动态填充注塑成型PP/nano-SiO2复合材料的力学性能与形貌分析

采用动态填充注塑成型(DFIM)制备了聚丙烯/二氧化硅(PP/nano-SiO2)复合材料。结果表明:与传统的注塑成型技术相比,采用DFIM法制备的PP/nano-SiO2复合材料的拉伸强度和冲击强度比纯PP材料和常规注射制备的复合材料有了较大提高;nano-SiO2通过DPIM技术可以更好地分散在PP基质中,形成的团聚较少。DFIM法制备的PP/nano-SiO2复合材料力学性能的提高,主要归因于nano-SiO2颗粒的均匀分布,使球晶的数量急剧增加,球晶的尺寸明显减小,小晶体有助于形成材料裂纹,从而进一步提高材料的力学性能。     

注塑成型导电高分子复合材料研究进展

综述了注塑成型导电高分子复合材料(CPCs)的典型微观结构,总结了提高注塑成型CPCs力学性能和电性能的方法,提出了优化工艺并进行复合材料微观结构设计是拓宽注塑成型CPCs应用领域的关键。     

聚丙烯/纳米碳纤维复合材料微孔注射成型加工与性能研究

将聚丙烯(PP)和纳米碳纤维(CNF)共混后,通过双螺杆挤出制备成不同组份的复合粒料,采用注射成型加工制备实体和发泡试样,研究不同CNF含量对PP基体复合材料性能的影响。结果表明,随着CNF含量的增加,微孔样品中的孔径显著的减小同时泡孔密度增加;注射成型的样品中,添加CNF后的模量和拉伸强度略微降低,但微孔注塑的PP/CNF复合材料的性能呈现出相反的效果。     

碳纤维增强环氧树脂复合材料的液体成型及其性能研究

本文研究了不同温度下RIM145树脂的粘度和适用期,分析了不同温度下RIM145树脂和碳纤维单丝之间的浸润性;并以碳纤维单向布为增强材料,采用真空辅助灌注成型工艺制备了碳纤维增强环氧树脂(CF/EP)复合材料,研究了复合材料的力学性能,对层间剪切试样剖断面形貌进行了SEM分析,并研究了使用VAP单向透气膜辅助真空灌注成型工艺对CF/EP复合材料厚制件灌注质量的影响。研究结果表明,RIM145树脂基体在50~70℃粘度低、适用期长且树脂与碳纤维单丝之间的浸润性良好,适用于CF/EP复合材料的真空辅助灌注成型工艺;灌注的CF/EP具有良好的力学性能,树脂和纤维具有中等粘结强度界面,采用VAP单向透气膜辅助真空辅助灌注成型工艺可降低CF/EP复合材料的孔隙率。     

短切CF增强TPEE热塑性复合材料的注射成型及力学性能研究

以热塑性聚酯弹性体(TPEE)为基体材料,8 mm短切碳纤维(CF)为增强材料,制备CF/TPEE复合材料。材料通过双螺杆挤出系统混合塑化、挤出造粒后,再经过注塑成型制备成标准拉伸试样,通过力学性能测试及微观结构观察,系统研究了碳纤维含量和等离子表面处理对CF/TPEE复合材料拉伸性能的影响。结果表明,当碳纤维含量为20%时,CF/TPEE复合材料的拉伸强度最大,为39.08 MPa;相比于纯TPEE,其拉伸强度提高了217%;经过等离子表面处理后,拉伸强度进一步提高了5%。结合拉伸后断面的SEM图发现,注塑试样表层碳纤维取向度高,而近中区和中心层取向度相对较低,这是注射CF/TPEE复合材料拉伸性能提高效应不明显的主要原因。     

聚丙烯结构发泡注塑成型研究进展

介绍了聚丙烯(PP)结构发泡注塑成型工艺及相应的PP树脂的改性方法,对PP结构发泡注塑成型的发展前景进行了展望。     

注塑成型工艺对透明PP光学性能的影响

采用不同的工艺条件注塑成型无规共聚透明聚丙烯(PP),测试透光率、雾度和表面光泽度,分析了成型工艺参数对制品光学性能的影响。所选透明PP的最佳注塑工艺为:加工温度220～230℃,模具温度40～60℃。在保证制品顺利成型的情况下应尽量采用较小的注塑压力。注塑速率和注塑时间对制品的光学性能影响较小。     

聚丙烯/亚麻纤维复合材料的成型工艺及力学性能研究

选取聚丙烯(PP)纤维为基体材料,亚麻纤维为增强材料。运用正交设计法,探讨了PP/亚麻纤维复合材料的模压成型工艺。研究分析了两种纤维的质量比、模压温度、热压保温时间对复合材料力学性能的影响。结果表明,两种纤维的质量比为50:50、模压温度为180℃、热压保温时间为60min时,PP/亚麻纤维复合材料的力学性能最佳。     

成型工艺对碳纤维增强热塑性聚酰亚胺复合材料性能的影响

采用双螺杆挤出共混的方法,制备了热塑性聚酰亚胺(TPI)/碳纤维(CF)复合材料,考察了注射和热模压两种成型工艺对 TPI/CF 复合材料力学性能、应力-应变曲线、线性膨胀系数以及摩擦磨损性能的影响。结果表明,注射成型试样的各项力学性能均比模压成型的高,达到1.5～2.0倍;相比模压成型,注射成型试样具有较高的断裂强度和断裂伸长率,其应力-应变曲线斜率也较大;由于纤维在注射流动方向上高度取向,注射成型试样具有最佳的高温尺寸稳定性;注射成型试样的摩擦系数和磨损率为模压成型的1.7倍和1.5倍;扫描电镜分析表明,纤维在注射流动方向上高度取向,模压成型试样呈现黏着磨损,注射成型试样以磨粒磨损为主。     

