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S.M. Pawar B.S. Pawar A.V. Moholkar J.H. Yun S.S. Kolekar 《Electrochimica acta》2010,55(12):4057-4061
The Cu2ZnSnS4 (CZTS) thin films have been electrodeposited onto the Mo coated and ITO glass substrates, in potentiostatic mode at room temperature. The deposition mechanism of the CZTS thin film has been studied using electrochemical techniques like cyclic voltammetery. For the synthesis of these CZTS films, tri-sodium citrate and tartaric acid were used as complexing agents in precursor solution. The structural, morphological, compositional, and optical properties of the CZTS thin films have been studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), EDAX and optical absorption techniques respectively. These properties are found to be strongly dependent on the post-annealing treatment. The polycrystalline CZTS thin films with kieserite crystal structure have been obtained after annealing as-deposited thin films at 550 in Ar atmosphere for 1 h. The electrosynthesized CZTS film exhibits a quite smooth, uniform and dense topography. EDAX study reveals that the deposited thin films are nearly stoichiometric. The direct band gap energy for the CZTS thin films is found to be about 1.50 eV. The photoelectrochemical (PEC) characterization showed that the annealed CZTS thin films are photoactive. 相似文献
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Galvanostatic pulsed current (PC) and pulse reverse (PR) plating of Sn–Pb coatings onto copper rotating disks from fluoroborate solutions has been conducted to obtain alloy compositions otherwise not achievable by DC plating. PC plating investigated over a wide range of pulse frequencies (20 Hz–200 kHz) and duty cycles produces coatings with compositions that differ only slightly from those obtained by DC plating at the same current density. On the other hand, the use of PR plating can be dramatic, producing Pb contents both well above and below that achievable by DC plating. Varying the frequency from 20 Hz to 200 kHz with the duty cycle and average current density fixed at 80% and 3.78 A dm–2 yields compositions between 2.5 and 28 wt.% Pb. The Pb:Sn ratio in the deposit is always lower than that in the plating bath when a PR frequency of 20 Hz is imposed, but generally exceeds it at a frequency of 20 kHz. Alloy composition appears to be closely related to the working electrode potential reached during the anodic pulse. A higher frequency leads to less positive potentials during the anodic pulse and shorter anodic pulse times, which may enhance Sn dissolution and enrich the coating in Pb. 相似文献
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聚苯乙烯球模板辅助电沉积制备多孔片晶ZnO薄膜 总被引:1,自引:0,他引:1
以pH值为5.0±0.1的0.5mol/L Zn(NO3)2溶液为电解液,在聚苯乙烯球(polystyrene spheres,PS)模板的辅助下,采用电沉积方法制备了多孔片晶ZnO薄膜。沉积电位为-0.8V和-0.9V,水浴温度为70℃。用扫描电镜观察了ZnO薄膜的表面形貌。用X射线衍射和紫外/可见光分光光度计对薄膜的性能进行了表征。结果表明:沉积电位对薄膜形貌有着显著的影响;多孔片晶ZnO为六方纤锌矿结构;在300~900nm波长范围内透光率较低,并随波长减小呈近似线性降低。此外,对PS模板辅助电沉积制备多孔片晶ZnO薄膜的形成过程进行了讨论。 相似文献
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In the present work pure nickel-phosphorous and nickel-phosphorous composite coatings with WC particles (mean diameter 200 nm) have been produced under both direct and pulse current conditions, from a modified, organic-free, Watts bath. The produced coatings were thermally treated at various temperatures and the structure, morphology and the microhardness of the deposits were examined after each cycle of heat treatment. Imposition of pulse current conditions led to composite deposits with high-incorporation percentage of WC particles in the matrix. Also, the presence of WC particles resulted in coatings with enhanced microhardness values and retarded diffusion phenomena in the deposits during thermal treatment. Annealing of all coatings at 400 °C revealed complete crystallization of the matrix to the phases of Ni, Ni2P and Ni3P accompanied by a significant increase of microhardness for all deposits. Further heating at higher temperatures demonstrated a decrease in microhardness of both kinds of deposits. The experimental data proved that it is possible to produce NiP-WC composite coatings under specific pulse current conditions followed by proper thermal treatment that exhibited considerable enhanced microhardness. 相似文献
