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1.
Jatropha curcas L. has recently been hailed as the promising feedstock for biodiesel production as it does not compete with food sources. Conventional production of biodiesel from J. curcas L. seeds involve two main processing steps; extraction of oil and subsequent esterification/transesterification to fatty acid methyl esters (FAME). In this study, the feasibility of in situ extraction, esterification and transesterification of J. curcas L. seeds to biodiesel was investigated. It was found that the size of the seed and reaction period effect the yield of FAME and amount of oil extracted significantly. Using seed with size less than 0.355 mm and n-hexane as co-solvent with the following reaction conditions; reaction temperature of 60 °C, reaction period of 24 h, methanol to seed ratio of 7.5 ml/g and 15 wt% of H2SO4, the oil extraction efficiency and FAME yield can reached 91.2% and 99.8%, respectively. This single step of reactive extraction process therefore can be a potential route for biodiesel production that reduces processing steps and cost. 相似文献
2.
Low quality rice bran with high free fatty acid content was utilized to produce fatty acid ethyl ester (FAEE) via in situ method. The effects of extraction solvent, acid and alkaline catalysts on the yield rate, esterification rate and transesterification rate were studied. About 12% (wFAEE/wrice-bran) of FAEE was obtained when absolute ethanol was used as solvent to extract rice bran oil. The esterification rate and transesterification rate reached 98% and 83%, respectively. With the aid of petroleum ether, the yield rate of FAEE could be improved to 16% (wFAEE/wrice-bran), and the esterification rate and transesterification rate reached 99% and 86%. Hydrophobic CaCO3 nanorods were also synthesized as value-added byproduct. Based on the proposed method, the production process of FAEE could be simplified and the production cost could be reduced. 相似文献
3.
Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production 总被引:4,自引:0,他引:4
In order to study solid base catalyst for biodiesel production with environmental benignity, transesterification of edible soybean oil with refluxing methanol was carried out in the presence of calcium oxide (CaO), -hydroxide (Ca(OH)2), or -carbonate (CaCO3). At 1 h of reaction time, yield of FAME was 93% for CaO, 12% for Ca(OH)2, and 0% for CaCO3. Under the same reacting condition, sodium hydroxide with the homogeneous catalysis brought about the complete conversion into FAME. Also, CaO was used for the further tests transesterifying waste cooking oil (WCO) with acid value of 5.1 mg-KOH/g. The yield of FAME was above 99% at 2 h of reaction time, but a portion of catalyst changed into calcium soap by reacting with free fatty acids included in WCO at initial stage of the transesterification. Owing to the neutralizing reaction of the catalyst, concentration of calcium in FAME increased from 187 ppm to 3065 ppm. By processing WCO at reflux of methanol in the presence of cation-exchange resin, only the free fatty acids could be converted into FAME. The transesterification of the processed WCO with acid value of 0.3 mg-KOH/g resulted in the production of FAME including calcium of 565 ppm. 相似文献
4.
Biodiesel is a renewable and environmentally friendly liquid fuel. However, the feedstock, predominantly crop oil, is a limited and expensive food resource which prevents large scale application of biodiesel. Development of non-food feedstocks are therefore, needed to fully utilize biodiesel’s potential. In this study, the larvae of a high fat containing insect, black soldier fly (Hermetiaillucens) (BSFL), was evaluated for biodiesel production. Specifically, the BSFL was grown on organic wastes for 10 days and used for crude fat extraction by petroleum ether. The extracted crude fat was then converted into biodiesel by acid-catalyzed (1% H2SO4) esterification and alkaline-catalyzed (0.8% NaOH) transesterification, resulting in 35.5 g, 57.8 g and 91.4 g of biodiesel being produced from 1000 BSFL growing on 1 kg of cattle manure, pig manure and chicken manure, respectively. The major ester components of the resulting biodiesel were lauric acid methyl ester (35.5%), oleinic acid methyl ester (23.6%) and palmitic acid methyl ester (14.8%). Fuel properties of the BSFL fat-based biodiesel, such as density (885 kg/m3), viscosity (5.8 mm2/s), ester content (97.2%), flash point (123 °C), and cetane number (53) were comparable to those of rapeseed-oil-based biodiesel. These results demonstrated that the organic waste-grown BSFL could be a feasible non-food feedstock for biodiesel production. 相似文献
5.
