RO,MSF and VTE/VC Desalination: A comparative evaluation

For sea water conversion in single-purpose plants, reverse osmosis (RO) is shown to be more economical than multistage flash (MSF) desalination over a wide range of unit size and fuel cost. Attention is focussed on vertical tube evaporation/vapor compression (VTE/VC) a self-contained, low-energy consuming thermal process which is potentially competitive with RO.     

Implications of desalination for water resources in China — an economic perspective

China is a country with severe water shortages. Water is becoming scarcer due to population growth, industrialization and urbanization. Recent studies show that by the next 50 years water resources per capita will go down to around 1700 m³, which is the threshold of severe water scarcity. Especially in North China, water shortage has become a critical constraint factor for socioeconomic development in the long run. To solve or eliminate water shortage problems, seawater desalination draws more and more attention as an alternative water supply source. The objective of the study is to assess the potential of desalination as a viable alternate water source for China through analysis of the costs of desalination, the water demand and supply situation as well as water pricing practices in China. Based on the investment costs and estimated operation and maintenance costs, an economic appraisal for the costs of desalination for two main processes, MSF and RO, has been conducted. The study shows that there is a decline of unit cost of desalination over time and the average unit cost of the RO process was lower than that of the MSF process. A unit cost of 0.6 $/m³ for desalting brackish water and 1.0 $/m³ for seawater are suggested to be appropriate for the potential application of desalination in China. Future trends and challenges associated with water shortages and water prices are discussed, leading to conclusions and recommendations regarding the role of desalination as a feasible source of water for the future.     

Optimal design of hybrid RO/MSF desalination plants Part III: Sensitivity analysis

This is the last paper in a series of three parts entitled “Optimal design of hybrid RO/MSF desalination plants”. This research is concerned with exploring the feasibility of hybridization of multi-stage flash (MSF) and reverse osmosis (RO) technologies in order to improve the performance characteristics and process economics ofthe conventional MSF process. The research project involved an optimization study where the water cost perunit product is minimized subject to a number of constraints. In the first part, the design and cost models were presented, the optimization problem formulated and solutions for a number of cases were outlined. In the second part, results were presented and discussed. In this paper we discuss the sensitivity of water cost from the alternative plant designs to variations in some cost elements and operating conditions. In general, it is concluded that, for the same desalting capacity, hybrid RO/MSF plants can produce desalted water at a lower cost than brine recycle MSF plants, while hybrid plants are characterized, by lower specific capital costs and higher water recovery fractions. Reduction in steam cost allows MSF to compete more with hybrid RO/MSF plants. This result explains the advantage of coupling MSF plants and steam power plants where the exhaust steam from the back pressure turbine represents a relatively cheaper source of heat for the MSF process. Results showed that the RO technology exceeds all other designs over the whole range of energy, chemicals and membrane costs studied here. However, water cost of the RO process was the most sensitive to variations in membrane and electricity costs compared to other hybrid configurations.     

MSF Desalination plants. Availability,reliability and safety analysis

While good MSF desalination plant performance exerts a positive influence on plant economics, as part of water supply systems in isolated regions, the availability of the desalination system becomes a major design criteria. Reliability problems have historically been a major cause of poor performance for desalination plants. The emphasis of this paper is on the importance of availability modeling methodology to MSF desalination plant reliability problems by providing a context in which the effect of unit unavailability can be quantified.An assessment is made of failures and outages which impact the availability of MSF desalination plants. Limited fault tree logic for system failures is developed and reliability data from the literature is incorporated, where possible. The impact of other water supply system failures on the reliability requirements of the desalination plant is quantified as are the effects of increased average water system demands.The single largest influence on the effective capacity of a water supply system based on MSF desalination of sea water is found to be the availability and maintainability of the desalination plant. Forced outages as a result of equipment failure are significant, but other dominant contributions to unit unavailability include externally caused problems, such as silting. The design configuration of the desalination plant is also found to have an impact on the acceptability of water supply system performance.     

