基于FDS程序的钠火事故情景模拟技术研究

钠火是钠冷快堆的典型事故,钠火事故情景计算机模拟仿真是对钠火事故风险评价的有力工具。本文以常规火灾三维计算流体力学软件FDS为平台,增加钠火燃烧模型,包括燃烧热模型、燃烧速率模型、喷射液钠粒径分布模型等,完成了钠火情景模型的开发,并通过与SPHINCS钠火试验和计算结果的温度分布与氧气含量对比,验证了模拟技术和模型开发方案的可行性。本文的研究成果能为后续钠火仿真模拟程序的开发提供研究基础和经验参考。     

池式钠火事故下燃烧产物气溶胶行为研究

在钠冷快堆的安全评估中,分析钠泄露导致的池式钠火事故下燃烧产物的气溶胶行为尤为重要。本文采用将池式钠火燃烧模型与气溶胶动力学模型耦合的方式,开发了池式钠火事故下燃烧产物气溶胶行为分析程序REBAC-SFR,基于该程序模拟了SAPFIRE-D1和ABCOVE池式钠火实验,并与实验数据进行了对比。结果表明,本文开发的程序具有良好的可靠性和正确性,可为钠工艺间内池式钠火事故下燃烧产物气溶胶行为分析研究提供理论工具。      

CONTAIN-LMR程序中池式钠火事故分析计算模型的验证

CONTAIN-LMR是针对以液态钠为冷却剂的反应堆而开发的安全壳事故一体化分析程序。我国目前的CONTAIN-LMR程序版本为2000年左右从法国引进,还未进行过面向工程设计的系统性地程序开发和验证。本文主要针对CONTAIN-LMR程序中模拟池式钠火事故的分析模型进行详细分析,并采用国际上的池式钠火实验进行验证,实验验证结果表明CONTAIN-LMR程序可以较准确地模拟池式钠火事故造成的钠工艺间内的温度、压力升高及放射性钠气溶胶行为。本文的研究结果初步表明CONTAIN-LMR程序可用于钠冷快堆的钠火事故分析。     

钠冷快堆钠池火事故数值模拟

为了估计和预测钠火事故的后果，构建了以“有火焰薄层”为理论基础的燃烧模型和热传输模型，给出了程序计算结果与试验值的比较。比较结果证实，该计算结果可信、模型合理。程序可用来分析和预测钠池火事故。     

基于FDS的钠火三维数值模拟研究

根据FDS火灾动力学分析软件的计算特点,结合钠火的燃烧模式,采用化学动力学建立了钠火燃烧的数值计算模型,将其与FDS软件相结合,使该软件具有模拟钠火燃烧的功能。使用两个钠火试验数据对程序计算得到的房间温度、压力、托盘内壁温度、氧气摩尔份额进行了验证。结果表明,房间温度、托盘内壁温度、氧气摩尔份额的计算结果与试验结果较为吻合,且计算结果也符合钠火实际燃烧的情况,但压力的计算结果与试验结果差异较大。     

Validation study of computer code sphincs for sodium fire safety evaluation of fast reactor

A computer code sphincs solves coupled phenomena of thermal hydraulics and sodium fire based on a multi-zone model. It deals with an arbitrary number of rooms, each of which is connected mutually by doorways and penetrations. With regard to the combustion phenomena, a flame sheet model and a liquid droplet combustion model are used for pool and spray fires, respectively, with the chemical equilibrium model based on the Gibbs free energy minimization method. The chemical reaction and mass and heat transfer are solved interactively. A specific feature of sphincs is detailed representation of thermalhydraulics of a sodium pool and a steel liner, which is placed on the floor to prevent sodium-concrete contact. The authors analyzed a series of pool combustion experiments, in which gas and liner temperatures are measured in detail. It has been found that good agreement is obtained and the sphincs code has been validated with regard to pool combustion phenomena. Further research needs are identified for pool spreading modeling considering thermal deformation of steel liner and measurement of pool fluidity property as a mixture of liquid sodium and reaction products. The sphincs code is to be used mainly in the safety evaluation of the consequence of a sodium fire accident in a liquid metal cooled fast reactor as well as fire safety analysis in general.     

