煤矸石混凝土抗氯离子渗透实验研究

为了解煤矸石混凝土抗氯离子渗透性能,以自燃煤矸石为粗、细集料,42.5普通硅酸盐水泥为胶凝材料并掺入粉煤灰,制备煤矸石混凝土试件,进行抗氯离子渗透实验,研究了水胶比、粉煤灰掺量以及抗压强度对煤矸石混凝土抗氯离子渗透性能的影响。结果表明：非稳态条件下煤矸石混凝土氯离子渗透深度随水胶比增加而加深,呈正相关,氯离子渗透深度增长速度在水胶比0.42~0.48时较快,在水胶比0.48~0.56时缓慢;氯离子迁移系数与水胶比呈正相关,与粉煤灰掺量呈负相关;氯离子迁移系数随抗压强度增大而减小,呈负相关,负相关显著性强弱表现为粉煤灰掺量0%<粉煤灰掺量20%<粉煤灰掺量40%。掺入粉煤灰可以改善煤矸石混凝土耐久性能。     

塑钢纤维增强橡胶混凝土耐硫酸盐侵蚀试验

通过研究3种水胶比、4种塑钢纤维掺量,探讨橡胶混凝土在硫酸盐干湿循环侵蚀作用下的溶液pH值变化、试件表面损伤、抗压强度耐蚀系数、质量经时损失率和相对弹性模量曲线影响,得到各因素对橡胶混凝土抗压强度耐蚀系数、质量经时损失率及相对弹性模量全曲线影响规律。试验结果表明:依次掺入橡胶集料、塑钢纤维,Ca(OH)_2溶出量减少,溶液pH值降低;150次干湿循环后,6 kg/m~3的塑钢纤维掺量对提高混凝土抗硫酸盐侵蚀强度等级非常显著,质量经时损失率最小,CRSF1-4、CRSF2-4、CRSF3-4所对应的质量经时损失率分别为2.0%、2.25%、2.97%,其相对弹性模量较基准混凝土提升6.25%、6.75%、10%,水胶比越大,塑钢纤维的增强、阻裂、抑制混凝土内部损伤劣化的能力越强。     

硫酸盐侵蚀粉煤灰混凝土的耐久性试验研究

针对盐渍土地区隧道衬砌混凝土耐久性问题,在不同质量分数硫酸盐溶液的侵蚀下,改变干湿循环次数,对粉煤灰混凝土抗硫酸盐侵蚀的耐久性进行了深入研究。结果表明:干湿循环作用下,硫酸盐溶液侵蚀粉煤灰混凝土试件,试件强度先小幅度增长,然后逐渐衰减。其中,质量分数为10%的溶液侵蚀的试件,强度增长最为明显,可达到57.5 MPa;而动弹性模量则与干湿循环次数成反比,表现出循环次数越多,相对动弹性模量越低的特征。其中,质量分数为10%的溶液侵蚀的试件,动弹性模量下降的速率最快,试件动弹性模量从339 MPa下降到235 MPa。粉煤灰混凝土的抗硫酸盐耐久性在一般盐渍土地区都可以较好的保持其强度。     

含高矿化度水地层深立井井壁高强混凝土耐久性研究

为防止穿越高矿化度水地层深立井井壁遭受腐蚀而影响安全运营,开展了硫酸盐全浸泡下井壁高强混凝土耐久性研究。通过3种不同水胶比混凝土和2种经防腐处理的混凝土在硫酸盐环境中侵蚀180 d的抗压强度、质量损失、相对动弹性模量等性能对比试验,来研究高强混凝土的性能。试验结果表明:在各侵蚀浓度下混凝土试件的抗压强度、质量与相对动弹性模量随龄期都呈现出先缓慢增长后加速减小的趋势,相对动弹性模量与抗压强度的变化趋势有着高度的相似性;水胶比越小混凝土密实性越好,硫酸根离子在混凝土内部的传输受到抑制,对混凝土的侵蚀性越小,井壁耐久性越好,水胶比为0.26的混凝土在整个侵蚀周期内抗硫酸盐侵蚀性能表现最佳;在水胶比不变的前提下,内掺防腐剂对提升混凝土抗硫酸盐侵蚀性能具有一定效果,而采用抗硫酸盐水泥的防腐措施在较高浓度硫酸盐侵蚀条件下适用性较差。本研究结果可为西北地区穿越高矿化度水地层深立井井壁混凝土配制提供参考。     

脱炭粉煤灰制备混凝土的试验研究

对经浮选脱炭后的粉煤灰进行了制备混凝土的配比试验, 研究了水胶比与粉煤灰掺量对混凝土抗折强度和抗压强度的影响, 试验结果表明, 当粉煤灰最大掺量为50%, 水胶比为0.34时, 混凝土28 d抗压强度为35.52 MPa, 达到了混凝土规定等级C30级以上, 其28 d抗折强度为4.58 MPa。     

