Optical absorption and fluorescent behaviour of titanium ions in silicate glasses

Titanium in normal melting conditions in air atmosphere present as Ti⁴⁺ ion in basic silicate glasses exhibited an ultra-violet cut-off in silicate glasses, viz. soda-magnesia-silica, soda-magnesia-lime-silica and soda-lime-silica glasses. This indicates that Ti⁴⁺ ion can be a good replacement for Ce⁴⁺ ion in producing UV-absorbing silicate glasses for commercial applications. The wavelength maxima at which the infinite absorption takes place in glasses was found to be around 310 nm against Ti-free blank glass in UV-region. The mechanism of electronic transition from O^2- ligands to Ti⁴⁺ ion was suggested as L→ M charge transfer. The low energy tails of the ultra-violet cut-off were found to obey Urbach’s rule in the optical range 360–500 nm. The fluorescence spectra of these glasses were also studied and based on the radiative fluorescent properties it was suggested that the soda-lime-silica glass containing Ti⁴⁺ ion with greater emission cross-section would emit a better fluorescence than the corresponding soda-magnesia-lime-silica and sodamagnesia-silica glasses. The shift of emission wavelengths maxima towards longer wavelength in titania introduced silicate glasses was observed on replacement of MgO by CaO which may be attributed due to an increase in basicity of the glass system.     

Composition and size dependent torsion fracture of metallic glasses

The fracture of metallic glasses(MGs)of different compositions and sizes down to micrometers under torsion loading were systematically investigated.Contrary to the flat shear fracture along the circumfer-ential plane as commonly supposed under torsion,we find that the torsion fracture of metallic glasses can deviate from flat shear plane,and the fracture angle is closely dependent on the composition and the size of MG samples.With a conversion method,we show that the torsion fracture of both millimeter-and micrometer-sized MGs can be described by the ellipse fracture criterion as originally proposed for the tension fracture.The deviation from the circumferential shear plane under torsion is further shown to intrinsically relate to the fracture toughness of MGs.The tougher MG tends to have a smaller fracture angle with respect to the maximum shear plane,and vice versa,indicating a correlation between the fracture toughness and pressure/normal stress sensitivity in MGs.Our results provide new insights on the fracture mechanism and are helpful to design and control the deformation and fracture behavior of MGs under torsion loading.     

Bond compression bulk modulus and Poisson’s ratio of the polycomponent silicate glasses

The theoretical bulk modulus and Poisson’s ratio of the 65SiO₂–15PbO–5CaO–(15−X)K₂O–XNa₂O glass system (X=0–15 mol%) have been calculated using the bond compression model. The atomic ring size of the network has been also obtained for each sample according to the ring deformation model. These parameters have been interpreted quantitatively in terms of the most important structure factors. The composition dependence of these parameters showed that the elasticity and hence the response of this glass system is influenced by the chemical nature of the modifying oxides. Moreover, variation of the estimated atomic ring size with the ratio of bond compression (K_bc) to experimental (K_e) bulk modulus was studied to obtain more information about the structure of these glasses. The results showed that the small values of K_bc/K_e are attributed to the very close (small-ringed) three-dimensional network of these glasses.     

Constraint effects on the elastic–plastic fracture behaviour in strain gradient solids

ABSTRACT Crack‐tip constraint effects (or T‐stress effects) on the elastic–plastic fracture behaviour in strain gradient materials are analysed in the present study. The T‐stress effects on the stress distributions along the plane ahead of the stationary and growing crack tip, respectively, are analysed by using the Fleck and Hutchinson strain gradient plasticity formation. For a steadily growing crack, the T‐stress effects on the steady‐state fracture toughness are analysed by adopting the embedded fracture process zone model. In addition, the analysis for the growing crack is applied to an interfacial cracking experiment for a metal/ceramic system, and the material length‐scale parameter appearing in the strain gradient plasticity theory is predicted. In the present analyses, a new finite element method specially designed for strain gradient problems by Wei and Hutchinson is adopted.     

Two opposite effects of sodium on elastic constants of silicate binary glasses

(1 - x)SiO₂-xNa₂O glasses have been studied by Brillouin scattering when sodium oxide molar concentration x, varies in the range 0.05 < x < 0.44. Non-linear dependence of elastic constants on sodium oxide concentration is shown unambiguously for the first time and the compressive elastic constant C₁₁ experienced a non-monotonic behaviour with a minimum value around x = 0.15. These results are compared with those obtained previously in the case of other alkali silicate glasses (Li, K). The variations of elastic constants of these glasses with the alkali metal nature and concentration are discussed on the basis of relations with the molar density of silicon atoms and the force constants between modifiers and non-bridging oxygens.     

