Effect of Zr Addition on Bi<Subscript>1.8</Subscript>Pb<Subscript>0.4</Subscript>Sr<Subscript>2.0</Subscript>Ca<Subscript>1.1</Subscript>Cu<Subscript>2.1</Subscript>O<Subscript><Emphasis Type="Italic">y</Emphasis></Subscript> Superconductor

The polycrystalline Bi_1.8Pb_0.4Sr_2.0Ca_1.1Cu_2.1 M_xO _y , with M = Zr (x = 0.0, 0.02, 0.04), were synthesized by solid-state reaction method and studied by X-ray diffraction analysis (XRD), scanning electron microscopy equipped with energy dispersive of X-ray analysis (SEM/EDX) and resistivity versus temperature measurements. The influence of the Zr addition on the Tc and microstructure properties of the superconducting compounds has been studied. SEM observations show whiskers grains randomly distributed and microstructural change due to the addition of Zr. The ZrO₂ was incorporated into the crystalline structure of BSCCO system in all samples. The crystallographic structure remains in a tetragonal form where a= b≠c. Generally, all samples exhibit semiconductor behaviour above \(T_{\mathrm {c}}^{\text {onset}}\). The onset critical temperature \(T_{\mathrm {c}}^{\text {onset}}\) increases up to 86 with x = 0.02. There is an enhancement in the critical temperature for doped samples as compared with pure Bi_1.8Pb_0.4Sr_2.0Ca_1.1Cu_2.1O _y .Changes in superconducting properties of ZrO₂ nanoparticle added Bi-2212 system were discussed.     

Synthesis and microwave dielectric properties of Zn<Subscript>1+<Emphasis Type="Italic">x</Emphasis></Subscript>Nb<Subscript>2</Subscript>O<Subscript>6+<Emphasis Type="Italic">x</Emphasis></Subscript>

We have studied the formation of zinc niobate, ZnNb₂O₆, with the columbite structure and the microstructure and microwave dielectric properties of Zn_1+x Nb₂O_6+x ceramics. The results demonstrate that, in the range 0.005 ≤ x ≤ 0.03, the excess zinc reduces the porosity of the material and increases its microwave quality factor Q. For x ≥ 0.03, the Q of the ceramics decreases because of the formation of an additional, zinc-enriched phase. Sintering in an oxygen atmosphere is shown to improve the dielectric properties of stoichiometric ZnNb₂O₆.     

Diffusion phase transition and impedance spectroscopy of Bi<Subscript>2</Subscript>O<Subscript>3</Subscript>/CuO co-doped BCZT lead-free ceramics

Perovskite type (Ba_0.85Ca_0.15?2x Bi_2x )(Zr_0.1Ti_0.9?x Cu _x )O₃ lead-free ceramics were prepared via a conventional solid-state reaction method. The phase structure, dielectric, ferroelectric properties and complex impedance were investigated in detail. XRD and dielectric measurements determined that single orthorhombic phase displayed in (Ba_0.85Ca_0.15)(Zr_0.1Ti_0.9)O₃ at room temperature. With the introduction of Bi₂O₃/CuO, the phase structure exhibited the mixture of orthorhombic and tetragonal phases, and then turned to single tetragonal phase. In contrast to the sharp dielectric transition of (Ba_0.85Ca_0.15)(Zr_0.1Ti_0.9)O₃ ceramics, a broad dielectric peak coupled with a slight decrease in Curie temperature was observed in (Ba_0.85Ca_0.15?2x Bi_2x )(Zr_0.1Ti_0.9?x Cu _x )O₃ ceramics with increasing x. The observed diffuse phase transition behavior was further confirmed by a couple of measurements with polarization loops and polarization current density curves. The structural and the composition fluctuations induced by ions doping should be responsible for the diffuse phase transition behavior. Furthermore, physical mechanisms of the conduction and relaxation processes were revealed by using impedance spectroscopy analyses. It was concluded that the conduction and relaxation processes were thermally activated, which was closely linked with the singly and doubly ionized oxygen vacancies.     

