ZrN／TiN复合涂层刀具的制备及切削性能

采用中频磁控溅射和电弧离子镀2种方法组合，在YG6硬质合金基体上沉积ZrN／TiN复合涂层．研究了复合涂层刀具的制备工艺，并对复合涂层刀具的性能参数进行了测试．通过切削试验研究了ZrN／TiN涂层对硬质舍金刀具切削性能的影响，并与未涂层刀具的切削效果做了对比．结果表明：ZrN／TiN涂层提高了硬质合金刀具的硬度，降低了涂层刀具的切削力，提高了涂层刀具的耐磨损能力．     

氮铝钛表面涂层刀具技术在切削加工中的应用

采用氮铝钛(TiAlN)涂层硬质合金刀具对不锈钢、模具钢进行切削实验,并与未涂层硬质合金刀具的寿命作比较.研究了TiAlN涂层刀具与未涂层硬质合金刀具在不同的切削参数下的刀具磨损状况,利用扫描电子显微镜对磨损后的刀具表面形貌进行了分析.同时深入研究TiAlN涂层刀具的切削长度与刀具磨损量之间的定量关系.结果表明:TiAlN涂层刀具有优良的物理性能、力学性能和很高的耐磨性能,与未涂层刀具相比,大幅提高了刀具的耐用度,是切削不锈钢、模具钢等难加工材料的理想刀具材料.     

MoS2-Zr复合涂层刀具的切削性能研究

刀具表面涂覆MoS2固体润滑涂层能够降低刀具在切削过程中的摩擦力,改善切削工况,然而存在涂层硬度低、高温下性能衰减快等缺陷.文中采用中频磁控溅射和多弧离子镀相结合的工艺,在硬质合金基体表面制备了MoS2-Zr复合涂层,分析了涂层的力学性能和涂层刀具的切削性能.结果表明,在低速切削条件下,MoS2-Zr复合涂层刀具的切削性能显著提高.     

涂层刀具高速铣削高温合金GH2132磨损形态及磨损机理

用2种硬质合金涂层刀具进行铁基高温合金GH2132的高速干铣削试验,采用电子扫描显微镜(scanning electron microscopy,SEM)观察刀具的磨损形貌,对刀具的主要磨损机理进行了分析.结果表明:刀具的磨损形态主要是后刀面磨损;KC725M涂层由TiN、TiAlN组成,涂层易剥落;KC525M涂层只有1层TiAlN,涂层不易脱落,但由于机械冲击产生沟槽磨损,形成应力集中,导致在切削刃处产生较大的磨损;不论KC525M还是KC725M,涂层剥落后,切削区产生的瞬时高温均使基体中粘结相发生软化,造成硬质相颗粒脱落和基体的剧烈磨损.研究结果可用于指导高速切削刀具材料的设计、合理选用及刀具磨损控制.     

超重型切削过程硬质合金刀具高温力学特性

超重型切削过程中,刀具的高温失效是硬质合金刀具破损的主要形式之一。首先,通过理论分析、切削仿真及数学模型进行切削热产生过程分析,并研究切削温度对硬质合金刀具变形抗力的影响;然后,进行切削温度及材料高温硬度测量实验,实验结果验证模型有效,硬质合金和工件材料试块的硬度在1000℃时分别下降了28%和60%左右;最后,从刀具几何结构优化设计和复合涂层技术两方面提出超重型切削专用硬质合金刀具抗高温性能的提效措施,在5组切削参数下进行刀具寿命对比实验,优化设计的XF8刀具寿命是YT15刀具的2~5倍。研究结果可以为重型高效切削刀具技术的研究及推广提供借鉴。     

镍基粉末高温合金的铣削加工

为了研究镍基粉末高温合金的切削加工性,用整体硬质合金TiC涂层和未涂层立铣刀对镍基粉末高温合金FGH95进行铣削试验.通过研究铣削力、铣削温度与铣削用量之间的关系,分析硬质合金刀具的磨损、破损机理,观察其切屑形态,得出了镍基粉末高温合金FGH95的铣削力和铣削温度经验公式.试验表明：硬质合金涂层刀具加工镍基粉末高温合金FGH95的性能要明显优于未涂层刀具,未涂层刀具的崩刃现象严重,涂层刀具最佳铣削速度为40m/min,铣削速度对铣削温度的影响最大,并且随着铣削速度的提高形成了锯齿状切屑.     

CVD涂层硬质合金刀具的失效机理

通过系统的实验研究和理论分析,揭示了 CVD(化学气相沉积)涂层硬质合金刀具在磨损和破损状态下的不同的失效机理,并在机理分析的基础上,阐明了涂层硬质合金刀具对于切削条件的特殊适应性.     