Finite fracture mechanics: A coupled stress and energy failure criterion

The aim of the present paper is to introduce a new failure criterion in the framework of Finite Fracture Mechanics. Criteria assuming that failure of quasi-brittle materials is affected by stress or energy flux acting on a finite distance in front of the crack tip are widely used inside the scientific community. Generally, this distance is assumed to be small compared to a characteristic size of the structure, i.e. to any length describing the macroscale. A key point of the present paper is to analyse what happens if the smallness assumption does not hold true. The proposed approach relies on the assumption that the finite distance is not a material constant but a structural parameter. Its value is determined by a condition of consistency of both energetic and stress approaches. The model is general. In order to check its soundness, an application to the strength prediction for three point bending tests of various relative crack depths and of different sizes is performed. It is seen that, for the un-notched specimens, the present model predicts the same trend as the Multi-Fractal Scaling Law (MFSL). Finally, a comparison with experimental data available in the literature on high strength concrete three point bending specimens is performed, showing an excellent agreement. It is remarkable to observe that the method presented herein is able to provide the fracture toughness using test data from un-notched specimens, as long as the range of specimen sizes is broad enough.     

Compositional effects in the dissolution of multicomponent silicate glasses in aqueous HF solutions

The dissolution rate of multicomponent silicate glasses in a 2.9m aqueous HF solution is investigated as a function of its composition. The glasses studied are composed of SiO₂, B₂O₃, Al₂O₃, CaO, MgO, ZnO, Na₂O and K₂O, covering the compositions of most of the technologically important glasses. Unlike many physical properties, no linear relations are observed between the composition of the glass and its dissolution rate. The dissolution rate of a multicomponent silicate glass is found to be largely determined by two factors: The degree of linkage or connectivity of the silicate network and the concentration of SiO₂ in the glass. It is proposed that the dissolution of the glasses is preceded by the leaching of alkali and alkaline earth components present in the glass, followed by the subsequent dissolution of the leached layer. Probably fluorine species will diffuse into the leached layer to enhance the dissolution rate. Analysis of the activation energy data indicates that in some corrosive glasses the leaching itself becomes rate determining.     

Comparative investigation on the effect of alkaline earth oxides on the intensity of absorption bands due to Cu<Superscript>2+</Superscript>, Mn<Superscript>3+</Superscript> and Cr<Superscript>3+</Superscript> ions in ternary silicate glasses

Absorption characteristics of Cu²⁺, Mn³⁺ and Cr³⁺ ions in ternary silicate (20Na₂O·10RO·70SiO₂, where R=Ca, Sr, Ba) glasses were investigated. The intensities of absorption bands due to Cu²⁺ ion was found to increase with increasing ionic radii of the alkaline earth ions whereas it was found to decrease in case of Mn³⁺ and Cr³⁺ ions with increasing ionic radii of the alkaline earth ions. The results were discussed in the light of relation between linear extinction coefficients of these ions and coulombic force of alkaline earth ions. The change in intensities of Cu²⁺, Mn³⁺ and Cr³⁺ ion is attributed due to change in silicate glass compositions.     

Multiresolution atomistic simulations of dynamic fracture in nanostructured ceramics and glasses

Multimillion atom molecular-dynamics (MD) simulations are performed to investigate dynamic fracture in glasses and nanostructured ceramics. Using multiresolution algorithms, simulations are carried out for up to 70 ps on massively parallel computers. MD results in amorphous silica (a-SiO₂) reveal the formation of nanoscale cavities ahead of the crack tip. With an increase in applied strain, these cavities grow and coalesce and their coalescence with the advancing crack causes fracture in the system. Recent AFM studies of glasses confirm this behavior. The MD value for the critical stress intensity factor of a-SiO₂ is in good agreement with experiments. Molecular dynamics simulations are also performed for nanostructured silicon nitride (n-Si₃N₄). Structural correlations in n-Si₃N₄ reveal that interfacial regions between nanoparticles are amorphous. Under an external strain, nanoscale cavities nucleate and grow in interfacial regions while the crack meanders through these regions. The fracture toughness of n-Si₃N₄ is found to be six times larger than that of crystalline -Si₃N₄. We also investigate the morphology of fracture surfaces. MD results reveal that fracture surfaces of n-Si₃N₄ are characterized by roughness exponents 0.58 below and 0.84 above a certain crossover length, which is of the order of the size of Si₃N₄ nanoparticles. Experiments on a variety of materials reveal this behavior. The final set of simulations deals with the interaction of water with a crack in strained silicon. These simulations couple MD with a quantum-mechanical (QM) method based on the density functional theory (DFT) so that chemical processes are included. For stress intensity factor K=0.4 MPa m^1/2, we find that a decomposed water molecule becomes attached to dangling bonds at the crack or forms a Si-O-Si structure. At K=0.5 MPa m^1/2, water molecules decompose to oxidize Si or break Si-Si bonds.     