Tuning of Dielectric Parameters of (NiFe<Subscript>2</Subscript>O<Subscript>4</Subscript>)<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>/CuTl-1223 Nano-superconductor Composites by Temperature and Frequency

Nickel ferrite (NiFe₂O₄) nanoparticles and Cu_0.5Tl_0.5Ba₂Ca₂Cu₃O_10?δ (CuTl-1223) superconductor were prepared separately and then mixed in an appropriate ratios at the final stage to obtain (NiFe₂O₄) _x /CuTl-1223 (x = 0, 0.5, and 1.0 wt%) nano-superconductor composites. There was no significant change observed in crystal structure of the host CuTl-1223 superconducting matrix after the addition of NiFe₂O₄ nanoparticles. The value of zero-resistivity critical temperature { T _{c(R = 0)} (K)} was decreased with increasing content of these nanoparticles in these composites. Maximum values of dielectric loss tangent (tanδ) at lowest possible frequency of 40 Hz were increased with the increase of operating temperature, while its values were decreased and become almost zero at higher frequencies for all these samples at all operating temperatures. A peak in dielectric loss tangent was shifted towards lower frequency values with the addition of these nanoparticles in CuTl-1223 superconducting matrix. The dielectric loss tangent peak was also shifted towards lower frequency values in all these samples with increasing operating temperature, which shows the relaxator-like behavior in these samples. The dielectric parameters of these composites can be tuned by frequency, operating temperatures, and nature and content of these nanoparticles.     

Formation of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>6 + <Emphasis Type="Italic">x</Emphasis></Subscript> clusters in laser-generated plasma

We have studied the influence of YBa₂Cu₃O_{6 + x} clusters formed in the plasma generated by laser ablation of a YBa₂Cu₃O_{7 ? δ} target on the optical transmission spectra of amorphous YBaCuO films deposited on glass substrates arranged along the direction of predominant plasma expansion in the laser plume. It is established that intense cluster formation begins in the region of rapid decrease in the film thickness, where the temperature of plasma decreases to a level at which stable atomic complexes characteristic of the target composition can form (under the experimental conditions studied, this was observed at as distance of L > 6 cm from the target). As the amount of clusters in the deposit increases, the magnitude of the interference fringes, which are characteristic of optically homogeneous media, gradually decreases and eventually almost vanishes. At the same time, features typical of the electron structure of YBa₂Cu₃O_{7 ? δ} appear and grow in the optical transmission spectra of the YBaCuO films, including the absorption due to free charge carriers at ?ω < 1.2 eV (characteristic of “metallic” clusters) and the minima at ?ω = 1.4 and 1.75 eV (characteristic of a dielectric state).     

Complex Electric Modulus Spectroscopy of (MnFe<Subscript>2</Subscript>O<Subscript>4</Subscript>)<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>/CuTl-1223 Nanoparticles-Superconductor Composites

Manganese ferrite (MnFe₂O₄) nanoparticles and Cu_0.5Tl₀.₅Ba₂Ca₂Cu₃O_10?δ(CuTl-1223) superconducting phase were synthesized by sol-gel and solid-state reaction methods, respectively. Different contents of MnFe₂O₄ nanoparticles were added in CuTl-1223 superconducting matrix to get (MnFe₂O₄)_x/CuTl-1223; x =? 0～2.0 wt% nanoparticles-superconductor composites. Complex electric modulus spectroscopy measurements of (MnFe₂O₄)_x/CuTl-1223 composites were carried out at different test frequencies from 20 Hz to 10 MHz and at different operating temperatures from 78 to 253 K to analyze and interpret the dynamical aspects of electrical transport phenomena (i.e., such as carrier hopping rate, conductivity, and blocking factor). The complex electric modulus spectra showed the effects of both grains and grain-boundaries on electrical properties. The capacitance of grain-boundaries was found higher than that of grains. The capacitive behavior of grains was increased and that of grain-boundaries was decreased with increasing operating temperature for all these samples. Blocking factor of these composites was increased with increasing contents of MnFe₂O₄ nanoparticles. Shifting of peaks in imaginary part of modulus spectra towards lower frequency with increasing contents of these nanoparticles showed non-Debye type relaxation phenomenon in the material.     

<Emphasis Type="Italic">p-T</Emphasis> Phase Diagram of the Cu-Te System

The p-T phase diagram of the Cu–Te system is constructed using the T-x phase diagram reported earlier, the vapor compositions over the copper tellurides Cu₂Te, Cu_{3 ? x} Te₂, and CuTe, and their dissociation pressures.     

