共查询到19条相似文献,搜索用时 109 毫秒
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丙烯酸型F-44光敏酚醛环氧树脂的合成 总被引:4,自引:1,他引:3
以溴化四丁基铵作催化剂,用丙烯酸改性F-44环氧树脂,合成了一种既含有丙烯酸基又含有环氧基的光敏酚醛环氧树脂。研究了丙烯酸基的引入量对树脂光学性能、力学性能等的影响。结果表明,当改性树脂中的丙烯酸基与环氧基之比等于1:1时,所制得的树脂具有优良的光化学活性,用改性树脂制成的漆膜具有优良的力学性能、耐溶剂性能和耐酸碱性能。 相似文献
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用月桂酸对醇酸树脂进行 性,。制得含羟基的浅色醇酸树酯。由该改性树脂同异氰酸酯组份配制的涂料,其干性,等各项性能均较好,讨论了各种合成因素对树脂及涂膜性能的影响。 相似文献
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《国际聚合物材料杂志》2012,61(1):11-19
An intercrosslinked network of varying percentages of N,N′-bismaleimido-4,4′-disphenyl methane (BMI), vinyl ester oligomer (VEO) modified unsaturated polyester (UP) matrices have been developed. Vinyl ester oligomer was prepared by reacting commercially available epoxy resin GY 250 (Ciba-Geigy) and acrylic acid was used as toughening agent for unsaturated polyester resin. BMI-VEO-UP matrices were characterized for their mechanical properties, viz tensile strength, flexural strength and unntoched Izod impact test as per ASTM standards. The dielectric strength and water absorption measurements were also performed according to ASTM standards. Data obtained from mechanical studies, dielectric strength and water absorption indicate that the introduction of VEO into unsaturated polyester resin improves mechanical properties and affects the moisture resistance according to its percentage concentration. The incorporation of BMI into the VEO modified unsaturated polyester system improves mechanical properties, dielectric strength and resistance to moisture absorption according to its percentage concentration. 相似文献
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Interpenetrating networks of varying percentages of bismaleimide (BMI) in vinyl ester oligomer (VEO) modified unsaturated polyester (UP) matrices have been developed. Vinyl ester oligomer was prepared by reacting commercially available epoxy resin GY 250 (Ciba‐Geigy) and acrylic acid, and used as a toughening agent for unsaturated polyester resin. Unsaturated polyesters modified with 10, 20, and 30 wt % vinyl ester oligomer were made. The VEO toughened unsaturated polyester matrix systems, further modified with 5, 10, and 15 wt % bismaleimide (BMI). BMI–VEO–UP matrices were characterized using differential scanning calorimetry, thermogravimetric analysis, and heat deflection temperature analysis. The matrices, in the form of castings, were characterized for their mechanical properties according to ASTM methods: tensile strength, flexural strength, and unnotched Izod impact test. Data obtained from mechanical studies and thermal characterization indicate that the introduction of VEO and BMI into unsaturated polyester resin improves thermomechanical properties according to their percentage concentration. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2502–2508, 2002 相似文献
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Block copolymers of unsaturated polyester were prepared by condensation polymerization of hydroxyl or carboxyl terminated liquid rubbers with maleic anhydride, phthalic anhydride, and propylene glycol. The condensate obtained was mixed with styrene monomer to get an unsaturated polyester resin formulation. In this study, copolymers of unsaturated polyesters with hydroxy terminated polybutadiene, carboxy terminated nitrile rubber, and hydroxy terminated natural rubber were prepared. Mechanical properties such as tensile strength, tensile modulus, elongation at break, toughness, impact strength, surface hardness, abrasion resistance, and water absorption were evaluated after the resin was cured in appropriate molds for comparison with the control resin. The fracture toughness and impact resistance of CTBN‐modified unsaturated polyester show substantial improvement by this copolymerization without seriously affecting any other property. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1956–1964, 2004 相似文献
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以高羟值弹性聚酯和羟基丙烯酸树脂混拼为基体树脂,金红石钛白粉为颜料,硅铝基陶瓷空心微珠为填料,纳米ATO和纳米SiO2为改性材料,在助剂和溶剂的配合下制备成甲组分,以HDI三聚体N-3390为乙组分,配制高速列车车厢面漆。经检测,该面漆各项性能指标均达到设计要求。 相似文献
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巴士客车用丙烯酸聚氨酯罩光清漆的制备 总被引:5,自引:0,他引:5
介绍了以聚酯树脂和特种助剂对罩光清漆进行改性,制得了适合巴士客车使用的丙烯酸聚氨酯罩光清漆。分析了聚酯树脂和特种助剂对罩光清漆的丰满度、抗划伤性能、流平性和施工性能的影响。结果表明当选用高固含、高羟基聚酯树脂对丙烯酸树脂进行改性时,涂料具有较好的丰满度和抗划伤性能;当流平剂选用丙烯酸类和有机硅类搭配使用时,可大大提高罩光清漆的流平性能;当触变剂BYK-410的用量为0.3%时,清漆一次涂装干膜60μm不流挂,当DBE慢干剂用量为2%时,涂料具有好的施工性能。 相似文献
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Ernesto L. Rodriguez 《Polymer Engineering and Science》1993,33(2):115-121
A general-purpose unsaturated polyester resin with 2:1 mol ratio of styrene to polyester unsaturation was modified with three vinyl monomers and two hydroxyl terminated polybutadienes. Tensile, flexural, and puncture impact properties were examined. The three acrylate monomers were tetraethylene glycol dimethylacrylate, 1,3 butylene glycol dimethacrylate, and trimethylpropane trimethylacrylate with weight percents of 2.5, 5, 15, and 30. Two hydroxyl terminated polybutadienes with slightly different contents of hydroxyl functionality were also employed in the weight percents of 2.5, 5.0, and 10.0. Results showed that an increase in the number of crosslinks and crosslink density resulted in a deterioration in the mechanical properties. The addition of an immiscible polybutadiene polymer to the polyester resin also showed a decrease in the mechanical performance of the resulting thermoset materials. 相似文献
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采用双环戊二烯改性不饱和聚酯树脂,使得不饱和聚酯树脂具有很多独特的优异性能。主要介绍以双环戊二烯与顺丁烯二酸酐合成双环戊二烯马来酸单酯为基础,经进一步扩链(加入多元醇酯化)之后得到不饱和聚酯树脂的合成过程。剖析了生产设备、生产工艺流程。 相似文献