinity. The properties of the polyurethanes prepared in this study were more affected by the characteristics of the macroglycol, and the crystallinity of the polyurethane had a more marked effect on the properties than the degree of phase separation. 相似文献
7.
Rubber-modified epoxy adhesives are used widely as structural adhesive owing to their properties of high fracture toughness. In many cases, these adhesively bonded joints are exposed to cyclic loading. Generally, the rubber modification decreases the static and fatigue strength of bulk adhesive without flaw. Hence, it is necessary to investigate the effect of rubber-modification on the fatigue strength of adhesively bonded joints, where industrial adhesively bonded joints usually have combined stress condition of normal and shear stresses in the adhesive layer. Therefore, it is necessary to investigate the effect of rubber-modification on the fatigue strength under combined cyclic stress conditions. Adhesively bonded butt and scarf joints provide considerably uniform normal and shear stresses in the adhesive layer except in the vicinity of the free end, where normal to shear stress ratio of these joints can cover the stress combination ratio in the adhesive layers of most adhesively bonded joints in industrial applications.In this study, to investigate the effect of rubber modification on fatigue strength with various combined stress conditions in the adhesive layers, fatigue tests were conducted for adhesively bonded butt and scarf joints bonded with rubber modified and unmodified epoxy adhesives, wherein damage evolution in the adhesive layer was evaluated by monitoring strain the adhesive layer and the stress triaxiality parameter was used for evaluating combined stress conditions in the adhesive layer. The main experimental results are as follows: S–N characteristics of these joints showed that the maximum principal stress at the endurance limit indicated nearly constant values independent of combined stress conditions, furthermore the maximum principal stress at the endurance limit for the unmodified adhesive were nearly equal to that for the rubber modified adhesive. From the damage evolution behavior, it was observed that the initiation of the damage evolution shifted to early stage of the fatigue life with decreasing stress triaxiality in the adhesive layer, and the rubber modification accelerated the damage evolution under low stress triaxiality conditions in the adhesive layer. 相似文献
8.
This paper reports on bonding characteristics of assemblies using as substrates poly(vinyl chloride) (PVC), acrylonitrile-butadiene-styrene (ABS) and polypropylene (PP), and as melt adhesives an ethylene-vinyl acetate (EVA) copolymer, a polyurethane (PUr), and low density polyethylene (LDPE). Peel strength measurements on freshly assembled joints were compared with results for samples aged under inert and humid conditions. Significant time-dependent variations of bond strength were observed in all cases, but the direction of change varied among the assemblies. Those involving only dispersion-force materials displayed losses of bond strength, attributable to the gradual accumulation of cohesively weak layers at the substrate/adhesive interface. In assemblies involving materials able to interact by non-dispersion (acid/base) forces, as indicated by inverse gas chromatographic data, a variety of responses was obtained. These have been rationalized by the ability of the EVA and PUr adhesives to reorient when in contact with an appropriate polymer substrate. Reorientation, leading to bond strength increments, was associated with substrate/adhesive pairs (e.g., PVC/EVA and ABS/PUr), in which significant acid/base interaction could take place. 相似文献
9.
Anna Rudawska Elżbieta Bociąga Ewa Olewnik-Kruszkowska 《Journal of Adhesion Science and Technology》2013,27(3):327-344
The paper presents selected aspects of the effect of primers on adhesive properties and strength of aluminium sheet adhesive joints, made using polyurethane adhesives. The strength of adhesive joints was determined based on two cure time variants: 15 and 64 h. It was found that the longer cure time at a humidity of 33% is more desired, as it leads to a substantial increase in strength of the tested adhesive joints. In addition, two variants of surface preparation were applied: degreasing and degreasing followed by the application of a primer (a pro-adhesive agent). It was observed that the primer application prior to the application of an adhesive leads to a significant increase in strength compared to the variant where the adhesive application is preceded only by degreasing. Moreover, the aluminium sheet surface that was subjected to cataphoretic painting and priming exhibits better adhesive properties. It has a higher value of both surface free energy and its dispersion and polar components compared to the surface that was only subjected to degreasing. 相似文献
10.
