Micro-infiltration of three-dimensional porous networks with carbon nanotube-based nanocomposite for material design

Epoxy composite beams reinforced with a complex three-dimensional (3D) skeleton structure of nanocomposite microfibers were fabricated via micro-infiltration of 3D porous microfluidic networks with carbon nanotube nanocomposites. The effectiveness of this manufacturing approach to design composites microstructures was systematically studied by using different epoxy resins. The temperature-dependent mechanical properties of these multifunctional beams showed different features which cannot be obtained for those of their individual components bulks. The microfibers 3D pattern was adapted to offer better performance under flexural solicitation by the positioning most of the reinforcing microfibers at higher stress regions. This led to an increase of 49% in flexural modulus of a reinforced-epoxy beam in comparison to that of the epoxy bulk. The flexibility of this method enables the utilization of different thermosetting materials and nanofillers in order to design multifunctional composites for a wide variety of applications such as structural composites and components for micro-electromechanical systems.     

Thermal and mechanical properties of phenolic-based composites reinforced by carbon fibres and multiwall carbon nanotubes

The thermal, mechanical and ablation properties of carbon fibre/phenolic composites filled with multiwall carbon nanotubes (MWCNTs) were investigated. Carbon fibre/phenolic/MWCNTs were prepared using different weight percentage of MWCNTs by compression moulding. The samples were characterized by scanning electron microscopy (SEM), flexural tests, thermal gravimetric analysis and oxyacetylene torch tests. The thermal stability and flexural properties of the nanocomposites increased by increasing MWCNTs content (wt% ⩽1), but they decreased when the content of MWCNTs was 2 wt%. The linear and mass ablation rates of the nanocomposites after modified with 1 wt% MWCNTs decreased by about 80% and 52%, respectively. To investigate the material post-test microstructure, a morphological characterization was carried out using SEM. It was shown that the presence of MWCNTs in the composite led to the formation of a strong network char layer without any cracks or opening.     

High performance polyimide composite films prepared by homogeneity reinforcement of electrospun nanofibers

Highly aligned polyimide (PI) and PI nanocomposite fibers containing carbon nanotubes (CNTs) were produced by electrospinning. Scanning electron microscopy showed the electrospun nanofibers were uniform and almost free of defects. Transmission electron microscopy indicated that the CNTs were finely dispersed and highly oriented along the CNT/PI nanofiber axis at a relatively low concentration. The as-prepared well-aligned electrospun nanofibers were then directly used as homogeneity reinforcement to enhance the tensile strength and toughness of PI films. The neat PI nanofiber reinforced PI films showed good transparency, decreased bulk density and significantly improved mechanical properties. Compared with neat PI film prepared by solution casting, the tensile strength and elongation at break for the PI film reinforced with 2 wt.% CNT/PI nanofibers were remarkably increased by 138% and 104%, respectively. The significant increases in the overall mechanical properties of the nanofibers reinforced polyimide films can be ascribed to good compatibility between the electrospun nanofibers and the matrix as well as high nanofiber orientation in the matrix. Our study demonstrates a good example for fabricating high performance and high toughness polyimide nanocomposites by using this facile homogeneity self-reinforcement method.     

Optical and mechanical anisotropies of aligned electrospun nanofibers reinforced transparent PMMA nanocomposites

This study aims to assess the nanofiber directionality effects on optomechanical properties of a widely used transparent thermoplastic poly(methyl methacrylate) (PMMA). Aligned fiber-hybrid mats consisted of nylon-6 (PA-6) nanofibers and PMMA microfibers are prepared using a self-blending co-electrospinning method, followed by hot press molding to fabricate into transparent nanocomposites. Effects of nanofiber orientation degree in two orthogonal directions and loading fraction on the optomechanical behavior of the nanocomposites are examined. Optical transmittance differences parallel and perpendicular to the nanofibers’ orientation are found to vary in a range of 3.9–5.4% at 589 nm, and strong mechanical anisotropy is observed with the 1% PA-6/PMMA nanocomposites. A maximal of 3% PA-6 nanofiber loading maintains the nanocomposite high transmittance (>75%) with improved strength and toughness along the nanofiber axis. This study reveals evident anisotropic optomechanical properties of transparent nanocomposites, and highlights the great designability of transparent nanocomposites by using aligned nanofibers as the designing elements.     

