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1.
以浓度为88%的甲酸溶液作为纺丝溶剂,采用静电纺丝和紫外光照射还原的方法制备了含纳米银颗粒的明胶/壳聚糖纳米纤维。研究发现,壳聚糖的加入量低于明胶质量的3/16时可以得到纳米纤维,纤维平均直径随着硝酸银加入量的增大而减小,纤维表面纳米银的平均直径随着硝酸银加入量的增大而增大,在纺丝体系中硝酸银的加入量存在一个极限值。所制得含纳米银的明胶/壳聚糖纳米纤维对金黄色葡萄球菌和绿脓杆菌具有较好的抑菌性能,纺丝时加入1%硝酸银制得纳米纤维膜的抑菌率达到99%以上,这种抗菌型纳米纤维可以应用于医用敷料等领域。  相似文献   

2.
纳米银纤维是在尼龙等柔性织物表面沉积纳米银颗粒而得到的复合材料,它不仅保持了原有的纺织品属性,还具有银的特殊功能。银具有很好的导电、导热性能,同时还具有非常有效的广谱抗菌性,因此银纤维具有很好的防辐射性和抗菌性,引起人们广泛的研究兴趣。综述了磁控溅射法制备纳米银纤维的研究近况和成果,介绍了其防辐射和抗菌性能的机理,提出了存在的问题及可能的改进方法。  相似文献   

3.
介绍纳米银颗粒与纤维的制备方法,以及纳米银的应用前景。  相似文献   

4.
纳米银强化地板的制备及其抗菌性能   总被引:1,自引:0,他引:1  
随着SARS、禽流感等传染性疾病的肆虐横行,能够控制和消除生物污染问题的抗菌地板成为市场的热点,强化地板因价廉物美而倍受广大消费者的青睐,因此制备具有持久抗菌作用的强化地板有着非常重要的现实意义。强化地板共分4层:从上到下依次是耐磨纸、木纹纸、装饰纸、高密度纤维板和平衡纸。耐磨纸的主要成份是三聚氰胺、水和Al2O3。含银强化地板的制备是以胶态的水溶性纳米银代替水加入到耐磨纸中,然后与强化地板的其它3层一起在180℃下热压30s成型。结果表明:当处理强化地板的纳米银溶胶的浓度达到20μg/g时,对大肠杆菌的杀菌率超过99.9%,而且该地板在经湿抹布20次擦洗之后,其抗菌活性未见明显下降,显示了良好的持久抗菌活性。  相似文献   

5.
纳米银及纳米银无纺布的制备及其抗菌性能的表征   总被引:3,自引:0,他引:3  
采用化学还原法制备了粒径10nm左右的纳米银溶液,并得到很高的反应产率。制备的纳米银溶液具备很好的抑菌性能,对表皮葡萄球菌和大肠杆菌的最低抑菌浓度(MIC)分别为3.125ppm和1.6ppm。无纺布经过500ppm纳米银溶液后,浸渍对表皮葡萄球菌和大肠杆菌约具有很好的抑菌性能。  相似文献   

6.
纳米银实木薄片的制备是将薄片浸没到水溶性纳米银溶胶中,1min后取出晾干,然后剪切成多个圆形小木片。用抑菌环法测量实木薄片的抗菌性能和耐擦拭性能。结果表明:当处理实木薄片的纳米银溶胶的浓度达到20μg/mL时,对大肠杆菌的抑菌环的直径超过10mm,而且该薄片有良好的耐擦拭功能,在经湿抹布10余次擦拭之后,其抗菌活性未见明显下降,显示了良好的持久抗菌活性。  相似文献   

7.
病原微生物严重威胁着人类的健康安全,纳米银作为一种新型抗菌材料,其制备与应用已成为纳米材料领域的研究热点。本文综述了纳米银的主要合成方法,包括多糖法、Tollens试剂法、辐射法、生物法和多金属氧酸盐法等,具有原料广泛、反应温和、成本低廉和环境友好等优点。基于纳米银的优异抗菌性能,总结了纳米银的抗菌机理及其抗菌应用,并展望了纳米银在抗菌涂料、抗菌包装等领域的发展前景。  相似文献   

8.
纳米银粉内墙抗菌涂料的制备及抗菌性研究   总被引:5,自引:0,他引:5  
使用纳米银粉、润湿剂、分散剂和消泡剂等原料,制备得到含有纳米银粉材料的内墙涂料.检测可知,涂料性能优良.经灭菌率测试,含有0.02%(wt)纳米银粉的涂料能够有效地起到抗菌效果,在1h内的灭菌率达到91.9%;再继续增加纳米银粉含量对提高抗菌效果意义不大.  相似文献   