聚合物改性煤矸石粉煤灰混凝土性能研究

为探讨聚合物对大掺量煤矸石粉煤灰混凝土性能的影响,制备不同掺量苯乙烯、191#UP和196#UP 3种聚合物改性大掺量煤矸石粉煤灰混凝土试件,进行抗压强度、抗折强度、碳化性能试验研究。结果表明,3种聚合物的加入均提升了混凝土试件抗压强度,且应控制掺加191#UP和196#UP的量在10%左右;掺加3种聚合物的混凝土试件抗折强度都有明显提高,折压比也呈增长趋势,测得掺191#UP和196#UP混凝土的韧性比掺苯乙烯的性能优越;混凝土试件的碳化深度随着聚合物掺量的增加而逐渐减小,说明聚合物可以改善混凝土的碳化性能,并且随着聚合物的增加,改善效果越明显。试验表明,适量掺入聚合物可以改善大掺量煤矸石粉煤灰混凝土的抗压强度、抗折强度及碳化性能,这为聚合物改性大掺量煤矸石粉煤灰混凝土性能的应用提供了试验依据。     

酸雨作用下钢纤维煤矸石混凝土耐久性研究

基于酸雨循环侵蚀试验,探究了在不同pH值酸雨溶液与钢纤维掺量条件下,钢纤维增强煤矸石混凝土质量、劈裂抗拉强度及碳化深度等耐久性指标的变化特性。结果表明：第1次酸雨循环时,pH值为2.0酸雨溶液中钢纤维煤矸石混凝土达到最大质量,其增加率为0.25%,随后骤降到最小质量,其质量损失率峰值2.37%;钢纤维煤矸石混凝土劈裂抗拉强度损失率与循环数呈近似线性关系,其最大损失率为21.91%;不同pH值酸溶液中钢纤维煤矸石混凝土碳化深度与酸雨循环数呈正相关,显著性表现为pH=2.0＞pH=3.0＞pH=4.0;1.0%钢纤维掺量是钢纤维煤矸石混凝土的最优掺量,可优化其空隙结构,有效抑制酸雨溶液的侵蚀。     

煤矸石掺再生骨料制备C30混凝土的试验研究

用煤矸石和建筑垃圾作为粗骨料按不同比例掺和后代替混凝土中部分碎石粗骨料,通过控制不同掺量配制混凝土试件,在相同湿度,不同温度的环境下养护,并通过3因素3水平的正交试验确定最佳配合比。测得7d、28d混凝土抗压强度,通过对强度进行极差和方差分析,探索各因素对制备混凝土抗压强度的影响。结果表明,每立方米混凝土中掺入20%的煤矸石粗骨料、20%的建筑垃圾再生粗骨料代替部分碎石粗骨料,且在20℃环境中养护,为最佳方案。为了进一步验证该配合比制备的混凝土满足耐久性要求,选取3组试件进行抗硫酸盐侵蚀对比试验,结果表明,制备混凝土试件抗压耐蚀系数大于规范规定的75%,满足要求。     

粉煤灰掺量对煤矸石骨料混凝土性能影响研究

为探讨粉煤灰作为矿物掺合料对煤矸石骨料混凝土性能的影响,在制备煤矸石骨料混凝土试件时,掺入0%、15%、25%、35%、50%的粉煤灰来取代等量的水泥,进行抗压强度、碳化性能及干燥收缩性能试验研究。结果表明,煤矸石混凝土的抗压强度随粉煤灰掺量的增加而有所降低,且均低于未掺粉煤灰时的混凝土抗压强度,但当掺量为15%时,煤矸石混凝土的90 d抗压强度超过同龄期未掺粉煤灰时的混凝土强度;当粉煤灰掺量不超过35%时,对煤矸石混凝土的碳化性能影响不大,粉煤灰掺量达到50%时,煤矸石混凝土的抗碳化能力降低明显;随粉煤灰掺量的增加,煤矸石骨料混凝土的干燥收缩性能得到改善,50%粉煤灰掺量时干燥收缩率最小。试验表明,适量掺入粉煤灰能改善煤矸石骨料混凝土的后期强度及干燥收缩性能,且对碳化性能影响不大,这为煤矸石骨料混凝土掺粉煤灰的应用提供了试验依据。     