Thermal buckling and postbuckling behavior of functionally graded carbon nanotube-reinforced composite plates

Thermal buckling and postbuckling behavior is presented for functionally graded nanocomposite plates reinforced by single-walled carbon nanotubes (SWCNTs) subjected to in-plane temperature variation. The material properties of SWCNTs are assumed to be temperature-dependent and are obtained from molecular dynamics simulations. The material properties of functionally graded carbon nanotube-reinforced composites (FG-CNTRCs) are assumed to be graded in the thickness direction, and are estimated through a micromechanical model. Based on the multi-scale approach, numerical illustrations are carried out for perfect and imperfect, geometrically mid-plane symmetric FG-CNTRC plates and uniformly distributed CNTRC plates under different values of the nanotube volume fractions. The results show that the buckling temperature as well as thermal postbuckling strength of the plate can be increased as a result of a functionally graded reinforcement. It is found that in some cases the CNTRC plate with intermediate nanotube volume fraction does not have intermediate buckling temperature and initial thermal postbuckling strength.     

Preparation and thermal properties of soluble poly(phthalazinone ether sulfone ketone) composites reinforced with multi-walled carbon nanotube buckypaper

A nanocomposite with soluble high-performance poly(phthalazinone ether sulfone ketone) (PPESK) as matrix and multi-walled carbon nanotube buckypaper (MWCNT-BP) as reinforcement was fabricated by hot-press processing. The morphologies, dynamic and static mechanical behavior, thermal stability of the MWCNT-BP/PPESK composites were studied using scanning electron microscope (SEM), dynamic mechanical analyzer (DMA) and thermogravimetric analyzer (TGA). SEM microphotographs revealed a high impregnation degree of the MWCNT-BP/PPESK composites. Dynamic and static mechanical analysis revealed that the nanocomposites possessed high storage modulus, and good retention rate of mechanical strength even at 250 °C, which is mainly attributed to satisfied impregnation and strong interactions between MWCNT-BP and PPESK. Thermogravimetric analysis exhibited that the nanocomposites had excellent thermal stability. These investigations confirm that MWCNT-BP can be effectively used to manufacture high-loading CNT/PPESK composites with improved properties.     

Nonlinear electro-mechanical responses of functionally graded piezoelectric beams

This study presents analyses of the nonlinear electro-mechanical responses of functionally graded piezoelectric beams undergoing small deformation gradients. The studied functionally graded beams comprise of electro-active and inactive constituents with gradual compositions varying through the thickness of the beams. Two types nonlinear electro-mechanical responses are considered for the active constituents, which are nonlinear electro-mechanical behaviors for the polarized piezoelectric constituent under electric fields smaller than the coercive limit, and polarization switching responses due to cyclic electric fields with high amplitude. The inactive constituent is modeled with uncoupled linear electro-elastic response. The functionally graded beam is discretized into several graded layers through its thickness. Each layer is comprised of different compositions of the active (piezoelectric) inclusions and conductive matrix. A particle-unit-cell micromechanical model is used to obtain the nonlinear electro-mechanical responses in each layer and is integrated within the laminate theory in order to obtain the overall nonlinear electro-mechanical responses of the functionally graded piezoelectric beams. The numerical predictions are compared with experimental data available in literature. Parametric studies are then performed in order to examine the effects of the thickness of the beam, of the concentration of the constituent, and the frequency of the cyclic electric field on the overall electro-mechanical response of the functionally graded piezoelectric beams.     

Surface coating on carbon nanofibers with alumina precursor by different synthesis routes

Alumina-reinforced carbon nanofiber nanocomposites were prepared using different routes; powders mixture, colloidal route and sol-gel process followed by spark plasma sintering (SPS). CNFs/xAl₂O₃ (x = 10-50 vol.%) were prepared through nanopowders mixing in a high-energy attrition milling. The main limitations in the preparation of this kind of nanocomposites are related to the difficulty in obtaining materials with a homogeneous distribution of both phases and the different chemical nature of CNFs and Al₂O₃, which causes poor interaction between them. A surface coating of CNFs by wet chemical routes with an alumina precursor is proposed as a very effective way to improve the interaction between CNFs and Al₂O₃. An improvement of 50% in fracture strength was found for similar nanocomposite compositions when the surface coating was used. The improved mechanical properties of these nanocomposites are caused by stronger interaction between the CNFs and Al₂O₃.     

