Intramolecular Negative-Effect in the Alkali-Metal-Doped C60; A2C60 and A4C60

It is investigated theoretically why alkali-metal-doped C₆₀, A_xC₆₀, is a nonmagnetic semiconductor for x=2 and 4. We find that this is the consequence of the intramolecular negative- U effect due to the strong electron-phonon interaction and the weak Hund coupling between conduction electrons.     

On the Action of γ Radiation on Solid C60 and C70 Fullerenes: A Comparison with Graphite Irradiation

C₆₀ and C₇₀ fullerene have been treated in sealed flasks under Ar with γ radiation using radiation dosages ranging from 10 to 1000 kGy. The treated samples studied by electronic and FT-IR spectroscopy have not shown any evidence about fullerenes decomposition or radiopolymerization. However, through Raman spectroscopy it was possible to observe that γ radiation induces C₆₀ dimerization and trimerization. It has additionally been discovered that γ-treated C₆₀ (oligomerized) can be easily photopolymerized in the solid state by post-irradiation with laser light at 514 nm while this phenomenon has not been observed by using laser light at 782 nm and considerably higher laser power. Previously to this study, C₆₀ photopolymerization was known to occur only by using ultraviolet light.

For comparison also graphite was irradiated with 1000 kGy of γ radiation. Irradiated graphite shows considerably changes in its Raman spectrum, showing the formation of glassy carbon domains, perhaps carbon onions. The l_d bandshift to 1310 cm^-1 could be interpreted in terms of formation of hexagonal diamond.     

Evolution of Superconducting and Normal-State Properties in C60 “Polymer” Doped with K

Abstract:

Bulk superconductivity was observed in a new iodine-treated aggregated form of solid C₆₀, believed to be a “polymer”, by doping with alkali metal. Evolution of superconducting (T_c = 17.2 K) and normal-state properties, has been studied as a function of doping with K. The normal-state dc susceptibility exhibited a complex behavior with the increasing K uptake, evolving from an enhanced paramagnetism at low doping level, to a weakly temperature-dependent diamagnetism at the optimum doping level for superconductivity, and ending with a strong temperature-independent diamagnetism in over-doped samples. The measured superconductivity parameters, such as T_c, London penetration depth and the Ginzburg-Landau coherence length, are compared with those of the monomer K₃C₆₀. and the main factors determining the differences between the two systems are discussed.     

A non-probabilistic prospective and retrospective human reliability analysis method — application to railway system

The paper describes a method to analyze human reliability. It defines human reliability as a degradation function related to deviations of both human behavioral state and system state due to this behavior. The method is called ACIH, a French acronym for Analysis of Consequences of Human Unreliability. It is a non-probabilistic approach, which aims at identifying both tolerable and intolerable sets of human behavioral degradations, which may affect the system safety. The corresponding scenarios of degradations are characterized by a behavioral model of unreliability including three main factors: acquisition related factors, problem solving related factors, and action related factors. Both prospective and retrospective analyses are taken into account to specify error prevention tools. They are applied to the railway system.     

Modelling and quality assessment of spots in digital images — With application to DNA microarrays

Based on a recently developed spot segmentation method, we here present a new approach to modelling of individual spots in digital images, e.g. images of DNA microarrays. From the model parameter estimates and residuals we have developed an expedient approach to automatic quality assessment and identification of corrupted spots. The suggested approach to quality control is shown to give a statistically significant decrease of the variance in gene expression log-ratio estimates for three different DNA microarray datasets.     

Zeolite heat pump — adsorption of methanol in synthetic zeolites 13X, 4A and 5A

The adsorption isotherms for methanol adsorption in synthetic zeolites 13X, 4A and 5A were measured gravimetrically at various temperatures. The model of Langmuir and the potential theory were used for correlating the equilibrium data. The monolayer capacity was calculated using these two models. A small deviation at elevated temperatures was observed. The differential heat of adsorption was measured calorimetrically for all three zeolites. The isosteric heat of adsorption was calculated for zeolite 13X using measured equilibrium data. The log p, 1/T equilibrium diagram for zeolite 13X was computed using the Langmuir equation.     

