平板感应加热磁-热耦合场的数值模拟研究

针对～种双线圈平板感应加热装置,利用ANSYS有限元分析软件对其感应加热过程中的磁—热耦合场分布进行数值模拟,通过对交变磁场产生涡流的分析,得到不同频率下平板各点温度随时间变化的分布图,以及整个加热过程中的温升特点.结果表明,这种双线圈平板感应加热装置对平板感应加热的温升速度有很大的提高,从而对平板的快速感应加热工艺的运用与改进具有一定的指导意义.     

铁磁壳层纳米颗粒周围局域电场的研究

研究了在外加磁场的影响下,铁磁流体溶液中壳层纳米颗粒周围局域电场的分布.其中,壳层结构的铁磁纳米颗粒是由磁性纳米颗粒(钴)核与贵金属(金)壳组成.该结构将金属的光学性质和颗粒的磁场驱动效应有效地结合起来.在外加磁场的影响下,复合铁磁颗粒将会沿着外加磁场的方向排列,形成磁纳米链.磁纳米链中复合颗粒在外加磁场的影响下发生极化,导致颗粒之间产生相互作用.通过解拉普拉斯方程,可以得到复合颗粒周围局域电场的表达式.计算结果表明,壳层颗粒周围的局域电场与金属壳层厚度、复合颗粒之间的距离以及颗粒中心连线的夹角有密切关系.     

一种弱磁作用下铁磁物体感应磁场的计算方法

铁磁物体感应磁场的数值计算研究在舰艇消磁等领域具有重要的应用价值.针对弱磁作用下铁磁物体感应磁场计算的问题,根据均匀磁化体的特点,建立了基于单元表面积分的铁磁物体感应磁场模型.为了解决工程中铁磁物体磁化率难以确定的困难,从弱磁作用下铁磁物体的磁化特点出发,利用磁场垂直分量测最值建立了以单元磁化率为未知量的数学模型,并运用寻优能力强、速度快、易于求解多维优化问题的微粒群算法对磁化率数学模型进行了优化求解,进而用单元表面磁场积分法解算了铁磁物体的感应磁场.通过钢板计算实例中磁场测昔值和计算值的比较,表明该方法计算精度较高,能够较好地反映弱磁作用下铁磁物体的感应磁场分布,有一定工程实用价值.     

石油钻进中平行水平井垂直距离测定方法研究

针对蒸汽辅助重力泄油(SAGD)中注气井和产油井垂直距离的测距问题,提出了通过磁通门感应旋转磁信标中产生的交变磁场来进行垂直距离测距.并利用磁通门三轴感应输出值来计算2井眼之间的垂直距离,使注汽井和产油井的井眼轨迹保持在一定的范围内.由于钻具铁磁性材料会对距离测量产生误差,用当地磁场来对干扰磁场进行距离测量的校正,实验测量表明,该校正方法能在磁性材料干扰的环境下获得准确的垂直距离,具有简单、有效、实用的特征.     

低频交变场磁模型实验方法

以低频交变磁场模拟地磁场,用可塑性高阻磁性材料作成磁性体模型,观测交变磁场激发下磁模型体产生的交变二次磁场。     

磁流体力学及磁流体的工程应用

简要介绍磁流体的一般性质、研究方法及研究现状．讨论磁流体的粘度、导热系数等物理特性及其在磁场作用下的变化规律．综述了磁流体力学的研究方法及磁流体流动时的控制方程组．给出磁流体在磁场方向与管轴一致的直管内流动时的流动方程．并举例介绍了磁流体在电子、机械、冶金、化工、动力、医疗等方面的应用开发及应用前景，指出磁流体在这些领域内应用有其他物质无法相比的优越性．     

平板式感应加热线圈磁场的分布特性

平板式感应加热加热死区的存在,使其不能广泛应用于工业领域.为了研究它的工业应用的潜力,文中对感应加热的核心部件——线圈进行了深入研究.依据经典电磁场理论,研究了线圈的磁场分布特性,先对圆环电流进行研究,计算它的磁场分布,进而对饼式线圈的磁场分布特型进行有限元计算,并与实验采集数据对比后,总结出饼式线圈的磁场分布特性.此特性表明,采用饼式线圈的平板感应加热,板上必然会出现加热死区.因此加热均衡性的实现需要对整个装置进行全方位的改进.以上结论可为平板式感应加热的后续研究提供参考.     