Improving the mechanical properties of multiwalled carbon nanotube/epoxy nanocomposites using polymerization in a stirring plasma system

Uniform treatment of multiwalled carbon nanotubes by plasma treatment has been investigated using a custom-built stirring plasma system. A thin plasma polymer with high levels of amine groups has been deposited on MWCNTs using a combination of continuous wave and pulsed plasma polymerization of heptylamine in the stirring plasma system. Scanning electron microscopy showed that the plasma polymerization improved the dispersion and interfacial bonding of the MWCNTs with an epoxy resin at loadings of 0.1, 0.3 and 0.5 wt%. The flexural and thermal mechanical properties of plasma polymerized MWCNT/epoxy nanocomposites were also significantly improved while untreated MWCNT/epoxy nanocomposites showed an opposite trend. The epoxy with 0.5 wt% plasma polymerized MWCNTs had the greatest increase in flexural properties, with the flexural modulus, flexural strength and toughness increasing by about 22%, 17% and 70%, respectively.     

Experimental and numerical investigations of low velocity impact on functionally graded circular plates

This paper addresses low-velocity impact behaviour of functionally graded clamped circular plates. An experimental work was carried out to investigate the impact behaviour of FG circular plates which is composed of ceramic (SiC) and metal (Al) phases varying through the plate thickness by using a drop-weight impact test system. The influence of the compositional gradient exponent and impactor velocity on the contact forces and absorbed energies was concentrated on the tests. The explicit finite element method, in which a volume fraction based elastic–plastic model (the TTO model) was implemented for the functionally graded materials, was used to simulate their drop-weight impact tests. Effective material properties at any point inside FGM plates were determined using Mori–Tanaka scheme. The experimental and numerical results indicated that the compositional gradient exponent and impactor velocity more effective on the elasto-plastic response of the FG circular plates to a low-velocity impact loading. The comparison at the theoretical and experimental results showed that the use of the TTO model in modelling the elasto-plastic behaviour of FG circular plates results in increasing deviations between the numerical and experimental contact forces for ceramic-rich compositions whereas it becomes more successful for metal-rich compositions.     

Effect of fabrication process on electrical properties of polymer/multi-wall carbon nanotube nanocomposites

Polymer/carbon nanotubes nanocomposites were fabricated by an in situ polymerization process using multi-wall carbon nanotubes (MWNT) as filler in an epoxy polymer. Effects of curing process, mixing speed, mixing time, addition of ethanol, timing of hardener addition, etc., in the fabrication process on the electrical properties of nanocomposites have been investigated. In the fabrication process, the effective formation of macroscopic conducting network in matrix is most important to enhance the electrical properties of nanocomposites. It was found that the curing temperature and the mixing conditions are key factors in the fabrication process, which influence the formation of conducting network significantly. Therefore, careful design of these factors in the fabrication process is required to achieve high electrical performances of nanocomposites. The experimental percolation threshold of the resultant nanocomposites was around 0.1 wt%. Moreover, a statistical percolation model was built up to numerically investigate the percolation threshold. The experimental electrical conductivity increases from the percolation threshold following a percolation-like power law with the identified critical exponent t as 1.75.     

Nonlinear free vibration of functionally graded carbon nanotube-reinforced composite beams

This paper investigates the nonlinear free vibration of functionally graded nanocomposite beams reinforced by single-walled carbon nanotubes (SWCNTs) based on Timoshenko beam theory and von Kármán geometric nonlinearity. The material properties of functionally graded carbon nanotube-reinforced composites (FG-CNTRCs) are assumed to be graded in the thickness direction and estimated though the rule of mixture. The Ritz method is employed to derive the governing eigenvalue equation which is then solved by a direct iterative method to obtain the nonlinear vibration frequencies of FG-CNTRC beams with different end supports. A detailed parametric study is conducted to study the influences of nanotube volume fraction, vibration amplitude, slenderness ratio and end supports on the nonlinear free vibration characteristics of FG-CNTRC beams. The results for uniformly distributed carbon nanotube-reinforced composite (UD-CNTRC) beams are also provided for comparison. Numerical results are presented in both tabular and graphical forms to investigate the effects of nanotube volume fraction, vibration amplitude, slenderness ratio, end supports and CNT distribution on the nonlinear free vibration characteristics of FG-CNTRC beams.     