Myth and reality of the hybrid desalination process

The paper discusses some misconceptions that have contributed to the continued use of thermal desalination processes and promotion of the hybrid desalination process for new plants being built or considered at Middle East locations. The misconceptions are examined both on the basis of fundamental thermodynamic principles and in terms of practical engineering parameters. The analysis shows that there is no economic or performance advantage in the installation of greenfield hybrid power/thermal desalination/ seawater reverse osmosis (SWRO) plants in preference to power/SWRO plants, because the latter would produce water more cheaply under all conditions and at all fuel costs, and would provide more operational flexibility than the former. The paper identifies situations where the hybrid desalination process can be fully justified: in existing power/desalination plants, where aging boilers and multistage flash (MSF) units need to be repaired or replaced, through retrofitting and repowering. In such situations, abandonment of the MSF process would result in a reduction in the power output of the plant. The paper refers to previous work which showed that the repowering of a typical existing power/desalination station with refurbishment/replacement of the MSF units, together with the addition of SWRO units, would result in a several-fold increase in the water and power output and a dramatic improvement in the fuel efficiency, without any additions to the existing seawater intake system. The paper emphasizes the importance of test stations/demonstration plants at existing power/desalination stations in the Middle East in order to obtain data and make improvements in the technology of higher temperature SWRO, with the feed obtained from the cooling water returning from the power plant condenser and the thermal desalination plant. The paper shows that the potential benefits would easily justify the investment in research and development required to validate this concept.     

Computer code for optimizing MSF desalination plant

Egypt faces the prospect of population growth pressing on available agricultural land resources. A very large areas of coastal desert could be helpful in population density redistribution and of great economical interest, with the installation of a suitable water supply.Of the many desalination processes, the Multi-Stage Flash (MSF) desalination process is still the most developed and reliable technology for large scale conversion of sea water to fresh water.In this paper, a computer code was developed for optimizing a large scale MSF plant. This code can calculate the optimum design for the plant, and the minimum cost of product fresh water, as a function of both design and operating variables.Sample results obtained using this code for the Egyptian conditions are presented. The effect of energy and material costs, the chemical treatment type, and the feed water salinity on the optimum performance ratio and the minimum fresh water cost are drawn.     

Optimal design of hybrid RO/MSF desalination plants Part II: Results and discussion

This paper presents the results of an optimization study, based on minimum water cost, to explore the feasibility of the hybridization of RO and MSF processes. The study explores the possible improvement of MSF process economics. Nine different scenarios for the production of the same capacity of desalted water are presented and compared from the standpoint of minimum water cost, specific capital cost and water recovery. The process and cost models, formulation of the optimization problem and solution outlines were previously presented in the first part of this study. In this work, results show that RO technology is recommended when building new desalination plants. RO technology becomes preferable at low feed concentrations and for brackish water desalination. Although they come in second position after the RO process, some hybrid plants economically exceed by far the MSF process. Computations gave a water cost of 1.1 $/m³ for the brine recycle MSF process against 0.75 $/m³ for the two-stage RO process. Water cost of the MSF process can be reduced by 17 to 24% through hybridization with RO technology.     

Desalination in Australia operational experience and future prospects

To provide high quality fresh water to meet peak demands at times of drought in large population centres and to satisfy the requirements for water standards in industrial processes are perhaps the prime attractions of sea water desalination plants. Australia, the driest of earth's continents, will probably have a need for such water supply supplementation and industrial process application long before desalting is applied generally to agriculture or rural production. As the cost of fossil fuel gradually increases, it would also seem likely that the thermal energy required for desalting will come from nuclear fuels. In this paper the existing fresh water resources of the Australian continent are briefly surveyed. Present costs associated with supplying fresh water for industrial and domestic consumption to selected communities at representative locations of the Australian continent are assessed. The technology and economics of large scale sea water desalination plants operating on thermal cycles are discussed. In particular, the multi-stage flash evaporator principle is reviewed and its potential discussed. Consideration is given to the advantages and disadvantages of nuclear powered heat sources. Proposals are made for the control and conjunctive use of reservoirs and desalination plants. The optimisation of desalination plant size and its integration with reservoir storage schemes in two potential Australian locations is discussed.     

