Interfacial evaluation of carbon fiber/epoxy composites using electrical resistance measurements at room and a cryogenic temperature

Interfacial properties between fiber and matrix were evaluated using an electrical resistance (ER) fragmentation method. The single carbon fiber (CF) tensile test was performed in conjunction with electrical resistance measurements. The relationship between tensile properties of single carbon fiber specimens and the electrical resistance ratio (ERR) was investigated. The data showed a linear relationship between these properties. Fragmentation specimens were tested under tensile loading, and it was observed that, due to stress transfer from the matrix to the reinforcing fiber, the single carbon fiber broke first. The stress distribution along the carbon fiber was monitored via electrical resistance changes. ER fragmentation measurements were performed to predict CF fractured strength embedded in epoxy by an empirical formula of CF tensile results. These interfacial properties of CF epoxy composites were measured at room and a cryogenic temperature. Work of adhesion between the carbon fiber and the matrix was measured to verify the results of the ER fragmentation method, and the two procedures yielded consistent results and conclusions.     

Electrical and mechanical characterization of stretchable multi-walled carbon nanotubes/polydimethylsiloxane elastomeric composite conductors

Stretchable, elastomeric composite conductor made of multi-walled carbon nanotubes (MWNTs) and polydimethylsiloxane (PDMS) has been fabricated by simple mixing. Electrical percolation threshold, amount of filler at which a sharp decrease of resistance occurs, has been determined to be ∼0.6 wt.% of MWNTs. The percolation threshold composition has also been confirmed from swelling experiments of the composite; the equilibrium swelling ratio slightly increases up to ∼0.6 wt.%, then decreases at higher amount of filler MWNTs. Upon cyclic stretching/release of the composite, a fully reversible electrical behavior has been observed for composites having filler content below the percolation threshold value. On the other hand, hysteretic behavior was observed for higher filler amount than the threshold value, due to rearrangement of percolative paths upon the first cycle of stretching/release. Finally, mechanical moduli of the composites have been measured and compared by buckling and microtensile test. The buckling-based measurement has led to systematically higher (∼20%) value of moduli than those from microtensile measurement, due to the internal microstructure of the composite. The elastic conductor may help the implementation of various stretchable electronic devices.     

Mechanical characterization of hierarchical carbon fiber/nanofiber composite laminates

Susceptibility to matrix driven failure is one of the major weaknesses of continuous-fiber composites. In this study, helical-ribbon carbon nanofibers (CNF) were dispersed in the matrix phase of a continuous carbon fiber-reinforced composite. Along with an unreinforced control, the resulting hierarchical composites were tested to failure in several modes of quasi-static testing designed to assess matrix-dominated mechanical properties and fracture characteristics. Results indicated CNF addition offered simultaneous increases in tensile stiffness, strength and toughness while also enhancing both compressive and flexural strengths. Short-beam strength testing resulted in no apparent improvement while the fracture energy required for the onset of mode I interlaminar delamination was enhanced by 35%. Extrinsic toughening mechanisms, e.g., intralaminar fiber bridging and trans-ply cracking, significantly affected steady-state crack propagation values. Scanning electron microscopy of delaminated fracture surfaces revealed improved primary fiber–matrix adhesion and indications of CNF-induced matrix toughening.     

Review of the mechanical properties of carbon nanofiber/polymer composites

In this paper, the mechanical properties of vapor grown carbon nanofiber (VGCNF)/polymer composites are reviewed. The paper starts with the structural and intrinsic mechanical properties of VGCNFs. Then the major factors (filler dispersion and distribution, filler aspect ratio, adhesion and interface between filler and polymer matrix) affecting the mechanical properties of VGCNF/polymer composites are presented. After that, VGCNF/polymer composite mechanical properties are discussed in terms of nanofibers dispersion and alignment, adhesion between the nanofiber and polymer matrix, and other factors. The influence of processing methods and processing conditions on the properties of VGCNF/polymer composite is also considered. At the end, the possible future challenges for VGCNF and VGCNF/polymer composites are highlighted.     

The effect of pin reinforcement upon the through-thickness compressive strength of foam-cored sandwich panels

Titanium and carbon fibre pins have been inserted into the polymethacrylimide foam core of a sandwich panel (with carbon fibre face sheets) in order to increase the through-thickness strength. The elevation in compressive strength has been measured both quasi-statically and dynamically using a direct Kolsky bar, and the sensitivity of strength to the relative density and thickness of foam have been determined. An X-ray CAT scan machine was used to examine the deformed shape of the pins during interrupted compression testing of the sandwich specimens. It was found that the foam core stabilises the pins against elastic buckling, and the pin-reinforced core has a strength and energy absorption capacity in excess of the individual contributions from the foam and unsupported pins. It is shown that the compressive strength is governed by elastic buckling of the pins, with the foam core behaving as an elastic Winkler foundation in supporting the pins. The peak strength of the pin-reinforced core is increased by a factor of about four when the speed of loading is increased from the quasi-static rate of about 10⁻⁶ ms⁻¹ to the dynamic value of 10 ms⁻¹; it is concluded that the micro-inertia of the pins stabilises them against elastic buckling and leads to the observed elevation in strength.     

Mechanical and electrical properties of carbon fiber composites with incorporation of graphene nanoplatelets at the fiber–matrix interphase

In this study, carbon fibers (CFs) were coated with graphene nanoplatelets (GnP), using a robust and continuous coating process. CFs were directly immersed in a stable GnP suspension and the coating conditions were optimized in order to obtain a high density of homogeneously and well-dispersed GnP. GnP coated CFs/epoxy composites were manufactured by a prepreg and lay-up method, and the mechanical properties and electrical conductivity of the composites were assessed. The GnP coated CFs/epoxy composites showed 52%, 7%, and 19% of increase in comparison with non-coated CFs/epoxy composites, for 90° flexural strength, 0° flexural strength and interlaminar shear strength, respectively. Meanwhile, incorporating GnP in the CF/epoxy interphase significantly improved the electrical conductivity through the thickness direction by creating a conductive path between the fibers.     

Sea-water effects on foam-cored composite sandwich lay-ups

This article concerns the effects of sea-water on foam cored composite sandwich structures under long-term exposure. Special attention is focused on sea-water induced damage in foam materials, weight gains and expansional strains, as well as on possible degradation in the properties of foam materials due to such extended exposure. In addition, sea-water effects on the fracture behavior of foam materials and on face/core interfacial debonding fracture are investigated experimentally and interpreted by means of computational fracture mechanics.     

Micromechanical deformations in PP/lignocellulosic filler composites: Effect of matrix properties

Polypropylene composites were prepared from three different PP matrices, a homopolymer, a random and a heterophase copolymer, and corn cob to study the effect of matrix characteristics on deformation and failure. The components were homogenized in an internal mixer and compression molded to 1 mm thick plates. Mechanical properties were characterized by tensile testing, while micromechanical deformations by acoustic emission measurements and fractography. The results proved that the dominating micromechanical deformation process may change with matrix properties. Yield stress determined from the stress vs. strain traces may cover widely differing processes. Debonding is the dominating process when the adhesion of the components is poor, while matrix yielding and/or filler fracture dominate when adhesion is improved by the introduction of a functionalized polymer. The dominating deformation mechanism is determined by component properties and adhesion. Interfacial adhesion, matrix yield stress and the inherent strength of the reinforcement can be limiting factors in the improvement of composite strength. The properties of polymer composites reinforced with lignocellulosic fillers are determined by micromechanical deformation processes, but they are independent of the mechanism of these processes.