The paper focuses on selected parameters of curing process – temperature and time. The tests aimed at evaluating the impact of short-term thermal recuring on 1050A and 2017A aluminium alloy sheet adhesive joints strength. Joints were formed with two different adhesives, the main component of which was in both cases epoxy resin Epidian 53 and two different cure agents – poliamineamide C (PAC) and triethylenetetraamine (PF) curing agents. Curing conditions – first curing time, recuring time and recuring temperature – were modified for each of the four tests conducted. For the sake of comparative analysis, adhesive joints were subjected to a single-stage cure cycle at ambient temperature. A two-stage cure cycle of both Epidian 53 compositions at 80?°C for 1 and 2?h produces a material of different mechanical properties than the same material which submits a single-stage cure cycle at ambient temperature, as well as at 60?°C for 30?min. Simultaneously, Epidian 53/PF/100:50 composition proves to produce higher joint strength after recuring than Epidian 53/PAC/100:80; the strength of a joint formed with the former composition increases up to 50% when compared with joints subjected to a single-stage cure cycle. Moreover, tests show that recuring of the adhesive joint formed with both compositions at 60?°C for 30?min does not have a considerable influence on either 1050A or 2017A aluminium adhesive joint strength. 相似文献
11.
《Journal of Adhesion Science and Technology》2013,27(1):19-27
We compared the wound-bursting strength (WBS), mode of adhesive failure and surface characteristics of two FDA-approved tissue adhesives for skin closure in an incisional rat model using a randomized, controlled, blind animal experiment. Standardized 2-cm full-thickness incisions were made in duplicate on both sides of 15 rats and closed with Indermil, or High Viscosity Dermabond (HVD) following manufacturers' instructions. WBS was measured 5 min later with a validated commercial instrument. Wound sections were also observed under light and scanning electron microscopies. Indermil was significantly weaker than HVD (mean difference, 143 mmHg; 95% CI, 42-229 mmHg, P = 0.002). The mode of failure for Indermil was primarily cohesive in the adhesive and the primary failure mode for the HVD was interfacial (χ2, P < 0.01). Microscopic observations demonstrated that application of HVD resulted in a thick, uniform and smooth surface while Indermil resulted in a thin, irregular, cracked surface. We conclude that HVD is stronger, thicker and more uniform than Indermil. 相似文献
12.
Mohammad Mizanur Rahman 《Journal of Adhesion Science and Technology》2013,27(23):2592-2602
Waterborne polyurethane (WBPU) adhesives were prepared using poly(tetramethylene oxide glycol), 4,4’-dicyclohexylmethane diisocyanate (H12MDI), hydrophilic agent dimethylol propionic acid and chain extender of 2,2,3,3-tetrafluoro-1,4-butanediol (TFBD), ethylene diamine (EDA), and 1,4-butanediol. All three chain extenders have been used as single and mixed (different ratio) content during synthesis, and the effect of chain extender and their content to the properties of tensile strength, Young’s modulus, water swelling (%), and adhesive strength was investigated. The adhesive strength value was higher using EDA as a single-chain extender; however, the potentiality of adhesive strength under water was improved using mixed-chain extenders of EDA and TFBD in WBPU adhesives. The maxima potentiality was observed with 6.31 mole% TFBD and 2.10 mole% EDA in WBPU adhesives. 相似文献
13.