Reduction of high content of free fatty acid in sludge palm oil via acid catalyst for biodiesel production 总被引:1,自引:0,他引:1
Adeeb HayyanMd. Zahangir Alam Mohamed E.S. MirghaniNassereldeen A. Kabbashi Noor Irma Nazashida Mohd HakimiYosri Mohd Siran Shawaluddin Tahiruddin 《Fuel Processing Technology》2011,92(5):920-924
In this study, sulphuric acid (H2SO4) was used in the pretreatment of sludge palm oil for biodiesel production by an esterification process, followed by the basic catalyzed transesterification process. The purpose of the pretreatment process was to reduce the free fatty acids (FFA) content from high content FFA (> 23%) of sludge palm oil (SPO) to a minimum level for biodiesel production (> 2%). An acid catalyzed esterification process was carried out to evaluate the low content of FFA in the treated SPO with the effects of other parameters such as molar ratio of methanol to SPO (6:1-14:1), temperature (40-80 °C), reaction time (30-120 min) and stirrer speed (200-800 rpm). The results showed that the FFA of SPO was reduced from 23.2% to less than 2% FFA using 0.75% wt/wt of sulphuric acid with the molar ratio of methanol to oil of 8:1 for 60 min reaction time at 60 °C. The results on the transesterification with esterified SPO showed that the yield (ester) of biodiesel was 83.72% with the process conditions of molar ratio of methanol to SPO 10:1, reaction temperature 60 °C, reaction time 60 min, stirrer speed 400 rpm and KOH 1% (wt/wt). The biodiesel produced from the SPO was favorable as compared to the EN 14214 and ASTM D 6751 standard. 相似文献
6.
Surachai JansriSukritthira B. Ratanawilai Michael L. AllenGumpon Prateepchaikul 《Fuel Processing Technology》2011,92(8):1543-1548
The production of biodiesel from high free fatty acid mixed crude palm oil using a two-stage process was investigated. The kinetics of the reactions was determined in a batch reactor at various reaction temperatures. It was found that the optimum conditions for reducing high free fatty acid (FFA) in MCPO (8-12 wt.%/wt oil) using esterification was a 10:1 molar ratio of methanol to FFA and using 10 wt.%/wt of sulfuric acid (based on FFA) as catalyst. The subsequent transesterification reaction to convert triglycerides to the methyl ester was found to be optimal using 6:1 molar ratio of methanol to the triglyceride (TG) in MCPO and using 0.6 wt.%/volTG sodium hydroxide as catalyst. Both reactions were carried out in a stirred batch reactor over a period of 20 min at 55, 60 and 65 °C. The concentration of compounds in each sample was analyzed by Thin Layer Chromatography/Flame Ionization Detector (TLC/FID), Karl Fischer, and titration techniques. The results were used for calculating the rate coefficients by using the curve-fitting tool of MATLAB. Optimal reaction rate coefficients for the forward and reverse esterification reactions of FFA were 1.340 and 0.682 l mol−1 min−1, respectively. The corresponding optimal transesterification, rate coefficients for the forward reactions of TG, diglyceride (DG), and monoglyceride (MG) of transesterification were 2.600, 1.186, and 2.303 l mol−1 min−1, and for the reverse reactions were 0.248, 0.227, and 0.022 l mol−1 min−1, respectively. 相似文献
7.