Noise and structural characteristics of high-<Emphasis Type="Italic">T</Emphasis><Subscript>c</Subscript> superconductor films and the numerical simulation of bolometers based on such films

The structure, electrical properties, and noise characteristics of the epitaxial YBa₂Cu₃O_7?x high-T _c superconductor films grown by laser ablation and magnetron sputtering on CeO₂/Al₂O₃ and LaAlO₃ substrates have been studied. Experimental values of the film parameters (effective noise voltage V _n, bolometer resistance R _b, working temperature T _b, etc.) were used to calculate the main characteristics of bolometers based on such films, intended for the absolute radiometry of synchrotron radiation in the 150–3000 eV range. Numerical estimates of the equivalent noise power, NEP _Σ = 8 × 10^?11?1.3 × 10^?10 W/Hz^0.5, show that the proposed films can be used for the creation of a high-precision absolute radiometer capable of detecting soft x-ray (synchrotron) radiation in a broad frequency range with a power of about 1 μW at an error not exceeding 1%.     

Skyrmion mechanism of hole pairing in the high-<Emphasis Type="Italic">T</Emphasis><Subscript><Emphasis Type="Italic">c</Emphasis></Subscript> cuprates

A topological mechanism of hole localization as two skyrmions in the CuO₂ layers of high-T _c superconductors is suggested on the basis of a nonlinear σ model.     

The enhanced interface effect induced by thermal pressure in Nd<Subscript>0.7</Subscript>Sr<Subscript>0.3</Subscript>MnO<Subscript><Emphasis Type="Italic">y</Emphasis></Subscript> ceramics

Polycrystalline ceramics Nd_0.7Sr_0.3MnO _y prepared by solid-state reaction were treated under high pressure of 9 GPa and temperature of 1000 K. The electrical transport behaviour of samples were investigated by a variable temperature system and a peculiar transport character was found at low temperature of 120 K, the I–V showed an obvious step-shape behaviour with the increase in the measurement voltages; at much lower temperature of 12.3 K, the I–V curves exhibited a notable symmetric hysteresis at a critical voltage of 4.5 V, although a linear I–V behaviour at 293 K. On the other hand, the R–T measurement revealed that the resistivity peak (resistivity at T _{M I} ) disappeared gradually and is replaced by a resistivity platform with the increase in the load currents, surprisingly, the resistivity platform broadened with continuous increase in the load currents but weakened when an external magnetic field was applied. All of these phenomena were not observed for the un-treated sample. The particle attenuated and the enhanced interface effect which resulted from the violent thermal-pressure treatment was responsible for the unique electromagnetic transport.     

Progress in Critical Current Density (<Emphasis Type="Italic">J</Emphasis><Subscript><Emphasis Type="Italic">c</Emphasis></Subscript>) in Sintered MgB<Subscript>2</Subscript> Bulks

The present paper focuses on methods of further improving the flux pinning and critical current density of disk-shaped MgB₂ bulk superconductors by adding excess Mg metal in combination with an optimum silver content and optimized processing conditions. Bulk MgB₂ samples were produced by in situ solid-state reaction in Ar gas ambient using high purity commercial powders of Mg metal and 1.5 wt% carbon-coated amorphous B powders mixed in a fixed ratio of Mg/B = 1.1:2. Further, 4 wt% silver was added to improve flux pinning as well as mechanical performance of the bulk MgB₂ material. The magnetization measurements confirmed a sharp superconducting transition with T_c,onset at around 37 K, which is only by 1 K lower than in bulk MgB₂ material produced without carbon-coated amorphous boron. The critical current density (J_c) values significantly improved in the MgB₂ material with 4 wt% of silver and 1.5 wt% of carbon-coated amorphous boron, sintered at 775 ^°C for 3 h. At 20 K, this sample showed J_c at around 500 and 350 kA/cm² in the self-field and 1 T, respectively, which makes it suitable for several industrial applications.     