磁流体力学及磁流体的工程应用

简要介绍磁流体的一般性质，研究方法及研究现状。讨论磁流体的粘度、导热系数等物理特性及其在磁场作用下的变化规律，综述了磁流体力学的研究方法及磁流体流动时的控制方程组，给出磁流体在磁场方向与管轴一致的直管内流动时的流动方程，并举例介绍了磁流体在电子、机械、冶金、化工、动力、医疗等方面的应用开发及应用前景，指出磁流体在这些领域内应用有其他物质无法相比的优越性。     

沉淀氧化法制备Fe3O4磁流体

采用沉淀氧化法制备了四氧化三铁磁流体,通过外加磁场对磁流体进行磁性能测试,并用XRD衍射、红外检测对制得的磁流体进行检测分析.     

磁流体的非均匀分布对磁感应热疗温度场的影响

温度场分布的均匀性决定了磁流体热疗的治疗效果,温度场的分布特性与磁场分布和磁流体分布密切相关.针对实际亥姆霍兹线圈产生的非均匀分布磁场情况,在多点注射策略的基础上,进一步探究磁流体非均匀分布对温度场的影响,为磁流体热疗的临床应用提供理论依据.以磁流体热疗过程中生物组织内的温度场分布为研究对象,以最大化肿瘤组织内温度达到...     

Surface Modfication of Fe3O4 Nanoparticles

Nanometer particles are important portion of magnetic fluid. Fe3O4 magnetic nanoparticles were studied in this paper and the surface modification of Fe3O4 nanoparticles was investigated by a series of experiments. Fe3O4 magnetic nanoparticles were synthesized with pH value, temperature, and the dosage of surfactant. The phase, structure, size and magnetism of nanoparticles were tested by X-ray diffration （XRD）, transmission electron microscopy （TEM） and magnetic balance. On the basis of the surface modification coating mechanism, the experimental phenomena and the effects on the variation of size, magnetism and stability of Fe3O4 nanoparticles were theoretically analyzed. X-Ray diffraction spectrum and TEM photograph show that 1） the nanoparticles structure is perfect, 2） the diameter of narnoparticles is small and have good deliquescence, and 3） Sodium oleate is the anion surfactant. Therefore 1） the good condition of surface modification is in an acidic solution, 2） the best temperature of surface modification is at 80 ℃, and 3） the dosage of surfactant should be about 0.6 times of that of Fe^2＋.     

磁场作用下锰锌铁氧磁流体承载能力试验研究

通过对MS-800四球试验机油杯的改进,在测试区域内产生可调磁场;利用改进后的油杯在四球机上测定磁场作用下添加锰锌铁氧纳米磁性颗粒润滑油的承载能力.结果表明：外加磁场作用下,磁性液体的摩擦学性能得到较大改善,首先磁性液体黏度值随磁场强度的增强而增大,从而提高了添加锰锌铁氧体磁性颗粒润滑油的综合磨损值,最大可达基础液的1.43倍;其次纳米磁性颗粒中的Zn元素可使润滑油的最大无卡绞负荷PB值提高50%,烧结负荷PD值提高100%.     

PREPARATION AND MAGNETORHEOLOGICAL PROPERTIES OF AQUEOUS SUSPENSION BASED ON EMULSION DROPLETS CONTAINING Fe_3O_4 NANOPARTICLES

The Fe3O4 nanoparticles with mean size of 10 nm were prepared by chemical common precipitation . The factors influencing the size and shape of Fe3O4 nanoparticles such as the adding rate of NaOII to the mixed solution and the final pH of the solution were studied . The Fe3O4 based magnetorheological(MR) fluid was formed by adding surfactant . The rheological properties of this MR fluid were studied when the magnetic fields with different direction are applied. It has been found that the MR fluid has the magnetic anisotropy.     

纳米Fe_3O_4类酶催化Na_2S_2O_8氧化降解对硝基酚

采用超声辅助反向共沉淀法制备了高活性的Fe3O4磁性纳米颗粒（Fe3O4MNPs）.采用XRD,FT-IR和Raman等仪器对Fe3O4MNPs的组成、结构进行了表征和研究.以Fe3O4MNPs为类酶催化剂,Na2S2O8为氧化剂,在室温25℃的条件下,降解对硝基酚的优化条件为：10 mg.L-1对硝基酚溶液,在pH=3.8,Fe3O4MNPs用量为0.9 g.L-1,Na2S2O8用量为6.3 mmol.L-1时,无需超声、紫外光照和Gamma辐射的条件下,30 min后其降解率达到97%以上.     