The micromechanisms of fracture of alumina and a ceramic-based fibre composite: Modelling the failure processes

The development of structural ceramics and ceramic composites often relies on assumptions about their cracking and fracture characteristics under load. It is most important to understand the nature of the cracking processes and the interaction between neighbouring cracks. In other words, a clear picture of the dynamic micromechanisms of cracking and the accumulation of damage is essential to the development of sound physical models to explain measurements of the strength and toughness of these materials.     

Influence of statistical and constraint loss size effects on cleavage fracture toughness in the transition - A model based analysis

A database derived from tests on specimens with a large range of ligament (b) and thickness (B) dimensions was systematically analyzed to evaluate constraint loss and statistical size effects on cleavage fracture toughness. The objectives were to: (1) decouple size effects related to constraint loss, mediated by b and B, from those arising from statistical effects, primarily associated with B; and, (2) develop procedures to transfer toughness data to different conditions of constraint and B. The toughness database for a Shoreham pressure vessel steel plate, tested at a common set of conditions, was described in a companion paper. Quantification of constraint loss was based on an independently calibrated 3D finite-element critical stress-area, σ^∗-[K_Jm/K_Jc], model. The measured toughness data, K_Jm, were first adjusted using computed [K_Jm/K_Jc] constraint loss factors to the corresponding values for small scale yielding conditions, K_Jc=K_Jm/[K_Jm/K_Jc]. The K_Jc were then statistically adjusted to a K_Jr for a reference B_r = 25.4 mm. The B adjustment was based on a critically stressed volume criterion, modified to account for a minimum toughness, K_min, consistent with modest modifications of the ASTM E 1921 Standard procedure. The combined σ^∗-[K_Jm/K_Jc]-K_min adjustment procedure was applied to the Shoreham b − B database, producing a homogeneous population of K_Jr data, generally within the expected scatter. The analysis suggests that: (1) there may be a maximum B beyond which statistical size effects diminish, and (2) constraint loss in the three-point bend specimens begins at a relatively low deformation level. A corresponding analysis, based on a Weibull stress, σ_w-[K_Jm/K_Jc]-K_min, adjustment procedure, yielded similar, but somewhat less satisfactory, results. The optimized adjustment procedure was also applied to other K_Jm data for the Shoreham plate from this study, as well as a large database taken from the literature. The population of 489K_Jr data points, covering an enormous range of specimen sizes, geometries and test temperatures, was found to be consistent with the same master curve T₀ = −84 °C derived from the b − B database. Thus, calibrated micromechanical models can be used to treat size and geometry effects on K_Jm, facilitating using small specimens and data transfer to predict the fracture limits of structures.     

金属玻璃基复合材料的制备及断裂韧性测试

采用铜模吸铸法制备了（Zr0.55Al0.1Ni0.05Cu0.30）100-xTix（x=0、2、4、6、8）板状哑铃型金属玻璃基复合材料试样。用X射线衍射（XRD）、岛津AG-10TA万能材料力学试验机和JSM-6700F场发射扫描电子显微镜（SEM）对试样的组织结构以及断裂韧性进行了测试。结果表明,当x=0、2、4时,试样为非晶-晶体复合材料,当x=6、8时,试样为晶体材料。表明通过调整Ti的含量可以制备出金属玻璃基复合材料。采用三点弯曲法测定了复合材料的断裂韧性,当x=0、2、4时,试样的断裂韧性KIC值分别为10.529、5.142和3.446MPa.m1/2。     

Synthesis and structural studies of Na<Subscript>2</Subscript>O-ZnO-ZnF<Subscript>2</Subscript>-B<Subscript>2</Subscript>O<Subscript>3</Subscript> oxyfluoride glasses

This paper describes the synthesis and spectroscopic studies of the glass system, 20Na₂O-(20-x) ZnO-xZnF₂-60B₂O₃(x = 0, 5, 10, 15, 20), prepared by melt quenching method. The analyses of DSC and XRD did not show the crystallinity of the glass sample. ¹¹B MAS-NMR shows the presence of sharp peak around −14 ppm. From the IR studies, the broadening of the peak around 1200–1400 and 800–1100 cm⁻¹ shows the presence of mixed linkages like B-O-B, B-O-Zn in the network.     

