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水体中存在的微量有机污染物对人类及生物的正常生命活动构成了严重威胁,有效去除这些污染物已成为当务之急。电催化氧化技术因具有适应性广,氧化性强,无二次污染,反应迅速,设备及其操作简单等优点而日益成为有机废水处理领域的研究热点。阳极材料是电化学氧化法处理有机废水的关键。文章综述了贵金属电极、碳素电极、钛基金属氧化物电极和合成掺硼金刚石薄层电极等常用阳极材料的性能,并对有机废水电催化氧化阳极材料的发展趋向进行了展望。 相似文献
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低碳烯烃和烷烃的分离是化工领域的难题,膜的气体分离工艺技术是减少对环境的影响和降低运营成本的一种理想方法。传统聚合膜通常受到渗透率和选择性权衡的限制。共价有机骨架(COFs)含有丰富且规则的孔道结构的优点从而可实现超快透过且高度选择性的性能。然而,COFs的孔道大小通常大于低碳烷烃的分子动力学直径,3D共价有机骨架(COFs)中的孔道虽然通过设计互穿结构可以将孔道缩小到5埃到7埃之间,可以实现低碳烷烃的筛分作用,但3D COFs膜的传输阻力要远大于层状原子厚片形式的2D COFs膜。本文对共价有机骨架(COFs)膜及其在气体分离方面的应用进行了介绍分析,为国内利用膜分离气体提供参考。 相似文献
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光催化氧化技术凭借其稳定高效且成本低等优势,已成为当前研究领域广泛采用的有效降解水环境中污染物的的门技术之一。相关研究报道称苝二酰亚胺(PDI)超分子光催化剂能够独立完成从光吸收、载体分离到催化反应的整个光催化过程。人们已经通过其使用作为一种优良的半导体光催化剂致力于改善可见光的光催化活性。然而,光生电子和空穴的转移速度慢和催化活性低,稳定性差限制了苝二酰亚胺的光催化效率。详细阐述了近几年苝二酰亚胺材料合成及光学性质、总结了PDI及其衍生材料在光催化领域的最新应用研究进展,并总结了苝二酰亚胺光催化材料的应用现状。将有助于开发新的策略,以进一步改善苝二酰亚胺材料的光催化效率,以便能实际大规模工程化应用的方向发展。 相似文献
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通过共聚共混法研制了用于制作和安装实验应力分析和传感器用耐高低温和塑性应变计的新型亚胺型基底胶和胶粘剂,同时介绍了获得优良性能材料的影响因素、工艺条件和基本特性以及初步应用结果。 相似文献
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共价有机骨架聚合物(COFs)是由共价键连接,经热力学可逆聚合形成的有序多孔有机晶态材料,具有比表面积大、孔分布规则可调和可拆剪等特性,其二维或三维COFs功能膜在气体分离、化学传感、催化、药物传输等方面具有广阔的发展前景。COFs膜材料的制备决定膜组成、微规整结构和性能,成为COFs膜功能应用的研究基础和技术关键。本文综述了COFs材料提出以来形成的共混法、原位聚合法、层层堆叠法和界面聚合等制备方法的研究现状,结合各方法优缺点,分析并提出COFs膜制备技术的关键方向和技术要点。为COFs功能膜分子设计、优化和功能化应用提供合理的制备方法,促进高性能COFs功能膜实用化制备方法的形成。 相似文献
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The reduction of oxygen in alkaline solution has been studied on highly oriented pyrolytic graphite (HOPG) electrodes modified with various quinones using a rotating disk electrode (RDE). The electrode surface was modified by adsorption of quinones from a 0.1 M KOH solution. The oxygen reduction activity of these electrodes was considerably higher than that for unmodified HOPG and characteristic current maxima for oxygen reduction was observed. All quinones studied catalysed the two-electron reduction of oxygen to hydrogen peroxide. The peak potentials for oxygen reduction were in good correlation with the redox potentials of the quinones that were found from the cyclic voltammograms in oxygen-free solutions. The results obtained give further evidence that oxygen reduction is catalysed by the semiquinone radical and that the redox potential of the quinone is the most important factor determining its electrocatalytic activity for oxygen reduction. 相似文献
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A nanocomposite based on layered double hydroxides (LDHs) and gold nanoparticles (AuNPs) was prepared via hydrothermal treatment followed by a reduction procedure. The AuNPs were obtained in Mg-Al LDHs, and they maintained good stability. The electrocatalytic activities of AuNPs/LDH-modified glassy carbon electrodes for methanol oxidation in alkaline medium were investigated in detail. Under the same conditions, the modified electrode exhibited higher electrocatalytic activity than both the pure AuNPs-modified electrode and LDH-modified electrode. The role of the AuNPs and LDHs in this composite system was explored by cyclic voltammetry and chronoamperometry, respectively. Further studies demonstrated that the promoting effect of LDHs could be due to its strong adsorption and partly to the discharge of OH− during methanol oxidation. This work indicates that LDHs is expected to be a good supporting material in the development of methanol anode catalysts. 相似文献
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稀土上转换发光材料是近年来发光材料领域研究的热点,结合稀土上转换发光材料的基质类型及特点,介绍了上转换过程的主要形式。通过对稀土离子上转换发光机理的分析,列举稀土上转换发光材料的主要应用领域,并针对如何提高上转换发光效率提出具体建议,为稀土上转换发光材料的研究提供理论参考。 相似文献
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This study concerns the efficient electrochemical reduction of molecular oxygen (O2), in O2-saturated 0.1 M KOH solution, to OH− through a four-electron reduction pathway by a novel binary catalyst that is comprised of two kinds of catalysts, i.e., Au nanoparticles (nano-Au) and manganese oxide nanoparticles (nano-MnOx) electrodeposited onto a relatively inert substrate, e.g., glassy carbon (GC) electrode. The nano-Au catalyst is efficiently used for the electro-reduction of O2 to hydrogen peroxide through a two-electron reduction pathway at a reasonably low overpotential. While the latter (i.e., nano-MnOx) is effectively used for the subsequent catalytic decomposition of the electrogenerated hydrogen peroxide to water and molecular oxygen. The dependence of the electrocatalytic activity of the proposed binary catalysts towards the oxygen reduction on the loading level of both species has been investigated in this paper. This is done aiming at the preparation of a binary catalyst composed of the optimum amounts of both species which supports an apparent four-electron reduction of O2 at sufficiently low overpotential in replacement of the costly Pt-based electrocatalysts. 相似文献
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Two different Ti/Pt–Ir materials (commercial and home made) and Ti/PdO + Co3O4 were investigated for their electrocatalytic properties versus Cl2 evolution reaction. The materials were used in a batch electrochemical reactor to treat biologically recalcitrant di-azo compound. An electrochemically driven oxidation, mediated by a Cl2/Cl− couple, proved efficient for destruction of this complex organic molecule, causing cleavage of the conjugated double bonds and destruction of unsatured bonds. Both Ti/Pt–Ir materials performed well; lower kinetics obtained with the Ti/PdO + Co3O4 anode was caused by adsorption of the model compound, evidenced in preliminary voltammetric measurements. The dye oxidation reaction followed the second order kinetics with partial orders in the model compound and (time varying) chlorine concentrations equal to one. Specific energy consumption of 3.12 kWh m−3 proved the process more economic than the homogeneous phase oxidation. 相似文献