Analysis of Critical Current Density in Bi<Subscript>2</Subscript>Sr<Subscript>2</Subscript>CaCu<Subscript>2</Subscript>O<Subscript>8+<Emphasis Type="Bold">x</Emphasis></Subscript> Round Wire with Filament Fracture

Bi₂Sr₂CaCu₂O_8+x (Bi-2212) round wires have outstanding electromagnetic behaviors in a high magnetic field. However, the filaments’ fracture or gas bubble is difficult to avoid during the fabrication and application of Bi-2212 round wire, which would affect the critical current density seriously. In this paper, the engineering current density is studied based on Kim model for 7-bundle and 18-bundle wires with filament fracture by considering the effect of bridges between filaments. The distributions of critical current density of filaments are also investigated for different external fields. Finally, we present the relation between the number of cracked filaments and the applied strain.     

Thermodynamic modeling of BC<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>N<Subscript><Emphasis Type="Italic">y</Emphasis></Subscript> chemical vapor deposition from mixtures of <Emphasis Type="Italic">N</Emphasis>-trimethylborazine and nitrogen

Thermodynamic modeling of the chemical vapor deposition of boron-carbonitride-based films in the B-C-N-H-O system using mixtures of N-trimethylborazine and nitrogen is carried out for reduced pressures (13.3 and 1.33 Pa) and a wide temperature range (300–1300 K). The source of oxygen impurities in this system is a residual pressure of 0.40 Pa. The results indicate that films of various compositions can be grown. The conditions for the deposition of BC _x N _y films are identified.     

Influence of isovalent and heterovalent substitution for Bi<Superscript>3+</Superscript> and Fe<Superscript>3+</Superscript> on the properties of Bi<Subscript>2</Subscript>Fe<Subscript>4</Subscript>O<Subscript>9</Subscript>-based solid solutions

Bi_2–хLa_хFe₄O₉ and Bi₂Fe_4–2xTi_xCo_xO₉ ferrites have been prepared by solid-state reactions at a temperature of 1073 K. X-ray diffraction data indicate that, in the Bi_2–хLa_хFe₄O₉ system, the limiting degree of La³⁺ substitution for Bi³⁺ ions in Bi₂Fe₄O₉ does not exceed 0.05 and that the limiting degree of substitution in the Bi₂Fe_4–2xTi_xCo_xO₉ system lies in the range 0.05 < x < 0.1. The specific magnetization and specific magnetic susceptibility of the samples have been measured at temperatures from 5 to 300 K in a magnetic field of 0.86 T. The field dependences of magnetization obtained for the Bi_2–хLa_хFe₄O₉ and Bi₂Fe_4–2xTi_xCo_xO₉ ferrites at temperatures of 300 and 5 K demonstrate that partial isovalent substitution of La³⁺ for Bi³⁺ ions in Bi₂Fe₄O₉ and heterovalent substitution of Ti⁴⁺ and Co²⁺ ions for two Fe³⁺ ions leads to partial breakdown of the antiferromagnetic state and nucleation of a ferromagnetic state.     

Electrical conductivity of Bi<Subscript>2</Subscript>O<Subscript>3</Subscript>-Tm<Subscript>2</Subscript>O<Subscript>3</Subscript>-Nb<Subscript>2</Subscript>O<Subscript>5</Subscript> solid solutions

New solid solutions, Bi_2?x?y Tm _x Nb _y O_3+δ, with tetragonal and cubic structures have been synthesized in the Bi₂O₃-Tm₂O₃-Nb₂O₅ system, and their electrical conductivity has been measured at temperatures from 670 to 1020 K. The 1020-K conductivity of the tetragonal solid solution Bi_1.8Tm_0.15Nb_0.05O_3+δ is comparable to that of Bi_1.75Tm_0.25O₃, the best conductor in the Bi₂O₃-Tm₂O₃ system.     

Investigation of Reflectance Properties in 1D Ternary Annular Photonic Crystal Containing Semiconductor and High-<Emphasis Type="Italic">T</Emphasis><Subscript><Emphasis Type="Bold">c</Emphasis></Subscript> Superconductor