A quantitative study of the morphology of montmorillonite filled thermosets based on a tailor made homogenisation model

Thermoset/montmorillonite nanocomposites were fabricated and their elastic modulus was measured using experimental modal analysis. The morphology of the nanocomposite was considered as a distribution of several components: exfoliated clay platelets, intercalated clay layers, primary particles and clay agglomerates. A novel homogenisation model, which involves a five-phase sequence based on the Halpin–Tsai equations, was developed to calculate the elastic modulus of the nanocomposites. This model was then used to quantify the morphology of the nanocomposites by back calculating the exfoliation, intercalation and agglomeration fractions from the measured values of the elastic modulus. Additionally, this approach led to quantify the efficiency of the fabrication process, which proved to be optimal for 2.5% clay content.     

Effect of coupling agent on mechanical properties of hollow carbon microsphere/phenolic resin syntactic foam

Various hollow carbon microspheres/phenolic resin syntactic foams were prepared by varying the content of hollow carbon microspheres. To improve the compressive and flexural strength and fracture toughness of syntactic foam, the hollow carbon microspheres were oxidized in nitric acid and followed by the treatment with a coupling agent of glutaric dialdehyde. Compression, flexural, and fracture toughness tests were performed to observe the mechanical behavior of the foams. Results demonstrated that compressive and flexural strength decrease with increasing filler content. On the other hand, it is found that better interfacial adhesion could be induced from coupling agent treated hollow carbon microspheres, hence resulted in better mechanical properties. The fracture toughness results revealed that the use of coupling agent increases the fracture toughness and the maximum fracture toughness values occurred at 28.12 vol.% for both untreated and coupling agent treated hollow carbon microspheres. The toughening mechanisms, such as crack deflection, crack bowing, and debonding mechanism, were discussed.     

Interfacial properties and self-sensing of single carbon fiber reinforced CNT-phenolic nanocomposites using electro-micromechanical and wettability tests

Interfacial and other properties along with self-sensing were investigated for single carbon fiber/neat phenolic resins and carbon nanotube (CNT)-phenolic nanocomposites by electro-micromechanical and wettability tests. The apparent modulus was higher for samples with a single carbon fiber in CNT-phenolic nanocomposite than for samples with a single carbon fiber in neat phenolic resin, indicating better stress transfer. In water droplet contact angle measurements the contact angle increased form slightly less than 90° on neat phenolic resin to more than 90° on CNT-phenolic nanocomposites. This behavior was attributed to hydrophobic domains randomly distributed on the surface as a result of the heterogeneous microstructure of CNT. The work of adhesion between a single carbon fiber and CNT-phenolic nanocomposites was greater than for neat phenolic resin which is attributed to an increase in viscosity by adding CNT. Micro-failure patterns and interfacial adhesion between CNT-phenolic nanocomposites and single carbon fibers were consistent with these other results.     

Novel toughened polylactic acid nanocomposite: Mechanical,thermal and morphological properties

The objective of the study is to develop a novel toughened polylactic acid (PLA) nanocomposite. The effects of linear low density polyethylene (LLDPE) and organophilic modified montmorillonite (MMT) on mechanical, thermal and morphological properties of PLA were investigated. LLDPE toughened PLA nanocomposites consisting of PLA/LLDPE blends, of composition 100/0 and 90/10 with MMT content of 2 phr and 4 phr were prepared. The Young’s and flexural modulus improved with increasing content of MMT indicating that MMT is effective in increasing stiffness of LLDPE toughened PLA nanocomposite even at low content. LLDPE improved the impact strength of PLA nanocomposites with a sacrifice of tensile and flexural strength. The tensile and flexural strength also decreased with increasing content of MMT in PLA/LLDPE nanocomposites. The impact strength and elongation at break of LLDPE toughened PLA nanocomposites also declined steadily with increasing loadings of MMT. The crystallization temperature and glass transition temperature dropped gradually while the thermal stability of PLA improved with addition of MMT in PLA/LLDPE nanocomposites. The storage modulus of PLA/LLDPE nanocomposites below glass transition temperature increased with increasing content of MMT. X-ray diffraction and transmission electron microscope studies revealed that an intercalated LLDPE toughened PLA nanocomposite was successfully prepared at 2 phr MMT content.     