The optimized bonding of glued finger joints is required for structural and nonstructural applications. The use of nonspecific adhesives, combined with the joint geometry and exposure of joints to humidity and temperature, are factors that can compromise the durability of glued joints. The main objective of this study is the development of cross-linking poly(vinyl acetate) (PVAc) hybrid adhesive to produce nonstructural finger joints of Pinus elliottii with finger lengths of 6.5 and 4.5 mm. The adhesives were produced by emulsion copolymerization of vinyl acetate with n-butyl acrylate with different amounts of N-methylol acrylamide and blended with resorcinol-formaldehyde resin (RF) and aluminum chloride (AlCl3). The rheological behavior of adhesives was investigated. We found that the joint configuration and the exposition time employed influenced joint strength. The PVAc/RF adhesive showed a thicker bond line and consequent deeper penetration into the pores of the wood as verified by microscopy analysis. Statistically differences in bond strength of the adhesive joints were found with respect to different conditioning times and finger length. The highest values were exhibited by the joints produced with a finger length of 6.5 mm and glued with the hybrid adhesive (AD-4) than that joints produced with a finger length of 4.5 mm. 相似文献
14.
H. Khoramishad O. Alizadeh L. F. M. da Silva 《Journal of Adhesion Science and Technology》2018,32(16):1795-1808
In this study, the deleterious influence of hot deionized water on adhesively bonded joints was reduced with silicon carbide (SiC) nanoparticles and multi-walled carbon nanotubes (MWCNTs). A gravimetric method was used to study the kinetics of water ingress into the neat and nanocomposite epoxy adhesives. Then, joints were manufactured using the same neat and nanocomposite adhesives and aged for different periods according to the results obtained from the bulk sample tests and finite element modeling. The results showed that the reinforcing effect of nanofillers on the strength was about three times higher for the wet epoxy adhesive compared to the dry one. Moreover, it was found out that introducing 4.4 wt% of SiCs or 0.52 wt% of MWCNTs to the adhesive can compensate the degrading influence of aging under near-saturated condition. Furthermore, the scanning electron microscope (SEM) fractography was used to assess the fracture surfaces of the neat and reinforced samples. 相似文献
15.
《Journal of Adhesion Science and Technology》2013,27(5):655-675
The effect of tapering the ends of the adherend on the joint strength and joint deformation behavior of a single lap joint geometry was studied. The joints were geometrically modeled using finite element (FE) techniques involving linear, as well as nonlinear (bilinear) material behavior. The FEA results were then compared with the experimental results for different single lap configurations, which had aluminum and steel adherends with different surface etch conditions, bonded using two different adhesives. The FEA results were found to be consistent with the experimental results with the normal and shear stresses significantly decreasing in the modified (tapered) geometries over those in unmodified geometries. The joint strength increased with decreasing taper angle, reaching a maximum at the smallest value considered (~10°). 相似文献
16.
环保型水性聚氨酯复膜胶的开发及其在软包装中的应用 总被引:4,自引:3,他引:1
合成出不同结构的水性聚氨酯(WPU)复膜胶,以PET镀铝膜(VMPET)、双向拉伸聚丙烯(BOPP)和聚乙烯(PE)为复合薄膜,探讨了聚酯结构对WPU复膜胶粘接性能的影响,分析了异氰酸酯、水性固化剂和外加溶剂等对WPU复膜胶剥离强度和干燥速率的影响。结果表明:以混合聚酯、芳香族异氰酸酯为主要原料,配合水性固化剂,合成的WPU复膜胶对多种复合薄膜具有较好的粘接性能,其平均剥离强度达到3.48N/15mm;添加少量易挥发的无害溶剂,能够提高水性复膜胶的干燥速率,其最大复合速率达到110m/min,并且完全满足工业化的生产要求。 相似文献
17.
