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1.
《International Journal of Cast Metals Research》2013,26(1-4):168-173
AbstractThe effects of different heating rates to a homogenisation temperature on the semisolid microstructure of Al–Mg–Si–Mn alloys are investigated. It is found that the size, morphology and distribution of the α-Al12Mn3Si2 intermetallic compound (Mn containing dispersoid) depend on the heating rate in the homogenisation process. Fine spherical and homogeneously distributed Mn containing dispersoid particles are found in the slow heated samples (0˙7°C min?1), while inhomogeneously distributed coarser particles with a rod-like shape are found in the rapid heated samples (110°C min?1). The homogenised sample is deformed by 60% cold rolling. It is found that the recrystallised and semisolid grain sizes of the rapid heated sample are smaller than those of the slow heated sample in all conditions. Compared with the M4 alloy (0˙4 mass-%Mn), the M7 alloy (0˙72 mass-%Mn) has much finer semisolid grain size and smaller values of the shape factor close to 1. The Mn containing dispersoid greatly affects the semisolid grain size of the alloys. The results in this work show that the rapid heating in the homogenisation process is useful to produce high quality semisolid products of the Al–Mg–Si–Mn alloys. 相似文献
2.
The experiments for rheologic behaviors of semisolid continuous casting billets of A356 alloy in semisolid state had been carried out with a multifunctional rheometer. The results show that the deformation rate increases with loading time, the maximum strain reaches to 120% (which is one time larger than that of traditional mold casting billet) and the strain can be rapidly eliminated to 10% after unloading. Moreover, there is a critic stress for billet deformation even in semisolid state, which is named as critic shear stress. This stress increases with the decreasing of heating time. The theologic behaviors can be expressed by five elements mechanical model (H_2- [N_1|H_2]-[N_2|S]) and can be modified with the increasing of heating time. 相似文献
3.
《中国有色金属学会会刊》2021,31(8):2232-2249
The differences in the microstructure and elevated temperature tensile properties of gravity die cast, squeeze cast, and semi-solid thixoformed Al–Si–Cu–Mn–Fe alloys after thermal exposure at 300 °C were discussed. The results demonstrate that the elevated temperature tensile properties of semi-solid thixoformed alloys were significantly higher than those of gravity die cast and squeeze cast alloys, especially after thermal exposure for 100 h. The ultimate tensile strength (UTS) of semi-solid thixoformed alloys after thermal exposure at 300 °C for 0.5, 10 and 100 h were 181, 122 and 110 MPa, respectively. The UTS values of semi-solid thixoformed alloys were higher than those of heat resistant aluminum alloys used in commercial applications. The enhanced elevated temperature tensile properties of semi-solid thixoformed experimental alloys after thermal exposure can be attributed to the combined reinforcement of precipitation strengthening and grain boundary strengthening due to thermally stable intermetallic phases as well as suitable grain size. 相似文献
4.
A. V. Pozdniakov V. S. Zolotorevskiy 《International Journal of Cast Metals Research》2014,27(4):193-198
The possibility of determining the hot cracking index using the calculated value of the effective solidification range is investigated for multicomponent cast aluminium alloys based on the system Al–Si–Cu–Mg with Mn, Ni, Fe and Zn additives. The upper limit of the effective solidification range was calculated as the temperature of formation of 65 wt-% solid phase using Sheil model. The linear relationship of the hot cracking index and the effective solidification range in the industrial and experimental multicomponent alloys based on the Al–Si–Cu–Mg system is demonstrated. 相似文献
5.
