共查询到17条相似文献,搜索用时 187 毫秒
1.
以湿法磷酸脱氟制备氟化钾时的副产物二氧化硅,聚乙二醇,VAE乳液,丙三醇和磷酸铝为主要原料,以水为溶剂制成包膜乳液,采用多次雾化喷涂的方式对磷酸二铵颗粒肥料进行喷涂,制备了包膜缓释肥。研究了包覆率和二氧化硅加入量对其缓释性能的影响以及产品在土壤中的保水性能;并通过扫描电镜观察了包膜后肥料表面和剖面的形貌特征。结果表明:当包覆率达到40%时,产品的初期养分释放率小于15%,28天累积养分释放率小于80%,达到了缓释肥料国家标准GB/T 23348-2009的要求;产品在土壤中可以提高土壤的最大持水率和保水性能,对水资源利用率的提高具有重要意义,同时包膜材料还具有可生物降解、无环境污染等优点。 相似文献
2.
3.
聚氨酯包膜控释尿素制备工艺与养分释放特性研究 总被引:4,自引:0,他引:4
4,4'-二苯基甲烷二异氰酸酯(MDI)与植物油多元醇均匀喷涂在流化状态的尿素颗粒表面并发生化学反应,形成聚氨酯膜层。以侧喷流化床包膜工艺为基础,通过研究包膜量、反应温度、反应物比例等不同工艺条件下包膜尿素的养分释放性能,获得的生产聚氨酯包膜尿素的最佳工艺条件为反应温度75℃、MDI与植物油质量比1.0:1.0、反应时间20 min、催化剂用量0.40%(质量分数)、包膜比率为4.0%(质量分数),此包膜控释尿素的养分释放周期可达70 d。 相似文献
4.
以烯丙基硫脲改性魔芋葡甘聚糖为包膜剂制备包膜缓释尿素。对包膜缓释材料进行扫描电子显微镜(SEM)表征,并分析其吸水性能;评价温度及土壤水含量对包膜缓释尿素氮素溶出率的影响,利用土柱淋溶法检测包膜缓释尿素的缓释效果,并分析缓释尿素对白菜的生长影响。结果表明,烯丙基硫脲接枝魔芋葡甘聚糖在接枝率为35%~45%时,吸水性能最好,吸水量高达794 g/g;随着温度和土壤水含量的升高,包膜缓释尿素氮素溶出率逐渐增加;氮素溶出具有典型的缓释肥溶出特征,表现出良好的缓释效果;白菜对缓释尿素中氮素的利用率提高。 相似文献
5.
为了优化聚氨酯(PUR)包膜尿素控释性能,采用多亚甲基多苯基异氰酸酯分别与聚酯和聚醚多元醇按不同配比混合,依照不同次序先后喷涂在尿素颗粒表面制备聚酯型和聚醚型PUR互换层包膜尿素并利用分光光度法研究其控释性能。通过接触角、热重分析和扫描电子显微镜对膜材的润湿性、热稳定性和形貌进行了表征,并采用傅立叶变换红外光谱分析了尿素释放过程中膜层的结构变化。结果表明,聚酯型PUR的疏水性弱于聚醚型PUR,但热稳定性高于后者;两者的包覆次序影响PUR包膜尿素的控释效果,聚酯型PUR为外层、聚醚型PUR为内层时控释性能优良,当两者包覆比例(质量比)为1.5∶1.5时,释放期最长可达84 d。 相似文献
6.
7.
8.
9.
通过一定比例合成含有NCO的聚氨酯预聚体为A组分,将粉料、聚醚、MOCA、助剂等制成B组分,将A、B组分按质量比1∶2混合成膜制得非焦油型双组分聚氨酯涂料。探讨了NCO含量、MOCA、催化助剂、消泡剂对双组分聚氨酯涂料的影响,结果表明:NCO含量在4.0%~4.6%、MOCA含量在2.5%~4.0%、催化剂在0.08%~0.12%、消泡剂在0.3%~0.7%,可以制得性能优异的双组分聚氨酯涂料。 相似文献
10.
