SiCp/Al复合材料与LD2的摩擦焊研究

采用摩擦焊方法对SiCp／Al复合材料与LD2进行连接。焊后借助于光学显微镜对焊接接头进行了微观组织和显微硬度分析。结果表明，在合适的工艺参数下，SiCp／Al复合材料与LD2的摩擦焊焊缝区结合致密，无气孔、夹杂和裂纹等缺陷，其接头强度略高于LD2与LD2的接头强度，因此采用摩擦焊方法焊接颗粒增强型复合材料是可行的。     

原位增强TiB2/2014Al复合材料的摩擦磨损性能

采用混合盐反应(MixedSaltReaction)原位合成法成功制备了TiB2/2014Al复合材料,并对其摩擦磨损性能进行了研究。采用X射线衍射分析物相和扫描、透射电镜观察了其微观组织。结果表明,原位生成的TiB2颗粒非常细小,尺寸小于1μm,内生TiB2颗粒分布均匀,明显细化了复合材料组织。室温干滑动摩擦磨损试验表明,复合材料耐磨性高于基体合金,基体合金磨损机制以粘着磨损为主,复合材料的磨损机制为典型的磨粒磨损。     

N2在等离子弧原位焊接SiCp/Al基复合材料中的作用

以0．8mm钛片作为填充材料，采用纯氩和氮氩混合等离子气体对SiCp／Al基复合材料进行等离子弧原位焊接，分析加入的N2对焊缝成形、焊缝组织和性能的影响。结果表明，随氮气体积分数增大，焊缝熔深也相应增大：增加氮气还改善了熔池中的热循环状态和冶金反应，生成TiN、AlN等新的增强相，有效地抑制脆性相的生成，改善了焊接接头的性能。力学性能实验表明，采用Ar＋N2作为离子气进行焊接时，焊缝硬度和强度都有提高。当N2体积分数约占15％时，拉伸强度达到最大值233．5MPa。     

SiCp/6061Al复合材料的电子束焊缝组织及性能

利用电子束焊焊接了2mm厚的SiCp/6061Al复合材料.通过OM、TEM、SEM、X射线衍射及MTS-810综合实验系统对焊缝组织和性能进行了分析.结果表明,随着热输入的减小,焊缝中的针状的Al4C3(界面反应产物)数量及尺寸均减小.热输入降低到30J/mm时可避免针状Al4C3的形成,焊缝中SiCp分布比母材更均匀.TEM分析表明,焊缝中所有残留的SiCp之表面附近均有Al4C3形成,而针状Al4C3是由许多晶体学位向不一的单晶Al4C3构成.SEM断口分析表明,随着热输入的增大,焊缝的断裂机制发生明显的变化,焊缝强度及塑性下降.     

原位Al2O3和TiB2粒子增强Al-Cu合金基 复合材料的制备和性能

由 TiO     

基于Ti中间层的SiCp/6061-T6Al MMCs低功率激光-TIG复合焊组织与性能

以0.1mm厚的Ti箔做中间夹层,使用低功率激光-TIG复合焊的方式对SiCp/6061-T6Al MMCs 进行焊接,并对接头的宏观形貌、显微组织、物相、电阻率、抗拉强度及断口形貌进行分析。结果表明：激光功率对焊缝的成形有着较大影响;Ti箔的加入基本抑制了焊缝中针状Al₄C₃生成,并生成TiC增强相以及条状TiAl₃;焊缝区为等轴晶组织,熔合区为柱状晶组织,热影响区组织变化不明显;随着激光功率的增加接头的电阻率呈现出增加的趋势,并明显高于母材;在554W时接头的抗拉强度可达196.98MPa,是母材强度的54.71%。接头断口中几乎没有气孔,韧窝中的第二相粒子以TiC为主,接头呈现出以脆性断裂为主的脆-韧性混合断裂特征。     

焊丝成分对SiCp/6061Al复合材料MIG焊焊缝组织及性能的影响

采用Al-Mg及Al—Si两种焊丝分别对SiCp／6061Al复合材料进行了MIG焊及脉冲MIG焊，利用光学显微镜、电子显微镜及MTS-810试验机对焊缝的组织及性能进行了分析。结果表明，采用Al—Mg焊丝焊接时，无论是MIG焊还是脉冲MIG焊，熔池中Al-SiC间的界面反应程度均较大，生成了较多的针状Al4C3，且Al4C3的尺寸较大。采用Al-Si焊丝时，MIG焊熔池中的界面反应程度显著降低，仅生成了少量尺寸较小的针状Al4C3；而采用Al—Si焊丝的脉冲MIG焊焊缝中没有发现针状Al4C3。同时，利用Al—Si焊丝可有效地防止焊缝熄弧处的宏观结晶裂纹。力学性能试验表明，采用同样焊丝时，脉冲MIG焊接头的强度及伸长率比MIG焊接头的高，而用Al-Si焊丝焊接的接头强度比用Al—Mg焊丝焊接的接头强度高。     