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In this paper, a modified electrodeposition method, occlusion electrosynthesis (OE), was used to prepare ZnO porous films. The processes of OE were similar to those of electrodeposition except the addition of ZnO nanoparticles in electrolyte. The ZnO porous film prepared by OE (OE-ZnO) was highly porous with considerable thickness (55 μm). The quantum dots-sensitized solar cell based on OE-ZnO porous film showed superior photoelectrochemical performance to that based on the ZnO porous film prepared by doctor-blade (DB) method at the suitable concentrations of ZnO nanoparticles in electrolyte, about 16–32 g/L. In addition to the ZnO porous film constructed with ZnO nanoparticles, the ZnO porous film constructed with ZnO nanorods, ZnO/multi-walls carbon nanotubes and ZnO/TiO2 composite porous films have also been successfully synthesized by OE, which were expected to be widely applied in various fields. The low temperature (60 °C) processes without post treatment made OE more promising for preparing ZnO porous films than DB, especially the ZnO porous films for flexible devices. 相似文献
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S. Michel N. Stein M. Schneider C. Boulanger J-M. Lecuire 《Journal of Applied Electrochemistry》2003,33(1):23-27
A 23–1 fractional factorial design comprising four runs and three centre points was applied in order to optimize the electrodeposition process to find a compound with the best stoichiometry leading to a Bi2Te2.7Se0.3 thin film suitable for thermoelectric applications. The key factors considered were the deposition potential, the percentage of bismuth and the percentage of selenium in the solution. The BiIII, SeIV, TeIV electrolyte mixtures in 1 M HNO3 (pH 0), allowed deposition of ternary alloys to be achieved at room temperature on stainless steel substrates. The deposition mechanism was investigated by linear voltammetry. The films were characterized by micropobe analysis, X-ray diffraction, scanning electron microscopy and atomic force microscopy. The XRD patterns of the film show that the as-deposited are polycrystalline and isostructural to Bi2Te3. The SEM study shows that the film is covered by crystallites while the AFM image reveals a low level of roughness. 相似文献
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用循环伏安法对半导体Cdse_xTe_(1-x)薄膜电池的光溶解性能进行了研究。在1mol/L KCl溶液中测量光溶解产物的阴极还原特性,考察了在多硫化钠,多硫化钾及铁氰化钾溶液中的光腐蚀行为。用此方法还研究了薄膜电极表面的光刻蚀过程和pH的影响,并用X射线光电子能谱分析光刻进行不同时间后,电极表面发生的变化。 相似文献
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用醋酸盐和钛酸四丁酯为原料,采用sol-gel工艺在Pt/TiO/SiO/Si基片上制备了含有Mg元素的Sr0.5Ba0.5-xMgxTiO3薄膜,其退火处理温度为750℃.通过X射线衍射和扫描电镜分析技术研究了薄膜的相结构和形貌.采用美国HP Angilent 4294A阻抗分析仪测试了以Pt为底电极、Ag为上电极的MFM电容器的介电性能.实验结果表明:掺镁Sr05Ba05.xMgxTiO3薄膜较未掺杂的Ba05Sr0.5TiO3薄膜相对介电常数高、介电损耗低.介温谱表明在居里温度附近发生了弥散型相变,且居里温度有向低温方向漂移的趋势. 相似文献
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Moustafa Ahmed Yas M. Al-Hadeethi Arwa T. Kutbee Essam R. Shaaban 《Ceramics International》2021,47(15):21117-21126
Thin films of semiconductor Se80Ge20-xAgx (x = 0, 3, 6, 9, 12 and 15 at.%) were deposited by the thermal evaporation technology. Through optical and electrical characterization, the influence of the Ag ratio on the photoelectric parameters of Se–Ge thin film was studied. The X-ray diffraction pattern showed the amorphous nature of the deposited films as well as the polycrystalline state when the films were annealed at the maximum crystallization temperature (415 K), which was determined by the first derivative of the resistivity curve with respect to temperature. The crystallization kinetics of the film was extracted from the electrical analysis by measuring the change in resistivity with temperature. The electrical results of the thin film showed three regions; namely, amorphous, extended (crystalline) and hopping. In the extended and hopping states, the activation energy and pre-exponential factors were calculated. The optical constants, extinction coefficient and refractive index were calculated using the transmittance and reflectance of the grown Se80Ge20-xAgx films. The energy gaps of the films were estimated in the strong absorption regions. The changes in the bandgap energy of the film by thermal annealing can help to produce materials with acceptable band gaps for use as absorber layers in solar cell applications. Also, the results provide microscopic insights and studies on the structure, electr-othermal and optical properties of Ag metal-doped GeSe as a back contact of solar cells. 相似文献
