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氧化钇纳米粉末的制备 总被引:10,自引:0,他引:10
使用草酸作沉淀剂,采用液相沉淀法成功制备了氧化钇纳米级粉末。对该粉末的扫描电镜图以及差热分析图等进行了分析以及对溶液的pH值、浓度、反应方式、分散剂及煅烧温度等因素进行了考察,得出了较为理想的工艺条件。在此工艺条件下制得的氧化钇粉末粒径为20~50m。 相似文献
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目前采用粉末原料通过等离子喷涂制备的最先进高纯氧化钇涂层的孔隙率通常为3%~5%。这种孔隙率的涂层在严重的腐蚀和侵蚀条件下会释放非常细小的颗粒。高纯氧化钇涂层主要应用于半导体领域,如,干法刻蚀腔室的抗冲蚀保护涂层(含氟和氯的等离子体),并且这些应用的需求条件也越来越严苛。当暴露于这种腐蚀性和侵蚀性气氛中时,涂层的致密度越高,它的耐侵蚀性就越强。侵蚀速率和细颗粒释放的降低将减少维护频率,从而提高生产效率。最近有文献报道通过悬浮液等离子喷涂(SPS)技术制备致密度更高的涂层,但这种新兴的工艺对制备技术提出了更高的挑战,如需要应对非常高的热通量和处理悬浮液作为原料来使用,增加了偏差的风险。本文开发了一种新的高纯氧化钇粉末,采用传统的大气等离子喷涂(APS)这种粉末能制备致密度范围与SPS技术相同的涂层。通过对粉末中颗粒致密度分布的调整和其狭窄精细粒度分布的微调得到一种独特的粉末材料来制备高质量的涂层。相比于通常报道的团聚和烧结粉末,采用Saint-Gobain ProPlasma HP等离子喷枪喷涂这种粉末显著降低了涂层的孔隙率,提高了沉积效率。 相似文献
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A novel yttrium citrate-templated conversion method for morphology controlled synthesis of Y2O3 microspheres, microflowers and microsheets was reported for the first time. The precursors with controllable morphologies were synthesized with a homogenous precipitation method in aqueous solution without any surfactant. Y2O3 samples with well-preserved morphological architectures were obtained by a subse-quent thermal transformation strategy. The chemical formula of the precursor was identified and a two-stage ... 相似文献
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《中国稀土学报(英文版)》2017,(1)
The nano-Y_2O_3 was prepared from YCl_3 by the citrate precipitation method. The precursor powders were prepared by 0.1 mol/L YCl_3 solution and 0.1 mol/L hydrochloric acid in the presence of 1% surfactant PEG2000, which was dried via an ethanol azeotropic distillation method. The effects of reaction temperature, precursor concentration, hydrochloric acid concentration, surfactant, and calcination temperature on the mean sizes of nano-Y_2O_3 were studied. It was found that the highest yield of precursor was about 70% at the p H value of 5.0, and the yield decreased rapidly at the p H value below 4 or over 6. The reaction temperature revealed no effect on the size of precursor. The optimized precursor concentration and hydrochloric acid concentration were both 0.1 mol/L. Several typical analytic techniques such as particle size analyzer, X-ray diffraction(XRD), thermogravimetric and differential thermal analyses(TG-DTA) and scanning electron microscopy(SEM) were used to determine the characteristics of the prepared nano powders. Homogeneous torispherical nano-Y_2O_3 with the smallest size(20 nm) could be obtained by calcining the precursor powders at 800 oC for an hour. 相似文献
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Yu. V. Levinskii A. P. Petrov S. V. Zavodnova 《Powder Metallurgy and Metal Ceramics》1993,32(2):108-111
A mathematical model is suggested for the process of titanium chip impregnation with oxygen. The model is based on the assumption that it is possible to ignore the effect of a thin surface oxide film on oxygen impregnation of -Ti solid solution. The process of producing TiO powder with a particle size of less than 100 µm has been optimized for the minimum expenditure of energy.Institute of Fine Chemical Technology, Moscow. Translated from Poroshkovaya Metallurgiya, No. 2(362), pp. 11–15, February, 1993. 相似文献
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The effect of yttrium oxide dispersoid volume fraction and particle size on the 1400†F (1033 K) and 1900†F (1311 K) rupture
strength of a dispersion strengthened nickel-base superalloy, made by mechanical alloying, was investigated. Yttrium oxide
Contents ranged from 0 pct to 4.5 pct by volume, and average oxide particle sizes varied from about 150Å (15 nm) to 580Å (15
nm) to 580Å (58 nm). High volume fractions and small particle sizes gave low grain aspect ratios and poor 1900†F (1311 K)
and 1400†F (1033 K) stress rupture properties following heat treatment. Rupture strengths at 1400†F (1033 K) were otherwise
relatively unaffected by dispersoid parameters. At grain aspect ratios less than 6.0, 1900†F (1311 K) rupture strength was
controlled by grain geometry while at higher values rupture strength was directly influenced by dispersoid parameters. 相似文献
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带式无舟皿连续还原炉制备粒度均匀的细颗粒钨粉 总被引:1,自引:1,他引:0
细晶粒、超细及纳米硬质合金的用途越来越广泛,制备粒度均匀的细钨粉是制备此类合金的关键.本试验研究以工业蓝色氧化钨和超细黄色氧化钨为原料,在带式无舟皿连续还原炉中用氢气还原制备钨粉.试验结果表明,采用带式无舟皿连续还原炉,以蓝色氧化钨为原料制备的细颗粒钨粉粒度均匀性明显优于四管炉生产的钨粉;以超细黄色氧化钨为原料可制备出粒度均匀、氧含量低、比表面在3.5 m2/g左右、粒度为90 nm左右的纳米钨粉;钨粉性能主要受还原温度、氢气流量、钢带传动速度及料层厚度等工艺参数的影响. 相似文献
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To prepare ytterbium doped lanthania yttria nanopowder a method of laser evaporation of mixed oxides was used. After calcinations of the powder at 1200 °C a pure single-phase solid solution Yb3+:(LaxY1–x)2O3 was formed in the nanoparticles. Influence of lanthanum oxide as an isovalent additive on the yttria structure was investigated. The lanthanium ions were proved to be a good aid to sinter yttria ceramics doped with Yb3+ at moderate temperatures about 1650 °С. The ceramics with relative density higher than 99.99% and grain size about 40 μm were fabricated. Full transmittance of 1.8 mm thick Yb0.11La0.23Y1.66O3 ceramics reached 82.5% at 800 nm. This material could be a good gain medium for ytterbium high power pulse lasers. 相似文献
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