FAME Production and Fatty Acid Profiles from Moist Chlorella sp. and Nannochloropsis oculata Biomass
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Rui C. M. Alves Sobrinho Laércio Vauchinski Renata Rodrigues de Moura Ednei G. Primel Paulo C. V. Abreu Marcelo G. Montes D’Oca 《Journal of the American Oil Chemists' Society》2015,92(3):423-430
In the present study, we investigated the production of fatty acid methyl esters (FAME) from moist Chlorella sp. and Nannochloropsis oculata biomass using a hydrolysis–esterification process. Additionally, we evaluated for the first time the fatty acid profile before and after this process. Hydrolysis of the lipid fraction was performed on a moist biomass in the presence of differing amounts of an acid catalyst in both 50 and 100 % w/w water relative to the biomass. The esterification of the crude extracts of the free fatty acids (FFA) was then investigated. The experiments show that in the presence of 50 % w/w water relative to the biomass, the hydrolysis–esterification process results in higher FFA and FAME yields. The analysis of the fatty ester profiles did not reveal any degradation of the FFA from the microalgae biomass under the hydrolysis–esterification conditions. The results were compared with both extraction–transesterification and direct transesterification processes using dry biomass. The extraction–transesterification and hydrolysis–esterification processes resulted in similar FAME yields and similar profiles of the fatty esters from dry and moist biomass materials, respectively. 相似文献
8.
The production of ethyl esters of fatty acids from a feed material of crude palm oil (CPO) with a high free fatty acid (FFA) content under microwave assistance has been investigated. Parametric studies have been carried out to investigate the optimum conditions for the esterification process (amount of ethanol, amount of catalyst, reaction time, and microwave power). As a result, a molar ratio of FFA to ethanol of 1:24 with 4% wt./wt. of H2SO4/FFA, a microwave power of 70 W, and a reaction time of 60 min have been identified as optimum reaction parameters for the esterification process aided by microwave heating. At the end of the esterification process, the amount of FFA had been reduced from 7.5 wt.% to less than 2 wt.%. Similar results were obtained following conventional heating at 70 °C, but only after a reaction time of 240 min. Transesterification of the esterified palm oil has been accomplished with a molar ratio of CPO to ethanol of 1:4, 1.5 wt.% KOH as a catalyst, a microwave power of 70 W, and a reaction time of 5 min. This two-step esterification and transesterification process provided a yield of 80 wt.% with an ester content of 97.4 wt.%. The final ethyl ester product met with the specifications stipulated by ASTM D6751-02. 相似文献
9.
Rod-like CaxSiOx + 2 catalysts were synthesized by using one-pot hydrothermal method. Catalysts calcined at 550 °C were used in the transesterification reaction of soybean oil with methanol. Under methanol reflux condition, FAME yields of 82% and 95% were achieved on Ca4SiO6 in a reaction time of 1 and 2 h, separately. Also, the FAME yields on different CaxSiOx + 2 catalysts were correlated with their basic properties. Besides, a FAME yield of ca. 80% can be achieved under room temperature over Ca4SiO6 catalyst. 相似文献
10.
Ji-Yeon Park Jin-Suk Lee Zhong-Ming Wang Deog-Keun Kim 《Korean Journal of Chemical Engineering》2010,27(6):1791-1795
The feasibility of the production of biodiesel from trap grease containing 51.5% free fatty acids (FFAs) was investigated.
The esterification of FFAs by an acid catalyst followed by the transesterification of triglycerides by an alkali catalyst
was examined. The esterification of trap grease by sulfuric acid as a homogeneous catalyst or by Amberlyst-15 as a heterogeneous
catalyst was optimized through a response surface methodology. After the two-step esterification of trap grease by sulfuric
acid, the acid value decreased from 102.9 mg KOH/g to 2.75 mg KOH/g. Through the transesterification by potassium hydroxide,
fatty acid methyl ester (FAME) content reached 92.4%. Following the esterification of trap grease by Amberlyst-15, the acid
value decreased to 3.23 mg KOH/g. With the transesterification by potassium hydroxide, FAME content increased to 94.1%. After
the distillation of the produced biodiesel, FAME content increased again, to 97.6%. The oxidation stability of the trap grease
biodiesel was 0.17 h, and its cold filter plugging point was 4 °C. As the FAME content of the trap grease biodiesel satisfies
the Korean Biodiesel Standard, the trap grease biodiesel seems to be applicable for use as an engine fuel after properties
improvement. 相似文献
11.