La2O3对MGH956合金TIG焊焊缝组织和性能的影响

为了研究La₂O₃对焊缝组织和性能的影响,分别以未填加、填加2%和4%La₂O₃的填充材料对MGH956合金进行TIG焊接,应用光学显微镜、扫描电镜和透射电镜对焊缝的微观组织和拉伸断口进行观察,同时测试焊缝的抗拉强度.结果表明,适当提高La₂O₃含量,可以使焊缝晶粒得到细化,填加2%La₂O₃的焊缝晶粒最细小均匀,焊缝中的颗粒相增多且分布均匀,强化机制是由细晶强化和Orowan强化共同作用,但当La₂O₃加入量达到4%时,发现颗粒相有团聚现象,强化主要由位错塞积引起.填加2%La₂O₃的焊缝抗拉强度最大,为628 MPa,拉伸断口为韧-脆混合断裂.     

SiCp/Al基复合材料等离子弧原位焊接研究

采用等离子弧原位焊接工艺研究了SiCp／Al基复合材料的可焊性。结果表明：以Ti为合金化填充材料，以N2＋Ar为离子气，可以大大减弱SiC颗粒与基体Al之间的界面反应。通过拉伸试验、显微硬度测试、金相观察、扫描电镜、X射线衍射分析，对焊接接头进行了研究。得出焊缝表面的蓝黑色薄膜状物质为AlN和Al的混合物，焊缝中心新生相为AlN、TiN和TiC。探讨了接头力学性能不高的原因，并提出了在等离子弧焊条件下提高SiCp／Al焊接接头质量应采取的措施。     

热处理对SiCp/6061Al基复合材料等离子弧焊接头性能的影响

热处理对SiCp/6061Al基复合材料等离子弧原位焊接接头组织与性能的影响较为明显,固溶处理 时效与退火相比,前者对接头的改善作用更佳.经500 ℃固溶处理2 h 12 h时效热处理后,接头组织得到良好的改善,细长的Al3Ti相变为短小棒状,消除了晶间偏析,组织更加均匀;热影响区组织中晶粒均得到比较明显的细化,比较接近母材晶粒的大小,焊接接头强度较未热处理时有了较大提高,达到245 MPa.     

Effects of ac arc ultrasonic on plasma arc in situ welding of SiCp/6061Al MMCs

Abstract

The isolation coupling device is designed based on the principle of high pass filter circuit, which can achieve isolation and coupling between ac welding power and ultrasonic frequency excitation source. In addition, ac arc ultrasonic vibration is obtained successfully. The plasma arc in situ welding of SiCp/6061Al was performed using two different processes. The first process is that the plasma gas is argon nitrogen mixture and the filler material is flux cored wire (Al–5Ti–5Si); the other process is that the plasma gas is argon and the filler material is flux cored wire (Al–15Ti–3Si). The two joints are respectively enhanced by nitride and Al₃Ti, which were obtained in these processes. After arc ultrasonic vibrations were imposed on the two welding processes, it was revealed that arc ultrasonic improved the distribution of the new nitride phases and optimised the morphology of Al₃Ti to improve the mechanical properties of joints that reached 246 and 263 MPa. Fracture analysis showed that the improvement of the mechanical properties resulting from Al₃Ti is better than that from nitride under the effect of arc ultrasonic.     

Effect of rare earth La2O3 on the microstructure and mechanical properties of TiC/W composites

In this study, La₂O₃ was investigated as an additive to TiC/W composites. The composites were prepared by vacuum hot pressing, and the microstructure and mechanical properties of the composites were investigated. Experimental results show that the grain size of the TiC/W composites is reduced by TiC particles. When 0.5 wt.% La₂O₃ is added to the composites, the grain size is reduced further. According to TEM analysis, La₂O₃ can alleviate the aggregation of TiC particles. With La₂O₃ addition, the relative density of the TiC/W composites can be improved from 95.1% to 96.5%. The hardness and elastic modulus of the TiC/W + 0.5 wt.% La₂O₃ composite are little improved, but the flexural strength and the fracture toughness increase to 796 MPa and 10.07 MPa·m^1/2 respectively, which are higher than those of the TiC/W composites.     