微发泡PP/GF复合材料力学性能研究

采用化学发泡注塑成型的方法制备了微发泡聚丙烯/玻璃纤维(PP/GF)复合材料;结合成核理论和玻纤增强机理,研究了发泡质量对微发泡PP/GF复合材料力学性能的影响。结果表明:在PP/GF复合材料中添加5.0%纳米SiO2后,纳米SiO2对PP与GF的相容性并无太大影响,微孔发泡PP/GF复合材料的拉伸强度和冲击强度得到较大提高。     

Mesostructure development during molding of sheet molding compounds

Experiments have been carried out with sheet molding compounds in which the amount of shear developed during molding was varied by changing the charge size. The effects of pressure and temperature were also investigated. The moldings were characterized by their mesostructures and the influence of the mesostructures on the Izod toughness and flexural strength was examined. It was found that high degrees of shear resulted in fiber orientation and the spreading of the fiber bundles. However, this did not improve properties, and it was concluded that for optimum properties, small amounts of shear were desirable.     

提高注塑件性能的熔体振荡技术

目前有一种新开发的注射熔体振荡技术,无需添加填料和助剂,就可提高注塑部件的机械特性。这项技术还可转移、隐藏或减少部件表面的注射熔接痕,并纠正制件取向应力等缺陷。     

Processing-property relationships in compression molding of sheet molding compounds

An experimental investigation was conducted into establishing relationships between the processing variables and the mechanical properties of compression-molded parts of sheet molding compounds (SMC). Emphasis was placed on investigating the effects on the tensile properties, impact strength, and dynamic mechanical properties of composite specimens, of low-profile additives, and of treating glass fibers (for reinforcement) with sizing chemicals. The processing variables investigated were cure time, mold temperature, and mold pressure. It was found that: (1) An optimum cure time and mold temperature exist for achieving molded SMC composites of the greatest tensile and impact strengths; (2) Of the four different types of low-profile thermoplastic additives employed, the poly(vinyl acetate) modified with acrylic acid gives rise to molded SMC composites having the greatest tensile and impact strengths; (3) An optimum cure time and mold temperature exist for achieving the highest glass-transition (T_g) of the low-profile additive; (4) The values of cure time and mold temperature that have yielded the greatest tensile and impact strengths also yield molded specimens having the highest T_g of the low-profile additive.     

Compression molding of sheet molding compounds in plate-rib type geometry

The flow of fiber-reinforced composite materials in a plate-rib type mold geometry during compression molding was investigated using a series of sheet molding compounds (SMC). Material anisotropy in relation to the amount and the length of reinforcing fibers was analyzed. The influence of the interfacial friction between SMC charge and the mold surface on the flow and sink mark formation was also examined. The results were explained qualitatively by computer simulation.     

Property modification of bulk molding compounds for use in injection molding

Although impact and flexural strength of injectionmolded bulk molding compounds increase initially with glass fiber content, these properties level out at a glass volume fraction between 0.1 and 0.2, limiting the achievable properties. Use of “special purpose” polyester resins gives no significant improvement in impact. The impact strength limitation is not worsened, however, by using the maximum processable level of filler, this being true for all fillers commonly used in polyester compounds. Replacement of a fraction of the glass by poly(ethylene terephthalate) fibers results in a substantial improvement in impact strength.     

Numerical simulation of non-isothermal SMC (sheet molding compound) molding

Design of molding tools and molding cycles for sheet molding compounds (SMC) is often expensive and time consuming. Computer simulation of the compression molding process is a desirable approach for reducing actual experimental runs. The focus of this work is to develop a computer model that can simulate the most important features of SMC compression molding, including material flow, heat transfer, and curing. A control volume/finite element approach was used to obtain the pressure and velocity fields and to compute the flow progression during compression mold filling. The energy equation and a kinetic model were solved simultaneously for the temperature and conversion profiles differential scanning calorimetry (DSC) was used to experimentally measure the polymer zation kinetics. A rheometrics dynamic analyzer (RDA) was used to measure the rheological changes of the compound. A series of molding experiments was conducted to record the flow front location and material temperature. The results were compared to simulated flow front and temperature profiles.     

Simulation-based design of sheet molding compound (SMC) compression molding

The design of moding tool and molding cycle for sheet molding compounds (SMC) is often expensive and time consuming. Computer simulation of the compression molding proces is a desirable approach to reduce experimental prototypes. The focus of this work is to develop an automatic optimization scheme utilizing an earlier developed SMC plrocess simulation program which is capable of simulating material flow, heat trensfer, and curing. The proposed scheme reduces computing time by using approximate responses, instead of actual simulated responses, to perform the optimization. The automated optimization package minimizes user intervention during optimal design by creating an automatic link between the optimization and simulation routines. A 2-level factorial design combined with regression analysis is adopted to gather and analyze computed information, and to serve as the approximation formula. Two examples are presented to test the applicability of the optimization scheme.     

注塑成型模拟技术在注塑工艺中的应用

注塑成型工艺已经发展成为塑料工业最重要的加工手段,注射模塑过程中需要选择和控制的压力包括塑化压力、注射压力和保压压力,它们直接影响塑料的塑化和塑件质量。通过对注塑过程中所涉及的工艺条件如何影响塑料制品的质量作了探讨,借助注塑工程分析软件对塑料制品的成型过程进行模拟,合理确定这些工艺参数,并分析了一个应用CAE技术优化工艺参数的实例,提出了比较切合实际并容易提高产品质量的注塑工艺方案。     

橡胶注射成型机注射装置结构分析研究

主要介绍了橡胶注射成型机及其注射装置的发展情况,阐述了橡胶注射成型的特点以及注射装置设计要求,并对三种常用的注射装置的结构特点及应用作系统的分析比较.