Fan-Rong Kong - Present address of Fan-Rong Kong is Research Center of Advanced Manufacturing Southern Methodist University Dyer Street Dallas TX USA. Min You Xiao-Ling Zheng 《The Journal of Adhesion》2008,84(2):105-124
A 3-D elastic finite element model was developed to investigate the stresses distribution of bi-adhesive bonded joints (i.e., the bond line of joints filled with two adhesives of dissimilar toughness). The effects of the loading mode on the stress distribution of joints, including the single-lap joints under tensile loading (i.e., single-lap joints) and the butt joints under cleavage loading (i.e., cleavage joints), were also studied in detail. Results showed that higher stress, distributed at the contact position of the dissimilar adhesives placed along the bond line of bi-adhesive bonded joints. Also, the maximum stress of the adhesive layer decreased when the length ratios and bonding sequence along the bond line, filled with two dissimilar adhesives, was appropriately designed. At the same time, stress convergence in the adhesive layer of bi-adhesive joints was also obviously reduced in contrast to the mono-adhesive joints. The numerical investigation shows that it is necessary to take into account the change of loading modes when optimizing the bi-adhesive joint design, because of the uneven and complex loading modes of the adhesive bonding structure in the engineering applications. 相似文献
18.
An investigation was made of the effects of extraction and various chemicals applied on veneer surface on the wettability and gluing properties of apitong, Dipterocarpus grandiflorus Blanco, using urea formaldehyde resin. Wettability was determined by measuring contact angles with distilled water.
It was found that extraction with methanol-benzene greatly improved the wettability and gluability of apitong veneer. Likewise, surface treatment with methanol-benzene significantly increased the wettability of the veneer as well as the dry and wet shear strengths of the resulting bond. Treatment with sodium hydroxide increased both wettability and dry shear, but decreased the wet shear strength of the bond. Acetone did not have a significant effect on both wettability and dry shear, but decreased wet shear strength. On the other hand, ether had adverse effects on the wettability and gluability of apitong veneer.
A positive linear correlation was found between wettability and gluability of apitong veneer. 相似文献
It was found that extraction with methanol-benzene greatly improved the wettability and gluability of apitong veneer. Likewise, surface treatment with methanol-benzene significantly increased the wettability of the veneer as well as the dry and wet shear strengths of the resulting bond. Treatment with sodium hydroxide increased both wettability and dry shear, but decreased the wet shear strength of the bond. Acetone did not have a significant effect on both wettability and dry shear, but decreased wet shear strength. On the other hand, ether had adverse effects on the wettability and gluability of apitong veneer.
A positive linear correlation was found between wettability and gluability of apitong veneer. 相似文献
19.
An investigation has been made of the effect of varying glue-spread on the bond strength of holly (Ilex aquifolium) using three adhesives and three different wood sections. The glue-spreads are lower than those normally used, and it has been found with edge-grain joints that 100% cohesive wood failure can occur with a glue-spread as low as 2.7mg/cm2. Scanning electron microscopy shows that interlocking between adhesive and adherend does not occur. Factors leading to delamination and joint failure are discussed.
Lignin, without further addition, has been shown to be a useful wood adhesive. It has also been shown that it is possible to make end-grain joints without the use of an adhesive; the lignin present in the wood specimens is considered to be responsible for such joints. 相似文献
Lignin, without further addition, has been shown to be a useful wood adhesive. It has also been shown that it is possible to make end-grain joints without the use of an adhesive; the lignin present in the wood specimens is considered to be responsible for such joints. 相似文献
20.
《国际聚合物材料杂志》2012,61(12):1061-1070
A series of acrylated polyols were prepared by grafting 2-hydroxyethyl methacrylate (HEMA) on to polyol backbone prepared from vegetable oil fatty acid and epoxy resin. Grafting was carried out by free radical mechanism on conjugated double bond present in the polyol using benzoyl peroxide (BPO) as an initiator. Polyols and polyurethane adhesives were characterized by IR spectroscopy. Polyurethane adhesive synthesized from the modified polyols were found to provide better peel strength to styrene butadiene rubber (SBR) joints. Mode of failure was studied using Scanning Electron Microscopy (SEM). Improvement in cohesive strength of the adhesives resulted in high bonding strength. Comparative study has been carried out to determine the effect of acrylation on polyurethane adhesive by Green strength, Curing behavior, and Chemical resistance studies. Loading of 20% HEMA gave significant results. However, 15% loading of HEMA resulted in a sample with highest peel strength. 相似文献