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The influence of pulse electrodeposition parameters (current on-time Ton, current off-time Toff, and pulse current density Jp) was investigated on the surface morphology and grain size of zinc electrodeposited from a sulfate bath containing polyacrylamide and thiourea additives. The grain size and surface morphology of zinc deposits were studied by field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM), and the preferred orientation of the deposits was studied by X-ray diffraction. At constant current off-time and pulse current density, the grain size decreased asymptotically with increasing current on-time. In contrast, increase in the current off-time at constant current on-time and pulse current density resulted in grain growth. A progressive decrease of the grain size was observed with increasing pulse current density at constant current on-time and off-time. Nanocrystalline zinc with an average grain size of 38 nm was obtained at a pulse current density of 1200 mA/cm2. The crystallographic orientations developed were correlated with the change in the cathodic overpotential, the angle between the preferred oriented plane and the lowest energy of formation plane (0 0 0 2), and the pulse electrodeposition parameters. 相似文献
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Andrei Ionut Mardare Andreas Dirk Wieck Achim Walter Hassel 《Electrochimica acta》2007,52(28):7865-7869
An experimental set-up is presented that allows direct writing on a metal by local anodisation in a confined electrolyte volume. A scanning droplet cell with reference electrode and counter electrode is attached to an automated xyz stage and allows an efficient addressing of a small surface area. An automatic mode investigation of a material under systematic variation of formation parameters such as formation voltage, scan rate and potentiostatic or potentiodynamic formation mode is demonstrated. The influence of these parameters on the oxide film thickness and film properties are discussed. An example for the method of direct electrochemical oxide spot writing is given. The set-up can also be used in a manual mode to address a surface area of interest such as a pit, single grain, grain boundary or intermetallic inclusion. 相似文献
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Here we investigated the analytical performances of the bismuth-modified zeolite doped carbon paste electrode (BiF-ZDCPE) for trace Cd and Pb analysis. The characteristics of bismuth-modified electrodes were improved greatly via addition of synthetic zeolite into carbon paste. To obtain high reproducibility and sensitivity, optimum experimental conditions for bismuth deposition were studied. Voltammetric responses of the BiF-ZDCPEs prepared with different ratios of zeolite, carbon powder, and silicone, were examined under same conditions. The in situ plated (zeolite/graphite powder/silicone, 10/190/80 w/w) BiF-ZDCPEs exhibited the most sensitive response to Cd and Pb in 0.10 M acetate buffer (pH 4.5). The detection limits of the modified electrode were 0.08 μg L−1 for Cd(II) and 0.10 μg L−1 for Pb(II) based on three times the standard deviation of the baseline with a preconcentration time of 120 s under optimal conditions, respectively. The modified electrode showed well linear response to both Cd(II) and Pb(II) over the concentration range from 1.0 to 20.0 μg L−1. The BiF-ZDCPEs were successfully applied to the determination of Cd(II) and Pb(II) in real samples, and the results were in agreement with those of atomic absorption spectroscopy (AAS). 相似文献
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