Ferromagnetic resonance in metallic glasses: study of fracture,stress and thermal stability

Effects of fracture, stress and isothermal annealing of Fe-Ni based metallic glasses have been investigated using the ferromagnetic resonance technique.fmr linewidth is quite sensitive to changes in the magnetic and structural order in metallic glasses, andfmr lineshape seems to provide useful qualitative information on the mechanical state of these systems. Our observations are compared with recent work of Baianu and co-workers.     

A note on the composition dependence of elastic properties of Se-P glasses

Longitudinal and shear wave ultrasonic velocities are reported in Se-P glasses over the composition range 0–50 at % P. The glass transition temperaturesT _g show maxima at 30 and 50 at % of P, in consonance with earlier data. The bulk modulus shows minima at these compositions, contrary to the expectation of maxima. These are discussed in relation to the formation of compounds at specific compositions and the nature of the covalent bonding in the glasses.     

Effect of alkali and alkaline earth oxides on crystallization of Li2O-Al2O3-SiO2 glasses

The effect of alkali and alkaline earth oxides on the crystallization of lithia-alumina-silica glasses has been studied. Crystallization behaviour of glasses has been investigated using DTA and XRD techniques. The principal crystallization phases are identified asβ-spodumene solid solution and lithium metasilicate. The crystallization temperature of glasses decreases with increase in the values of the ionic field strength of the alkali and alkaline earth cations. Addition of these oxides at lower concentrations has no significant effect on the crystalline phases.     

Experimental research on the compressive fracture toughness of wing fracture of frozen soil

It is commonly found that not only bending fracture but also compressive fracture occur frequently in compression, furthermore, in some specific conditions, compressive fracture sometimes has dominant effect on frozen soil. Therefore, it is extremely necessary to study the mechanical characteristics of the compressive fracture of frozen soil and to investigate the damage and fracture mechanism of frozen soil based on the previous research on frozen soil damage in compression. This study draws on the ideas and methods used in compression fracture research on ice that is very similar to frozen soil, and specific clay in Shenyang region was adopted as the experimental material, to make compressive specimens containing tilted wing crack of different angles, and uniaxial unconfined compression fracture experiments were conducted at different temperatures and loading rates. The fracture toughness K_IC and K_IIC of the main crack tip of the specimens are calculated with obtained experimental results and the law of K_IC and K_IIC changing with tilted angles, temperatures and loading rate is obtained to gain an insight to damage mechanism of frozen soil in compression. This paper presents a meaningful attempt for the research on compressive fracture of frozen soil, so as to better solve practical engineering problems.     

Effect of high pressure on chalcogenide glasses

The effect of high pressures on the various properties of the chalcogenide glasses is reviewed. The properties discussed include the mechanical, electrical, optical and magnetic properties. The phenomena of the crystallization of the chalcogenide glasses under high pressure is also discussed. This article is dedicated to the memory of late Dr N S Satya Murthy who had been intimately associated directly and indirectly with the development of condensed matter physics in India.     

长余辉光致发光玻璃的制备及其性能研究

利用陶瓷制备方法合成了ＳｒＡｌ２Ｏ４：Ｅｕ,Ｄｙ长余辉发光粉体,该磷光体主发射波长位于５２０ｎｍ,余辉时间长达８ｈ以上,并以硼硅酸盐低熔点玻璃为底材,掺杂该发光粉体,在一定温度下烧成,制得长余辉发光玻璃。     

时效制度对7B04铝合金断裂韧性的影响

为研究不同时效制度对7B04铝合金断裂韧性的影响,测定了15种时效工艺的常规力学性能和断裂韧度,并利用扫描电镜对拉伸断口进行分析.通过比较不同时效工艺制度的性能指标和断口形貌,总结出时效制度对7B04铝合金断裂韧度的影响规律.结果表明:随着第二级时效温度的提高和时效时间的延长,7B04铝合金强度下降,断裂韧性提高,其中,温度对性能的影响更大;采用115℃×7 h 185℃×13 h双级时效工艺时,对应的强度和断裂韧度指标均比T73和T76工艺对应的指标高.