The present study reports the results of kinetics study of acid base catalyzed two step transesterification process of waste cooking oil, carried out at pre-determined optimum temperature of 65 °C and 50 °C for esterification and transesterification process respectively under the optimum condition of methanol to oil ratio of 3:7 (v/v), catalyst concentration 1%(w/w) for H2SO4 and NaOH and 400 rpm of stirring. The optimum temperature was determined based on the yield of ME at different temperature. Simply, the optimum concentration of H2SO4 and NaOH was determined with respect to ME Yield. The results indicated that both esterification and transesterification reaction are of first order rate reaction with reaction rate constant of 0.0031 min− 1 and 0.0078 min− 1 respectively showing that the former is a slower process than the later. The maximum yield of 21.50% of ME during esterification and 90.6% from transesterification of pretreated WCO has been obtained. This is the first study of its kind which deals with simplified kinetics of two step acid-base catalyzed transesterification process carried under the above optimum conditions and took about 6 h for complete conversion of TG to ME with least amount of activation energy. Also various parameters related to experiments are optimized with respect to ME yield. 相似文献
12.
Kusum (Schleichera triguga), a non-edible oil bearing plant has been used as an ideal feedstock for biodiesel development in the present study. Various physical and chemical parameters of the raw oil and the fatty acid methyl esters derived have been tested to confirm its suitability as a biodiesel fuel. The fatty acid component of the oil was tested by gas chromatography. The acid value of the oil was determined by titration and was found to 21.30 mg KOH/g which required two step transesterification. Acid value was brought down by esterification using sulfuric acid (H2SO4) as a catalyst. Thereafter, alkaline transesterification was carried out using potassium hydroxide (KOH) as catalyst for conversion of kusum oil to its methyl esters. Various parameters such as molar ratio, amount of catalyst and reaction time were optimized and a high yield (95%) of biodiesel was achieved. The high conversion of the feedstock into esters was confirmed by analysis of the product on gas chromatograph-mass spectrometer (GC-MS). Viscosity and acid value of the product biodiesel were determined and found to be within the limits of ASTM D 6751 specifications. Elemental analysis of biodiesel showed presence of carbon, hydrogen, oxygen and absence of nitrogen and sulfur after purification. Molar ratio of methanol to oil was optimized and found to be 10:1 for acid esterification, and 8:1 for alkaline transesterification. The amounts of H2SO4 and KOH, 1% (v/v) and 0.7% (w/w), respectively, were found to be optimum for the reactions. The time duration of 1 h for acid esterification followed by another 1 h for alkaline transesterification at 50 ± 0.5 °C was optimum for synthesis of biodiesel. 相似文献
13.
Zanthoxylum bungeanum seed oil (ZSO) with high free fatty acids (FFA) can be used for biodiesel production by ferric sulfate-catalyzed esterification followed by transesterification using calcium oxide (CaO) as an alkaline catalyst. Acid value of ZSO with high FFA can be reduced to less than 2 mg KOH/g by one-step esterification with methanol-to-FFA molar ratio 40.91:1, ferric sulfate 9.75% (based on the weight of FFA), reaction temperature 95 °C and reaction time 2 h, which satisfies transesterification using an alkaline catalyst. The response surface methodology (RSM) was used to optimize the conditions for ZSO biodiesel production using CaO as a catalyst. A quadratic polynomial equation was obtained for biodiesel conversion by multiple regression analysis and verification experiments confirmed the validity of the predicted model. The optimum combination for transesterification was methanol-to-oil molar ratio 11.69:1, catalyst amount 2.52%, and reaction time 2.45 h. At this optimum condition, the conversion to biodiesel reached above 96%. This study provided a practical method to biodiesel production from raw feedstocks with high FFA with high reaction rate, less corrosion, less toxicity, and less environmental problems. 相似文献
14.