The effect of the composition and cooling rate of the melt on the microhardness, phase composition, and fine-structure parameters of as-cast and splat-quenched (SQ) high-entropy (HE) Al–Cu–Fe–Ni–Si alloys was studied. The quenching was performed by conventional splat-cooling technique. The cooling rate was estimated to be ~106 K/s. Components of the studied HE alloys were selected taking into account both criteria for designing and estimating their phase composition, which are available in the literature and based on the calculations of the entropy and enthalpy of mixing, and the difference between atomic radii of components as well. According to X-ray diffraction data, the majority of studied Al–Cu–Fe–Ni–Si compositions are two-phase HE alloys, the structure of which consists of disordered solid solutions with bcc and fcc structures. At the same time, the Al0.5CuFeNi alloy is single-phase in terms of X-ray diffraction and has an fcc structure. The studied alloys in the as-cast state have a dendritic structure, whereas, after splat quenching, the uniform small-grained structure is formed. It was found that, as the volume fraction of bcc solid solution in the studied HE alloys increases, the microhardness increases; the as-cast HE Al–Cu–Fe–Ni–Si alloys are characterized by higher microhardness compared to that of splat-quenched alloys. This is likely due to the more equilibrium multiphase state of as-cast alloys. 相似文献
6.
Composite materials based on alloys of the Al–Si–Mg system have been obtained via the introduction of 5, 10, and 15 wt % of SiC particles into the alloy melt and the solidification under a pressure. As a result of solidification under pressure, the porosity of the composite materials decreased substantially. An increase in the content of SiC particles in the composites enabled a smaller size of dendritic cells to be obtained. It has been shown by the X-ray diffraction method that, in the process of solidification under pressure, an interaction occurred between the matrix and reinforcing SiC particles. The presence of SiC particles in the structure of composites led to the acceleration of the aging process and to an increase in the peak hardness in comparison with the matrix alloy. 相似文献
7.
In this article, a novel Al-6Zr-2P master alloy with ZrP particles was successfully synthesized, and the refining performance of this novel master alloy for the primary Si in Cu-50Si alloys was also investigated. By means of the fracture plane observation, it is found that the ZrP phase would precipitate first in the solidification process, and then, the ZrAl 3 phase grows around them. Furthermore, it is observed that the refining effect can be remarkably improved by changing the addition sequence of the raw materials. After the melting of commercial Cu, the 2.0 wt% Al-6Zr-2P master alloy and crystalline Si were added in sequence, and the mean size of the primary Si in Cu-50Si alloy can be significantly refined from 255.7 to 75.3 lm. Meanwhile, the refining mechanism was discussed in detail. 相似文献
8.
Conclusions
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 6, pp. 37–40, June, 2000. 相似文献
1. | For alloys of the Al−Si−Cu system that bear a diminished iron content the optimum alloying combination is Ti+B+Cd, which increases the dispersity of the structure and elevates the properties due to the modifying action of the alloying elements. |
2. | Microalloying of cast alloy AK11M5 with an alloying set of 0.17% Ti+0.04% B+0.15% Cd increases the strength by ≥25% with a simultaneous increase in the ductility. |
9.
《Acta Materialia》1999,47(14):3927-3934
Wetting of porous TiC0.17N0.83 by six alloys from the Al–Mg–Si system (pure Al, pure Mg, Al–15 at.% Mg, Al–10 at.% Si, Mg–5 at.% Si, and Al–10 at.% Mg–10 at.% Si) in an argon atmosphere was studied using the sessile drop experiment. The contact angle of the liquid drops on TiC0.17N0.83 substrates was measured as a function of temperature. Aluminium, Al–10 at.% Si, and Al–10 at.% Mg–10 at.% Si did not wet TiC0.17N0.83 in the studied temperature range. Magnesium always wetted TiC0.17N0.83 with a minimum contact angle of ≈44° at 900°C, and alloying with Mg significantly lowered the contact angle of Al on TiCN. Alloying with Si deteriorated the wetting of TiCN by Mg. A comparative study between the systems was conducted, based on the results and on data available in the literature. The improvement of the wetting of TiCN by Al due to alloying with Mg can be explained by the segregation of Mg to the interface with TiCN, where it lowers the interface energy. The addition of Si to pure Mg or to Al–Mg results in an increase in the contact angle on TiCN. 相似文献
10.