Conceptual design of a novel hybrid fuel cell/desalination system

A novel concept for integrating fuel cells with desalination systems is proposed and investigated in this work. Two unique case studies are discussed — the first involving a hybrid system with a reverse osmosis (RO) unit and the second — integrating with a thermal desalination process such as multi-stage flash (MSF). The underlying motivation for this system integration is that the exhaust gas from a hybrid power plant (fuel cell/turbine system) contains considerable amount of thermal energy, which may be utilized for desalination units. This exhaust heat can be suitably used for preheating the feed in desalination processes such as reverse osmosis which not only increases the potable water production, but also decreases the relative energy consumption by approximately 8% when there is an increase of just 8°C rise in temperature. Additionally, an attractive hybrid system application which combines power generation at 70%+ system efficiency with efficient waste heat utilization is thermal desalination. In this work, it is shown that the system efficiency can be raised appreciably when a high-temperature fuel cell co-generates DC power in-situ with waste heat suitable for MSF. Results indicate that such hybrid system could show a 5.6% increase in global efficiency. Such combined hybrid systems have overall system efficiencies (second-law base) exceeding those of either fuel-cell power plants or traditional desalination plants.     

Energetic aspects of the fouling of MSF desalination plants with and without the use of on load ball cleaning system

Multi-stage flash (MSF) desalination plants are designed with specific permissible fouling factors. When these conditions are met, the performance is said to “meet design”.With single- purpose desalinators, fouling of the brine heater can be compensated for by increasing the steam pressure without substantial increase of heat consumption and within the limits of the boiler pressure. With dual-purpose desalinators, the brine heater pressure will influence the efficiency of the turbine process.Fouling of the heat recovery section increases the heat consumption of the MSF process. The distillate production can be maintained within the limits of the boiler.Typical “design fouling factors” have been compiled from literature.The influence of fouling factor on specific heat consumption has been calculated for typical MSF design conceptions, as well as the increase of water costs per m³ with different fuel prices.The costs of various scale prevention methods have been evaluated. The effectiveness of such countermeasures can be quantified by plant experience.This analysis of cost/return gives a basis for a correct economic comparison.     

Investment costs and energy consumption of the MSF/FBE in comparison with the MSF

The use of the MSF process in seawater desalination is broad because of simplicity and reliability and an improvement of this process has been proven in the use of the fluidized bed heat exchanger. The choice of most economical gain ratio of a multi-stage flash evaporator is very dependent on energy cost, i.e. steam-and electricity cost. Because of lower investment and electricity costs the MSF/FBE has always lower product water cost than the MSF with equal gain ratio.     

Distillation vs. membrane filtration: overview of process evolutions in seawater desalination

The worldwide need for fresh water requires more and more plants for the treatment of non-conventional water sources. During the last decades, seawater has become an important source of fresh water in many arid regions. The traditional desalination processes [reverse osmosis (RO), multi stage flash (MSF), multi effect distillation (MED), electrodialysis (ED)] have evoluated to reliable and established processes; current research focuses on process improvements in view of a lower cost and a more environmentally friendly operation. This paper provides an overview of recent process improvements in seawater desalination using RO, MSF, MED and ED. Important topics that are discussed include the use of alternative energy sources (wind energy, solar energy, nuclear energy) for RO or distillation processes, and the impact of the different desalination process on the environment; the implementation of hybrid processes in seawater desalination; pretreatment of desalination plants by pressure driven membrane processes (microfiltration, ultrafiltration and nanofiltration) compared to chemical pretreatment; new materials to prevent corrosion in distillation processes; and the prevention of fouling in reverse osmosis units. These improvements contribute to the cost effectiveness of the desalination process, and ensure a sustainable production of drinking water on long terms in regions with limited reserves of fresh water.     

热膜耦合海水淡化系统的优化设计

采用混合节点和分配节点的概念,建立了多级闪蒸(MSF)和反渗透(RO)海水淡化集成系统的超结构模型,以年度总费用最小为目标,引入产水比的概念,并将该参数作为集成系统的一个优化变量,采用改进的遗传算法进行求解,获得了集成系统的最优结构及相应的操作条件。实例结果表明:集成海水淡化系统的淡水成本比独立运行的RO和MSF低,产水比为0.45时集成系统的费用最小,流程结构为MSF-RO。     

Selection of small desalination plants for specific locations — reverse osmosis,flash distillation,vapour compression

Selection criteria are given for small desalination plants (2000–3000 m³/d) for specific locations using RO, MSF or mechanical VC processes. Of prime economic importance to customers, consultants and manufacturers are peripheral location conditions and operating suitability. Choice by the manufacturers is especially complicated due to the fact that the decision for small plants is left to the bidder. However, based on knowledge of local conditions, manufacturers can anticipate costs.Examples given show that under the assumed conditions the MSF process cannot possibly be the most cost-effective. This applies also to RO when the required product is high-purity process water instead of drinking water. For drinking water any choice between MVC and RO is dependent on energy costs and the capitalization factor.     