Safety analysis and information system (SAIS)—A living PSA computer system to support NPP-safety management and operators

In 1987, the TÜV Norddeutschland, in cooperation with the Technical University of Berlin, began planning a so-called Safety Analysis and Information System (SAIS). The system integrates a PSA event and fault tree construction and management system, a probabilistic data bank, a fault tree reduction and quantification code all linked to an extensive set of plant specific qualitative information will help the non-PSA plant experts to become specific qualitative information will help the non-PSA plant experts to become familiar with using PSA generated information to support safety related decisions.     

Calculation of thermodynamic properties of R407C and R410A by the Martin–Hou equation of state — part I: theoretical development

A theoretical development of the thermodynamic properties of two mixtures of hydrofluorocarbon (HFC) refrigerants, i.e. R407C and R410A (in the superheated vapour state), is carried out. The modelling is based on the Martin-Hou equation of state, which has long been used for pure hydrofluorocarbons (e.g. R134a) with good results. Since R407C and R410A are very well investigated refrigerants, the analytical procedure here derived concerns with those thermodynamic properties of R407C and R410A (in the superheated state) that are not published in the current specialised literature. They are: compressibility factor, isentropic and isothermal compressibility, volume expansivity, isentropic and isothermal exponent, speed of sound and Joule–Thomson coefficient. These properties may be used as a theoretical basis for research into the optimal HFC-mixture for compressor efficiency and for performing cycle calculations in the vapour-phase region for systems working with R407C and R410A.     

Experimental research on bolted joint strength and dispersion in steel lattice transmission tower legs under low temperatures (−20°C to −45°C)

Cold regions with subzero temperatures (?20°C to ?45°C) have important impacts on the mechanical properties of structural steel used in lattice steel towers of overhead transmission line systems. The results from regular material tests are not appropriate for the accurate analysis of joint strength in cold weather conditions. This paper presents the tensile test results of 18 coupons of steel material and eight groups (18 specimens per group) of bolted joints with Q345 and Q420 steel under temperatures of 20°C, ?20°C, and ?45°C. The results show that the yield‐to‐ultimate strength ratio of the joints under low temperature conditions is beyond the range of 0.60 to 0.75 for Q420 structural steel. Suggestions are made on how to improve the accuracy of joint design for both the partial resistance factor and the design value of joint yield strength in cold regions.     

A unified formalism using effective surface permittivity to study acoustic waves in various anisotropic and piezoelectric multilayers

A unified formalism is presented that uses the effective surface permittivity (ESP) to study surface acoustic waves (SAW) in layered substrates and guided waves in layered plates. Based on known mathematical tools, such as ordinary differential equation and transfer matrix, a generalized surface impedance (GSI) concept is developed and exploited to investigate the acoustic propagation in various anisotropic and piezoelectric layered structures. The ESP function, originally defined for the surface of a homogeneous and semi-infinite piezoelectric substrate, is extended to both the top surface of and an interface in a layered half space, as well as to either surface of a finite-thickness plate. General ESP expressions for all mentioned configurations are derived in terms of an equivalent GSI matrix. It is shown that, when using the appropriate GSI matrices, the same form of the ESP expressions applies no matter whether the structure is a homogeneous half space alone or coated with a layered plate or a layered plate alone. GSI matrices are explicitly given in terms of the bulk partial mode solutions for a substrate and via the transfer matrix for a plate. Modified GSI matrices for structures consisting of both a plate and a substrate are also specified. Analytical development is fully detailed to suit program implementation. To illustrate its versatility, the formalism is also applied to two-substrate configurations, allowing one to analyze guided waves in a plate sandwiched between and interfacial waves existing along the boundary of two different media. Numerical examples are given to illustrate the spectrum features that the ESP shows for various structures. Deduced ESP expressions allow one to locate directly all piezoelectrically active waves in any structure including at least one piezoelectric layer. Acoustic modes that are not piezoelectrically active and those in non-piezoelectric materials can be also obtained by using the intermediate results, such as derived GSI matrices.     