9.
纳米银对大肠杆菌的抗菌作用及其机制   总被引:11,自引:0,他引:11  
以大肠杆菌为研究对象,对纳米银的抗菌效果进行了研究.并对其抗菌机制做了初步探讨.纳米银对大肠杆菌的抑制生长曲线的结果表明,20 μg/mL的纳米银能够完全抑制106 cfu/mL的大肠杆菌细胞生长,纳米银使大肠杆菌的延滞期加长,并且纳米银浓度越高,延滞期越长.采用透射电镜观察了经纳米银粒子处理过的大肠杆菌细胞形态变化过程,结果显示纳米银粒子先在细胞壁上产生小的孔洞,通过这些孔洞进入周质空间,导致细胞膜成分渗漏和破坏细胞膜,进而进入细胞内部.进入细胞内部的纳米银粒子使DNA浓缩呈紧张态,并与破损细菌的细胞质结合积聚,最后引起胞内物质流失.另外,纳米银对大肠杆菌总DNA影响的分析表明.随着纳米银浓度的增高,大肠杆菌总DNA样品降解的程度增大.  相似文献   

10.
纳米银粒子在微乳液中的制备及其抗菌性能   总被引:1,自引:0,他引:1  
在以二丁酸二异辛酯磺酸钠为表面活性剂、异辛烷为油相形成的W/O型微乳体系中,以AgNO3为银源、抗坏血酸为还原剂,讨论了AgNO3浓度、抗坏血酸浓度以及水核半径(W)对制备纳米银粒子的影响。利用紫外一可见光谱分析(UV-Vis)、透射电镜(TEM)和纳米粒度仪对制得的纳米银进行表征。结果表明,在AgNO3浓度为0.2mol/L,抗坏血酸浓度为0.2mol/L,W值为10的条件下,得到大小为10nm左右,单分散性好的均匀球状纳米银溶胶。抗菌性能测试表明,当纳米银粒子质量浓度为10μg/mL时,对大肠杆菌的杀菌率达98%以上。  相似文献   

11.
一种新型无机抗菌剂--钼酸银   总被引:2,自引:0,他引:2  
介绍了一种新型无机抗菌剂钼酸银的制法与应用 ,特别是用作抗菌陶瓷制品和抗菌混凝土制品。  相似文献   

12.
Material properties are strongly dependent on material structure. The large diversity and complexity of material structures provide significant opportunities to improve the properties of the materials, expanding their applications. Here, we discuss the fabrication of a multifunctional silver film prepared by controlling the nucleation and growth of silver particles. Silver films with high hydrophobicity and antibacterial activity were fabricated by adopting an electrochemical approach. The dependence of the hydrophobic and antibacterial properties on the size and shape of the silver particles was first investigated. Small-sized silver particles exhibited a high antibacterial rate, while a porous silver film composed of dendritic particles showed a significant hydrophobic activity. By regulating the reaction time, current density, and silver salt concentration, a silver film with a contact angle of 150.9° and an antibacterial rate of 54.7% was synthesized. This study demonstrates that finding a compromise between different material structures is a suitable way to fabricate multifunctional devices.
  相似文献   

13.
镀银碳纳米管的抗菌性研究   总被引:2,自引:0,他引:2  
用离子束辅助沉积(IBAD)方法在碳纳米管表面制备银膜.用琼脂平板法测试了抗菌率,测试菌种为革兰氏阴性大肠杆菌(E.coil)和革兰氏阳性金黄色葡萄球菌(S.aureus);用扫描电子显微镜(SEM) 观测了镀银碳纳米管的微观形貌;用能量散射X射线谱(EDX)分析了镀银碳纳米管表面元素的原子百分比;用X射线光电子能谱(XPS) 分析了镀银碳纳米管的表面元素的价态.研究结果表明,镀银碳纳米管具有优良的抗菌性能,且比在热解碳上镀银样品的抗菌性强.  相似文献   