In this paper, we present the theoretical investigation and study of reflectance properties in a 1D ternary annular photonic crystal (TAPC) containing a semiconductor and a high-temperature superconductor. The proposed structure consists of alternate layers of indium nitride (InN), Bi₂Sr₂CaCu₃O₈ (BSCCO), and air placed in free space. A reflectance spectrum of the TAPC is obtained by employing the transfer matrix method (TMM) in the cylindrical waves for both transverse electric (TE) and transverse magnetic (TM) polarized waves. From the study of reflectance spectra, it is observed that the reflection band of the annular photonic crystal depends on the azimuthal mode number m in addition to other parameters. It is found that for azimuthal mode number m = 0, the width of the reflection band of the annular photonic crystal is the same as that of a planar photonic crystal (PPC). When the azimuthal mode number increases, the width of the reflection band increases at higher m values (m >5) for TE waves. In the case of the TM wave, it is interesting to observe that a superpolariton gap is created for a higher value of the azimuthal number (m >0). Further, we see the effect of the starting radius (ρ ₀) on the reflection band of the TAPC structure at the given m number for both TE- and TM-polarized waves. Finally, the effect of temperature on the reflectance spectra for both TE and TM waves at the given ρ ₀ and azimuthal mode has been studied.     

Modeling of the Complex Doping Dependence of dT<Emphasis Type="Italic">c</Emphasis>/dP of YBa2Cu3O6+<Emphasis Type="Italic">x</Emphasis>

The pressure-induced intrinsic effects in the CuO₂ plane within the van Hove singularity (VHS) scenario is combined with the modified two-dimensional (2D) lattice gas phenomenology for the basal plane to model the complex structure of the hole-doping dependence of the pressure derivatives of T _c of YBa₂Cu₃O_6+x. The experimentally observed structure is found to be reproduced reasonably satisfactorily in the present formalism. This shows that the pressure-induced changes in the CuO₂ plane and the oxygen ordering in the basal plane both play important roles in explaining the doping dependent pressure derivative of T _c .     

Enhanced magnetoelectric coupling in La-modified Bi<Subscript>5</Subscript>Co<Subscript>0.5</Subscript>Fe<Subscript>0.5</Subscript>Ti<Subscript>3</Subscript>O<Subscript>15</Subscript> multiferroic ceramics

Multiferroic properties of La-modified four-layered perovskite Bi_5?x La _x Fe_0.5Co_0.5Ti₃O₁₅ (0 ≤ x ≤ 1) ceramics were investigated, by analyzing the magnetodielectric effect, magneto-polarization response and magnetoelectric conversion. X-ray diffraction indicated the formation of pure Aurivillius ceramics, and Raman spectroscopy revealed the Bi ions displacement and the crystal structure variation. The enhancement of ferromagnetic and ferroelectric properties was observed in Bi_5?x La _x Fe_0.5Co_0.5Ti₃O₁₅ after La modification. The evidence for enhanced ME coupling was determined by magnetic field-induced marked variations in the dielectric constant and polarization. A maximum ME coefficient of 1.15 mV/cm·Oe was achieved in Bi_4.25La_0.75Fe_0.5Co_0.5Ti₃O₁₅ ceramic, which provides the possible promise for novel magnetoelectric device application.     

MOF-derived,CeO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>-modified CoP/carbon composites for oxygen evolution and hydrogen evolution reactions

Development of low-cost, highly efficient catalysts for water splitting is required to replace precious metal catalysts. CeO _x -modified CoP@carbon composites are prepared via Ce-doped metal–organic frameworks. The as-prepared CeO _x -modified CoP@carbon composites have excellent electrocatalytic activity with respect to the oxygen evolution reaction, for which an overpotential (η) up to?~?313 mV is achieved at the current density of 10 mA cm^?2. In addition, CeO _x -modified CoP@carbon composites show an overpotential of up to 127 mV at the current density of 10 mA cm^?2 for the hydrogen evolution reaction, showing excellent catalytic activity for water splitting.     

Growth and properties of LiCu<Subscript>2</Subscript>O<Subscript>2</Subscript>-NaCu<Subscript>2</Subscript>O<Subscript>2</Subscript> crystals

Platelike Li_{1 ? x} Na _x Cu₂O₂ single crystals up to 2 × 10 × 10 mm in dimensions have been grown by slowly cooling (1 ? x)Li₂CO₃·xNa₂O₂·4CuO melts in alundum crucibles in air. Li_{1 ? x} Na _x Cu₂O₂ solid solutions in the LiCu₂O₂-NaCu₂O₂ system have been shown to exist in the composition range 0.78 < x < 1. The temperature stability ranges of NaCu₂O₂ and LiCu₂O₂ are 780–930 and 890–1050°C, respectively. The Mössbauer spectra and electrical conductivity of the crystals have been measured.