Modification of Fe3O4 Magnetic Nanoparticles by L-dopa or Dopamine as an Enzyme Support

Fe3O4 magnetic nanoparticles were prepared by co-precipitation of Fe2+ and Fe3+ in an ammonia solution,and its size was about 36 am measured by an atomic force microscope.Fe3O4 magnetic nanopanicles were modified by L-dopa or dopamine using sonication method.The analysis of FTIR clearly indicated the formation of Fe-O-C bond.Direct immobilization of trypsin(EC:3.4.21.4)on Fe3O4 magnetic nanoparticles with L-dopa and dopamine spacer was investigated using glutaraldehyde as a coupling agent.No significant changes in the size and magnetic property of the three kinds of magnetic nanoparticles linked with or without trypsin were observed.The existence of the spacer molecule on magnetic nanoparticles could greatly improve the activity and the storage stability of bound trypsin through increasing the flexibility of enzyme and changing the microenvironment on nanoparticles surface compared to the naked magnetic nanoparticles.     

CHARACTERIZATION OF MANGANESE PHTHALOCYANINE-Fe_3O_4 NANOPARTICLE COMPOSITE AND ITS ELECTROMAGNETORHEOLOGICAL FLUID

Manganese phthalocyanine (MnPc)-Fe3O4 nanoparticles composite was prepared and characterized. The results show that MnPc are completed on the surface of Fe3O4 nanoparticles in the state of single molecule. There is effective composite between MnPc and Fe3O4 nanoparticles which can improve the antioxidization ability of Fe3O4 nanoparticles greatly. The composite was dispersed into chlorinated paraffin oil to form electromag-netorheological (EMR) fluid with high activity, and the EMR properties of this EMR fluid are studied.     

磁场对Fe3O4⁃水纳米流体传热特性的影响

对电加热器中纳米流体的传热效果进行了实验研究,采用两步法制备Fe3O4⁃水纳米流体。此外,还研究了质量分数为0.1%~2.0%的Fe3O4⁃水纳米流体在有/无磁场作用下对电加热器换热效率的影响,探讨了磁场作用下纳米流体的强化换热机理。结果表明,与基液（去离子水）相比,无磁场时质量分数为1.0%的Fe3O4⁃水纳米流体可使环境温度提升18.2%;在外磁场作用下,质量分数为1.0%的Fe3O4⁃水纳米流体可使环境温度提升35.1%。研究结果可为纳米流体在电加热器中的强化传热研究提供重要参考。     

Surface Organic Modification of Fe3O4 Magnetic Nanoparticles

The surface organic modification of Fe3O4 nanoparticles with silane coupling reagent KH570 was studied.The modified and unmodified nanoparticles were characterized by FT-IR,XPS and TEM.The spectra of FT-IR and XPS revealed that KH570 was coated onto the surface of Fe3O4 nanoparticles to get Fe-O-Si bond and an organic coating layer also was formed.Fe3O4 nanoparticles were spheres partly with mean size of 18.8 nm studied by TEM,which was consistent with the result 17.9 nm calculated by Scherrer'S equation.KH570 was adsorbed on surface and formed chemistry bond to be steric hindrance repulsion which prevented nanoparticles from reuniting.Then glycol-based Fe3O4 magnetic liquids dispersed stably was gained.     

纳米Fe_3O_4粒子的制备及表面包覆

采用化学共沉淀法和氧化沉淀法制备磁性纳米Fe3O4粒子,并用柠檬酸三钠为表面活性剂包覆制备纳米Fe3O4粒子,同时利用包覆磁性粒子制备水基纳米磁性液体。对两种方法制备的纳米Fe3O4粒子的晶体结构、微观形貌及化学共沉淀法制备的Fe3O4在包覆前后等电点的变化进行了表征。结果表明,化学共沉淀法制备的纳米Fe3O4粒子平均粒径约为20 nm且分布比较均匀,表面活性剂包覆后,等电点由原来的pH=6.70移向pH=2.35,证实了Fe3O4粒子表面被柠檬酸离子所包覆,且制得的磁性液体的稳定性比较高;而氧化沉淀法制备Fe3O4纳米粒子粒径分布是从几十纳米到上百纳米,制得的磁性液体出现很明显的团聚。     

Mg、Cu 掺杂对锰锌铁氧体居里温度的影响研究

采用水热合成法(180℃、10h),选择不同元素掺杂制备出不同的锰锌铁氧体纳米磁粉Mn(1-x)ZnxFe2O4、MnxZnyMg(1-x-y)Fe2O4和MnxZnyCu(1-x-y)Fe2O4.通过XRD、SEM、EDS图谱对其进行分析表征,并用古埃磁天平法测量其居里温度Tc.结果表明,掺杂Mg、Cu元素后,会使锰锌铁氧体的居里温度下降,特别是掺杂Cu元素时,居里温度的下降更加明显,Mn0.3Zn0.4Cu0.3Fe2O4的居里温度Tc已达到49℃.