TiN涂层刀具高速车铣切削性能及磨损机理

实验研究了高速车铣D60钢时TiN涂层刀具的切削性能和磨损机理.结果表明,在水溶性冷却液浇注冷却条件下,高频交变热应力较大,涂层剥落较快,TiN涂层刀具的耐磨性较差,不能适应切削加工的要求.与此相反,干式切削时,高频交变热应力较小,虽在涂层表面有微裂纹产生,但涂层不易剥落,刀具耐磨性较好,可进行长时间稳定切削.干式切削过程中,由于机械冲击,在刀刃处产生的微小凹缺陷,是造成刀具磨损的主要原因.不论湿式切削还是干式切削,涂层剥落后,切削区产生的瞬时热量聚集将使基体粘结相软化,进而导致硬质相颗粒脱落和基体的剧烈磨损.     

铣削508Ⅲ钢不同涂层对刀具切削性能影响

核电水室封头部件属于难加工零件,材料为508Ⅲ高强度钢。针对铣削加工过程中刀具切削性能差、寿命短与加工效率低等问题,首先对涂层硬质合金刀具进行切削仿真,从切削温度和应力方面,分析涂层对刀具切削性能影响;然后进行铣削508Ⅲ钢涂层刀具磨损实验,通过刀具磨损观测及前刀面形貌分析,探究涂层对刀具磨损与刀具寿命的影响;最后进行涂层性能对比实验,讨论不同类型涂层、涂层厚度和不同涂层热扩散率对硬质合金刀具铣削508Ⅲ钢切削过程影响。研究结果为铣削水室封头硬质合金刀具开发及核电零件高效加工等提供技术支持。     

AlCrSiN涂层刀具干车削Ti-6Al-4V钛合金的切削性能研究

使用未涂层的和AlCrSiN涂层的硬质合金车刀片以3种切削速度干式车削Ti-6Al-4V钛合金.研究发现AlCrSiN涂层刀片的切削寿命在各切削速度下都超过无涂层刀片,而切削力、切削温度和工件表面粗糙度3项指标均低于无涂层刀具,说明AlCrSiN涂层能够有效地保护基体从而维持刀具的锋利度.2种刀具在切削过程中均出现切削...     

PVD法制备TiN/AlTiN涂层的摩擦与磨损性能

采用物理气相沉积法在Cr12MoV钢基体上沉积TiN和AlTiN涂层,用扫描电镜、X射线衍射仪和划痕仪分析了涂层表面与界面形貌、物相和结合强度,并进行了摩擦与磨损试验。结果表明,TiN和AlTiN涂层具有较高硬度,AlTiN涂层表面粗糙度优于TiN涂层,TiN涂层表面轮廓算术平均偏差Ra为328.91nm,AlTiN表面轮廓算术平均偏差Ra为112.49nm;TiN涂层结合强度为28.85N,而AlTiN涂层结合强度为27.35N;AlTiN摩擦因数在磨合期和波动期略高于TiN涂层,在稳定期摩擦因数基本接近,维持在0.44-0.46左右;AlTiN涂层韧性比TiN涂层有一定的提高,其磨损性能优于TiN涂层。     

Effect of Al and Si additions on microstructure and mechanical properties of TiN coatings

Ti-X-N (X=Al, Si or Al+Si) coatings were grown onto cemented carbide substrates by cathodic arc evaporation. The hardness of the coatings was obtained by nanoindentation and the microstructure was investigated by XRD, XPS and SEM. Solid solution hardening results in a hardness increase from 24 GPa for TiN to 31.2 GPa for TiAlN. The higher hardness values of 36.7 GPa for TiSiN and 42.4 GPa for TiAlSiN are obtained by the incorporation of Si into TiN (TiAlN) coatings due to the formation of special three-dimensional net structure consisting of nanocrystalline (nc) TiN (TiAlN) encapsulated in an amorphous (a) Si₃N₄ matrix phase. Furthermore, the nc-TiAlN/a-Si₃N₄ coating shows the best machining performance.     

Impact fatigue behavior of ZrN/Zr-N/Zr coatings on H13 steel by CFUBMSIP

ZrN/Zr-N/Zr coatings were deposited on H13 steel by close field unbalanced magnetron sputtering ion plating （CFUBMSIP） technique. The effect of two main parameters such as OEM and bias voltage for the CFUBMSIP process on the microstructure, mechanical properties and impact fatigue behavior of the coatings was investigated. The results indicate that with OEM increasing from 55% to 65% the surface particles size of the coatings increases while it remains almost similar when the bias voltage changes from 60 to 75 V. An aggregation of the particles occurs on the coatings surface, with further increasing the OEM and bias voltage to 75% and 90 V, respectively. The coatings show a columnar grain structure and are mainly composed of two phases of ZrN and Zr. The coating hardness decreases with OEM value increasing and both the coating hardness and modulus go up with bias voltage. The coating deposited under OEM of 65% and bias voltage of 75 V shows the best impact fatigue property.     