Ana Rita RodriguesAlexandre Paiva Marco Gomes da SilvaPedro Simões Susana Barreiros 《The Journal of Supercritical Fluids》2011,56(3):259-264
A continuous process for biodiesel production in supercritical carbon dioxide was implemented. In the transesterification of virgin sunflower oil with methanol, Lipozyme TL IM led to fatty acid methyl esters yields (FAME) that exceeded 98% at 20 MPa and 40 °C, for a residence time of 20 s and an oil to methanol molar ratio of 1:24. Even for moderate reaction conversions, a fractionation stage based on two separators afforded FAME with >96% purity. Lipozyme TL IM was less efficient with waste cooking sunflower oil. In this case, a combination of Lipozyme TL IM and Novozym 435 afforded FAME yields nearing 99%. 相似文献
15.
This paper describes the effect of important reaction variables on the production of biodiesel from non-edible microalgae lipids, using the acid-catalysed in situ transesterification process. The specific gravity of the biodiesel product was used to monitor the conversion progress. The results indicate that increasing the reacting alcohol volume and the temperature lead to improved fatty acid methyl ester (FAME) conversions. With the exception of in situ transesterification carried out at room temperature (23 °C), the equilibrium FAME conversions appear to approach asymptotic limits for reaction times greater than 8 h for all temperatures investigated. Stirring the reaction vessel had a significant positive influence on the rate of biodiesel formation. Increasing the moisture content of the microalgae biomass had a strong negative influence on the equilibrium FAME yield, and in situ transesterification was inhibited when the biomass water content was greater than 115% w/w (based on oil weight). 相似文献
16.
M.A. Olutoye 《Fuel Processing Technology》2010,91(6):653-659
The Mg-Zn interaction effect of KyMg1 − xZn1 + xO3 heterogeneous type catalyst and its performance on transesterification of palm oil have been studied using the response surface methodology and the factorial design of experiments. The catalyst was synthesized using the co-precipitation method and the activity was assessed by transesterification of palm oil into fatty acid methyl esters. The ratio of the Mg/Zn metal interaction, temperature and time of calcination were found to have positive influence on the conversion of palm oil to fatty acid methyl ester (FAME) with the effect of metal to metal ratio and temperature of calcination being more significant. The catalytic activity was found to decrease at higher calcination temperature and the catalyst type K2Mg0.34Zn1.66O3 with Mg/Zn ratio of 4.81 gave FAME content of 73% at a catalyst loading of 1.404 wt.% of oil with molar ratio of methanol to oil being 6:1 at temperature of 150 °C in 6 h. A regression model was obtained to predict conversions to methyl esters as a function of metal interaction ratio, temperature of calcination and time. The observed activity of the synthesized catalyst was due to its synergetic structure and composition. 相似文献
17.
Comprehensive utilization of the mixture of oil sediments (OS) and soapstock (SS) for producing FAME and phosphatides was investigated. A process consisting of three steps was employed for obtaining high conversion and by-product. In the first step, the OS–SS mixture was extracted with ethyl ether and the mixture was divided into three phases. The organic top phase contained triglycerides and phosphatides was extracted with cooled acetone and the acetone insoluble (phosphatides) was obtained. At the same time, triglycerides were separated also. In the second step, soap phase was then acidified with sulfuric acid to yield fatty acid. This “high-acid” acid oil was efficiently converted to methyl esters by acid-catalyzed esterification. The esterification reaction has been carried out with 5:1 methanol/oil (mol/mol) in the presence 3% H2S04 (wt.%) as an acid catalyst at 85 °C for 5 h. FAME recovery under these conditions was 92.1% of theoretical. In the third step, alkaline catalyzed transesterification process converts the triglycerides to its mono-esters and glycerol. The optimized variables, 6:1 methanol/oil (mol/mol) with 1% NaOH (wt.%) reacted at 65 °C for 1 h, giving a maximum ester yield of 94%. Five important fuel properties of FAME from the OS–SS mixture were found to be comparable to those of No. 2 diesel fuel and conforming to both the American and German standards for biodiesel. 相似文献
18.