Design analysis of three-layered structural composites based on post-consumer recycled plastics and wood residues

Three-layered structural composites were produced from municipal plastic wastes and wood flour residues to investigate the effects of design parameters on their flexural and impact performance. The studied parameters include wood content, thickness of individual composite layers, as well as stacking sequence and configuration (symmetric and asymmetric structures). The results indicate that the core layer has a lower influence on the flexural properties of structural beams in comparison with the skins. But depending on beam configuration (stacking sequence), different flexural characteristics can be obtained using the same composite layers. The classical beam theory was used to predict the flexural modulus with high precision. In addition, performance of the beams under impact tests was shown to be independent from their stacking sequences and layer thicknesses for each configuration.     

Thermo-mechanical vibration analysis of sandwich beams with functionally graded carbon nanotube-reinforced composite face sheets based on a higher-order shear deformation beam theory

This article proposes a higher-order shear deformation beam theory for free vibration analysis of functionally graded carbon nanotube-reinforced composite sandwich beams in a thermal environment. The temperature-dependent material properties of functionally graded carbon nanotube-reinforced composite beams are supposed to vary continuously in the thickness direction and are estimated through the rule of mixture. The governing equations and boundary conditions are derived by using Hamilton's principle, and the Navier solution procedure is used to achieve the natural frequencies of the sandwich beam in a thermal environment. A parametric study is led to carry out the effects of carbon nanotube volume fractions, slenderness ratio, and core-to-face sheet thickness ratio on free vibration behavior of sandwich beams with functionally graded carbon nanotube-reinforced composite face sheets. Numerical results are also presented in order to compare the behavior of sandwich beams including uniformly distributed carbon nanotube-reinforced composite face sheets to those including functionally graded carbon nanotube-reinforced composite face sheets.     

Synthesis and characterization of biodegradable poly(l-lactide)/layered double hydroxide nanocomposites

This study reports the preparation and physical properties of biodegradable nanocomposites fabricated using poly(l-lactide) (PLLA) and magnesium/aluminum layered double hydroxide (MgAl-LDH). The MgAl-LDH with molar ratio of Mg/Al = 2 were synthesized by the co-precipitation method. In order to improve the chemical compatibility between PLLA and LDH, the surface of LDH was organically-modified by polylactide with carboxyl end group (PLA–COOH) using ion-exchange process. Then, the PLLA/LDH nanocomposites were prepared by solution intercalation of PLLA into the galleries of PLA–COOH modified LDH (P-LDH) in tetrahydrofuran solution. Both X-ray diffraction data and Transmission electron microscopy images of PLLA/P-LDH nanocomposites indicate that the P-LDHs are randomly dispersed and exfoliated into the PLLA matrix. Mechanical properties of the fabricated 1.2 wt.% PLLA/P-LDH nanocomposites show significant enhancements in the storage modulus when compared to that of neat PLLA. Adding more P-LDH into PLLA matrix induced a decrease in the storage modulus of PLLA/P-LDH nanocomposites, probably due to the excessive content of PLA–COOH moleculars with low mechanical properties. The thermal stability and degradation activation energies of the PLLA and PLLA/P-LDH nanocomposites can also be discussed.     

Effect of surfactant treatment on thermal stability and mechanical properties of CNT/polybenzoxazine nanocomposites

The mechanical and thermo-mechanical properties of polybenzoxazine nanocomposites containing multi-walled carbon nanotubes (MWCNTs) functionalized with surfactant are studied. The results are specifically compared with the corresponding properties of epoxy-based nanocomposites. The CNTs bring about significant improvements in flexural strength, flexural modulus, storage modulus and glass transition temperature, T_g, of CNT/polybenzoxazine nanocomposites at the expense of impact fracture toughness. The surfactant treatment has a beneficial effect on the improvement of these properties, except the impact toughness, through enhanced CNT dispersion and interfacial interaction. The former four properties are in general higher for the CNT/polybenzoxazine nanocomposites than the epoxy counterparts, and vice versa for the impact toughness. The addition of CNTs has an ameliorating effect of lowering the coefficient of thermal expansion (CTE) of polybenzoxazine nanocomposites in both the regions below and above T_g, whereas the reverse is true for the epoxy nanocomposites. This observation has a particular implication of exploiting the CNT/polybenzoxazine nanocomposites in applications requiring low shrinkage and accurate dimensional control.