共查询到20条相似文献,搜索用时 265 毫秒
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α-硅钼黄吸光光度法测定陶瓷粉笔中高含量硅 总被引:3,自引:0,他引:3
基于α型硅钼黄比β型硅钼黄更稳定,且灵敏度更低,有利于高含量硅的比色测定的特点,建立了α-硅钼黄吸光光度法测定陶瓷粉笔中高含量硅的分析方法。试验结果表明:α型硅钼黄比β型硅钼黄吸光光度法稳定性和准确性都有较大提高,可用于陶瓷粉笔中高含量硅的日常快速测定。 相似文献
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非离子表面活性剂存在下结晶紫-硅钼杂多酸退色机理的研究 总被引:1,自引:0,他引:1
研究了非离子表面活性剂对结晶紫-硅钼杂多酸显色反应的影响。研究结果表明,非离子表面活性剂醚氧原子的质子化作用导致生成(钅羊)离子,与硅钼杂多酸缔合,形成一种离子缔合物。所以,非离子表面活性剂存在下,结晶紫-硅钼杂多酸的退色现象,可归结于竞争反应。退色速度随氢离子浓度的增加而加快。 相似文献
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对硅钼蓝分光光度法测定磷矿石中的二氧化硅进行了研究。研究了硅钼黄的显色条件及干扰因素,在本方法试验控制H2SO4浓度范围内硅与钼酸钠生成硅钼黄,经FeSO4还原成硅钼蓝,SiO2含量在0~600μg/100ml范围内服从比耳定律。操作简便,重现性好,结果准确,测定磷矿石中的二氧化硅含量,结果满意。 相似文献
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还原硅钼酸盐分光光度法测定偏钒酸铵中硅的含量 总被引:1,自引:0,他引:1
李静 《化学工业与工程技术》2002,23(5):47-49
介绍了还原硅钼酸盐分光光度法测定偏钒酸铵中的硅含量 ,讨论了吸收波长、还原剂、酸度及掩蔽剂加入量等因素对测定结果的影响。结果表明 ,还原硅钼酸盐分光光度法测定偏钒酸铵中的硅含量 ,数据准确 相似文献
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三种理气类中药挥发性成分的GC-MS分析 总被引:2,自引:0,他引:2
研究了三种(厚朴、檀香、木香)理气类中药挥发油的化学成分。用水蒸气蒸馏提取三种药材的挥发油,用GC-MS分离检测其化学成分,并结合气相色谱程序升温指数辅助定性确定出挥发油中的化学组分。鉴定出木香挥发油中29个成分(占挥发油总量的92.00%);厚朴挥发油中26个成分(占挥发油总量的91.88%);檀香挥发油中10个成分(占挥发油总量的94.51%),三中药物挥发油的主要成分大不相同。计算了各种化合物的保留指数,使用保留指数辅助定性鉴定出的化合物所占挥发油百分含量明显多于文献中所报道的数据。 相似文献
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M. A. Bedair S. A. Soliman M. A. Hegazy I. B. Obot A. S. Ahmed 《Journal of Adhesion Science and Technology》2019,33(11):1139-1168
Synthesis, adsorption and corrosion inhibiting effect of three new Schiff base compounds on mild steel in 1.0?M HCl were explored using weight loss, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization techniques. The empirical results showed that three Schiff base compounds inhibited the corrosion reaction in aggressive acid medium. Impedance results indicate that the three organic compounds were adsorbed on the mild steel/solution interface, while polarization data show that the three compounds performed typically as a mixed-type inhibitor. A theoretical study of the adsorption performance of some of the components of Schiff base inhibitors was carried out in the basis of the density functional theory (DFT) and Monte Carlo simulations. 相似文献
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合成了3种2-芳氧基-1,8-邻苯二甲酰基萘类光致变色化合物,通过核磁共振谱、红外光谱、质谱和元素分析确定了结构.对产物进行了荧光光谱测定,3种光致变色化合物的荧光强度和Stoke位移都较大.用紫外-可见分光光度计对其在丙酮溶液中的光致变色行为进行了测定,3种光致变色化合物在300—600 nm范围内都具有一定的光致变色性能和较大的吸光系数. 相似文献
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《Inorganic chemistry communications》2001,4(1):36-40
The synthesis and spectroscopic characterization of three novel phosphorus(V) compounds, chiral at phosphorus, are reported. All three compounds were characterized by X-ray crystallography, and for one compound a 1H–31P HETCOR experiment was performed. 相似文献
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Amine compounds, bi-functional compounds (EDTA, ethylene diamine tetra acetic acid type), and Salen compounds were investigated for catalytic hydration of ethylene oxide (EO) to monoethylene glycol (MEG). Many of the catalysts studied are selective for the formation of MEG compared with thermal hydration without any catalyst present. The results of the catalytic hydration with three types of catalysts were rationalized using acid and base catalyzed reaction mechanisms. 相似文献
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An organ culture assay system using cockroach leg regenerates and fat body has been developed in which compounds that either
inhibit molting hormone metabolism or act as molting hormone antagonists can be tested. Representatives of three classes of
compounds were tested in the system: ecdysteroids, azasteroids, and nonsteroidal amines and amides. Inhibitory compounds were
found in all three of the classes. Certain of these inhibitors represent a new class of insect hormonal compounds with a novel
mode of action—the disruption of molting hormone metabolism. 相似文献
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HPLC separation and wavelength area ratios of more than 50 phenolic acids and flavonoids 总被引:1,自引:0,他引:1
W. L. Banwart P. M. Porter T. C. Granato J. J. Hassett 《Journal of chemical ecology》1985,11(3):383-395
Relative retention times and wavelength area ratios for over 50 standard compounds were calculated using reverse-phase HPLC. The standard compounds analyzed included benzoic acids, cinnamic acids, benzene carboxylic acids, acetic acids, coumarins, benzaldehydes and a variety of flavonoid compounds including flavanones, flavones, isoflavones, and their glycosides. Each standard compound was chromatographed by three different gradient elutions. Compounds were detected by UV absorption at 254 nm and 280 nm. Relative retention times with respect to two different internal references and the 254nm: 280nm wavelength area ratio was determined for each standard. Soybean root and seed extracts were analyzed for the presence of the standard compounds using the chromatographic conditions described. 相似文献