11.
12.
13.
14.
Asma Sofyane Mohammed Lahcini Abdellatif El Meziane Mehdi Khouloud Abdelmalek Dahchour Sylvain Caillol Mustapha Raihane 《Journal of the American Oil Chemists' Society》2020,97(7):751-763
In an effort to enhance the efficiency of fertilizer use and minimize their negative impact on the environment, a novel biomass-based, functional controlled-release fertilizer was used to improve nutrient use efficiency and increase crop production systems for more sustainable agriculture practices. Here, bio-based amino-oil (Priamine) mixtures were proposed as an outer coating with different layers for the control of phosphorus release from diammonium Phosphate (DAP). These hydrophobic coatings conferred excellent barrier properties and flexibility to coatings. The morphological characterization of the coated fertilizer was performed by scanning electronic microscopy (SEM), electronic diffraction X-ray (EDX) and mapping, and revealed the formation of a cohesive film and a good adhesion between DAP fertilizer and coating film. The release rate of nutrients (phosphate) in water was investigated by UV–Vis spectrophotometer. The effect of coating thickness was investigated on release time and diffusion coefficient of phosphor release in distilled water. Release time increased with the coating thickness. The diffusion coefficient of nutrient release decreased with the coating thickness. Compared with uncoated granule which is totally solubilized after less than 2 hours, the P release profiles of the coated granules reached the equilibrium stage approximately after 98 and 126 hours when the DAP is coated with only Priamine single-layer (1L) and double-layer (2L), respectively. Moreover, the strategy adopted has successfully provided a very slow release and long-term availability of nutrient sources with bio-based coating oil compared to uncoated fertilizer (DAP) and therefore exhibited promising application for sustainable development of modern agriculture and circular economic. 相似文献
15.
Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and th... 相似文献
16.
羧甲基纤维素接枝丙烯酸/丙烯酰胺缓释肥包膜材料的制备、性能及应用 总被引:2,自引:0,他引:2
以过硫酸钾为引发剂、N,N′-亚甲基双丙烯酰胺为交联剂,采用水溶液聚合法制备了羧甲基纤维素接枝丙烯酸/丙烯酰胺缓释肥包膜材料,对其吸水性及耐盐性进行了检测,并将其应用于包膜尿素缓释肥的制备。结果表明,在羧甲基纤维素与丙烯酸质量比为3∶17、丙烯酰胺用量为12%时,所制备包膜材料在去离子水、自来水和0.4%盐水中的吸水率分别达到743g·g-1、497g·g-1和329g·g-1;包膜尿素缓释肥的氮素释放率满足GB/T 23348-2009要求,缓释周期达63d。 相似文献
17.
A. Golgoon M. Aliofkhazraei M. Toorani M.H. Moradi A. Sabour Rouhaghdam 《Polymer Engineering and Science》2017,57(8):846-856
The corrosion and wear behavior of powder coatings fabricated by the electrostatic method was investigated in this study. Pure polyester coating and fabricated nanocomposite powder coating with 10 and 20 mass.% alumina nanoparticles were coated with electrostatic spraying method on the surfaces of carbon steel substrate. Coatings were cured in two regimes by oven and microwave for the appropriate time. The effects of alumina nanoparticles on the corrosion resistance of coated samples were studied by immersion and electrochemical impedance spectroscopy (EIS) tests. Also, pin‐on‐disk test was applied to evaluate the wear properties and coefficient of friction (COF) of the coatings. The results of the corrosion test reveal that the samples with 10 mass.% alumina show the best corrosion resistance and cause a reduction in corrosion rates which is about 36 times to that of the pure sample. The wear rate of nanocomposite coatings is 10 times lower than that of pure ones and also the coefficient of friction of nanocomposite samples is almost half of the pure samples. Furthermore, the nanocomposite coatings cured in the microwave show better protection properties and wear resistance than that of ones cured in an oven. POLYM. ENG. SCI., 57:846–856, 2017. © 2016 Society of Plastics Engineers 相似文献