乏燃料后处理厂有机相燃烧事故研究进展

核能的广泛利用伴随着乏燃料的产生和累积,乏燃料后处理技术将乏燃料再循环利用受到重要推崇,但乏燃料后处理设施的安全是发展后处理技术的重要前提,后处理中的有机相着火事故作为后处理的设计基准事故之一,得到了国内外的重要关注。为分析后处理厂在有机相着火事故中,有机相的燃烧行为、放射性气溶胶的扩散和沉积、高效过滤器的性能等,美国、日本等国分别建立了实验设施并进行了有机相燃烧的实验研究。本文综合评述了国内外关于后处理厂有机相着火事故的试验技术方法和研究结果,提出了当前研究存在的问题以及未来有待进一步研究的方向。     

钠冷快堆钠雾火事故三维数值模拟

针对钠冷快堆可能发生的钠雾火事故,开发和研制了一套用于钠火事故分析,能求解发生钠雾火事故后,事故空间3维的气体温度分布和化学成份分布的程序。本文详细介绍了分析求解钠雾火的燃烧模型和热传输模型,以及计算空间流场采用的计算方法和步骤,并将计算结果与试验值进行了比较：结果表明,二者符合较好。     

Experimental study on combustion characteristics of sodium fire in a columnar flow

In the operation of the sodium-cooled fast reactor, the accident caused by the leakage and combustion of liquid sodium is common and frequent in sodium-related facilities. This paper is based on an experimental study of sodium fire in a columnar flow, which was carried out to focus on the burning characteristics by analyzing the temperature fields in the burner. The injection of 200 °C liquid sodium with the flux of 0.5 m³/h was poured into a 7.9 m³ volume stainless steel cylindrical burner to shape a sodium fire, and the data of temperature fields in the burner have been collected by dozens of thermocouples which are laid in the combustion space and sodium collection plate. These results show that the sodium fire in a columnar flow is composed of the foregoing centered columnar fire, the subsequent spray fire caused by atomization and the pool fire on the collection plate. The temperature close to the burning sodium flow maximally reaches up to 950 °C. The radial temperatures apart from the sodium flow are relatively low and generally about 200 °C, and maximally just 300 °C even when close to the sodium collection plate. The maximum temperature of the burning sodium dropping on the collection plate rises in the center of plate, about 528 °C. This study is helpful to evaluate the combustion characteristics, formation process and composing forms of the sodium fire in the sodium-related facilities.     

钠滴氧化燃烧特性的实验研究

液态钠泄漏和燃烧是钠冷快堆在运行中一多发的常见事故。本文主要针对液态钠滴在不同初始温度(140~370℃)和氧浓度(4%~21%)条件下的氧化燃烧行为进行实验研究。实验通过1套钠滴燃烧装置和高速摄像机使钠滴的氧化燃烧行为可视化。实验结果表明:钠滴的初始温度和氧浓度越低,钠滴表面产生的柱状氧化物越长;在相同氧浓度条件下,钠滴初始温度越高,越易着火燃烧;钠滴初始温度在200℃以下时很难点燃,当有扰动破坏了表面的氧化层结构时,钠滴也会逐渐燃烧;钠滴初始温度在140~370℃的条件下,氧浓度≥12%时,钠滴能燃烧充分,最高温度基本可升至600~800℃;氧浓度12%时,燃烧并不充分,燃烧的最高温度均在600℃以下。这些结果对柱状流及雾状钠火的研究有重要的指导意义。     

钠冷快增殖堆钠雾火分析计算

在钠冷快增殖堆假想事故中 ,由于管道破裂 ,钠喷出到有氧的房间引起钠雾火 ,导致房间内温度及压力的上升。在NACOM单个液滴燃烧模型的基础上 ,考虑燃烧钠液滴的运动以及由于钠液滴与气体的热平衡关系 ,并忽略由于液滴间的相互作用影响 ,编制程序SPCOM。对钠雾火过程中涉及的液滴运动、液滴燃烧、喷雾燃烧以及质量热量传递问题进行了模拟。计算了钠雾火引起的房间的温度及压力瞬变 ,并与实验进行了比较 ,符合良好     

后处理厂1A柱有机相着火事故源项估算

我国对于后处理工业的需求随着核电事业的迅猛发展变得愈发强烈,为了满足后处理工业安全发展必不可少的核应急需求,为核应急工况下后处理厂的核应急响应与决策支持提供依据。针对后处理厂1A柱有机相着火事故这一基准事故,结合实际工艺流程及监测手段,选取了核应急工况下的可获得参数(有机溶剂泄漏质量等)作为输入,在有机相燃烧速率经验公式基础上,结合后处理的工艺特点,引入少量修正建立了后处理厂1A柱有机相着火事故源项估算模型,并使用FORTRAN编程语言开发了相应软件。数值验证结果表明,该估算模型可以满足后处理厂1A柱有机相着火事故的核应急需求。     