增强相含量对SiCp/3003Al复合材料闪光对焊焊接性的影响

用连续闪光对焊方法在同种焊接规范下分别对增强相含量为0％、15％、30％的SiCp／3003Al复合材料进行了连接，利用光学显微镜、SEM、AG-25TA型电子拉伸试验机对焊缝组织及性能进行分析，结果表明：含15％、30％SiCp的复合材料焊缝成型良好，含30％SiCp的复合材料接头强度最高。分析表明：随着SiCp含量的增加．复合材料的电阻率增大、热导率降低、线膨胀系数降低，而这些物理性能的变化使得焊接过程中产热更多，热量更集中于焊缝，闪光过程连续、稳定、激烈，自保护作用更好，焊后接头应力减少，即闪光对焊焊接性变好。     

燃烧合成技术焊接TiB2陶瓷/金属Fe

燃烧合成技术是近年来迅速兴起的材料制备新技术，文中将燃烧合成技术对TiB2陶瓷／金属Fe片进行了焊接。对中间焊接反应料的产物进行了XRD物相分析，主要产物为TiB2。并对关于中间层不同Fe含量时的界面扩散情况进行了定量分析，对焊接性能的影响进行了探讨。试验表明，采用燃烧合成技术可成功地制取TiB2陶瓷／金属Fe试样，且焊接界面结合良好，中间焊料层Fe的质量百分含量较高时，界面结合优于Fe质量百分含量低的界面结合情况。     

Processing, microstructure, and properties of laser remelted Al2O3/Y3Al5O12（YAG） eutectic in situ composite

Laser remelting and rapid solidification were performed in preparing the high-performance Al2O3/Y3Al5O12（YAG） eutectic in situ composite. The microstructure characteristic and solidification behavior were studied using scanning electron microscopy（SEM）, energy dispersive spectroscopy（EDS）, X-ray diffractometry（XRD） and simultaneous thermal analysis（STA）. The hardness and fracture toughness were obtained using an indentation technique. The results show that the laser remelted Al2O3/YAG composite has a homogeneous eutectic microstructure without microcrack and pore. The component phases of Al2O3 and YAG are three-dimensionally and continuously reticular connected, and finely coupled without grain boundaries, colonies and amorphous phases between interfaces. The eutectic interspacing is greatly refined with increasing the scanning rate and average is only l μm. The synthetically thermal analysis indicates that the eutectic temperature of Al2O3-YAG is 1 824 ℃, well matching the phase diagram of Al2O3-Y2O3 system. The maximum hardness reaches 19.5 GPa and the room fracture toughness is 3.6 MPa.m^1/2.     

Effect of temperature field on types and distribution of reinforcing phases in "in-situ" weld-alloying/PAW of SiCp/6061 Al

Based on theories of heat transfer, physical metallurgy and hydro-mechanical, in order to analyze the effect of welding parameters on species and distribution of reinforcing phases visually and legibly,finite element software ANSYS was used to simulate transient temperature field for SiCp/Al in " in-situ" weld-alloying/plasma arc welding. The results show that the calculated results approximately agreed with the experimental measured results. So the model is basically correct and credible. Based on the numerical solutions and experimental results, effect of temperature field in different welding process parameters( welding current, welding velocity) on species and distribution of reinforcing phases is analyzed. The results show that adjusting and optimizing temperature field appropriately is an effective method to obtain welded joint with better microstructure and property.     

Effect of rare earth Pr on microstructure and mechanical properties of Al2O3-SiO2（sf）/Al-Si composites

The Al₂O₃-SiO₂(sf) (volume fraction, 20%)/Al-12.6Si metal matrix composites(MMCs) with or without rare earth Pr addition were fabricated by infiltration squeeze method. Effect of Pr addition on microstructures and fractographs of Al-Si MMCs was investigated by SEM and TEM. Tensile properties at room temperature and 200 °C were tested. It is shown that the addition of Pr is favorable to produce uniform microstructures and modify the eutectic Si crystal effectively. Compounds/intermetallics with high content of Pr are formed at the interface between short fiber and matrix. Yield strength(σ_0.2), ultimate tensile strength(σ_b) and fracture elongation of Al-Si MMCs are improved by adding suitable amount of Pr. Compared with those values of Al-Si based MMC at 200 °C, σ_0.2 and σ_b of MMC with 0.29% Pr are increased by 33% and 55%, respectively. The tensile fracture surface of Al-Si MMCs with Pr addition presents ductile fracture features.     

Interfacial microstructure of 20% SO2/Al matrix composites reinforced with in situ formation ceramic phases

Al matrix composites reinforced with in situ ceramic phases by adding 20% SiO2 were fabricated by powder metallurgy process.The interfacial microstructure of the composites was studied by means of SEM and HREM.It was shown that the ceramic phases mainly composed of spinel MgAl2O4 are formed in situ in the original SiO2 particle and the size of small MgAl2O4 crystallites is about dozens of nanometers,which can adjacent to Al and Si.MgO could not found in original SiO2 particle but a little in matrix and may exist with Si,Mg2Si and Al.Si is mostly distributed in matrix and forms some segregation zones.The size of Mg2Si is about 50-100nm and can usually be seen in the matrix.