干湿循环作用下聚丙烯纤维对混凝土力学性能影响

为研究干湿循环作用对混凝土力学性能的影响,在混凝土中分别掺入质量分数为1%、2%、3%、4%的聚丙烯纤维来改善混凝土的弹性模量、抗压强度和抗折强度等力学性能。结果表明,在相同的循环次数下,随着纤维掺量的增加,混凝土的弹性模量、抗压强度和抗折强度逐渐增加,增加速率呈现先增加而后下降的趋势;在相同的纤维掺量下,混凝土的弹性模量、抗压强度和抗折强度随着干湿循环次数的增加而逐渐降低,下降速率随着循环次数的增加而增加。聚丙烯纤维对混凝土的耐干湿循环性能有着明显提高,其最佳掺量为2%。     

Current situation and future trend of China rare earth luminescent material industry

<正>Rare earth luminescent material is one of the most important application sectors of rare earths.China enjoys the exceptional advantage to develop rare earth luminescent material for its abundant rare earth resources.After several decades'endeavor,China's rare earth luminescent material industry,headed by rare earth phosphor for lamp and LED and high efficient rare earth energy-saving light source,has been gradually developed into a scale industry.China has become a major production base of rare earth phosphor for lamps and rare earth     

China rare earth market review

正June 1~10,2014Rare earth market remained weak.Quoted price of rare earth products was similar to that in May.There was no sign of recovery in downstream market.The market of NdFeB magnetic materials and phosphor was depressed.Catalyst,polishing powder and ceramic industries remained inactive.Demand from downstream industry was soft.Consumers purchased on their needs.Suppliers had strong intention to sell.Prices of rare earth products     

Annual Report analysis of Chinese rare earth-related listed companies in 2013

<正>Chinese rare earth-related listed companies have published their 2013 annual reports.It can be understood from their reports that production and operation activities of Chinese rare earth-related companies were still heavily affected by macro economy and industrial policies.They basically followed the steps of national economy.In 2013,world economy recovered slowly but the economy     

Market opportunities and challenges for rare earth polishing powder

正1.Status of rare earth polishing powder Rare earth polishing powder with high content of cerium oxide began to replace iron oxide for glass polishing and became one of the key materials in glass polishing process since 1940.Compared with traditional iron oxide,rare earth polishing powder has many advantages,such as fast polishing rate,high polishing quality and long service life.It can achieve good surface quality and improve operation conditions.For example,in lens polishing,the polishing work that cerium     

Baotou Research Institute of Rare Earths developed a new RE alloy preparation technology

正Pyrometallurgy Laboratory of Baotou Research Institute of Rare Earths had independently developed a new preparation technology of rare earth alloy for NdFeB.The alloy can remarkably enhance the coercivity of NdFeB magnet but also evidently reduce the production cost of the magnet.The new master alloy was prepared in the kA pilot-scale electrolytic cell by the independent technology.The rare earth master alloy can be used as the raw material for NdFeB.Compared     

Market and recycling of NiMH battery

<正>Market status and future trend of NiMH battery1.Global market of small NiMH battery Global market size of small NiMH batteries declined year on year since 2011.The trend will continue to 2018,at the rate of 5%to 10%annually.Demand for small NiMH batteries will be stable gradually.Many electrical apparatuses are powered by the built-in lithium battery today,which is the main reason for the shrunk market of small NiMH batteries.But,for some products,small NiMH     

China rare earth market review

正September 1-10,2014 Affected by the National Day holiday,rare earth transaction was stagnant and the market showed a weak steady state.As there was no good news for downstream market,some products with flat demand would likely rally slightly for some time to     

2014 second batch of rare earth quota released

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矿用防爆轴流对旋主要通风机叶片ANSYS模态分析及应用

高效节能矿用防爆对旋主要通风机的叶片是主要通风机运行的关键部件,叶片在运行时不断受到气流的作用力,从而使叶片产生振动,当叶片振动的频率与叶片的固有频率接近时,容易产生共振从而导致叶片的断裂。一旦叶片断裂时,对主要通风机的安全运行产生致命的影响,从而导致矿山、化工等企业发生重大事故,将会产生不可估量的损失。基于有限元分析软件ANSYS,对高效节能矿用防爆轴流对旋主要通风机叶片进行模态分析及产生对应的六阶模态频率,对主要通风机叶片的运行频率、固有频率及产生的共振问题进行了原理分析,并且解决了叶片频率共振的问题,从而为主要通风机叶片结构设计提供理论依据,并对主要通风机叶片的安全运行提供保障。     

2013 NdFeB export analysis

<正>China totally exported nearly 24,000 tonsof NdFeB products during 201 3,including 18,825 tons of permanent magnet,valued USD 1.34 billion at an average price of 71.4 USD/kg;3,277 tons of NdFeB magnetic powder,valued USD 1 01 million at an average price of 30.9 USD/kg;1,334 tons of strip casting ribbon,with total export value of USD 74million at an average price of 55.3 USD/kg;and 586