Synthesis of nanoscale multilayered ZrN/W coatings by ion beam assisted deposition

ZrN/W multilayered coatings with different modulation periods at the nanoscale have been synthesized at different N+ beam bombarding energies using IBAD. Various characterization techniques such as XRD, AES, nano indenter and profiler were employed to investigate the influence of modulation period and bombarding energy on microstructure and mechanical properties of the coatings. The results showed that all superlattice coatings had better mechanical properties than the monolithic ZrN and W coatings. At an optimal condition with 300 eV N+ beam bombarding energy and 8―9 nm modulation period, XRD pattern possessed a sig- nificantly structural mixture of strong ZrN (111), W (110), as well as weak ZrN (220) textures in the multilayered coating. The optimal condition resulted in higher hardness (26 GPa), elastic modulus (310 GPa) and fracture resistance of the coat- ing than other conditions.     

TiN／CrN multilayered hard coatings with TiCrN interlayer deposited by a filtered cathodic vacuum arc technique

TiN/CrN multilayered hard coatings with TiCrN interlayer were deposited on high speed steel substrates by using a filtered cathodic vacuum arc technique. The structure and composition of the coatings were characterized by scanning electron microscopy (SEM) and Auger electron spectroscopy (AES). A high adhesion of up to 80 N was demonstrated by scratching tests for the multilayered coatings. Nanoindentation tests were performed to determine the hardness and elastic modulus of the coatings as a function of the multiplayer modulation period. It was observed that the hardness of the multilayered coatings is higher than those of either TiN or CrN single coatings, and it increases with decreasing modulation periods, which is consistent with predictions from the Hall-Petch type strengthening mechanism, though at small modulation periods, deviation from the Hall-Petch relation has been observed for the multilayered coatings. The life-span of drills coated with TiN/CrN multilayered is triple as long as that coated with TiN layer.     

Nanoindentation analysis of TiN,TiAlN,and TiAlSiN coatings prepared by cathode ion plating

The TiN,TiAlN and TiAlSiN coatings were deposited on H13 hot-worked mold steel by cathodic arc ion plating(CAIP).The morphologies,phase compositions,and nanoindentation parameters,such as creep hardness,elastic modulus and plastic deformation energy of the coatings were analyzed with field emission scanning electron microscopy(FESEM),X-ray diffraction(XRD) and nanoindentation testing,respectively,and the test results were compared with equation describing the indentation model.The results show that the TiN,TiAlN and TiAlSiN coating surfaces were dense and composed of TiN,TiN + TiAlN,TiN + Si3N4 + TiAlN phases,respectively.There was no spalling or cracking on the indentation surface.The creep hardness of the TiN,TiAlN and TiAlSiN coatings was 7.33,13.5,and 15.2 GPa,respectively;the corresponding hardness measured by nanoindentation was 7.09,15.6,and 21.7 GPa,respectively;and the corresponding elastic modulus was 201.93,172.79,and 162.77 GPa,respectively.The contact depth and elastic modulus calculated by the indentation model were close to those of the test results,but the remaining indentation parameters showed discrepancies.The sequence of plastic deformation energy was TiN TiAlNTiAlSiN.     

High temperature behaviors of high velocity arc sprayed Fe-Al/Cr3C2 composite coatings

Fe-Al/Cr3C2 composite coatings were manufactured using high velocity arc spraying （HVAS） technology. The high temperature erosion, wear and corrosion resistance of the coatings were investigated. The coating properties such as bonding strength, porosity, hardness as well as microstructures were characterized. The results show that the coatings have relatively high heat tremble bond strength, hardness, and typical layer-shaped coatings＇ microstructures. With the rise of temperature, the coating erosion resistance increases too; the impingement angel does effects on erosion properties, and the erosion mechanism changes from ductile to brittle behaviors at 450℃. The coatings have good room temperature wear resistance and relatively good high temperature resistance. The wear mechanism of the coatings is peeling wear behavior. The coatings have excellent high temperature corrosion resistance because of the produce of oxides during corrosion.     

多弧离子镀TiN涂层工艺及耐蚀性研究

为提高4Cr13马氏体不锈钢的耐蚀性,对其进行多弧离子镀处理,获得TiN涂层,并用X射线衍射仪、显微硬度计、扫描电子显微镜、电化学测量仪对涂层进行物相分析、表面形貌观察、硬度检测以及电化学腐蚀性能测试.结果表明:随着电流的增大,表面的液滴数目和尺寸增大,涂层厚度增加,薄膜硬度也增大;相结构主要为TiN,有明显的择优取向,且随着弧电流的增强,衍射峰强度略有增加.TiN试样在3.5％的NaCl溶液中耐蚀性与基体相当,在1 mol/L的H2SO4溶液中的耐蚀性比基体提高了800倍.     

沉积电压对辅助加热PCVD-TiN涂层的影响

研究了不同的沉积电压对辅助加热式PCVD-TiN涂层的影响。实验证明,提高沉积电压可以细化TiN涂层的柱状晶结构,增加TiN涂层的显微硬度和沉积速率。在试验范围内,涂层内残存的氯含量基本不受沉积电压的影响。