《中国有色金属学会会刊》2020,30(7):1717-1730
The effect of thermal exposure at 350 °C for 200 h on microstructure and mechanical properties was investigated for Al−Si−Cu−Ni−Mg alloy, which was produced by permanent mold casting (PMC) and high pressure die casting (HPDC). The SEM and IPP software were used to characterize the morphology of Si phase in the studied alloys. The results show that the thermal exposure provokes spheroidization and coarsening of eutectic Si particles. The ultimate tensile strength of the HPDC alloy after thermal exposure is higher than that of the PMC alloy at room temperature. However, the TEPMC and TEHPDC alloys have similar tensile strength around 67 MPa at 350 °C. Due to the coarsening of eutectic Si, the TEPMC alloy exhibits better creep resistance than the TEHPDC alloy under studied creep conditions. Therefore, the alloys with small size of eutectic Si are not suitably used at 350 °C. 相似文献
11.
《International Journal of Cast Metals Research》2013,26(1-4):174-179
AbstractThe semisolid microstructures and the mechanical properties of Al–1˙35Mg–1˙04Si–0˙67Mn alloy produced by deformation semisolid forming (D-SSF) process were studied. Fine α-Al15Mn3Si2 compounds precipitate homogeneously during the homogenisation treatment. These compounds effectively inhibit the coarsening of recrystallised grains during heating to the semisolid temperature. When the liquid fraction is controlled to be ~23%, the complete die filling is not achieved. Therefore, in order to achieve good fluidity, it is necessary to control the liquid fraction to be more than 30%. The average grain size and the liquid fraction at the semisolid temperature influence directly mechanical properties. Therefore, the relationship among the average grain size, the liquid fraction at the semisolid temperature and mechanical properties was evaluated. Furthermore, the optimum semisolid microstructure was determined and the condition for the D-SSF process was established. 相似文献
12.
Sun Ting 《中国有色金属学会会刊》1999,9(3):3
1 INTRODUCTIONThepreparationofAlSialloysbyelectrothermalprocesshasbeenadvancingmoregreatlythanthatbycryolitealuminameltingelectrolysis.Ithasmanyadvantagessuchasshortcircuit,smallinvestmentofequipments,highproductionandutilizationrateofenergy.Espec… 相似文献
13.
《Acta Materialia》2001,49(1):65-75
In the present investigation a special control volume formulation of the classical precipitation model for coupled nucleation, growth and coarsening has been adopted to describe the evolution of the particle size distribution with time during thermal processing of Al–Mg–Si alloys. The analysis includes both isothermal and non-isothermal transformation behaviour. Well established dislocation theory is then used to evaluate the resulting change in hardness or yield strength at room temperature, based on a consideration of the intrinsic resistance to dislocation motion due to solute atoms and particles, respectively following heat treatment. The model is validated by comparison with experimental microstructure data obtained from transmission electron microscope examinations and hardness measurements, covering a broad range in the experimental conditions. It is concluded that the model is sufficiently relevant and comprehensive to be used as a tool for predicting the response of Al–Mg–Si alloys to thermal processing, and some examples are given towards the end. 相似文献
14.
《Acta Materialia》2003,51(14):4197-4208
Three different aluminum–iron alloys were produced by electron-beam deposition with the iron content in the range 1.15–1.71 at.%. These alloys did not contain any identifiable iron-bearing particles, and exhibited full density with high-angle grain boundaries in the micrometer range, and a sub-grain size typically smaller than 100 nm. The tensile deformation characteristics of the alloys were examined at a dynamic strain rate of 1.1×103 s−1 and a quasi-static strain rate of 1×10−3 s−1 at room temperature. The alloy containing 1.7% Fe exhibited an abnormally high tensile strength of about 950 MPa with a ductility of up to 6%. Detailed atomic resolution imaging of the structure of the alloys has been performed along with an examination of their fracture surface features. The fracture surfaces of the alloys showed ductile dimples which typically spanned five to 10 times the sub-grain diameter. It is postulated that the nano-scale sub-grains of the alloy impart high strength, while the structure associated with high-angle boundaries provides reasonable ductility. Possible mechanisms responsible for the high strength in the present Al–Fe alloys are explored. The present results are also examined in conjunction with a comprehensive survey of available results on the strain-rate sensitivity of tensile yield strength and ductility in microcrystalline, sub-microcrystalline and nanocrystalline metals and alloys, and on the solid-solution strengthening of aluminum alloys. 相似文献
15.
