共查询到16条相似文献,搜索用时 171 毫秒
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
介绍了重量法研制高纯氦气中微量氢气、氖气、氧气、氩气、氮气、甲烷、一氧化碳和二氧化碳8种杂质标准物质的过程,包括重量法制备技术、稀释气中相关杂质的定量及稳定性考察等。研制的8种微量气体标准物质的种类和摩尔分数参照国标GB/T 4844-2011中对高纯氦气的规定,摩尔分数范围在0.5~4.0μmol/mol之间,扩展不确定度为1%~3%(k=2)。通过参加CCQM相关国际关键比对,验证了标准物质量值的准确度。与现有的国家二级标准物质相比,研制的标准物质在种类和不确定度方面都已达到了较高水平。 相似文献
12.
This paper presents the results of detonation studies conducted by the Bureau of Mines on nitric oxide, nitrous oxide, nitrogen tetroxide, carbon monoxide, and ethylene to evaluate the potential hazards of these materials to explosive shock initiation. Charge arrangements, construction details, and interpretation of results are given.Nitric oxide was observed to be the simplest known molecule capable of detonation-detonating in all three phases. Nitrous oxide, as a solid, nonboiling liquid, and nitrogen tetroxide and carbon monoxide, as nonboiling liquids, could not be initiated to detonation. Ethylene, as a gas at elevated pressure, gave evidence of a mild reaction but did not detonate; as a nonboiling liquid, it could not be initiated to detonation. 相似文献
13.
National and international measurements are underpinned by accurate, low concentration standards. These standards are typically produced gravimetrically, or volumetrically, by a series of dilutions of the pure material by the balance gas. This blend technique is time-consuming and may involve the handling of pure, hazardous material. These problems have been overcome by developing a novel blend technique whereby the process gas stream, from an appropriate permeation tube, was cryogenically trapped in an aluminum cylinder. The permeation rate of the component is monitored by real time mass determinations using a magnetic suspension balance system. With the combination of the real-time calculated permeation rate, plus the use of a dilution system, a one step production of a very low concentration of the minor component in nitrogen gas can be achieved. This method was used to prepare low μmol/mol standards of propane, a known stable compound. Analysis of a conventional gravimetrically prepared 10 μmol/mol propane standard and a cryogenically prepared standard via a permeation gas stream resulted in agreement between the two of <0.1% at 10 μmol/mol, confirming the accuracy of the permeation method. After confirmation of the validity of the permeation/cryogenic trapping system, the propane permeation tube was replaced with a methyl mercaptan tube (a toxic, reactive compound) in balance nitrogen. After cryogenically trapping the methyl mercaptan output stream from the permeation system into a cylinder, the output stream and the cylinder gas mixture were analyzed. The results showed agreement of <0.6% for methyl mercaptan at 5, 10, 15, and 20 μmol/mol to the expected blend concentration, thereby demonstrating the validity of the method. 相似文献
14.
15.
16.
Semiconducting tin oxide precursor powders were synthesized via three different chemical processing routes. The influence of powder processing conditions on the physical properties, e.g., particle size, surface area and phase composition of both uncalcined and calcined materials, was investigated. These powders were used to fabricate gas sensors using thick-film screen-printing technology. The effect of precursor powders, sintering conditions, sensor temperature and Pd catalyst on the carbon monoxide, methane, propane and ethanol gas sensing characteristics of the sensors were investigated. Sensors were also fabricated using tin oxide powders obtained from a commercial source and their gas sensing properties were also investigated. The data indicates that the powder processing methodology, sensor fabrication conditions and Pd catalyst can profoundly influence the physical characteristics as well as the gas sensing properties of the sensors. 相似文献