14.
采用液相氧化沉淀法制备纳米氧化高银颗粒.以硝酸银为原料,氢氧化钠为沉淀剂,过硫酸钾为氧化剂,控制pH值为11,反应温度为80℃,在磁力搅拌器上反应30min,静置3h后,离心洗涤数次,70℃真空干燥3h,得到黑色纳米氧化高银颗粒.通过X射线衍射(XRD)、透射电子显微镜(TEM)对纳米氧化高银颗粒的形貌和结构进行表征;采用异养菌测试瓶法,用制备的氧化高银和粒径为30nm的纳米银对金黄色葡萄球菌进行抗菌性能测试.结果表明:制得的球形纳米颗粒粒径为10~30ntn;纳米氧化高银颗粒比纳米银具有更强的杀菌性能.  相似文献   

15.
Microbial silver nanoparticles have been known to have bactericidal effects but the antimicrobial mechanism has not been clearly revealed. The use of microorganisms in the synthesis of nanoparticles emerges as an ecofriendly and exciting approach. Here we report on the extracellular synthesis method for the preparation of silver nanoparticles in water using the extract of Agaricus bisporus, a naturally occurring edible mushroom, as reducing and protecting agents. The silver nanoparticles were characterised by ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction (XRD) analysis. The synthesised silver nanoparticles showed antibacterial activity against the multi-drug resistant Gram positive and Gram negative bacterial pathogens.  相似文献   

16.
The biosynthesis of silver nanoparticles (AgNps) has a wide range of applications, and here we develop a rapid synthesis using the leaf extract of Ipomea carnea. We demonstrated that 100?mL of a 1?mM silver nitrate solution was reduced to AgNps by 500?µL of I. carnea extract in 5?min and that one or more of the chemical constituents present in the extract acted as the reducing agent. Surface plasmon resonance peaks were observed from 410 to 440?nm for AgNps synthesised using the plant extract, and the peaks showed a characteristic blue shift with variation of pH from 2 to 8. Particle size analysis revealed the size of the AgNps to be from 30 to 130?nm, which was also confirmed by dynamic light scattering, atomic force microscopy and transmission electron microscopy. Additionally, the antibacterial effects of the AgNps were evaluated against selected human pathogens such as Staphylococcus aureus, Bacillus cereus, Bacillus subtilis, Klebsiella pneumoniae, Aeromonas hydrophila, Salmonella typhi, Proteus vulgaris and Pseudomonas aeruginosa. Finally, the AgNps were impregnated with a cellulose acetate membrane to form an antimycobacterial membrane. Antimycobacterial activity against a non-pathogenic Mycobacterium smegmatis showed that the AgNp-embedded membrane system has a zone of inhibition of 14?mm.  相似文献   

17.
This study investigates the ability of cellulose filter paper coated with silver nanoparticles to remove Escherichia coli from drinking water. The cellulose filter paper was coated with silver nanoparticles by a chemical reduction method using two different ratios of sodium borohydride and silver nitrate. In consideration of drinking-water quality standards and non-carcinogenic health risks, the optimum sodium borohydride:silver nitrate ratio for coating the cellulose filter paper was determined by comparing the silver in the effluent after E. coli removal. For both ratios, 100% E. coli removal was realised. In terms of the silver in the effluent, only the first two lowest concentrations for both ratios of sodium borohydride and silver nitrate were compliant with the drinking-water quality standards, demonstrating hazard quotients (HQs) between 0.084 and 0.484. On the basis of the highest level of E. coli removal with the lowest HQ value, the optimum sodium borohydride:silver nitrate ratio for coating the cellulose filter paper as an antibacterial water filter was 2:1 molar ratio (0.002 M:0.001 M). Silver nanoparticle-coated cellulose filter paper was found to be an inexpensive and easy-to-use emergency antibacterial water filter to generate clean drinking water.  相似文献   

18.
新型抗菌聚乙烯塑料制备及性能研究   总被引:1,自引:0,他引:1  
采用熔融共混法制备得到具有负离子释放功能的低密度聚乙烯(LDPE)/稀土复合矿粉(Eli)、LDPE/Eli/吡啶硫铜锌(ZPT)(LDPE/Eli/ZPT)两种LDPE抗茵塑料.通过对其结晶行为、抗菌性能及抗菌持久性系统研究表明:Eli的加入对LDPE有异相成核作用;Eli用量为1份时,LDPE/Eli复合材料负离子释放量为790 ions/co,与公园中负离子释放量相当,抗菌率达到45%以上;ZPT用量为0.15份时,LDPE/Eli/ZPT复合体系对大肠杆菌(E. coli)抗菌率达到98.21%,对金黄色葡萄球菌(S. aureus)抗菌率达到96.15%,经过30天的水洗后,其抗菌率仍能保持82.14%(E coli)和81.25%(S.aureus).  相似文献   

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