钠冷快堆混合钠火程序开发

钠管道泄漏继而发生钠的燃烧为钠冷快堆特有的事故。在喷雾钠火模型和池式钠火模型基础上,将钠喷雾燃烧和池式燃烧进行了耦合,并针对钠冷快堆钠工艺间的结构特点,最终开发了混合钠火计算程序COMSFIRE。使用该程序计算了FAUNA喷雾钠火试验和CADARACHE池式钠火试验,并与试验结果和部分程序计算结果进行了对比。同时设计了混合燃烧算例,并使用该程序与CONTAIN-LMR程序进行了对比。通过计算结果的对比和分析,初步验证了程序的正确性。     

Development of Sodium-cooled Fast Reactor Sodium Combined Fire Code

Sodium fire caused by sodium pipe leakage is the specific accident for sodium-cooled fast reactor. Based on the sodium spray fire model and sodium pool fire model, sodium spray fire and sodium pool fire were coupled together. A sodium combined fire code COMSFIRE was finally developed based on the structure characteristic of sodium technology room in sodium-cooled fast reactor. FAUNA sodium spray fire experiment and CADARACHE sodium pool fire experiment were calculated with the developed COMSFIRE code, the results of which were compared with the experiments results and some other code results. A combined fire case was designed, and the results were compared with CONTAIN-LMR code. The correctness of the COMSFIRE code was primarily proved through the comparison and analysis.     

Experimental study on combustion and suppression characteristics of sodium fire in a columnar flow using extinguishing powder

In the operation of the sodium-cooled fast reactor, the leakage and fire accident of liquid sodium is common and it is frequent in sodium-related facilities. This study focuses on the combustion and suppression characteristics of sodium fire in a columnar flow. Liquid sodium (250 °C) is injected into a 7.9 m³ cylindrical chamber at a flow rate of about 1.0 m³/h to create a columnar sodium fire, and 18.4 kg class D extinguishing powder is sprayed after the liquid sodium injection. The temperature in the chamber space and sodium collection plate and the heat release rate from sodium fire are measured and analyzed. Based on the temperature data the sodium fire under suppression could be divided into four phases of dropping sharply, continuously remaining lower, rising and declining mildly, and depressing. The sodium fire in the space could be suppressed and cooled down if the extinguishing agent could spray in the early period of the liquid sodium injection. The extinguishing agent could suppress the combustion and spreading of liquid sodium dropping on the collection plate, limit the pool combustion area and postpone the commencement of sodium pool burning in spite of its later re-ignition happening. This study promises to evaluate the combustion and suppression characteristics of sodium fire in the sodium-related facilities.     

雾状钠火钠滴燃烧比率的模拟及应用

将雾状钠火中钠滴的燃烧分成预燃阶段和燃烧阶段,利用雾状钠火程序计算得到钠滴燃烧比率和时间的关系曲线,分别用幂函数、指数函数和线性函数对曲线进行拟合,拟合效果较好。拟合函数中包含钠滴下落时间和钠滴最大燃烧比率等参数,这些参数可通过钠滴下落燃烧试验或雾状钠火程序计算得到。通过推导得到了雾状钠火燃烧和单个钠滴燃烧的关系,钠滴燃烧比率的拟合函数被用来模拟雾状钠火燃烧的过程,包括用于计算已燃烧的钠质量、空气中未燃烧的钠质量、进入钠池的钠质量和雾状钠火的燃烧速率。当雾状钠火燃烧过程中钠泄漏流量恒定不变时,空气中未燃烧的钠质量和钠泄漏流量呈正比,雾状钠火的燃烧速率和钠泄漏流量呈正比。雾状钠火的燃烧速率和钠火造成的事故工艺间内的温度与压力变化直接相关。雾状钠火的燃烧速率被用来求解钠气溶胶的生成速率、钠燃烧火焰层和空气之间的传热、钠燃烧火焰层和墙壁之间的传热。总之,使用简单的函数模拟钠滴的燃烧比率曲线,将雾状钠火燃烧当成事故工艺间的热源和钠气溶胶源作为输入,便可模拟雾状钠火的整个燃烧过程,计算得到工艺间温度、压力和钠气溶胶浓度的变化。钠滴的燃烧比率曲线、雾状钠火的燃烧速率曲线还可与试验数据进行对比验证后作为雾状钠火模拟的输入,这种模拟方法可用于钠火事故安全分析中雾状钠火的模拟。     