Elastic constants for an intercalated layered-silicate/polymer nanocomposite using the effective particle concept – A parametric study using numerical and analytical continuum approaches

The elastic constants are calculated for a layered-silicate/polymer nanocomposite with intercalated morphology using the effective particle concept. Two continuum approaches are employed and compared: a 2D numerical strategy using the finite element method (FEM) and Monte-Carlo simulation of the morphology, and an analytical approach based on the orientation averaged Mori-Tanaka method.The particular contribution of this paper is to study systematically the concept of the effective particle, as an aid to more efficient FEM modelling, or more accurate analytical modelling of elastic constants for layered-silicate nanocomposites, with different degrees of intercalation. In particular, it is shown that the concept is successful, provided that full anisotropy of the effective particle is acknowledged. It is also demonstrated that the effect of anisotropy is particularly pronounced, when transverse or shear response of the nanocomposite is considered, even for fully aligned reinforcement. If the effective particles become misaligned, this effect diminishes (for transverse and shear properties), especially for fully random orientations of particles. Finally, it is shown that the effect of anisotropy is also pronounced, when the gallery material is softer than the surrounding polymer.     

Student Participation,Faculty Involvement,and Costs in the NGV Challenge — A Large-Scale Automotive Design Project

Large-scale automotive design projects offer an outstanding opportunity for students to obtain practical experience in engineering design. This paper reports a survey of faculty advisors for student teams participating in the Natural Gas Vehicle Challenge. About fifteen students were typically involved in the project at each university participating in the competition. Five or six were typically “key” to the project. Usually faculty advisors had a research interest in automotive engineering or alternate fuels, and they often incorporated the project into a design course. Although the funding level for such a design project varied substantially, the typical funding level was about $25,000, most of which came from local sponsors. Faculty advisors often commented on the educational value of the project and their satisfaction in working closely with students.     

A New Approach to In‐Situ “Micromanufacturing”: Microfluidic Fabrication of Magnetic and Fluorescent Chains Using Chitosan Microparticles as Building Blocks

An in situ microfluidic assembly approach is described that can both produce microsized building blocks and assemble them into complex multiparticle configurations in the same microfluidic device. The building blocks are microparticles of the biopolymer chitosan, which is intentionally selected because its chemistry allows for simultaneous intraparticle and interparticle linking. Monodisperse chitosan‐bearing droplets are created by shearing off a chitosan solution at a microfluidic T‐junction with a stream of hexadecane containing a nonionic detergent. These droplets are then interfacially crosslinked into stable microparticles by a downstream flow of glutaraldehyde (GA). The functional properties of these robust microparticles can be easily varied by introducing various payloads, such as magnetic nanoparticles and/or fluorescent dyes, into the chitosan solution. The on‐chip connection of such individual particles into well‐defined microchains is demonstrated using GA again as the chemical “glue” and microchannel confinement as the spatial template. Chain flexibility can be tuned by adjusting the crosslinking conditions: both rigid chains and semiflexible chains are created. Additionally, the arrangement of particles within a chain can also be controlled, for example, to generate chains with alternating fluorescent and nonfluorescent microparticles. Such microassembled chains could find applications as microfluidic mixers, delivery vehicles, microscale sensors, or miniature biomimetic robots.     

Improved recovery of admissible stress in domain decomposition methods — application to heterogeneous structures and new error bounds for FETI‐DP

This paper investigates the question of the building of admissible stress field in a substructured context. More precisely, we analyze the special role played by multiple points. This study leads to (1) an improved recovery of the stress field, (2) an opportunity to minimize the estimator in the case of heterogeneous structures (in the parallel and sequential case), and (3) a procedure to build admissible fields for dual‐primal finite element tearing and interconnecting and balancing domain decomposition by constraints methods leading to an error bound that separates the contributions of the solver and of the discretization. Copyright © 2016 John Wiley & Sons, Ltd.