《稀有金属(英文版)》2015,(8)
In this study, the stirred casting with various processing parameters, such as stirring temperature and stirring speeds, was carried out on the Al–Pb monotectic alloys in order to make Pb particles distribute much more uniformly. More importantly, their damping capacities were systematically studied. The results show tha mechanical stirring can not only make Pb in the aluminum matrix uniformly distribute but also dynamically influence the damping capacity of this alloy system. The Al–Pb alloy was prepared under a slow speed at solid–liquid temperature region, wherein high volume fraction of Pb in alloy could be obtained. The high volume fraction of Pb gives high overall damping capacity. The dislocation damping and interface damping theories are mainly dominated to the alloys. 相似文献
16.
《Scripta materialia》2002,46(8):617-622
The influence of heat treatments on the softening process of a TiAl intermetallic alloy containing three phases (namely γ, α2 and B2) has been examined. At the annealing temperatures studied, the lamellar microstructure exhibits faster softening kinetics than the globular one due to the transformation that takes place between the α2 and B2 phases while the globular structure softens by a coarsening/dissolution process of the respective B2 and α2 globules initially present. 相似文献
17.
《Intermetallics》2013
Crystallization property of amorphous GeTe can be significantly improved by doping Cu. However, the effect of Cu on the structure and electrical properties of crystalline GeTe is not clear, which is of great importance for phase-change memory. In this work, we have studied the effect of Cu on the structure and properties of crystalline GeTe by means of ab initio calculations. The results show that it is energetically favorable to obtain rhombohedral structured CunGe32–m–nTe32 films by co-sputtering defective Ge32–mTe32 and Cu as characterized by the negative formation energies. The doped Cu has slight effect on the structure property and chemical bonding of GeTe but has remarkable effect on the electrical properties. The results show that CunGe32–nTe32 alloys might be a good candidate material for phase-change memory. 相似文献
18.
《International Journal of Cast Metals Research》2013,26(5):264-266
AbstractThe microstructure and properties of three Al–3Li–1Cu ternary alloys have been studied, in particular the effect of Zr additions on the microstructure, precipitation and mechanical properties. The results showed that, for these Al–Li casting alloys, Zr content up to 0.2 wt-% was acceptable, and the Zr additions appeared to refine the grain structure. During aging, the Zr rich phase provided nucleation sites for δ' phase and promoted δ' phase refinement and homogenisation. Under optimised conditions, the tensile strength and elongation to failure of the Al–Li–Cu–Zr casting alloys were 400 MPa and 2.5%, respectively. 相似文献
19.
《Scripta materialia》2003,48(5):565-570
To design an alloy with high strength around 1773 K and good ductility at room temperature, the microstructure, the compression strength and the creep properties at 1773 K of the Ir–Al alloys with an fcc and B2 two-phase structure were investigated. High-temperature mechanical properties are discussed in terms of microstructure. 相似文献
20.
A. D. Kotov A. V. Mikhaylovskaya A. A. Borisov O. A. Yakovtseva V. K. Portnoy 《The Physics of Metals and Metallography》2017,118(9):913-921
During high-strain-rate superplastic deformation, superplasticity indices, and the microstructure of two Al–Zn–Mg–Cu–Zr alloys with additions of nickel and iron, which contain equal volume fractions of eutectic particles of Al3Ni or Al9FeNi, have been compared. It has been shown that the alloys exhibit superplasticity with 300–800% elongations at the strain rates of 1 × 10–2–1 × 10–1 s–1. The differences in the kinetics of alloy recrystallization in the course of heating and deformation at different temperatures and rates of the superplastic deformation, which are related to the various parameters of the particles of the eutectic phases, have been found. At strain rates higher than 4 × 10–2, in the alloy with Fe and Ni, a partially nonrecrystallized structure is retained up to material failure and, in the alloy with Ni, a completely recrystallized structure is formed at rates of up to 1 × 10–1 s–1. 相似文献