Yong Wang Shun Ma Lili Wang Shuze Tang William W. Riley Martin J. T. Reaney 《European Journal of Lipid Science and Technology》2012,114(3):315-324
The free fatty acids (FFAs) of waste cooking oil (WCO) are readily esterified with crude glycerol in the presence of the solid superacid SO/ZrO2–Al2O3. This reaction lowers the acidity of WCO before biodiesel production. The solid superacid SO/ZrO2–Al2O3 catalyzes both FFA esterification and TAG glycerolysis during the reaction. The conversion of FFA in the WCO with an acid value of 88.4 ± 0.5 mg KOH/g to acylglycerols was 98.4% under optimal conditions (mole ratio of glycerol to FFA = 1.4:1; reaction time = 4 h; reaction temperature = 200°C; catalyst loading = 0.3 wt%) obtained through an orthogonal experiment. The final FAME product with a FAME content of 96.9 ± 0.3 wt% yield was 94.8 wt%, after transesterification of the esterified WCO with methanol, catalyzed by potassium hydroxide. The FAME composition of the products produced by transesterification were identified and quantified by GC–MS. The results suggest that this new glycerol esterification process, using a solid superacid catalyst, affords a promising method to convert oils with high FFA levels, like WCO, to biodiesel. The process has the inherent advantage of easy separation steps for removing excess alcohol and significant savings in energy, when compared to acid catalyzed reactions with methanol to lower acidity. Practical applications : In this work, WCO with a high acid value was esterified with crude glycerol catalyzed by solid super acid, whose formula was expressed as SO/ZrO2–Al2O3. There are distinct advantages to this new esterification process, which include easy separation of the excess crude glycerol by sedimentation or centrifugation, the use of the low cost reactant crude glycerol direct from the byproducts of transesterification, the potential to achieve a very low content of FFAs by post‐refining to improve the yield of the final product, and time and energy saving are found as compared to the traditional methanol esterification process. This new technology provides a promising alternative method for processing feedstocks of high acid value, such as WCO, for the production of biodiesel. 相似文献
19.
In this paper response surface methodology (RSM) was used to study the transesterification reaction of rapeseed oil for biodiesel production. The three main factors that drive the conversion of triglycerides into fatty acid methyl esters (FAME) were studied according to a full factorial design at two levels. These factors were catalyst concentration (KOH), temperature and reaction time. The range investigated for each factor was selected taking into account the process of Fox Petroli S.p.A. Analysis of variance (ANOVA) was used to determine the significance of the factors and their interactions which primarily affect the first of the two transesterification stages. This analysis evidenced the best operating conditions of the first transesterification reaction performed at Fox’s plant: KOH concentration 0.6% w/w, temperature 50 °C and reaction time 90 min with a CH3OH to KOH ratio equal to 60. Three empirical models were derived to correlate the experimental results, suitable to predict the behavior of triglyceride, diglyceride and monoglyceride concentration. These models showed a good agreement with the experimental results, demonstrating that this methodology may be useful for industrial process optimization. 相似文献
20.
Ozan Nazim CiftciFeral Temelli 《The Journal of Supercritical Fluids》2011,58(1):79-87
Continuous production of fatty acid methyl esters (FAMEs) from corn oil was studied in a supercritical carbon dioxide (SC-CO2) bioreactor using immobilized lipase (Novozym 435) as catalyst. Response surface methodology (RSM) based on central composite rotatable design (CCRD) was employed to investigate and optimize the reaction conditions: pressure (11-35 MPa), temperature (35-63 °C), substrate mole ratio (methanol:corn oil 1-9) and CO2 flow rate (0.4-3.6 L/min, measured at ambient conditions). Increasing the substrate mole ratio increased the FAME content, whereas increasing pressure decreased the FAME content. Higher conversions were obtained at higher and lower temperatures and CO2 flow rates compared to moderate temperatures and CO2 flow rates. The optimal reaction conditions generated from the predictive model for the maximum FAME content were 19.4 MPa, 62.9 °C, 7.03 substrate mole ratio and 0.72 L/min CO2 flow rate. The optimum predicted FAME content was 98.9% compared to an actual value of 93.3 ± 1.1% (w/w). The SC-CO2 bioreactor packed with immobilized lipase shows great potential for biodiesel production. 相似文献