Numerical prediction of fire extinguishment characteristics of sodium leak collection tray in a fast breeder reactor

Sodium leak collection tray (LCT) is an efficient passive device used for the extinguishment of liquid sodium fire in case of an accidental leakage from the secondary circuit of a fast breeder reactor. The LCT essentially isolates the leaking sodium into closed containers where the resulting fire is extinguished due to limited availability of oxygen. The current work aims to highlight the combustion extinguishment characteristics of LCT through a lumped formulation by conserving the mass and energy of liquid sodium and constituent gases in various parts of the LCT. Here, the complex hydrodynamics of liquid sodium is emulated through a semi-analytical draining/sloshing model and its burning rates are predicted through a three-dimensional open pool combustion model for the tray region and a closed pool combustion model for the holdup vessel. These simulations evaluate the burning rates at discrete levels of liquid sodium which are subsequently interpolated to establish correlations involving instantaneous liquid levels and oxygen concentration. Using the correlations obtained from the draining and combustion models, the overall lumped formulation directly predicts the un-burnt sodium recoverable after the extinguishment of fire in the LCT. The predicted results of this model compare well with the available experimental data.     

Experimental study on characteristics of sodium fire in a columnar flow with discontinuous injections

In the operation of the sodium-cooled fast reactor, the accident caused by the leakage and combustion of liquid sodium is common and frequent in sodium-related facilities. In this paper, an experiment Harbin Engineering University-Sodium Columnar Fire 4 (HEU-SCF4) is carried out to focus on the combustion characteristics in a discontinuous columnar flow. Liquid sodium (250°C) with the flux of about 1.0 m³/h was injected into a 7.9 m³ stainless steel cylindrical test chamber twice to shape the sodium fire in a columnar flow with discontinuous injections. The temperature, pressure data, and heat release rate in the test chamber were acquired and analyzed. It is found that each injection would cause a peak of space temperature, and it takes much shorter time to reach temperature peak in the second injection than the first injection. The peaks of pressure and heat release rate caused by the second injection are much higher than those caused by the first injection. This study is promising to evaluate the combustion characteristics of sodium fire in a columnar flow with different injection forms in the sodium-related facilities.     

A study on sodium spray combustion

Sodium spray combustion was studied through experiments and analysis, in order to clarify the burning rate, pressure and temperature transients in a sodium spray fire. In the experiments, about 400 g sodium was sprayed in a closed vessel of 2 m³, containing nitrogen and 0–21 vol% oxygen. Pressure, temperature and oxygen concentration were measured during and after sodium injection. The experimental results revealed that the temperature in the spray outer region was higher than that of inner region and observed oxygen consumption was not more than 80% of that expected for complete combustion of sodium. To analyze the experiments, a computer program SOFIA-II was developed based on an analytical single droplet combustion model and a two-dimensional temperature and oxygen concentration distribution model in the vessel. The calculated pressure agreed with the experimental pressure on the whole and the peak pressure difference was within 10% error.     

Experimental study on sodium droplet combustion and spatial temperature distribution characteristics

In the operation of the sodium-cooled fast reactor, the accident caused by the leakage and combustion of liquid sodium is common and frequent. In this paper, the combustion and spatial temperature distribution characteristics at the different distances from the center of droplet and the different angles (0–30°) were studied by carrying out the experiments of the oxidation and combustion under initial temperatures (200–350°C) of sodium droplet, oxygen concentrations (12–21%) and ambient atmosphere temperatures (80°C and 180°C). The experiment results show that the ambient atmosphere temperature cannot change the three stages (surface oxidation, preignition, and combustion) of sodium droplet combustion but it will change the characteristics of every stage. When the temperature of sodium droplet excesses the characteristic temperature (600°C), the temperatures of all spatial measuring points begin to rise noticeably. The peak temperature of the sodium droplet that completely burned could roughly reach 580–1000°C. The distributions of the spatial maximum temperature in three angle directions are in conformity with exponential function as the distance increases. The study provides the technical support on the evaluation and analysis of various forms of sodium fire accidents.