Integrating hybrid systems with existing thermal desalinationplants

In Gulf countries, most power plants are co-generation power desalting plants (CPDP) that generate electric energy and also produce fresh water through the desalination of seawater. This paper provides detailed technical and economical analyses to evaluate a new generation of dual purpose technology that includes the integration of reverse osmosis (RO) processes with existing thermal desalination processes and power generation (triple hybrid system) at Layyah plant, Sharjah, UAE. Hybridization of sweater reverse osmosis (SWRO) and the multi-stage flash (MSF) technology was considered to improve the performance of latter and reduce the cost of the produced water. Moreover, “idle” power in winter (seasonal surplus of unused power) was mainly utilized by RO to further reduce the cost of the hybrid system for six months of the year. Spinning reserve was also used to further reduce the cost of the proposed hybrid system. Integration ofthe three processes of MSF, MED, and RO desalination technologies could be made at different levels through which the resulting of water cost will depend on the selected configuration and the cost of materials of construction, equipment, membrane, energy, etc. Thus, the capital and annual operating costs were calculated for all potential alternatives for various plant capacities. It was found that for all plant capacities, integrated hybrid systems resulted in most cost effective solution. For example, at a capacity of 50 MIGD, the present worth of the cost was calculated to be 588.7, 443.2, and 380 million US$ for MSF, MED, and hybrid RO systems, respectively.     

Application of the multi-effect process at high temperature for large seawater desalination plants

A large sea water desalination plant, using the multi-effect process at high temperature has been described and a comparison is given with the other distillation processes.The multi-effect plant is easily adaptable in a wide range of operating conditions. It has a low total energy consumption (8.75 KWh per m3 produced (expressed as electrical energy). A high GOR is obtained (12.4). Compared with a MSF of the same production capacity, the investment costs are smaller. This leads to a substantial decrease in cost of the produced water. The technology of horizontal sprayed tubes is a proven one and has been executed more than a hundred times on small and medium units.     

Comparative cost analysis of nuclear versus oil-fired dual-purpose desalination plants

Prospects for the application of nuclear energy to sea water desalination for the Kingdom of Saudi Arabia have been evaluated here based only on economic considerations. Updated capital costs of power plants and current prices of oil and nuclear fuel are used. Information on the Kingdom's water demand and current status of water desalination is provided. A comparison is also made of costs of water production from power-cum-desalination nuclear plants versus oil-fired plants. Only dual-purpose nuclear plants are considered because of their overall economic advantages over single purpose (water only) plants. The scope of available data and information can not be provided in such detail as to allow for system planning or for a site-specific feasibility study. However, the results provide guidelines for more in-depth analysis. The results show that, compared to oil-fired plants, there is a net saving of costs in using nuclear plants for desalination. If interest on capital is disregarded in calculation of total capital costs and also in calculation of annual capital charges, the economic advantages of nuclear power plants improved significantly over the oil-fired power plants.     

Analysis of water and power costs by various methods,based on Jeddah IV

The Jeddah IV Power and Desalination Plant is the biggest, dual-purpose plant in the world. Moreover, it is perhaps the first plant of this kind for which authentic cost and operational data are available. As such, it provides a reliable means of assessing the present status of desalination technology and its influence on the cost of power and water.The well-known theoretical methods of cost allocation are used in deriving the product cost from the Jeddah IV plant. The influence of local factors and contractual constraints is discussed. Extrapolations are made to determine the projected cost of water on similar plants but with different performance ratios. Recommendations are made on cost optimization and the most favourable combination for dual-purpose power/desalination plants based on steam turbines and MSF process.     

MSF海水淡化系统热经济学优化分析

热经济学理论和方法在能量系统分析中占有重要地位。本文以年度化平均淡水成本为目标函数,对ＭＳＦ海水淡系统建立了较完善的优化模型。并就国产化日产３０００吨ＭＳＦ海水淡化系统进行了较详细的浮动价格结构下的优化设计分析。